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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Microstructural diversity and digestion yields of select bituminous and subbituminous coals as raw material candidates for carbon fiber precursor production

Here, this work investigates the use of coals as raw materials for carbon fiber precursor production as a new alternative to coal utilization. Coal being a highly complex and heterogeneous material with different macerals and minerals complicates this task. Extensive microstructural characterization as well as preliminary digestion studies are performed on three bituminous coals (Herrin and Springfield from the Illinois Basin and the Blue Gem from the Central Appalachians) and one subbituminous coal from the Powder River Basin (Monarch), as raw material candidates. The subbituminous coal was richer in oxygen, lower in sulfur, and had a higher volatile matter yield. Microstructural investigations were performed using X-ray diffraction, X-ray/neutron computed tomography, scanning electron microscopy with energy dispersive spectroscopy, and petrology. Mild solvent extraction studies were conducted using creosote and decant oil as solvents in microreactors. The extraction yield was sensitive to temperature and time (350 to 450 °C between 30 and 120 mins.) for both creosote and decant oil digestions. While the Blue Gem coal had more desirable microstructural properties with less mineral content and cleaner macerals, it had the lowest coal conversion to quinoline soluble ‘liquid’ (of the bituminous coals). The lower coal conversion yield was hypothesized to be connected to the lack of FeS2 which could act as a catalyst when Fe is liberated from the structure under solvent extraction conditions. The Herrin and Springfield coals revealed similar microstructures and coal conversion efficiencies (higher than Blue Gem). These coals were the most promising candidates for further examination from this first approximations study. The subbituminous Monarch coal, however, was deemed less suitable due to poor coal conversion and less desirable microstructures. Additionally, the presented results with combined microstructural data from multiple length scales established a framework necessary for a first approximations study in this new coal utilization approach.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2025

Integrated thermal and biological conversion of microalgal proteins to lipids

Microalgal composition varies with cultivation strategy, and low-cost approaches often produce high-protein biomass. This presents challenges for biorefineries designed around static, lipid-rich feedstocks. In particular, hydrolysates from high-protein algae are nitrogen-rich and sugar-poor, limiting microbial conversion and reducing product yields. This study develops a sequential thermal conditioning and biological upgrading strategy to integrate high-protein hydrolysate processing within conventional lipid extraction and upgrading designs. Oxidative deconstruction was used to break down proteins into ammonium and short-chain carboxylates. Ammonium was subsequently removed to yield a nitrogen-depleted, carboxylate-rich medium suitable for microbial lipid production. Bioconversion trials with Cutaneotrichosporon oleaginosum showed lipid accumulation only from hydrolysates treated with both oxidative deconstruction and nitrogen removal, reaching 1.2 g/L lipids at 30 % intracellular content. This integrated approach enables protein-to-lipid conversion and improves flexibility to process variable algal feedstocks, advancing fuel-oriented microalgal biorefineries.

09 BIOMASS FUELS↗
DOE OSTI2022

Determining the hydronium pKα at platinum surfaces and the effect on pH-dependent hydrogen evolution reaction kinetics

Electrocatalytic hydrogen evolution reaction (HER) is critical for green hydrogen generation and exhibits distinct pH-dependent kinetics that have been elusive to understand. A molecular-level understanding of the electrochemical interfaces is essential for developing more efficient electrochemical processes. Here we exploit an exclusively surface-specific electrical transport spectroscopy (ETS) approach to probe the Pt-surface water protonation status and experimentally determine the surface hydronium pK a = 4.3. Quantum mechanics (QM) and reactive dynamics using a reactive force field (ReaxFF) molecular dynamics (RMD) calculations confirm the enrichment of hydroniums (H 3 O + * ) near Pt surface and predict a surface hydronium pK a of 2.5 to 4.4, corroborating the experimental results. Importantly, the observed Pt-surface hydronium pK a correlates well with the pH-dependent HER kinetics, with the protonated surface state at lower pH favoring fast Tafel kinetics with a Tafel slope of 30 mV per decade and the deprotonated surface state at higher pH following Volmer-step limited kinetics with a much higher Tafel slope of 120 mV per decade, offering a robust and precise interpretation of the pH-dependent HER kinetics. These insights may help design improved electrocatalysts for renewable energy conversion.

Zhong, Guangyan↗
NASA NTRS1992

Microwave Electrothermal Propulsion for Space

The microwave electrothermal thruster (MET) concept for medium or high-power spacecraft propulsion is described. The MET employs continuous wave microwave energy to create and maintain a plasma discharge in a flowing propellant gas. The discharge then acts to absorb the applied microwave energy and transform it into thermal and internal energy of the propellant. Expansion and expulsion of the hot propellant through a throat and nozzle finally converts the energy of the gas into thrust. The MET concept is electrodeless, synergistically combines high pressure and high power capability, provides external control over the energy-conversion discharge, and operates on hydrogen propellant. The potential performance of the MET on hydrogen propellant has been modeled with a two-dimensional kinetics computer code. The MET concept is particularly suitable for use with a magnetic nozzle. Apparatus is described for testing the resonant-cavity MET to power levels of 30 kW at 915 MHz on nitrogen, helium, and hydrogen. The low-ripple operation of the microwave generator has been verified, as has a procedure for starting the microwave discharge and raising the power applied to the cavity via a phase shifter-tuner.

Power, John L.↗
NASA NTRS1981

Anomalous extinction in the planetary nebula Abell 30

The stellar continuous energy distribution from 8000 to 1250 A in Abell 30 is quite peculiar. The observed flux can be understood if a hot central star (approximately 200,000 K) is immersed in an absorbing dust cloud which has anomalous absorption with its peak near 2470 A. The dust nebula is a strong infrared source, maintained by conversion of the stellar UV flux. The internal reddening is E(B - V) = 0.30 mag and reaches 2.5 mag at 2470 A; it is best matched not by graphite but by laboratory observations of carbon smoke. Intense P Cygni lines show that a strong stellar wind exists. The central star may be an O subdwarf, approaching more nearly a helium-carbon degenerate DO.

Greenstein, J. L.↗
DOE OSTI2025

An overview of switchgrass phenotypes variability across diverse populations and their implications for conversion to fuels

There have been substantial changes to the human lifestyle over the past two centuries, which are reflected in the amount of fuel we consume to power our day-to-day needs. The way we use these resources has indeed manifested in an overdependence on non-renewable energy sources, such as coal and petroleum, for generating electricity and powering our transportation needs. There is a pressing need to explore alternative ways of fueling our current lifestyle without impacting the environment. Biofuels have long been touted as a sustainable solution for use as drop-in fuels in aviation and maritime applications. Still, they have yet to establish themselves as a competitive commercial alternative, necessitating further research and development. Lignocellulosic biomass is an underutilized resource that is widely accessible for the commercial processing of renewable biofuels. Bioenergy crops, such as switchgrass (Panicum virgatum L.), which can be cultivated on marginal lands with minimal competition for agricultural land, are an ideal and promising candidate for bulk-scale biofuel synthesis. Over the past 30 years, significant progress has been made in breeding and genetically modifying these grasses to enhance their drought resilience and subsequent yields. However, discrepancies in biomass composition can lead to irregular feedstocks for downstream operations, which in turn affect overall production targets for biofuels. Here, this review examines the variability in switchgrass (P. virgatum L.) biomass phenotypes across diverse populations and plant components, and their implications for biofuel conversion. The study highlights significant variations in biomass yield, composition, and cell wall chemistry both between switchgrass genotypes and within individual cultivars. Key findings include differences in cellulose, hemicellulose, and lignin content between leaves and stems, which affect biomass digestibility and ethanol yield. The review also discusses the impact of lignin chemistry, particularly the syringyl/guaicyl (S/G) ratio, on the efficiency of biomass saccharification. Furthermore, it explores how these variations respond differently to various pretreatment techniques, affecting overall biofuel production. We conclude that understanding and quantifying this variability is crucial for optimizing switchgrass as a feedstock for commercial biofuel production, thereby potentially addressing the pressing need for sustainable energy sources in sectors such as aviation.

Kousika, Rohit [Univ. of Tennessee, Knoxville, TN ↗
DOE OSTI2025

Fabricating Silver Nanowire–IZO Composite Transparent Conducting Electrodes at Roll-to-Roll Speed for Perovskite Solar Cells

This study addresses the challenges of efficient, large-scale production of flexible transparent conducting electrodes (TCEs). We fabricate TCEs on polyethylene terephthalate (PET) substrates using a high-speed roll-to-roll (R2R) compatible method that combines gravure printing and photonic curing. The hybrid TCEs consist of Ag metal bus lines (Ag MBLs) coated with silver nanowires (AgNWs) and indium zinc oxide (IZO) layers. All materials are solutions deposited at speeds exceeding 10 m/min using gravure printing. We conduct a systematic study to optimize coating parameters and tune solvent composition to achieve a uniform AgNW network. The entire stack undergoes photonic curing, a low-energy annealing method that can be completed at high speeds and will not damage the plastic substrates. The resulting hybrid TCEs exhibit a transmittance of 92% averaged from 400 nm to 1100 nm and a sheet resistance of 11 Ω/sq. Mechanical durability is tested by bending the hybrid TCEs to a strain of 1% for 2000 cycles. The results show a minimal increase (<5%) in resistance. The high-throughput potential is established by showing that each hybrid TCE fabrication step can be completed at 30 m/min. We further fabricate methylammonium lead iodide solar cells to demonstrate the practical use of these TCEs, achieving an average power conversion efficiency (PCE) of 13%. The high-performance hybrid TCEs produced using R2R-compatible processes show potential as a viable choice for replacing vacuum-deposited indium tin oxide films on PET.

14 SOLAR ENERGY↗
DOE OSTI2021

Introducing Low-Cost Pyrazine Unit into Terpolymer Enables High-Performance Polymer Solar Cells with Efficiency of 18.23%

Recently, a random ternary copolymerization strategy has become a promising and efficient approach to develop high-performance polymer donors for polymer solar cells (PSCs). Here, in this study, a low-cost electron-withdrawing unit, 2,5-bis(4-(2-ethylhexyl)thiophen-2-yl)pyrazine (PZ-T), is incorporated into the polymer backbone of PM6 as the third component, and three D-A 1 -D-A 2 type terpolymers PMZ-10, PMZ-20, and PMZ-30 are synthesized by the random copolymerization strategy, with the PZ-T proportion of 10%, 20%, and 30%, respectively. The terpolymers exhibit downshifted highest occupied molecular orbital energy levels than PM6, which is beneficial for obtaining higher open-circuit voltage (V oc ) of the PSCs with the polymer as a donor. Importantly, the PSCs based on PMZ-10:Y6 demonstrate efficient exciton dissociation, higher and balanced electron/hole mobilities, desirable aggregation, and high power conversion efficiency of 18.23%, which is the highest efficiency among the terpolymer-based PSCs so far. The results indicate that the ternary copolymerization strategy with PZ-T as the second A-unit is an efficient approach to further improve the photovoltaic performance and reduce the synthetic cost of the D-A copolymer donors.

36 MATERIALS SCIENCE↗
NASA NTRS1990

Preliminary design of an advanced Stirling system for terrestrial solar energy conversion

A preliminary design was generated for an advanced Stirling conversion system (ASCS) that will be capable of delivering about 25 kW of electric power to an electric utility grid. Stirling engines are being evaluated for terrestrial solar applications. A two-year task to complete detailed design, fabrication, assembly and testing of an ASCS prototype began in April, 1990. The ASCS is designed to deliver maximum power per year over a range of solar inputs with a design life of 30 years (60,000 h). The ACSC has a long-term cost goal of about $450 per kilowatt, exclusive of the 11-m parabolic dish concentrator. The proposed system includes a Stirling engine with high-pressure hydraulic output, coupled with a bent axis variable displacement hydraulic motor and a rotary induction generator. The major thrusts of the preliminary design are described, including material selection for the hot-end components, heat transport system (reflux pool boiler) design, system thermal response, improved manufacturability, FMECA/FTA analysis, updated manufacturing cost estimate, and predicted system performance.

White, M. A.↗
NASA NTRS2022

Recent Concept Study for Cryogenic Fluid Management to Support Opposition Class Crewed Missions to Mars

NASA recently completed a mission concept study to evaluate the feasibility and propulsion technology development requirements for reduced travel duration crewed missions to Mars. A high-level goal of the study was to minimize the health impact on the crew caused by the space environment. This was implemented in the study by limiting the crew to a total of approximately-two years of in-space operations and travel time. For the initial mission, the crew would stay about 30 days on the Martian surface. The propulsive demands of such a mission are immense, and the study identified two advanced propulsion options with the potential to meet the mission requirements—both options rely on nuclear fission to provide efficient propulsive energy. One propulsion option was a nuclear electric propulsion (NEP)/Chem Hybrid, with a reactor and energy conversion system powering xenon propellant ion thrusters to provide an efficient, but lower-thrust, push for most of the mission duration. This concept also relied on a liquid oxygen/liquid methane (LO2/LCH4) chemical propulsion stage to provide high thrust for maneuvers while near the Earth and Mars. The second propulsion option was nuclear thermal propulsion (NTP), in which the reactor heats liquid hydrogen (LH2) propellant to expand through a nozzle for thrust at about twice the efficiency of the best chemical propulsion systems. Both vehicle concepts rely on storing large amounts of cryogenic propellant (either LO2/LCH4 or LH2) for multiple years in space without loss, far exceeding state-of-the-art capability. To enable this new capability, the team assumed the use of several advanced cryogenic fluid management (CFM) technologies and analyzed the integrated system performance. This included considering the vehicle-level effects of the size, mass, and power requirements of these CFM elements. Further, the team evaluated the development required to enable such a mission in the mid-2030 s and determined that it was feasible. The paper elaborates on the assumed CFM technologies, provides key analysis results, and illustrates the feasibility of technology development for the proposed solutions to the CFM challenges for each propulsion concept.

cryogenic propellant↗
DOE OSTI2020

Effects of Photonic Curing Processing Conditions on MAPbI 3 Film Properties and Solar Cell Performance

Thermal annealing is the most used postdeposition materials processing method in laboratory research, but due to its slow speed and high energy cost, it is not compatible with the upscaling and commercialization of perovskite solar cell (PSC) manufacturing. Here, we adapt photonic curing (PC), which uses millisecond light pulses to deliver energy to the sample, to replace thermal annealing for crystallization of methylammonium lead iodide (MAPbI 3 ) films and rapid fabrication of PSCs. We study how PC conditions affect the outcome of MAPbI 3 conversion from the precursor to the crystalline perovskite phase by evaluating the films’ optical, crystalline, and morphological properties, as well as PSC performance. The results are understood using simulated film temperature profiles. We show that MAPbI 3 is readily converted under a wide range of PC conditions. While previous reports all used short pulses (<3 ms), we find that longer pulses produce more dense films and higher-performing PSCs. We achieve a champion power conversion efficiency in a PC-processed MAPbI 3 PSC of 11.26% under forward scan and 10.34% under reverse scan, with the processing time for the MAPbI 3 layer reduced by 30,000-fold, from 10 min to 20 ms. Using a 6 in. lamp, spatial uniformity tests show a cross-web efficiency variation of 5%. Our results indicate that using longer pulse lengths, >10 ms, is the best PC strategy for perovskite conversion, and PC is a promising annealing method for large-area, high-throughput PSC manufacturing.

14 SOLAR ENERGY↗
DOE OSTI2021

Combined Land Use of Solar Infrastructure and Agriculture for Socioeconomic and Environmental Co-Benefits in the Tropics

Solar photovoltaics (PV) are on the rise even in areas of low solar insolation. However, in developing countries with limited capital, land scarcity, or with geographically isolated agrarian communities, large solar infrastructures are often impractical. In these cases, implementation of low-density PV over existing crops may be required to integrate renewable energy services into rural communities. Here, using Indonesia as a model system, we investigated the land use, energy, greenhouse gas emissions, economic feasibility, and the environmental co-benefits associated with off-grid solar PV when combined with high value crop cultivation. The life cycle analyses indicate that small-scale dual land-use systems are economically viable in certain configurations and have the potential to provide several co-benefits including rural electrification, retrofitting diesel electricity generation, and electricity for processing agricultural products locally. A hypothetical full-density off-grid solar PV for a model village in Indonesia shows that electricity output (1907.5 GJ yr-1) is much higher than the total residential consumption (678 GJ yr-1), highlighting the opportunity to downscale the PV infrastructure by half to lower capital cost, to co-locate crops, and to support secondary income generating activities. Economic analysis shows that the 30-year net present cost of electricity from the half-density co-located PV system (12,257 million IDR) is significantly lower than that of the flat cost of diesel required to generate equivalent electricity (14,702 million IDR). Our analysis provides insights for smarter energy planning by optimizing the efficiency of land use and limiting conversion of agricultural and forested areas for energy production.

agrivoltaics↗
NASA NTRS1978

Helicopter internal noise reduction research and development application to the SA 360 and SA 365 Dauphin

Noise sources inside helicopter cabins are considered with emphasis on the mechanisms of vibration generation inside the main gear box and mechanisms of transmission between source and cabin. The dynamic behavior of the main gear box components is examined in relation to the transfer of vibration energy to the structure. It is indicated that although improvements can be made in noise reduction at the source, a soundproofing treatment isolating the passenger from the noise source is necessary. Soundproofing treatments installed and optimized include: (1) an acoustic screen using the weight effect to isolate the passenger from the noise source; (2) a damping treatment to limit the conversion of the vibratory energy into acoustic energy; and (3) an absorbing treatment achieved either through HELMHOLTZ resonators or through a glass wool blanket to limit the propagation of acoustic waves and the wave reflection effects in the cabin. The application of treatments at the source and the optimization of the sound barriers improved the noise level by about 30 db.

Marze, H. J.↗
DOE OSTI2020

Innovative Pathways: Transforming Impact Investments to Working Capital For Early Stage Cleantech Companies: Los Angeles Cleantech Incubator (January 1, 2020 to March 31, 2020)

Project Objectives: The focus for the entirety of the last quarter was on the completion of the pilot loan funding within our portfolio, and the closing out of our DOE-CAP Grant: “Innovative Pathways: Transforming Impact Investments to Working Capital for Early Stage Cleantech Companies.” The fourteenth quarter (Q14) of the program performance was also dedicated toward two main activities: the continued fundraising efforts for a formalized LACI debt fund, as well as finalization of the lending processes for pilot underwriting amongst the LACI Team and with Mission Driven Finance. This quarter marked key successes around the workflows of the DOE-CAP grant, specifically around fund capitalization efforts. Activities during the thirteenth quarter included: 1. Finalization of the DOE-CAP grant activities and work-flows; 2. Due diligence, underwriting and issuance of one (1) loan in Q1 2021 and three (3) in Q4 2020 for technology providers in grant-funded zero emissions mobility & community pilots, in partnership with LACI and local organizations, totaling ten (10) total loans; 3. Development of fundraising and marketing materials, and distribution to 30+ possible funding sources over the course of Q13 & Q14; and 4. Reinvigoration of conversations with Mission Driven Finance, the prospective underwriting partner for key activities and governance documents, and finalization of all loan processing activities once the fund is capitalized

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2022

Solar cell efficiency tables (Version 61)

Abstract Consolidated tables showing an extensive listing of the highest independently confirmed efficiencies for solar cells and modules are presented. Guidelines for inclusion of results into these tables are outlined, and new entries since July 2022 are reviewed. Graphs showing progress with each cell technology over the 30‐year history of the tables are also included plus an updated list of designated test centres.

14 SOLAR ENERGY↗
DOE OSTI2026

Characterization of Low-energy Ionization Signals in Silicon Detectors for the Nab Experiment

The Nab (Neutron a b) experiment is designed to measure the beta-antineutrino angular correlation in free neutron 𝛽 decay with an ultimate precision goal of 0.1%, providing input for tests of Cabibbo-Kobayashi-Maskawa matrix unitarity. This measurement is performed via detection of electrons and protons in delayed coincidence using custom large-area segmented silicon detectors. We present the characterization of one such detector system to establish the proton energy and timing response, using a dedicated proton accelerator. The detected proton peak was studied for 25, 30, and 35 keV incident protons on a set of detector segments and multiple cooling cycles over a one-year period. Ionization losses were consistent with models of the detector dead layer with thicknesses less than 100 nm. The detected proton peak was stable within the uncertainty from energy calibration (0.25 keV). The rise times of detector pulses from 109Cd and 113Sn conversion electron sources were used to extract the impurity density profile and establish a precise model for the detector timing response. The observed impurity density profile varied from (2±2)×109/cm3 at the center to (26±2)×109/cm3 at the edge. This impurity density profile was then used to characterize systematic effects in proton time-of-flight measurements due to detector pulse-shape effects; the resultant proton timing systematic uncertainties were below 0.3 ns, which is sufficient for the Nab experiment.

Taylor, RJ [North Carolina State University]↗
DOE OSTI2023

Enzyme-assisted liquefaction for different fractions of corn stover pellets

With an increase in population, the world will depend on renewable sources to meet the increasing energy needs. The use of lignocellulosic biomass as a renewable source has been proven efficient for conversion to cellulosic ethanol and capable of contributing to thresholds for energy demand while reducing greenhouse gases by 90% when compared with fossil fuels. However, limitations in feeding and flow within biorefineries are encountered when system plugging occurs due to biomass compaction and a high yield stress for slurries formed during its processing. Furthermore, differences in the biomass source present a challenge to the continuity of operations and reliability in the process. This work explores enzyme-assisted liquefaction for solid loadings up to 30% as an alternative for the creation of slurry from two different types of biomass (pelleted corn stover and cobs) that were liquefied in a fed-batch process using commercial enzymes Celluclast 1.5L or Ctec-2 at 1FPU/g or 3 FPU/g of dry solids in a 10 mM sodium citrate buffer solution (pH 4.8). Pellets were fed into a 1 L stirred bioreactor according to a predefined fed-batch protocol during the first 5 hours until 30% solid loading was reached. After 6, 24 and 96 hours, samples were taken and characterized with respect to their composition, rheology, and water absorption. Successful slurry creation with dramatically reduced yield stress was achieved for corn stover for both enzymes assessed. Yield stresses of 178±7 Pa (3 FPU, Celluclast 1.5L) and 79±6 Pa (3 FPU, Ctec-2) were measured for corn stover at 24 hours, compared to 6,000 Pa for samples without enzyme. Yield stress was 155± 29 Pa (3FPU, Ctec-2) and 257 ± 72 Pa (1 FPU, Celluclast 1.5L) for corn cobs at 24 hours. A profile for 6, 24 and 96h of yield stress measurements and sugar conversion is presented.

Gutierrez, Diana↗
DOE OSTI2024

Simple and Scalable Process for Nanocellulose Production from Residues and Waste (CRADA Final Report)

This project successfully developed an innovative, cost-effective, and scalable method for converting low-cost agricultural waste feedstocks into nanocellulose—a sustainable material with wide-ranging industrial applications. It addressed the critical challenges of high production costs and limited global supply, which have hindered the widespread adoption of nanocellulose in industry. Through this work, significant advancements were made in optimizing resource use, improving process efficiency, and reducing costs. Notable achievements included a 50% reduction in water usage, 30% lower chemical consumption, and 20% energy savings, all while maintaining high-quality product standards. The technical feasibility of the process was further validated at a 10L scale in collaboration with the Advanced Biofuels and Bioproducts Development Unit (ABPDU), demonstrating scalability and replicability. Key challenges in reducing nanocellulose production costs were addressed by utilizing low-cost biomass feedstocks and implementing low-temperature conversion reactions, leading to lower capital and operating expenses. The project also mitigated financial risk by generating critical data on the feasibility, adaptability, and scalability of the conversion technology, paving the way for its commercial implementation. Public benefits include advancing the circular bioeconomy, reducing environmental impact, fostering job creation, and enabling a shift toward biobased materials as sustainable alternatives to fossil-based products. These outcomes align closely with national goals to reduce greenhouse gas emissions and promote sustainable technological innovation.

09 BIOMASS FUELS↗