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At least 91 records · Page 5

A Model Study of the Impact of Magnetic Field Reversal on Atmospheric Composition during Solar Proton Events

During a polarity transition of the Earth's magnetic field, the structure and strength of the field change significantly from their present values. This will alter the global pattern of charged particle precipitation into the atmosphere. Thus, particle precipitation is possible into regions that are at the moment effectively shielded by the Earth's magnetic field. A two-dimensional global fbHy coupled chemistry, radiation, and transport model of the atmosphere has been used to investigate how the increased particle precipitation affects the chemical composition of the middle and lower atmosphere. Ozone losses resulting from large energetic particle events are found to increase significantly, with resultant losses similar to those observed m the Antarctic ozone hole of the 1990s. This results in significant increases in surface UV-B radiation as well as changes in stratospheric temperature and circulation over a period of several months after large particle events.

Sinnhuber, Miaiam

Mass spectrometric measurements of atmospheric composition

The development of a magnetic sector field analyzer for continuous sampling and measurement of outer planetary atmospheres is discussed. Special features of the analyzer include a dynamic range of 10 to the minus 7th power, a mass range from 1 to 48 AMU, two ion sensitivities, a special scan time of 35 sec at 14 BPS, and the use of ion counting techniques for analysis.

Hoffman, J. H.

Atmospheric Composition and Radiative Forcing Effects due to UN International Ship Emissions Regulations (ACRUISE) Field Campaign Report

Aerosols, or atmospheric particulates, are long known to be able to seed clouds and modify their characteristics (e.g., cloud brightness, coverage, lifetime). However, the impact of aerosols on clouds is highly complex and non-linear. As a result, aerosol-cloud interaction remains the largest uncertainty in our understanding of the Earth’s radiative balance and in any future climate projections. Aerosols are also a principal component of air pollution and are known to adversely affect respiratory and cardiovascular health.

54 ENVIRONMENTAL SCIENCES

Dust in the Sky: Atmospheric Composition. Modeling of Aerosol Optical Thickness

Aerosol is any small particle of matter that rests suspended in the atmosphere. Natural sources, such as deserts, create some aerosols; consumption of fossil fuels and industrial activity create other aerosols. All the microscopic aerosol particles add up to a large amount of material floating in the atmosphere. You can see the particles in the haze that floats over polluted cities. Beyond this visible effect, aerosols can actually lower temperatures. They do this by blocking, or scattering, a portion of the sun's energy from reaching the surface. Because of this influence, scientists study the physical properties of atmospheric aerosols. Reliable numerical models for atmospheric aerosols play an important role in research.

Chin, Mian

Terrestrial atmospheric composition from stellar occultations

Stellar ultraviolet light transmitted through the upper mesosphere and lower thermosphere of the earth's atmosphere is primarily affected by the photoabsorption processes of ozone and molecular oxygen. The stellar ultraviolet photometers aboard the OAO-2 satellite have measured the intensity changes of several stars during occultation of the star by the earth. The measurements of the relative intensity change in certain atmospheric absorption bands are used to recover the vertical number density profiles of the absorbing species. Using the OAO-2 occultation data, the vertical number density profiles of molecular oxygen in the 100-200 km altitude region and ozone in the 60-100 km altitude region are determined.

Hays, P. B.

Titan's Atmospheric Composition from Observations by the Cassini Infrared Spectrometer

The Composite Infrared Spectrometer (CIRS) aboard the Cassini spacecraft has been making observations during the fly-bys of Titan since the Saturn-Orbit-Insertion in July 2004. The observations provide infrared them1 emission spectra of Titan s atmosphere in three spectral channels covering the 10/cm to 1400/cm spectral region, with variable spectral resolutions of 0.53/cm and 2.8/cm. The uniquely observed spectra exhibit rotational and vibrational-rotational spectral lines of the molecular constituents of Titan s atmosphere that may be analyzed to retrieve information about the composition, thermal structure, and physical and dynamical processes in the remotely sensed atmosphere. We present an analysis of Titan's infrared spectra observed during July 2004 (TO), December 2004 (Tb) and February 2005 (T3), for retrieval of the stratospheric thermal structure, distribution of the hydrocarbons, nitriles, and oxygen bearing constituents, such as C2H2, C2H4, C2H6, C3H8, HCN, HC3N, CO, and CO2 . Preliminary results on the distribution and opacity of haze in Titan s atmosphere are discussed.

Abbas, M. M.

The satellite power system - Assessment of the environmental impact on middle atmosphere composition and on climate

Numerical models were developed to calculate the total deposition of watervapor, hydrogen, CO2, CO, SO2, and NO in the middle atmosphere from operation of heavy lift launch vehicles (HLLV) used to build a satellite solar power system (SPS). The effects of the contaminants were examined for their effects on the upper atmosphere. One- and two-dimensional models were formulated for the photochemistry of the upper atmosphere and for rocket plumes and reentry. An SPS scenario of 400 launches per year for 10 yr was considered. The build-up of the contaminants in the atmosphere was projected to have no significant effects, even at the launch latitude. Neither would there by any dangerous ozone depletion. It was found that H, OH, and HO2 species would double in the thermosphere. No measurable changes in climate were foreseen.

Whitten, R. C.

Measurement of atmospheric composition by the ATMOS instrument from Table Mountain Observatory

Following its first flight on board the Space Shuttle 'Challenger' as part of the Spacelab 3 payload, the Atmospheric Trace Molecule Spectroscopy (ATMOS) instrument has been operated at the Jet Propulsion Laboratory's Table Mountain Observatory (TMO; 34.4 deg N, 117.7 deg W, 2.23 km altitude) in the San Gabriel Mountains of Southern California. With the delay in the resumption of regular Shuttle flights, ATMOS has acquired a large number of high-quality, high-resolution infrared solar absorption spectra, spanning a period between late-1985 and mid-1990. These spectra are being analyzed to derive the column abundances of several atmospheric species including O3, HCl, HF, and HNO3. Although limited in temporal coverage, the preliminary results for these gases are discussed here in the context of the requirement and contribution to be made by similar instruments in detecting long term changes in stratospheric composition.

Gunson, Michael R.

Lunar atmospheric composition results from Apollo 17

The Apollo 17 mass spectrometer has confirmed the existence of helium, neon, argon, and possibly molecular hydrogen in the lunar atmosphere. Helium and neon concentrations are in agreement with model predictions based on the solar wind as a source and their being noncondensable gases. Ar-40 and Ar-36 both exhibit a predawn enhancement which indicates that they are condensable gases on the nightside and are re-released into the atmosphere at the sunrise terminator. Hydrogen probably exists in the lunar atmosphere in the molecular rather than atomic state, having been released from the surface in the molecular form. Total nighttime gas concentration of known species in the lunar atmosphere is 200,000 molecules/cu cm.

Hoffmann, J. H.

A New Parameterization of H2SO4/H2O Aerosol Composition: Atmospheric Implications

Recent results from a thermodynamic model of aqueous sulfuric acid are used to derive a new parameterization for the variation of sulfuric acid aerosol composition with temperature and relative humidity. This formulation is valid for relative humidities above 1 % in the temperature range of 185 to 260 K. An expression for calculating the vapor pressure of supercooled liquid water, consistent with the sulfuric acid model, is also presented. We show that the Steele and Hamill [1981] formulation underestimates the water partial pressure over aqueous H2SOI solutions by up to 12% at low temperatures. This difference results in a corresponding underestimate of the H2SO4 concentration in the aerosol by about 6 % of the weight percent at approximately 190 K. In addition, the relation commonly used for estimating the vapor pressure of H2O over supercooled liquid water differs by up to 10 % from our derived expression. The combined error can result in a 20 % underestimation of water activity over a H2SO4 solution droplet in the stratosphere, which has implications for the parameterization of heterogeneous reaction rates in stratospheric sulfuric acid aerosols. The influence of aerosol composition on the rate of homogeneous ice nucleation from a H2SO4 solution droplet is also discussed. This parameterization can also be used for homogeneous gas phase nucleation calculations of H2SO4 solution droplets under various environmental conditions such as in aircraft exhaust or in volcanic plumes.

Tabazadeh, Azadeh

Remote Sensing of Icy Galilean Moon Surface and Atmospheric Composition Using Low Energy (1 eV-4 keV) Neutral Atom Imaging

We describe a low energy neutral atom imager suitable for composition measurements Europa and other icy Galilean moons in the Jovian magnetosphere. This instrument employs conversion surface technology and is sensitive to either neutrals converted to negative ions, neutrals converted to positive ions and the positive ions themselves depending on the power supply. On a mission such as the Jupiter Icy Moons Orbiter (JIMO), two back-to-back sensors would be flown with separate power supplies fitted to the neutral atom and iodneutral atom sides. This will allow both remote imaging of 1 eV < E < 4 keV neutrals from icy moon surfaces and atmospheres, and in situ measurements of ions at similar energies in the moon ionospheres and Jovian magnetospheric plasma. The instrument provides composition measurements of the neutrals and ions that enter the spectrometer with a mass resolution dependent on the time-of-flight subsystem and capable of resolving molecules. The lower energy neutrals, up to tens of eV, arise from atoms and molecules sputtered off the moon surfaces and out of the moon atmospheres by impacts of more energetic (keV to MeV) ions from the magnetosphere. Direct Simulation Monte Carlo (DSMC) models are used to convert measured neutral abundances to compositional distributions of primary and trace species in the sputtered surfaces and atmospheres. The escaping neutrals can also be detected as ions after photo- or plasma-ionization and pickup. Higher energy, keV neutrals come from charge exchange of magnetospheric ions in the moon atmospheres and provide information on atmospheric structure. At the jovicentric orbits of the icy moons the presence of toroidal gas clouds, as detected at Europa's orbit, provide M e r opportunities to analyze both the composition of neutrals and ions originating from the moon surfaces, and the characteristics of magnetospheric ions interacting with neutral cloud material. Charge exchange of low energy ions near the moons, and directional distributions of the resultant neutrals, allow indirect global mapping of magnetic field structures around the moons. Temporal variation of the magnetic structures can be linked to induced magnetic fields associated with subsurface oceans.

Collier, M. R.

Venus lower atmospheric composition - Preliminary results from Pioneer Venus

Initial examination of data from the neutral mass spectrometer on the Pioneer Venus sounder probe indicates that the abundances of argon-36, argon-38, and neon-20 in the Venus atmosphere are much higher than those of the corresponding gases in Earth's atmosphere, although the abundance of radiogenic argon-40 is apparently similar for both planets. The lower atmosphere of Venus includes significant concentrations of various gaseous sulfur compounds. The inlet leak to the mass spectrometer was temporarily blocked by an apparently liquid component of the Venus clouds during passage through the dense cloud layer. Analysis of gases released during the evaporation of the droplets shows the presence of water vapor to some compound or compounds of sulfur.

Hoffman, J. H.

Atmospheric Composition Forecast Model Evaluation Using Ozone Measurements Collected by the Langley Mobile Ozone Lidar

The Langley Mobile Ozone Lidar (LMOL) is a mobile ground based lidar system based at NASA Langley in Hampton, Virginia. Between 2022 and 2024, LMOL collected over 2500 hours of ozone measurements for a range of different atmospheric conditions, including calm days, stratospheric intrusions, surface frontal passages, and long-range transported wildfire smoke plumes. Here, the data is used to evaluate the forecast accuracy of NASA’s Global GEOS Composition Forecasting (GEOS-CF) model. GEOS-CF makes daily three-dimensional forecasts of trace gases and aerosol species. Overall, for calm periods, the forecast model predicts lower tropospheric ozone at NASA Langley with reasonable accuracy (within 20%). The model best predicts the timing and extent of stratospheric intrusions but often vary in the magnitude of the ozone mixing ratio. Among the other types of atmospheric conditions, there is more variability in the model forecasts. Based on this analysis, model forecasts are utilized to determine future data acquisition opportunities with the goal of providing feedback to the modeling teams, thereby enabling them to better understand the model biases and improve the model forecasts of ozone during these different atmospheric conditions.

Daniel B Phoenix

Surface ices and the atmospheric composition of Pluto

Observations of the 1.4- to 2.4-micrometer spectrum of Pluto reveal absorptions of carbon monoxide and nitrogen ices and confirm the presence of solid methane. Frozen nitrogen is more abundant than the other two ices by a factor of about 50; gaseous nitrogen must therefore be the major atmospheric constituent. The absence of carbon dioxide absorptions is one of several differences between the spectra of Pluto and Triton in this region. Both worlds carry information about the composition of the solar nebula and the processes by which icy planetesimals formed.

Owen, Tobias C.

ROSAT EUV and soft X-ray studies of atmospheric composition and structure in G191-B2B

Previous studies of the hot DA white dwarf GI91-B2B have been unable to determine whether the observed soft X-ray and EUV opacity arises from a stratified hydrogen and helium atmosphere or from the presence of trace metals in the photosphere. New EUV and soft X-ray photometry of this star, made with the ROSAT observatory, when analyzed in conjunction with the earlier data, shows that the stratified models cannot account for the observed fluxes. Consequently, we conclude that trace metals must be a substantial source of opacity in the photosphere of G191-B2B.

Barstow, M. A.

Jupiter's atmospheric composition and cloud structure deduced from absorption bands in reflected sunlight

The spectrum of sunlight reflected by Jupiter is analyzed by comparing observations of Woodman (1979) with multiple-scattering computations. The analysis yields information on the vertical cloud structure at several latitudes and on the abundance of CH4 and NH3 in the atmosphere of Jupiter. The abundances of CH4 and NH3 suggest that all ices and rocks are overabundant on Jupiter by a factor of 2 or more, providing an important constraint on models for the formation of Jupiter from the primitive solar nebula. The pressure level of the clouds, the gaseous NH3 abundance, the mean temperature profile, and the Clausius-Clapeyron relation suggest that these clouds are predominantly ammonia crystals with the cloud bottom at 600-700 mb. A diffuse distribution of aerosols exists between 150 and 500 mb, and the spectral variation of albedo reflects a changing bulk absorption coefficient of the material composing the aerosols and is diagnostic of the aerosol composition.

Sato, M.

Titan's upper atmosphere - Composition and temperature from the EUV solar occultation results

It is inferred from observation of an occultation of the sun by Titan, using the Voyager 1 UV spectrometer, that temperatures are 176 + or - 20 K near the evening terminator and 196 + or - 20 K near the morning terminator, and that the major atmospheric constituent is N2, with a density of 2.7 + or - 0.2 x 10 to the 8th/cu cm at 3840 km. A layer of absorbing molecules, possibly polymers, is found near both morning and evening terminators. A photochemical model suggests that the homopause is located at 3500 + or - 70 km, with an eddy diffusion coefficient of 1(+2, -0.7) x 10 to the 8th/sq cm per sec, which decreases to about 1000 sq cm/sec in the lower stratosphere as N2 to the -2/3 power.

Smith, G. R.