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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5

All sources NASA NTRS DOE OSTI

NASA NTRS1986

The materials processing research base of the Materials Processing Center

An annual report of the research activities of the Materials Processing Center of the Massachusetts Institute of Technology is given. Research on dielectrophoresis in the microgravity environment, phase separation kinetics in immiscible liquids, transport properties of droplet clusters in gravity-free fields, probes and monitors for the study of solidification of molten semiconductors, fluid mechanics and mass transfer in melt crystal growth, and heat flow control and segregation in directional solidification are discussed.

Latanision, R. M.↗

DOE OSTI2024

Dynamic Activation of Single-Atom Catalysts by Reaction Intermediates: Conversion of Formic Acid on Rh/Fe 3 O 4 (001)

The stability and activity of supported single-atom catalysts (SACs) represent critical yet opposing factors limiting our ability to explore and exploit their unique properties. Here, this study demonstrates the operation of a switchable catalyst that is activated in the presence of surface intermediates and reverts back to a stable but inactive form when the reaction is completed. We employ atomically defined Rh-Fe 3 O 4 (001) catalysts to demonstrate how structurally stable Rh, bound in surface octahedral Fe sites, gets destabilized to form highly active Rh adatoms and small clusters. Conversion of formic acid, leading initially to surface formate and hydroxyl species, is employed as a model reaction to probe the dynamics of such processes. We find that surface hydroxyl recombination to water through the Mars van Krevelen mechanism reduces Rh coordination, triggering its conversion to active Rh adatoms. Since such lattice oxygen exchange is observed in many acid-base and redox chemistries, the process can be broadly applicable to controlling the activation of the range of SACs.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1963

Mariner II Deep Space Telecommunications

Two major telecommunication activities were in process during the Venus encounter of 1962, the largest, activity involved the two-way communications and tracking of the Mariner spacecraft from the DSIF (Deep Space Instrumentation Facility) stations on the earth. The first, and by far the largest activity involved the two-way communications and tracking of the Mariner spacecraft from the DSIF stations on the earth. The DSIF includes stations at Goldstone, California; Woomera, Australia; and Johannesburg, South Africa. The second activity involved an earth-based radar which reflected signals off the planet Venus during the same month that the Mariner spacecraft was traveling toward the planet.

TELECOMMUNICATION↗

NASA NTRS1990

The early Earth Observing System reference handbook: Earth Science and Applications Division missions, 1990-1997

Prior to the launch of the Earth Observing System (EOS) series, NASA will launch and operate a wide variety of new earth science satellites and instruments, as well as undertake several efforts collecting and using the data from existing and planned satellites from other agencies and nations. These initiatives will augment the knowledge base gained from ongoing Earth Science and Applications Division (ESAD) programs. This volume describes three sets of ESAD activities -- ongoing exploitation of operational satellite data, research missions with upcoming launches between now and the first launch of EOS, and candidate earth probes.

Source record↗

DOE OSTI2025

Clear as mud redefined: Tunable transparent mineral scaffolds for visualizing microbial processes below ground

Microbes inhabiting complex porous microenvironments in sediments and aquifers catalyze reactions that are critical to global biogeochemical cycles and ecosystem health. However, the opacity and complexity of porous sediment and rock matrices have considerably hindered the study of microbial processes occurring within these habitats. Here, we generated microbially compatible, optically transparent mineral scaffolds to visualize and investigate microbial colonization and activities occurring in these environments, in laboratory settings and in situ. Using inexpensive synthetic cryolite mineral, we produced optically transparent scaffolds mimicking the complex 3D structure of sediments and rocks by adapting a suspension-based, freeze-casting technique commonly used in materials science. Fine-tuning of parameters, such as freezing rate and choice of solvent, provided full control of pore size and architecture. The combined effects of scaffold porosity and structure on the movement of microbe-sized particles, tested using velocity tracking of fluorescent beads, showed diverse yet reproducible behaviors. The scaffolds we produced are compatible with epifluorescence microscopy, allowing the fluorescence-based identification of colonizing microbes by DNA-based staining and fluorescence in situ hybridization (FISH) to depths of 100 µm. Additionally, Raman spectroscopy analysis indicates minimal background signal in regions used for measuring deuterium and 13 C enrichment in microorganisms, highlighting the potential to directly couple D 2 O or 13 C stable isotope probing and Raman-FISH for quantifying microbial activity at the single-cell level. To demonstrate the relevance of cryolite scaffolds for environmental field studies, we visualized their colonization by diverse microorganisms within rhizosphere sediments of a coastal seagrass plant using epifluorescence microscopy. The tool presented here enables highly resolved, spatially explicit, and multimodal investigations into the distribution, activities, and interactions of underground microbes typically obscured within opaque geological materials until now.

36 MATERIALS SCIENCE↗

NASA NTRS1993

Solar Cycle Variations of Electron Density and Temperature in the Venusian Nightside Ionosphere

The return of periapsis to low altitudes during the Summer and Fall of 1992 provided a unique opportunity for the Pioneer Venus Orbiter (PVO) to make in situ measurements in the Venusian ionosphere at much lower levels of solar activity (F10.7=120) than existed when periapsis was at low altitudes in 1979 and 1980 (F10.7=220). We present the observations of electron density (N(sub e)) and temperature (T(sub e)) made by the Orbiter Electron Temperature Probe (OETP) during the Entry Period. Empirical models of the Ne and Te height variations are presented and compared with similar models based on OETP measurements made at solar maximum. The median Ne at the ionospheric peak (approx. 140 km) was essentially unchanged from its solar maximum value, but the ionosphere was increasingly depleted at higher altitudes, reaching a factor of 7 lower densities at 200 km. T(sub e) was lower by almost a factor of 2 at 140 km but was rather significantly enhanced at higher altitudes; exceeding its solar maximum values by a factor of 1.3 at 200 km and a factor of 2 at 500 km. In general these results support the earlier conclusions that the nightside upper ionosphere is depleted at lower levels of solar activity by a reduction of the nightward ion flow. The lack of N(sub e) variation near the peak (between solar maximum and entry) suggests that nightward ion transport does not play as large a role in the peak formation as does local ion production by energetic particles. The decrease in T(sub e) at low altitudes suggests that the low densities of the upper ionosphere at the time of PVO entry could no longer support the conduction of heat from the dayside ionosphere, thus allowing the lower nightside ionosphere to cool by collisions with ions and neutrals, and by heat conduction to the cooler regions below.

Theis, Robert F.↗

DOE OSTI2024

CatTestHub: A benchmarking database of experimental heterogeneous catalysis for evaluating advanced materials

The ability to quantitatively compare newly evolving catalytic materials and technologies is hindered by the widespread availability of catalytic data collected in a consistent manner. While certain catalytic chemistries have been widely studied across decades of scientific research, quantitative comparisons based on literature information is hindered by variability in reaction conditions, types of reported data, and reporting procedures. Here, we present CatTestHub, an open-access database dedicated to benchmarking experimental heterogeneous catalysis data. Combining systematically reported catalytic activity data for selected probe chemistries, with relevant material characterization and reactor configuration information, the database provides a collection of catalytic benchmarks for distinct classes of active site functionality. Through key choices in data access, availability, and traceability, CatTestHub seeks to balance the fundamental information needs of chemical catalysis and the FAIR data design principles. Details of the database architecture and the means through which to navigate it are presented, highlighting examples of catalytic insights readily drawn from the available benchmarking data. In its current iteration, CatTestHub spans over 250 unique experimental data points, collected over 24 solid catalysts, that facilitated the turnover of 3 distinct catalytic chemistries. Here, a roadmap is presented through which to expand the open-access platform that serves as a community wide benchmark, primarily through continuous addition of kinetic information on select catalytic systems by members of the heterogeneous catalysis community at large.

Benchmark↗

NASA NTRS1986

Strategy for exploration of the outer planets: 1986-1996

Over the past decade COMPLEX has published three strategy reports which, taken together, encompass the entire planetary system and recommend a coherent program of planetary exploration. The highest priority for outer planet exploration during the next decade is intensive study of Saturn (the planet, satellites, rings, and magnetosphere) as a system. The Committee additionally recommends that NASA engage in the following supporting activities: increased support of laboratory and theoretical studies; pursuit of earth-based and earth-orbital observations; commitment to continued operation of productive spacecraft; implementation of the instrument development plan as appropriate for the outer solar system; studies of deep atmospheric probes; development of penetrators or other hard landers; development of radiation-hardened spacecraft; and development of low-thrust propulsion systems. Longer-term objectives include exploration and intensive study of: the Uranus and Neptune systems; planetology of the Galilean satellites and Titan; and the inner Jovian system.

Source record↗

NASA NTRS2006

Managing Flap Vortices via Separation Control

A pilot study was conducted on a flapped semi-span model to investigate the concept and viability of near-wake vortex management by means of boundary layer separation control. Passive control was achieved using a simple fairing and active control was achieved via zero mass-flux blowing slots. Vortex sheet strength, estimated by integrating surface pressures, was used to predict vortex characteristics based on inviscid rollup relations and vortices trailing the flaps were mapped using a seven-hole probe. Separation control was found to have a marked effect on vortex location, strength, tangential velocity, axial velocity and size over a wide range of angles of attack and control conditions. In general, the vortex trends were well predicted by the inviscid rollup relations. Manipulation of the separated flow near the flap edges exerted significant control over either outboard or inboard edge vortices while producing small lift and moment excursions. Unsteady surface pressures indicated that dynamic separation and attachment control can be exploited to perturb vortices at wavelengths shorter than a typical wingspan. In summary, separation control has the potential for application to time-independent or time-dependent wake alleviation schemes, where the latter can be deployed to minimize adverse effects on ride-quality and dynamic structural loading.

Greenblatt, David↗

NASA NTRS1986

The identification of solar He-3-rich events and the study of particle acceleration at the sun

Kilometric radio observations are to associate type III radio bursts with solar He-3-rich events and to identify and study the sources of those events at the sun and the transport of the particles outward toward earth. The events exhibit an impulsive behavior that earns them a natural role in the event classification scheme based upon the time scale of the particle acceleration process. Multiple He-3-rich events are observed frequently from a single active region where they provide a convenient signature to test theories of particle storage and transport. These multiple events act as impulsive probes of the condition of the interplanetary medium. Their profiles contrast with the source-acceleration-induced profiles of the long-duration events from the same active region that are interspersed among them.

Reames, D. V.↗

DOE OSTI2024

Dark Sector and Gravitational Waves Searches with SRF Cavities at SQMS

The Superconducting Quantum Materials and Systems Center, led by Fermi National Accelerator Laboratory, is one of five research centers funded by the U.S. Department of Energy as part of a national initiative to develop and deploy the world’s most powerful quantum computers and sensors. The SQMS Center uses world-record quality-factor superconducting radio-frequency, or SRF, cavities as ultra-sensitive quantum probes. Within the quantum sensing thrust, researchers are developing experiments based on cavities and novel quantum devices to search for particles beyond the Standard Model, dark matter candidates, gravitational waves and fundamental material properties. The seminar will focus on Dark SRF and MAGO activities.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

NASA NTRS1990

Quantitative assessment of human motion using video motion analysis

In the study of the dynamics and kinematics of the human body, a wide variety of technologies was developed. Photogrammetric techniques are well documented and are known to provide reliable positional data from recorded images. Often these techniques are used in conjunction with cinematography and videography for analysis of planar motion, and to a lesser degree three-dimensional motion. Cinematography has been the most widely used medium for movement analysis. Excessive operating costs and the lag time required for film development coupled with recent advances in video technology have allowed video based motion analysis systems to emerge as a cost effective method of collecting and analyzing human movement. The Anthropometric and Biomechanics Lab at Johnson Space Center utilizes the video based Ariel Performance Analysis System to develop data on shirt-sleeved and space-suited human performance in order to plan efficient on orbit intravehicular and extravehicular activities. The system is described.

Probe, John D.↗

DOE OSTI2024

Mechanical and electrical changes in electrochemically active polyimide binders for Li-ion batteries

Polyimide binders are often used in electrodes made with silicon for lithium-ion batteries for their mechanical strength and adhesion, which help mitigate mechanical issues associated with large volumetric expansion. These binders can be electrochemically active, but it is difficult to characterize what physical and chemical changes occur due to a composite electrode with multiple components and processes at play. Here, in this work, we study electrodes consisting only of polyimide binder and conductive carbon, using scanning probe-based techniques—contact resonance, force volume, and scanning spreading resistance microscopy—along with cryo-scanning transmission electron microscopy, electron energy loss spectroscopy, and energy dispersive X-ray spectroscopy. We show that lithium becomes trapped in the binder during cycling and results in large initial capacity losses, the formation of dendrite-like features, column-like domains of significantly increased mechanical modulus, and a slight increase in electronic resistivity.

25 ENERGY STORAGE↗

DOE OSTI2024

Cavity Based Searches for New Particles and Gravitational Waves

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

NASA NTRS2005

Identification of transcribed sequences in Arabidopsis thaliana by using high-resolution genome tiling arrays

Using a maskless photolithography method, we produced DNA oligonucleotide microarrays with probe sequences tiled throughout the genome of the plant Arabidopsis thaliana. RNA expression was determined for the complete nuclear, mitochondrial, and chloroplast genomes by tiling 5 million 36-mer probes. These probes were hybridized to labeled mRNA isolated from liquid grown T87 cells, an undifferentiated Arabidopsis cell culture line. Transcripts were detected from at least 60% of the nearly 26,330 annotated genes, which included 151 predicted genes that were not identified previously by a similar genome-wide hybridization study on four different cell lines. In comparison with previously published results with 25-mer tiling arrays produced by chromium masking-based photolithography technique, 36-mer oligonucleotide probes were found to be more useful in identifying intron-exon boundaries. Using two-dimensional HPLC tandem mass spectrometry, a small-scale proteomic analysis was performed with the same cells. A large amount of strongly hybridizing RNA was found in regions "antisense" to known genes. Similarity of antisense activities between the 25-mer and 36-mer data sets suggests that it is a reproducible and inherent property of the experiments. Transcription activities were also detected for many of the intergenic regions and the small RNAs, including tRNA, small nuclear RNA, small nucleolar RNA, and microRNA. Expression of tRNAs correlates with genome-wide amino acid usage.

Arabidopsis/genetics↗

NASA NTRS2009

Mobile Instruments Measure Atmospheric Pollutants

As a part of NASA's active research of the Earth s atmosphere, which has included missions such as the Atmospheric Laboratory of Applications and Science (ATLAS, launched in 1992) and the Total Ozone Mapping Spectrometer (TOMS, launched on the Earth Probe satellite in 1996), the Agency also performs ground-based air pollution research. The ability to measure trace amounts of airborne pollutants precisely and quickly is important for determining natural patterns and human effects on global warming and air pollution, but until recent advances in field-grade spectroscopic instrumentation, this rapid, accurate data collection was limited and extremely difficult. In order to understand causes of climate change and airborne pollution, NASA has supported the development of compact, low power, rapid response instruments operating in the mid-infrared "molecular fingerprint" portion of the electromagnetic spectrum. These instruments, which measure atmospheric trace gases and airborne particles, can be deployed in mobile laboratories - customized ground vehicles, typically - to map distributions of pollutants in real time. The instruments must be rugged enough to operate rapidly and accurately, despite frequent jostling that can misalign, damage, or disconnect sensitive components. By measuring quickly while moving through an environment, a mobile laboratory can correlate data and geographic points, revealing patterns in the environment s pollutants. Rapid pollutant measurements also enable direct determination of pollutant sources and sinks (mechanisms that remove greenhouse gases and pollutants), providing information critical to understanding and managing atmospheric greenhouse gas and air pollutant concentrations.

Source record↗

NASA NTRS1993

Solar cycle variations of electron density and temperature in the Venusian nightside ionosphere

The return of periapsis to low altitudes during the Summer and Fall of 1992 provided a unique opportunity for the Pioneer Venus Orbiter (PVO) to make in situ measurements in the Venusian ionosphere at much lower levels of solar activity (F10.7 approx. equals 120) than existed when periapsis was at low altitudes in 1979 and 1980 (F10.7 approx. equals 220). We present the observations of electron density (N(sub e)) and temperature (T(sub e)) made by the Orbiter Electron Temperature Probe (OETP) during the Entry Period. Empirical models of the N(sub e) and T(sub e) height variations are presented and compared with similar models based on OETP measurements made at solar maximum. The median N(sub e) at the ionospheric peak (approx. 140 km) was essentially unchanged from its solar maximum value, but the ionosphere was increasingly depleted at higher altitudes, reaching a factor of 7 lower densities at 200 km. T(sub e) was lower by almost a factor of 2 at 140 km but was rather significantly enhanced at higher altitudes; exceeding its solar maximum values by a factor of 1.3 at 200 km and a factor of 2 at 500 km. In general these results support the earlier conclusions that the nightside upper ionosphere is depleted at lower levels of solar activity by a reduction of the nightward ion flow. The lack of N(sub e) variation near the peak (between solar maximum and entry) suggests that nightward ion transport does not play as large a role in the peak formation as does local ion production by energetic particles. The decrease does local ion production by energetic particles. The decrease in T(sub e) at low altitudes suggests that the low densities of the upper ionosphere at the time of PVO entry could no longer support the conduction of heat from the dayside ionosphere, thus allowing the lower nightside ionosphere to cool by collisions with ions and neutrals, and by heat conduction to the cooler regions below.

Theis, Robert F.↗

DOE OSTI2025

Oxygen Evolution on Mechanically Strained TiO2/NiTi: Implications of Compositional Heterogeneity at (Photo)Electrocatalytic Interfaces

The adsorption and activation energetics underpinning small molecule conversion on heterogeneous (photo)electrocatalysts are intrinsically tied to catalyst surface properties. Absent compositional characterization techniques with sufficient interface sensitivity, however, (photo)electrochemical performance can be misinterpreted in the context of bulk or near-surface material properties. Here we provide a fundamental investigation of the convoluting role of near-surface compositional heterogeneity in the interpretation of (photo)electrochemical alkaline oxygen evolution reaction (OER) activity, highlighting challenges in correlating composition measured by surface- and near-surface-sensitive probes. TiO2 thin films grown by air-annealing the superelastic alloy Nitinol (TiO2/NiTi) crack under tensile mechanical strain, increasing the number of electrochemically active Ni sites (Ni site density) that are probed via voltammetric features corresponding to Ni3+/Ni2+ redox events. (Photo)electrochemical OER kinetics trend with Ni site density, with overpotentials and Tafel slopes decreasing for Ni site densities < 1013 Ni/cm2geo and asymptotically approaching the performance of the base NiTi substrate for Ni site densities > 1013 Ni/cm2geo. Photoelectrochemical fill factors follow similar Ni site density dependent trends. When probing unstrained TiO2/NiTi, Ni site densities are two orders of magnitude higher when comparing near-surface-sensitive techniques (e.g., X-ray photoelectron spectroscopy (XPS), time of flight secondary ion mass spectrometry (TOF-SIMS), and scanning transmission electron microscopy-energy dispersive X-ray spectroscopy (STEM-EDS)) to surface-sensitive electrochemical measurements. This result highlights the challenge of correlating kinetic performance with intrinsic surface properties of electrochemical interfaces in the presence of near-surface compositional heterogeneity. Further, it reinforces the importance of fundamental investigations of surfaces with well-controlled composition and structure and the need for physically grounded and self-consistent interpretation of multiple near-surface characterization techniques.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗