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At least 91 records · Page 5

Astrochemical Bistability: Autocatalysis in Oxygen Chemistry

The origin of bistable solutions in the kinetic equations describing the chemistry of dense interstellar clouds is explained as being due to the autocatalysis and feedback of oxygen nuclei from the oxygen dimer (O2). We identify four autocatalytic processes that can operate in dense molecular clouds, driven respectively by reactions of H+, He+, C+, and S+ with O2. We show that these processes can produce the bistable solutions found in previous studies, as well as the dependence on various model parameters such as the helium ionization rate, the sulfur depletion and the H+ electron recombination rate. We also show that ion–grain neutralizations are unlikely to affect the occurrence of bistability in dense clouds. It is pointed out that many chemical models of astronomical sources should have the potential to show bistable solutions.

Dufour, Gwenaelle C.

Astrochemical Bistability: Autocatalysis in Oxygen Chemistry

The origin of bistable solutions in the kinetic equations describing the chemistry of dense interstellar clouds is explained as being due to the autocatalysis and feedback of oxygen nuclei from the oxygen dimer (O2).We identify four autocatalytic processes that can operate in dense molecular clouds, driven respectively by reactions of H(+), He(+), C(+), and S(+) with O2. We show that these processes can produce the bistable solutions found in previous studies, as well as the dependence on various model parameters such as the helium ionization rate, the sulfur depletion and the H3(+) electron recombination rate. We also show that ion–grain neutralizations are unlikely to affect the occurrence of bistability in dense clouds. It is pointed out that many chemical models of astronomical sources should have the potential to show bistable solutions.

Gwénaëlle Dufour

Astrochemical Bistability: Autocatalysis in Oxygen Chemistry

The origin of bistable solutions in the kinetic equations describing the chemistry of dense interstellar clouds is explained as being due to the autocatalysis and feedback of oxygen nuclei from the oxygen dimer (O2). We identify four autocatalytic processes that can operate in dense molecular clouds, driven respectively by reactions of H+, He+, C+, and S+ with O2. We show that these processes can produce the bistable solutions found in previous studies, as well as the dependence on various model parameters such as the helium ionization rate, the sulfur depletion and the ${{\rm{H}}}_{3}^{+}$ electron recombination rate. We also show that ion–grain neutralizations are unlikely to affect the occurrence of bistability in dense clouds. It is pointed out that many chemical models of astronomical sources should have the potential to show bistable solutions.

astrochemistry – ISM: abundances – ISM: molecules

Providing Comprehensive and Consistent Access to Astronomical Observatory Archive Data: The NASA Archive Model

Since the turn of the millennium a constant concern of astronomical archives have begun providing data to the public through standardized protocols unifying data from disparate physical sources and wavebands across the electromagnetic spectrum into an astronomical virtual observatory (VO). In October 2014, NASA began support for the NASA Astronomical Virtual Observatories (NAVO) program to coordinate the efforts of NASA astronomy archives in providing data to users through implementation of protocols agreed within the International Virtual Observatory Alliance (IVOA). A major goal of the NAVO collaboration has been to step back from a piecemeal implementation of IVOA standards and define what the appropriate presence for the US and NASA astronomy archives in the VO should be. This includes evaluating what optional capabilities in the standards need to be supported, the specific versions of standards that should be used, and returning feedback to the IVOA, to support modifications as needed. We discuss a standard archive model developed by the NAVO for data archive presence in the virtual observatory built upon a consistent framework of standards defined by the IVOA. Our standard model provides for discovery of resources through the VO registries, access to observation and object data, downloads of image and spectral data and general access to archival datasets. It defines specific protocol versions, minimum capabilities, and all dependencies. The model will evolve as the capabilities of the virtual observatory and needs of the community change.

Virtual observatory; data archives; standards; IVO

Development of a self-priming high-capacity heat pipe for flight on OAO-C.

This paper describes the development of a 0.500-inch OD heat pipe with a spiral artery designed to fill under surface tension forces in a one-g field. Capacities in excess of 12,000 watt-inches have been achieved with ammonia as the working fluid. The paper presents the analysis, design, and test of the three-foot-long development models. Also included are some design and fabrication details, along with qualification ground test data for a 12-foot-long spiral artery isothermalizer type heat pipe that is installed on the Orbiting Astronomical Observatory C Model scheduled for launch in 1972.

Edelstein, F.

Millimeter-wave spectra of the Jovian planets

The millimeter wave portion of the electromagnetic spectrum is critical for understanding the subcloud atmospheric structure of the Jovian planets (Jupiter, Saturn, Uranus, and Neptune). This research utilizes a combination of laboratory measurements, computer modeling, and radio astronomical observation in order to obtain a better understanding of the millimeter-wave spectra of the Jovian planets. The pressure broadened absorption from gaseous ammonia (NH3) and hydrogen sulfide (H2S) was measured in the laboratory under simulated conditions for the Jovian atmospheres. Researchers developed new formalisms for computing the absorptivity of gaseous NH3 and H2S based on their laboratory measurements. They developed a radiative transfer and thermochemical model to predict the abundance and distribution of absorbing constituents in the Jovian atmospheres. They used the model to compute the millimeter wave emission from the Jovian planets.

Joiner, Joanna

Astronomical variation experiments with a Mars general circulation model

In time scales of a hundred thousand to a million years, the eccentricity of Mars orbit varies in a quasi-periodic manner between extremes as large as 0.14 and as small as 0 and the tilt of its axis of rotation with respect to the orbit normal also varies quasi-periodically between extremes as large as 35 deg and as small as 15 deg. In addition, the orientation of the axis precesses on comparable time scales. These astronomical variations are much more extreme than those experienced by the Earth. These variations are thought to have strongly modulated the seasonal cycles of dust, carbon dioxide, and water. One manifestation of the induced quasiperiodic climate changes may be the layered terrain of the polar regions, with individual layers perhaps recording variations in the absolute and/or relative deposition rates of dust and water in the polar regions, most likely in association with the winter time deposition of carbon dioxide ice. In an attempt to understand the manner in which atmospheric temperatures and winds respond to the astronomical forcings, we have initiated a series of numerical experiments with the NASA/Ames general circulation model of the Martian Atmosphere.

Pollack, J. B.

The Chemical Evolution of Cosmic Dust: From Gas-Phase Precursors to Solid Grains - Laboratory Studies with the COSmIC Facility

Cosmic dust in in its gas phase and solid phase components plays an essential role in the chemical and physical evolution of the universe. Our understanding of cosmic dust properties relies on a combination of astronomical observations, astrophysical modeling and laboratory studies of realistic analogs of cosmic dust being gas-phase molecules and/or solid grains. The COSmIC facility was developed at NASA Ames to study the evolution of cosmic carbon from circumstellar outflows to interstellar clouds to planetary atmospheres in the laboratory. COSmIC stands for “Cosmic Simulation Chamber” and is dedicated to the study of neutral and ionized molecules and grain particles under the low temperature and density conditions that are required to simulate space environments. It integrates a variety of instruments that allow generating, processing, and monitoring simulated space conditions in the laboratory. It is composed of a Pulsed Discharge Nozzle (PDN) expansion that generates a plasma in a free supersonic jet expansion, coupled to high-sensitivity, complementary in situ diagnostic tools used for the detection and characterization of the species present in the expansion: Cavity Ring Down Spectroscopy (CRDS) and fluorescence spectroscopy systems for photonic detection and an orthogonal Reflectron Time-Of-Flight Mass Spectrometer (oReTOF-MS) for mass detection. Recent advances achieved using COSmIC’s laboratory data in synergy with observational data will be presented. These results include the formation of dust grains and aerosols from gas-phase molecular precursors in environments as varied as circumstellar outflows of late AGB stars and planetary atmospheres [4] and the evolution of our understanding of the diffuse interstellar bands (DIBs) with applications to the ESO Diffuse Interstellar Bands Large Exploration Survey (EDIBLES). Plans for future laboratory developments and techniques to study the evolution of cosmic carbon molecules and grains (including NIR-MIR CRDS, laser induced fluorescence (LIF) and incandescence (LII)) will also be addressed as well as their astronomical applications.

Farid Salama

The Chemical Evolution of Cosmic Dust: From Gas-Phase Precursors to Solid Grains - Laboratory Studies with the COSmIC Facility

Cosmic dust in in its gas phase and solid phase components plays an essential role in the chemical and physical evolution of the universe. Our understanding of cosmic dust properties relies on a combination of astronomical observations, astrophysical modeling and laboratory studies of realistic analogs of cosmic dust being gas-phase molecules and/or solid grains. The COSmIC facility was developed at NASA Ames to study the evolution of cosmic carbon from circumstellar outflows to interstellar clouds to planetary atmospheres in the laboratory [1]. COSmIC stands for “Cosmic Simulation Chamber” and is dedicated to the study of neutral and ionized molecules and grain particles under the low temperature and density conditions that are required to simulate space environments. It integrates a variety of instruments that allow generating, processing, and monitoring simulated space conditions in the laboratory. It is composed of a Pulsed Discharge Nozzle (PDN) expansion that generates a plasma in a free supersonic jet expansion, coupled to high-sensitivity, complementary in situ diagnostic tools used for the detection and characterization of the species present in the expansion: Cavity Ring Down Spectroscopy (CRDS) and fluorescence spectroscopy systems for photonic detection and an orthogonal Reflectron Time-Of-Flight Mass Spectrometer (oReTOF-MS) for mass detection. Recent advances achieved using COSmIC’s laboratory data in synergy with observational data will be presented. These results include the formation of dust grains and aerosols from gas-phase molecular precursors in environments as varied as circumstellar outflows of late AGB stars [2, 3] and planetary atmospheres [4] and the evolution of our understanding of the diffuse interstellar bands (DIBs) with applications to the ESO Diffuse Interstellar Bands Large Exploration Survey (EDIBLES [5, 6]). Plans for future laboratory developments and techniques to study the evolution of cosmic carbon molecules and grains (including NIR-MIR CRDS, laser induced fluorescence (LIF) and incandescence (LII)) will also be addressed as well as their astronomical applications.

Planetary

Impact of the Earth’s Density Profile on Atmospheric Neutrino Oscillations

As atmospheric neutrinos traverse the Earth, the matter potential influences their oscillation probabilities in intricate ways, enhancing and suppressing the conversion of one neutrino’s flavor to another along the propagation. Comprehending their behavior within Earth’s complex density profile, primarily described by the Preliminary Reference Earth Model (PREM) [1], is essential for accurately describing oscillations and determining expected atmospheric neutrino event rates in the DUNE Far Detector. In this study, we address this challenge by considering an ensemble of Earth models constrained by astronomical measurements of the planet’s mass and moment of inertia. We evaluate how variations in densities and layer boundaries can affect oscillation probabilities and event rates, and what implications this could have on various physics analyses.

Ismerio Oliveira, Marcelo [Rio de Janeiro, Pont. U

Modeling and Correcting the Time-Dependent ACS PSF

The ability to accurately measure the shapes of faint objects in images taken with the Advanced Camera for Surveys (ACS) on the Hubble Space Telescope (HST) depends upon detailed knowledge of the Point Spread Function (PSF). We show that thermal fluctuations cause the PSF of the ACS Wide Field Camera (WFC) to vary over time. We describe a modified version of the TinyTim PSF modeling software to create artificial grids of stars across the ACS field of view at a range of telescope focus values. These models closely resemble the stars in real ACS images. Using 10 bright stars in a real image, we have been able to measure HST s apparent focus at the time of the exposure. TinyTim can then be used to model the PSF at any position on the ACS field of view. This obviates the need for images of dense stellar fields at different focus values, or interpolation between the few observed stars. We show that residual differences between our TinyTim models and real data are likely due to the effects of Charge Transfer Efficiency (CTE) degradation. Furthermore, we discuss stochastic noise that is added to the shape of point sources when distortion is removed, and we present MultiDrizzle parameters that are optimal for weak lensing science. Specifically, we find that reducing the MultiDrizzle output pixel scale and choosing a Gaussian kernel significantly stabilizes the resulting PSF after image combination, while still eliminating cosmic rays/bad pixels, and correcting the large geometric distortion in the ACS. We discuss future plans, which include more detailed study of the effects of CTE degradation on object shapes and releasing our TinyTim models to the astronomical community.

Rhodes, Jason

Organic Chemistry in Space

Astronomical observations, theoretical modeling, laboratory simulation and analysis of extraterrestrial material have enhanced our knowledge of the inventory of organic matter in the interstellar medium (ISM) and on small bodies such as comets and asteroids (Ehrenfreund & Charnley 2000). Comets, asteroids and their fragments, meteorites and interplanetary dust particles (IDPs), contributed significant amounts of extraterrestrial organic matter to the young Earth. This material degraded and reacted in a terrestrial prebiotic chemistry to form organic structures that may have served as building blocks for life on the early Earth. In this talk I will summarize our current understanding of the organic composition and chemistry of interstellar clouds. Molecules of astrobiological relevance include the building blocks of our genetic material: nucleic acids, composed of subunits such as N-heterocycles (purines and pyrimidines), sugars and amino acids. Signatures indicative of inheritance of pristine and modified interstellar material in comets and meteorites will also be discussed.

Charnley, Steven

Theoretical Models of Astrochemical Processes

Interstellar chemistry provides a natural laboratory for studying exotic species and processes at densities, temperatures, and reaction rates. that are difficult or impractical to address in the laboratory. Thus, many chemical reactions considered too sloe by the standards of terrestrial chemistry, can be 'observed and modeled. Curious proposals concerning the nature and chemistry of complex interstellar organic molecules will be described. Catalytic reactions on "rain surfaces can, in principle, lead to a lame variety of species and this has motivated many laboratory and theoretical studies. Gas phase processes may also build lame species in molecular clouds. Future laboratory data and computational tools needed to construct accurate chemical models of various astronomical sources to be observed by Herschel and ALMA will be outlined.

Charnley, Steven

Theoretical Models of Astrochemical Processes

Interstellar chemistry provides a natural laboratory for studying exotic species and processes at densities, temperatures, and reaction rates, that are difficult or impractical to address in the laboratory. Thus, many chemical reactions considered too slow by the standards of terrestrial chemistry, can be 'observed' and modeled. Various proposals concerning the nature and chemistry of complex interstellar organic molecules will be described. Catalytic reactions on grain surfaces can, in principle, lead to a large variety of species and this has motivated many laboratory and theoretical studies. Gas phase processes may also build large species in molecular clouds. Future laboratory data and computational tools needed to construct accurate chemical models of various astronomical sources to be observed by Herschel and ALMA will be outlined

Charnley, Steven B.