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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

Atomic oxygen durability of solar concentrator materials for Space Station Freedom

The findings are reviewed of atomic oxygen exposure testing of candidate solar concentrator materials containing SiO2 and Al2O3 protective coatings for use on Space Station Freedom solar dynamic power modules. Both continuous and iterative atomic oxygen exposure tests were conducted. Iterative air plasma ashing resulted in larger specular reflectance decreases and solar absorptance increases than continuous ashing to the same fluence, and appears to provide a more severe environment than the continuous atomic oxygen exposure that would occur in the low Earth orbit environment. First generation concentrator fabrication techniques produced surface defects including scratches, macroscopic bumps, dendritic regions, porosity, haziness, and pin hole defects. Several of these defects appear to be preferential sites for atomic oxygen attack leading to erosive undercutting. Extensive undercutting and flaking of reflective and protective coatings were found to be promoted through an undercutting tearing propagation process. Atomic oxygen erosion processes and effects on optical performance is presented.

Degroh, Kim K.↗
NASA NTRS1977

An experimental estimate of the O/+/-O resonant charge transfer cross section, collision frequency, and energy transfer rate

The resonant-charge-transfer cross section dominates the interaction between neutral and ionized atomic oxygen at temperatures greater than several hundred degrees Kelvin. This cross section is of direct importance to F-region studies of ion diffusion, ion thermal balance, and neutral atmospheric winds and pressure gradients, since it determines collision frequencies and energy and momentum transfer rates. However, the uncertainty in this cross section is roughly 25-40%. Incoherent-scatter measurements allow determination of the product of the atomic oxygen concentration multiplied by the cross section. If present-day atmospheric models are accepted as statistically representative of F-region atomic oxygen concentrations experimental (aeronomical) data presented indicate that the resonant-charge-transfer cross section is about 1.3 times greater than the value presently in general use, though in excellent agreement with the only other available (laboratory) experimental value. This revised cross section has obvious implications for thermospheric studies.

Carlson, H. C.↗
NASA NTRS1975

The absolute concentration of O/3P/ in the earth's stratosphere

Results are presented for an experimental application of the laminar flow-through/resonance technique, which allows direct observations of the absolute concentration of atoms and radicals in the earth's upper atmosphere. Atomic resonance fluorescence was used in conjunction with a parachute-borne flow-through module deployed from a balloon at a height of 40 km to determine the concentration of ground-state atomic oxygen at 40 to 25 km in the atmosphere. The equipment is described, and the measurements and experimental uncertainties are plotted. It is shown that the observed absolute concentration of ground-state atomic oxygen is similar to that predicted by model calculations, and it is concluded that this technique provides a simple and direct means of measuring atomic and radical concentrations in the part-per-trillion range in unperturbed stratospheric samples.

Anderson, J. G.↗
NASA NTRS1972

Mariner 6 and 7 ultraviolet spectrometer experiment - Analysis of the O I 1304- and 1356-A emissions.

Analysis of the O I 1304- and 1356-A data from Mariner 6 and 7, and estimation of the atomic oxygen concentration of the Martian atmosphere. Derived values of the parameters describing the sources of excitation differ considerably from previous estimates. A detailed statistical treatment is used in the analysis. At an exospheric temperature of 350 K the atomic oxygen concentration at 135 km is estimated to be between 0.5 and 1%. The likely source of the 1304-A intensity is resonance scattering of solar 1304-A photons. For the 1356-A emission, the likely source is photodissociation of CO2. There is an indication of a diurnal variation of the Martian upper atmosphere.

Strickland, D. J.↗
NASA NTRS1990

The effect of leveling coatings on the atomic oxygen durability of solar concentrator surfaces

Space power systems for Space Station Freedom will be exposed to the harsh environment of low earth orbit (LEO). Neutral atomic oxygen is the major constituent in LEO and has the potential of severely reducing the efficiency of solar dynamic power systems through degradation of the concentrator surfaces. Several transparent dielectric thin films have been found to provide atomic oxygen protection, but atomic oxygen undercutting at inherent defect sites is still a threat to solar dynamic power system survivability. Leveling coatings smooth microscopically rough surfaces, thus eliminating potential defect sites prone to oxidation attack on concentrator surfaces. The ability of leveling coatings to improve the atomic oxygen durability of concentrator surfaces was investigated. The application of a EPO-TEK 377 epoxy leveling coating on a graphite epoxy substrate resulted in an increase in solar specular reflectance, a decrease in the atomic oxygen defect density by an order of magnitude and a corresponding order of magnitude decrease in the percent loss of specular reflectance during atomic oxygen plasma ashing.

Degroh, Kim K.↗
NASA NTRS1996

Atomic Oxygen Durability of Second Surface Silver Microsheet Glass Concentrators

Second surface silver microsheet glass concentrators are being developed for potential use in future solar dynamic space power systems. Traditional concentrators are aluminum honeycomb sandwich composites with either aluminum or graphite epoxy face sheets, where a reflective aluminum layer is deposited onto an organic leveling layer on the face sheet. To protect the underlying layers, a SiO2 layer is applied on top of the aluminum reflective layer. These concentrators may be vulnerable to atomic oxygen degradation due to possible atomic oxygen attack of the organic layers at defect sites in the protective and reflective coatings. A second surface microsheet glass concentrator would be inherently more atomic oxygen durable than these first surface concentrators. In addition, a second surface microsheet glass concentrator design provides a smooth optical surface and allows for silver to be used as a reflective layer, which would improve the reflectivity of the concentrator and the performance of the system. A potential threat to the performance of second surface microsheet glass concentrators is atomic oxygen attack of the underlying silver at seams and edges or at micrometeoroid and debris (MMD) impacts sites. Second surface silver microsheet glass concentrator samples were fabricated and tested for atomic oxygen durability. The samples were iteratively exposed to an atomic oxygen environment in a plasma asher. Samples were evaluated for potential degradation at fabrication seams, simulated MMD impact sites, and edges. Optical microscopy was used to evaluate atomic oxygen degradation. Reflectance was obtained for an impacted sample prior to and after atomic oxygen exposure. After an initial atomic oxygen exposure to an effective fluence of approx. 1 x 10(exp 21) atoms/cm(exp 2), oxidation of the silver at defect sites and edges was observed. Exposure to an additional approx. 1 x 10(exp 21) atoms/cm(exp 2) caused no observed increase in oxidation. Oxidation at an impact site caused negligible changes in reflectance. In all cases oxidation was found to be confined to the vicinity of the seams, impact sites, edges or defect sites. Asher to in-space atomic oxygen correlation issues will be addressed.

deGroh, Kim K.↗
NASA NTRS1980

Absolute concentrations of O/3P/ in the lower thermosphere at night

A rocketborne instrument module for detecting atomic oxygen concentrations by the resonance fluorescence technique is reported. The module contained a source lamp emitting O I 1304 A photons and a detector for the scattered photons. The module was constructed so that it could be coupled to a fast flow reactor for calibration purposes. During the flight the module was radially deployed from the payload on an oscillating boom with a maximum extension of 90 cm from the skin. Analysis of the initial flight data indicates that the shock formed by the motion of the rocket had a substantial effect on the data and the maximum concentration of the layer at 93 km was about 1.1 x 10 to the 11th/cu cm.

Sharp, W. E.↗
NASA NTRS1974

Helium in the Martian atmosphere - Thermal loss considerations

Helium concentrations in the Martian atmosphere are estimated assuming that the helium production on Mars (comparable to its production on earth) via the radioactive decay of uranium and thorium is in steady state equilibrium with its thermal escape. Although nonthermal losses would tend to reduce the estimated concentrations, these concentrations are not necessarily an upper limit since higher production rates and/or a possibly lower effective exospheric temperature over the solar activity cycle could increase them to even higher values. The computed helium concentration at the Martian exobase (200 km) is 8 million atoms/cu cm. Through the lower exosphere, the computed helium concentrations are 30-200 times greater than the Mariner-measured atomic hydrogen concentrations. It follows that helium may be the predominant constituent in the Martian lower exosphere and may well control the orbital lifetime of Mars-orbiting spacecraft.

Levine, J. S.↗
NASA NTRS1975

Study of the reaction of atomic oxygen with aerosols

The rate of disappearance of atomic oxygen was measured at several pressures in a fast flow pyrex reactor system with its walls treated with (NH4)2SO4 (s), H2SO4 (l), and NH4CL (s). Atomic oxygen, P-3 was generated by dissociation of pure, low pressure oxygen in a microwave discharge. Concentrations of atomic oxygen were measured at several stations in the reactor system using chemiluminescent titration with NO2. Recombination efficiencies calculated from experimentally determined wall recombination rate constants are in good agreement with reported values for clean Pyrex and an H2SO4 coated wall. The recombination efficiency for (NH4)2SO4, results in a slightly lower value than for H2S04. A rapid exothermic reaction between atomic oxygen and the NH4Cl wall coating prevented recombination efficiency determination for this coating. The results show that the technique is highly useful for wall recombination measurements and as a means of extrapolating to the case of free stream aerosol-gas interactions.

Akers, F. I.↗
NASA NTRS1995

Vacuum Ultraviolet Absorption Measurements of Atomic Oxygen in a Shock Tube

The absorption of vacuum ultraviolet light by atomic oxygen has been measured in the Electric Arc-driven Shock Tube (EAST) Facility at NASA-Ames Research Center. This investigation demonstrates the instrumentation required to determine atomic oxygen concentrations from absorption measurements in impulse facilities. A shock wave dissociates molecular oxygen, producing a high temperature sample of atomic oxygen in the shock tube. A probe beam is generated with a Raman-shifted ArF excimer laser. By suitable tuning of the laser, absorption is measured over a range of wavelengths in the region of the atomic line at 130.49 nm. The line shape function is determined from measurements at atomic oxygen densities of 3x10(exp 17) and 9x10(exp 17) cm(exp -3). The broadening coefficient for resonance interactions is deduced from this data, and this value is in accord with available theoretical models.

Meyer, Scott Andrew↗
NASA NTRS1995

Vacuum Ultraviolet Absorption Measurements of Atomic Oxygen in a Shock Tube

The absorption of vacuum ultraviolet light by atomic oxygen has been measured in the Electric Arc-driven Shock Tube (EAST) Facility at NASA-Ames Research Center. This investigation demonstrates the instrumentation required to determine atomic oxygen concentrations from absorption measurements in impulse facilities. A shock wave dissociates molecular oxygen, producing a high temperature sample of atomic oxygen in the shock tube. A probe beam is generated with a Raman-shifted ArF excimer laser. By suitable tuning of the laser, absorption is measured over a range of wavelengths in the region of the atomic line at 130.49 nm. The line shape function is determined from measurements at atomic oxygen densities of 3 x 10(exp 17) and 9 x 10(exp 17) cm(exp -3). The broadening coefficient for resonance interactions is deduced from this data, and this value is in accord with available theoretical models.

Meyer, Scott Andrew↗
NASA NTRS1995

Vacuum Ultraviolet Absorption Measurements of Atomic Oxygen in a Shock Tube

The absorption of vacuum ultraviolet light by atomic oxygen has been measured in the Electric Arc-driven Shock Tube (EAST) Facility at NASA-Ames Research Center. This investigation demonstrates the instrumentation required to determine atomic oxygen concentrations from absorption measurements in impulse facilities. A shock wave dissociates molecular oxygen, producing a high temperature sample of atomic oxygen in the shock tube. A probe beam is generated with a Raman-shifted ArF excimer laser. By suitable tuning of the laser, absorption is measured over a range of wavelengths in the region of the atomic line at 130.49 nm. The line shape function is determined from measurements at atomic oxygen densities of 3 x 10(exp 17) and 9 x 10(exp 17)/cu cm. The broadening coefficient for resonance interactions is deduced from this data, and this value is in accord with available theoretical models.

Meyer, Scott Andrew↗
NASA NTRS2003

New Methods of Sample Preparation for Atom Probe Specimens

Magnetite is a common conductive mineral found on Earth and Mars. Disk-shaped precipitates approximately 40 nm in diameter have been shown to have manganese and aluminum concentrations. Atom-probe field-ion microscopy (APFIM) is the only technique that can potentially quantify the composition of these precipitates. APFIM will be used to characterize geological and planetary materials, analyze samples of interest for geomicrobiology; and, for the metrology of nanoscale instrumentation. Prior to APFIM sample preparation was conducted by electropolishing, the method of sharp shards (MSS), or Bosch process (deep reactive ion etching) with focused ion beam (FIB) milling as a final step. However, new methods are required for difficult samples. Many materials are not easily fabricated using electropolishing, MSS, or the Bosch process, FIB milling is slow and expensive, and wet chemistry and the reactive ion etching are typically limited to Si and other semiconductors. APFIM sample preparation using the dicing saw is commonly used to section semiconductor wafers into individual devices following manufacture. The dicing saw is a time-effective method for preparing high aspect ratio posts of poorly conducting materials. Femtosecond laser micromachining is also suitable for preparation of posts. FIB time required is reduced by about a factor of 10 and multi-tip specimens can easily be fabricated using the dicing saw.

rock varnish↗
NASA NTRS1977

Comparison of drag and mass spectrometer measurements during small geomagnetic disturbances

During small geomagnetic disturbances, ESRO 4 and OGO 6 gas analyzer measurements at high altitudes suggest that helium and atomic oxygen concentrations in the lower thermosphere decrease, whereas satellite drag measurements indicate that density increases. This discrepancy is explained by the corresponding temperature increases maximizing at high latitudes. ESRO 4 data suggest that at altitudes where atomic oxygen or helium predominates, the temperature increase compensates for the decrease in lower thermospheric concentrations. This yields a net density increase with geomagnetic disturbances. The Explorer 39 drag satellite measurements verify this conclusion. It is felt that the composition variations associated with minor disturbances indicate the upwelling of the polar atmosphere, circulation towards the equator, and subsidence in the equatorial region. ESRO measurements show that at low latitudes the increases in helium concentrations with geomagnetic disturbances are chiefly caused by the circulation from high latitudes and the subsidence at lower latitudes.

Keating, G. M.↗
NASA NTRS1977

An experiment to measure variations in nighttime E-region neutral concentration

An experimental procedure is demonstrated which holds promise for the nighttime measurement of ion-neutral collision frequencies or net neutral concentration in the E-region by combining incoherent scatter data with appropriate photometric measurements. Data illustrating the technique are applied to comparing relative variations in atomic oxygen concentrations (from the E-region component of the O I 5577 A emission) near 100 km to those in the net neutral concentration obtained from combined incoherent scatter data and neutral temperature data extracted from Fabry-Perot measurement of the O I 5577 A line profile.

Cogger, L. L.↗
DOE OSTI2025

Atomically Dispersed Ni‐N‐C Catalysts for Electrochemical CO 2 Reduction

Abstract The atomic dispersion of nickel in Ni‐N‐C catalysts is key for the selective generation of carbon monoxide through the electrochemical carbon dioxide reduction reaction (CO 2 RR). Herein, the study reports a highly selective, atomically dispersed Ni 1.0% ‐N‐C catalyst with reduced Ni loading compared to previous reports. Extensive materials characterization fails to detect Ni crystalline phases, reveals the highest concentration of atomically dispersed Ni metal, and confirms the presence of the proposed Ni‐N x active site at this reduced loading. The catalyst shows excellent activity and selectivity toward CO generation, with a faradaic efficiency for CO generation (FE CO ) of 97% and partial current density for CO (j co ) of ‐9.0 mA cm −2 at ‐0.9 V in an electrochemical H‐type cell. CO 2 RR activity and selectivity are also studied by rotating disk electrode (RDE) measurements where transport limitations can be suppressed. It is expected that the utility of these Ni‐N‐C catalysts will lie with tandem CO 2 RR reaction schemes to multi‐carbon (C 2+ ) products.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗