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At least 91 records · Page 5

Catastrophic fragmentation of asteroids: Evidence from meteorites

Meteorites are impact-derived fragments from approximately 85 parent bodies. For seven of these bodies, the meteorites record evidence suggesting that they may have been catastrophically fragmented. We identify three types of catastrophic events: (1) impact and reassemble events greater than 4.4 Gy ago, involving molten or very hot parent bodies (greater than 1200 C); this affected the parent bodies of the ureilites, Shallowater, and the mesosiderites. In each case, the fragments cooled rapidly (approximately 1-1000 C/day) and then reassembled. (2) Later impacts involving cold bodies which, in some cases, reassembled; this occurred on the H and L ordinary chondrite parent bodies. The L parent body probably suffered another catastrophic event about 500 My ago. (3) Recent impacts of cold, multi-kilometer-sized bodies that generated meter-sized meteoroids; this occurred on the parent bodies of the IIIAB irons (650 My ago), the IVA irons (400 My ago), and the H ordinary chondrite (7 My ago).

Keil, K.↗

First-principles calculations of structural, electrical, and optical properties of ultra-wide bandgap (Al$_x$Ga$_{1-x}$)$_2$O$_3$ alloys

Alloys between Ga 2 O 3 and Al 2 O 3 (AGO) present a rich material space exhibiting numerous structural phases with unique optoelectronic properties that make them attractive candidates as ultra-wide bandgap (UWBG) semiconductors for next-generation power devices. Here we review the properties of AGO, focusing on theoretical results on the thermodynamics of Al incorporation and its consequences on the electronic structure. We review predictions and progress in experimentally realizing these alloys, as well as how composition influences important optoelectronic variables such as the band gap, band offsets, transport properties, and n-type dopability. A number of these parameters, such as the breakdown field (related to the band gap) and electron mobility, are discussed in assessing AGO in terms of relevant power device figures of merit. Altogether, the rapid progress and predicted properties highlight the promise of AGO as a model UWBG semiconductor platform with the potential to revolutionize power devices.

36 MATERIALS SCIENCE↗

The development and diversification of Precambrian life

The temporal relationships among various prominent events occurring in the evolution of life are considered. It is seen that the Precambrian encompasses an enormous segment of geologic time and includes more than 80% of the history of life on this planet. As a result of the studies of the past decade it appears that living systems were probably extant as early as 3300 m.y. ago. Photoautotrophs, apparently including blue-green algae, originated earlier than 3000 m.y. ago. Blue-green algae were the dominant components of earth's biota for the period extending from about 3000 to 1000 m.y. ago. The nucleated, eukaryotic cell type had become established at least as early as 900, and possibly prior to 1300 m.y. ago.

Schopf, J. W.↗

Lunar Rb-Sr chronology

It has been established with the aid of Rb-Sr studies that lunar chronology consists of five episodes, including the formation of the moon approximately 4.6 AE ago (1 AE = 1000 million years), a period of intense bombardment by planetary debris resulting in the formation of the major lunar basins, the end of this period at 3.9-4.0 AE ago, a period of mare flooding extending from 3.9 to 3.2 AE ago, and a relatively quiescent period from 3.2 AE ago to the present. In addition, Rb-Sr-studies have provided valuable constraints on the geochemical evolution of the moon through the determination of the initial Sr-87/Sr-86 ratios which limit the Rb/Sr ratios of the source materials for lunar rocks. Attention is given to the characteristics of the Rb-Sr method, the analytical techniques, the ages of lunar mare basalts, the non-mare rocks, the studies conducted in connection with the various Apollo missions, the lunar cataclysm, lunar soils, and aspects of crustal contamination.

Nyquist, L. E.↗

The regolith history of 14307

Noble gas and trace element analyses of matrix and a clast from breccia 14307 are reported. This sample was exposed to a large neutron fluence, as seen by an elevated Sm-150/Sm-149 ratio and by noble gases, particularly Xe-136 from neutron fission of U-235. Strong constraints on the exposure history result from combined consideration of Sm-150, Xe-136, and spallation noble gases. Both clast and matrix were irradiated for about 1 AE under substantial shielding beginning at least 2 AE ago, probably more than 3 AE ago. The manifestations of soil exposure seen in the matrix - solar wind gases, glass formation, etc. - thus must have been acquired in an ancient epoch. The matrix has had a longer exposure to cosmic rays than the clast, presumably during its prebrecciation history as a soil. Brecciation probably occurred more than 1 AE ago, perhaps more than 3 AE ago, but at least 0.4 AE after the formation of the matrix constituents.

Bernatowicz, T.↗

Characterization and depositional and evolutionary history of the Apollo 17 deep drill core

With a depth resolution of about 0.5 cm, the stratigraphy of the approximately 3 m Apollo 17 deep drill core by measurement of the total FeO concentration is characterized along with the FMR surface exposure (maturity) index Is/FeO, the metallic iron concentration Fe-vsm, and the FMR linewidth delta-H. For stratigraphic characterization, the first two parameters are the most important. Most of the core is characterized by a FeO concentration of approximately 15.5 wt. %; there is a more mafic zone in the upper approximately 75 cm where the maximum FeO concentration is approximately 18.5 wt. %, and a more felsic zone between approximately 225 and 260 cm where the minimum FeO concentration is approximately 14.0%. As indicated by Is/FeO, most of the soil in the core is submature to mature; the only immature zone is located between approximately 20 and 60 cm and is one of the most distinctive features in the core. A two stage model for the depositional and evolutionary history of the Apollo 17 deep drill core is proposed: (1) deposition by one event approximately 110 m.y. ago or deposition by a sequence of closely spaced events initating a maximum of approximately 200 m.y. ago and terminating approximately 110 m.y. ago, (2) in situ reworking (gardening) to a depth of approximately 26 cm in the period between approximately 110 m.y. ago and the present day.

Morris, R. V.↗

Computer studies of baroclinic flow

Programs necessary for computing the transition curve on the regime diagram for the atmospheric general circulation experiment (AGOE) were completed and used to determine the regime diagram for the rotating annulus and some axisymmetric flows for one possible AGOE configuration. The effect of geometrical constraints on the size of eddies developing from a basic state is being examined. In AGOE, the geometric constraint should be the width of the shear zone or the baroclinic zone. Linear and nonlinear models are to be used to examine both barotropic and baroclinic flows. The results should help explain the scale selection mechanism of baroclinic eddies in the atmosphere experimental models such as AGOE, and the multiple vortex phenomenon in tornadoes.

Gall, R.↗

Evolutionary history of the mesosiderite asteroid - A chronologic and petrologic synthesis

The evolutionary history of the mesosiderite parent body is composed of six principal epochs. (1) Accretion occurred about 4.56 Ga ago, and (2) initial melting occurred less than about 26 Ma after accretion. (3) Significant crustal remelting occurred more than 4.47 Ga ago, possibly during metal-silicate mixing caused by the accretion of a large metallic Fe-Ni core fragment with some overlying mantle to the MPB regolith. (4) Localized impact melting 4.5-3.9 Ga ago produced quench-textured clasts and caused mesosiderite metamorphism and the extensive melting of type-4 mesosiderites. (5) Collisional disruption and gravitational reassembly occurred about 3.9 Ga ago, causing extensive degassing of Ar and resetting the metallographic cooling rates to about 1 C/Ma. (6) Impact excavitation and ejection of deeply buried breccias occurred much less than 3.9 Ga.

Rubin, Alan E.↗

The PMIP4 Contribution to CMIP6 - Part 1: Overview and Over-Arching Analysis Plan

This paper is the first of a series of four GMD (Geoscientific Model Development) papers on the PMIP4-CMIP6 (Paleoclimate Modelling Intercomparison Project - Phase 4 -- Coupled Model Intercomparison Project - Phase 6) experiments. Part 2 (Otto-Bliesner et al., 2017) gives details about the two PMIP4-CMIP6 interglacial experiments, Part 3 (Jungclaus et al., 2017) about the last millennium experiment, and Part 4 (Kageyama et al., 2017) about the Last Glacial Maximum experiment. The mid-Pliocene Warm Period experiment is part of the Pliocene Model Intercomparison Project (PlioMIP) - Phase 2, detailed in Haywood et al. (2016). The goal of the Paleoclimate Modelling Intercomparison Project (PMIP) is to understand the response of the climate system to different climate forcings for documented climatic states very different from the present and historical climates. Through comparison with observations of the environmental impact of these climate changes, or with climate reconstructions based on physical, chemical, or biological records, PMIP also addresses the issue of how well state-of-the-art numerical models simulate climate change. Climate models are usually developed using the present and historical climates as references, but climate projections show that future climates will lie well outside these conditions. Palaeoclimates very different from these reference states therefore provide stringent tests for state-of-the-art models and a way to assess whether their sensitivity to forcings is compatible with palaeoclimatic evidence. Simulations of five different periods have been designed to address the objectives of the sixth phase of the Coupled Model Intercomparison Project (CMIP6): the millennium prior to the industrial epoch (CMIP6 name: past1000); the mid-Holocene, 6000 years ago (midHolocene); the Last Glacial Maximum, 21,000 years ago (lgm); the Last Interglacial, 127,000 years ago (lig127k); and the mid-Pliocene Warm Period, 3.2 million years ago (midPliocene-eoi400). These climatic periods are well documented by palaeoclimatic and palaeoenvironmental records, with climate and environmental changes relevant for the study and projection of future climate changes. This paper describes the motivation for the choice of these periods and the design of the numerical experiments and database requests, with a focus on their novel features compared to the experiments performed in previous phases of PMIP and CMIP. It also outlines the analysis plan that takes advantage of the comparisons of the results across periods and across CMIP6 in collaboration with other MIPs.

climate↗

Mechanisms of Ethylene Epoxidation over Silver from Machine Learning-Accelerated First-Principles Modeling and Microkinetic Simulations

In this work we employed machine learning-augmented density functional theory (DFT) thermodynamic calculations to assess the stability of different AgO x structures under catalytic ethylene epoxidation reaction conditions. We found that there are multiple AgO x surface motifs that could co-exist under the relevant conditions. These included Ag surface oxides (e.g., AgO_p(4 × 4) and Ag 1.83 O) and atomic oxygen-covered Ag(111) surfaces. Furthermore, we employed DFT calculations to evaluate the energetics of different reaction mechanisms by which ethylene and oxygen can react on these surfaces. These studies revealed several energetically viable reaction pathways for ethylene epoxidation. Microkinetic modeling analyses, based on the DFT-calculated reaction pathways, showed that ethylene epoxidation can proceed on all surfaces and that multiple pathways, including those involving Langmuir–Hinshelwood and Eley–Rideal mechanisms, could be involved in selective and unselective reactions. The diversity of mechanisms that we discovered in the context of the relatively simple ethylene epoxidation reaction on Ag suggests that the richness and complexity of surface chemistry are most likely a rule rather than an exception in heterogeneous catalytic chemical transformations on metal surfaces and that the concept of a single or even a dominant mechanism and reaction intermediates might need to be revisited for many reactions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Cell specific photoswitchable agonist for reversible control of endogenous dopamine receptors

Dopamine controls diverse behaviors and their dysregulation contributes to many disorders. Our ability to understand and manipulate the function of dopamine is limited by the heterogenous nature of dopaminergic projections, the diversity of neurons that are regulated by dopamine, the varying distribution of the five dopamine receptors (DARs), and the complex dynamics of dopamine release. In order to improve our ability to specifically modulate distinct DARs, here we develop a photo-pharmacological strategy using a Membrane anchored Photoswitchable orthogonal remotely tethered agonist for the Dopamine receptor (MP-D). Our design selectively targets D1R/D5R receptor subtypes, most potently D1R (MP-D1 ago ), as shown in HEK293T cells. In vivo, we targeted dorsal striatal medium spiny neurons where the photo-activation of MP-D1 ago increased movement initiation, although further work is required to assess the effects of MP-D1 ago on neuronal function. Our method combines ligand and cell type-specificity with temporally precise and reversible activation of D1R to control specific aspects of movement. Our results provide a template for analyzing dopamine receptors.

59 BASIC BIOLOGICAL SCIENCES↗

A 2-million-year-old ecosystem in Greenland uncovered by environmental DNA

Late Pliocene and Early Pleistocene epochs 3.6 to 0.8 million years ago had climates resembling those forecasted under future warming. Palaeoclimatic records show strong polar amplification with mean annual temperatures of 11–19 °C above contemporary values. The biological communities inhabiting the Arctic during this time remain poorly known because fossils are rare. Here we report an ancient environmental DNA (eDNA) record describing the rich plant and animal assemblages of the Kap København Formation in North Greenland, dated to around two million years ago. The record shows an open boreal forest ecosystem with mixed vegetation of poplar, birch and thuja trees, as well as a variety of Arctic and boreal shrubs and herbs, many of which had not previously been detected at the site from macrofossil and pollen records. The DNA record confirms the presence of hare and mitochondrial DNA from animals including mastodons, reindeer, rodents and geese, all ancestral to their present-day and late Pleistocene relatives. The presence of marine species including horseshoe crab and green algae support a warmer climate than today. The reconstructed ecosystem has no modern analogue. The survival of such ancient eDNA probably relates to its binding to mineral surfaces. Our findings open new areas of genetic research, demonstrating that it is possible to track the ecology and evolution of biological communities from two million years ago using ancient eDNA.

58 GEOSCIENCES↗

Photoluminescence spectroscopy of Cr 3+ in β-Ga 2 O 3 and (Al 0.1 Ga 0.9 ) 2 O 3

Alloying β-Ga 2 O 3 with Al 2 O 3 to create (Al x Ga 1–x ) 2 O 3 enables ultra-wide bandgap materials suitable for applications deep into ultraviolet. In this work, photoluminescence (PL) spectra of Cr 3+ were investigated in monoclinic single crystal β-Ga 2 O 3 , and 10 = mol. % Al 2 O 3 alloyed with β-Ga 2 O 3 , denoted β-(Al 0.1 Ga 0.9 ) 2 O 3 or AGO. Temperature-dependent PL properties were studied for Cr 3+ in AGO and β-Ga 2 O 3 from 295 to 16 K. For both materials at room temperature, the red-line emission doublet R 1 and R 2 occurs at 696 nm (1.78 eV) and 690 nm (1.80 eV), respectively, along with a broad emission band at 709 nm (1.75 eV). Here, the linewidths for AGO are larger for all temperatures due to alloy broadening. For both materials, the R-lines blue-shift with decreasing temperature. The (lowest energy) R 1 line is dominant at low temperatures due to the thermal population of the levels. For temperatures above ~50 K, however, the ratio of R 2 to R 1 peak areas is dominated by nonradiative combination.

36 MATERIALS SCIENCE↗

AR-39Ar-40 dating of basalts and rock breccias from Apollo 17 and the malvern achondrite

The principles and the potential of the Ar-39/Ar-40 dating technique are illustrated by means of results obtained for 12 Apollo 17 rocks. Emphasis is given to methodical problems and the geological interpretation of lunar rock ages. Often it is ambigious to associate a given lunar breccia with a certain formation, or a formation with a basin. In addition, large-scale events on the Moon have not necessarily reset radiometric clocks completely. One rock fragment has a well-defined plateau age of 4.28 b.y., but the ages of two Apollo 17 breccias define an upper limit for the formation age of the Serenitatis basin at 4.05 b.y. Ages derived from five mare basalts indicate cessation of mare volcanism at Taurus-Littrow approximately 3.78 b.y. ago. Ca/Ar-37 exposure ages show that Camelot Crater was formed by an impact approximately 95 m.y. ago. After a short summary of the lunar timetable as it stands at the end of the Apollo program, we report about Ar-39/Ar-40 and rare gas studies on the Malvern meteorite. This achondrite resembles lunar highland breccias in texture as well as in rare-gas patterns. It was strongly annealed at some time between 3.4 and 3.8 b.y. ago. The results indicate that very similar processes have occurred on the Moon and on achondritic parent bodies at comparable times, leading to impact breccias with strikingly similar features, including the retention of rare-gas isotopes from various sources.

Kirsten, T.↗

Paleoatmospheric temperature structure

Radiative equilibrium and radiative convective temperature profiles for the earth's evolving atmosphere have been calculated. If the atmosphere evolved from one rich in carbon dioxide, and deficient in oxygen, to its present composition, the temperature structure showed considerable change. The models of 3 to 4 billion years ago display steadily decreasing temperatures with altitude, being 185 K at pressures associated with the present-day upper stratosphere. A lapse rate feature similar to the present-day tropopause is not indicated until about 1 billion years ago; but the stratospheric region is approximately 15 K colder than presently found at comparable pressures. Surface temperatures approximately 10 K warmer than at present existed until nearly 1 billion years ago. When the oxygen content exceeded roughly 0.1 times the present level, surface temperatures began to decrease. If biological processes are important to carbon dioxide - ozone variations, such as has been suggested during the Ice Ages, then estimates of surface temperature should include the effects of both gases.

Morss, D. A.↗

Evolution of early life inferred from protein and ribonucleic acid sequences

The chemical structures of ferredoxin, 5S ribosomal RNA, and c-type cytochrome sequences have been employed to construct a phylogenetic tree which connects all major photosynthesizing organisms: the three types of bacteria, blue-green algae, and chloroplasts. Anaerobic and aerobic bacteria, eukaryotic cytoplasmic components and mitochondria are also included in the phylogenetic tree. Anaerobic nonphotosynthesizing bacteria similar to Clostridium were the earliest organisms, arising more than 3.2 billion years ago. Bacterial photosynthesis evolved nearly 3.0 billion years ago, while oxygen-evolving photosynthesis, originating in the blue-green algal line, came into being about 2.0 billion years ago. The phylogenetic tree supports the symbiotic theory of the origin of eukaryotes.

Dayhoff, M. O.↗

Depositional and surface exposure history of the Shorty Crater core 74001/2 - FMR and magnetic studies

Surface exposure (maturity) indices and concentrations of FeO and metallic iron were determined at 0.5-cm intervals of the Apollo 17 core section, which sampled a pyroclastic deposit on the rim of Shorty Crater. The determinations showed that all of the soil in the core is extremely immature. An exposure history of the core is proposed: accumulation (about 3.6 billion years ago), shallow burial (during the first 20 million years), deep burial (till about 10-15 million years ago), followed by excavation (10-15 million years ago), and in situ reworking (till the present).

Morris, R. V.↗

Rb-Sr age of the Shergotty achondrite and implications for metamorphic resetting of isochron ages

The age of the Shergotty achondrite is determined by Rb-Sr isotope analysis and the metamorphic resetting of isochron ages, which is presumed to have occurred during a shock event in the history of the meteorite, is discussed. The isochron best fitting the Rb-Sr evolution diagram is found to correspond to an age of 165 million years, with an initial Sr-87/Sr-86 value of 0.72260. Different apparent ages obtained by the K-Ar and Sm-Nd methods are interpreted in terms of a model which quantifies the degree of resetting of internal isochron ages by low temperature solid state diffusion. On the basis of these considerations, it is concluded that Shergotty crystallized from a melt 650 million years ago, was shock heated to 300 to 400 C after its parent body was involved in a collision 165 million years ago, and was first exposed to cosmic rays two million years ago.

Nyquist, L. E.↗