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At least 91 records · Page 5

Laser flash photolysis of ozone - O/1D/ quantum yields in the fall-off region 297-325 nm

The wavelength dependence of the quantum yield for O(1D) production from ozone photolysis has been determined between 297.5 nm and 325 nm in order to resolve serious discrepancies among previous studies. The results of this investigation are compared to earlier work by calculating atmospheric production rate constants for O(1D). It is found that for the purpose of calculating this rate constant, there is now good agreement among three studies at 298 K. Furthermore, it appears that previous data on the temperature dependence of the O(1D) quantum yield fall-off is adequate for determining the vertical profile of the O(1D) production rate constant. Several experimental difficulties associated with using NO2(asterisk) chemiluminescence to monitor O(1D) have been identified.

Brock, J. C.↗

DeCoM Validation

Deepak Condenser Model (DeCoM) was validated in a two-step process. The first step validated DeCoM/TTH/FloCAD against a simplified 1D (1D fluid flow and 1D heat flow) scenario. Through this simplification the fluid calculations were simple enough that the results were comparable to hand calculations. Once a method was compared against 1D case, the next step was the verification against a 2D test case. 2D is only for heat flow, while the fluid flow is still 1D. The test data was obtained from the project Geoscience Laser Altimeter System (GLAS) which performed a Looped Heat Pipe (LHP) test and contained necessary condenser information; such as a test point and condenser configuration. From the GLAS LHP test report, the construction of the LHP condenser and correlation was roughly possible. The assumptions and limitations are discussed, within this paper, of the 2D correlation. The success of DeCoM is illustrated by the results after correlation to the test data. Results show the differences between the model and the test setup, as well as explaining the probable cause for the differences; another set of results were produced after taking into account these differences, such as parasitic heat leak. Substantial effort has been made in listing the possibilities to further develop DECOM, thus to make it more reliable, user-friendly, and better integrated with generic SINDA models. The comparison of DeCoM to FloCAD and TTH LHP should not be taken as a definite answer to choosing DeCoM as a condenser modeler, rather as an alternate to obtaining preliminary results without the complexity of TTH LHP and license of FloCAD.

Patel, Deepak↗

Steady and Unsteady Nozzle Simulations Using the Conservation Element and Solution Element Method

This paper presents results from computational fluid dynamic (CFD) simulations of a three-stream plug nozzle. Time-accurate, Euler, quasi-1D and 2D-axisymmetric simulations were performed as part of an effort to provide a CFD-based approach to modeling nozzle dynamics. The CFD code used for the simulations is based on the space-time Conservation Element and Solution Element (CESE) method. Steady-state results were validated using the Wind-US code and a code utilizing the MacCormack method while the unsteady results were partially validated via an aeroacoustic benchmark problem. The CESE steady-state flow field solutions showed excellent agreement with solutions derived from the other methods and codes while preliminary unsteady results for the three-stream plug nozzle are also shown. Additionally, a study was performed to explore the sensitivity of gross thrust computations to the control surface definition. The results showed that most of the sensitivity while computing the gross thrust is attributed to the control surface stencil resolution and choice of stencil end points and not to the control surface definition itself.Finally, comparisons between the quasi-1D and 2D-axisymetric solutions were performed in order to gain insight on whether a quasi-1D solution can capture the steady and unsteady nozzle phenomena without the cost of a 2D-axisymmetric simulation. Initial results show that while the quasi-1D solutions are similar to the 2D-axisymmetric solutions, the inability of the quasi-1D simulations to predict two dimensional phenomena limits its accuracy.

Nozzle gross thrust calculations↗

CO2 photodissociation and vibrational excitation in the planetary atmospheres

The principal subjects of investigation were the determination of the CO2 photodissociation quantum yields at the wavelengths from 1200 A to 1500 A, and the efficiency of electronic-to-vibrational energy transfer in the systems 0(1D) + CO, N2, CO2 yields 0(3P) + CO N2, CO2 vibrational energies. Measurements on the photodissociation quantum yield of CO2 in the 1200-1500 A region show that it is wavelength dependent, and for the six atomic line sources used, the quantum yield varied from 0.2 to 0.8. The data appear to fit the interpretation of stable CO2 bound states mixed with repulsive or predissociating states, since the low quantum yields coincide with the maximum structure in the CO2 absorption spectrum. The first reliable measurements were made on the efficiency of electronic-to-vibrational energy transfer in the systems 0(1D)-CO and 0(1D)-N2, using a uv resonance fluorescence technique. The 0(1D)-CO2 interaction was investigated by infrared techniques.

Slanger, T. G.↗

Absolute rate constant determinations for the deactivation of O/1D/ by time resolved decay of O/1D/ yields O/3P/ emission

Absolute rate constants for the deactivation of O(1D) atoms by some atmospheric gases have been determined by observing the time-resolved emission of O(1D) at 630 nm. O(1D) atoms were produced by the dissociation of ozone via repetitive laser pulses at 266 nm. Absolute rate constants for the relaxation of O(1D) at 298 K are reported for N2, O2, CO2, O3, H2, D2, CH4, HCl, NH3, H2O, N2O, and Ne. The results obtained are compared with previous relative and absolute measurements reported in the literature.

Davidson, J. A.↗

Destruction of N/2D/ by O2 - A major source of 6300 A dayglow emission

The paper discusses the N(2D) + O2 yields NO + O(1D), for k1 reaction, and examines under different geophysical conditions, the effect of this source of 6300 A surface brightness on the dayglow redline. In calculating the 6300 A volume emission rate, a computer code is used which provides the thermal electron density, photoelectron flux, ion concentrations, electron and ion temperatures and odd nitrogen densities required to evaluate the O(1D) sources and sinks. It is found that under most conditions this source is the dominant mechanism responsible for the production of the 6300 A dayglow above 150 km. The volume emission rate of this source in summer is 2.5 times larger than the sum of all other sources at 180 km, and 1.5 times as large in winter. In addition, when the N(2D) source of O(1D) is taken into account, the rate coefficient for quenching of O(1D) by N2 is estimated to be 4 plus or minus 1 x 10 to the -11th cu cm per sec.

Torr, D. G.↗

The role of metastable species in the thermosphere

Metastable excited states of various ions and neutrals in the thermosphere provide reservoirs for the temporary storage of a large portion of solar EUV energy, and permit the conversion of this photon energy by kinetic or vibrational heating, ion formation metastable species formation and nonlocal energy deposition. The present paper reviews current understandings of the chemistry of O(1D), O(1S), O(+)(2D), O(+)(2P), N(2D), N(2P), N(+)(1S), N(+)(1D), NO(+)(a), O2(+)(a), N2(A) and the vibrationally excited states of O2, N2, O2(+) and N2(+). The role of these species in the overall thermospheric energy budget and ionization balance is also quantified. It is noted that of the species considered, O(1D), O(1S), O(+)(1S), O(+)(2D), N(2D), N2(A) and the vibrationally excited states of the oxygen and nitrogen molecules are most significant, with a major fraction of the kinetic heating of the thermosphere taking place through O(1D).

Torr, M. R.↗

CFD Analysis of Thermal Control System Using NX Thermal and Flow

The Thermal Control Subsystem (TCS) is a key part of the Advanced Plant Habitat (APH) for the International Space Station (ISS). The purpose of this subsystem is to provide thermal control, mainly cooling, to the other APH subsystems. One of these subsystems, the Environmental Control Subsystem (ECS), controls the temperature and humidity of the growth chamber (GC) air to optimize the growth of plants in the habitat. The TCS provides thermal control to the ECS with three cold plates, which use Thermoelectric Coolers (TECs) to heat or cool water as needed to control the air temperature in the ECS system. In order to optimize the TCS design, pressure drop and heat transfer analyses were needed. The analysis for this system was performed in Siemens NX Thermal/Flow software (Version 8.5). NX Thermal/Flow has the ability to perform 1D or 3D flow solutions. The 1D flow solver can be used to represent simple geometries, such as pipes and tubes. The 1D flow method also has the ability to simulate either fluid only or fluid and wall regions. The 3D flow solver is similar to other Computational Fluid Dynamic (CFD) software. TCS performance was analyzed using both the 1D and 3D solvers. Each method produced different results, which will be evaluated and discussed.

CFD↗

Uncertainty Analysis of Coaxial Thermocouple Calorimeters Used in Arc Jets

Recent introduction of Coaxial Thermocouple type calorimeters into the NASA Ames arc jet facilities has inspired an analysis of 2D conduction effects internal to this type of calorimeter. Lateral conduction effects violate the 1D finite slab inverse analysis which is typically used to deduce the heat transfer to such calorimeters. The spherical shaped nose associated with most calorimeters (rather than flat) leads to a bias error that over-estimates the stagnation heating. Non-uniform heating on the face of spherically shaped calorimeters leads to conduction losses to the colder rim of the calorimeter which causes an underestimate of the stagnation heating. These two effects come into play at different times of the calorimeter's exposure to the arc jet, so they do not cancel. The spherical body effects come into play in the early stages of exposure, while the non-uniform heating effect becomes most severe at the later stages of exposure. The bias associated with spherical effects can be avoided by rewriting the 1D finite slab inverse analysis code to solve for 1D conduction in spherical coordinates. However, reducing the bias error associated non-uniform heating requires a somewhat ad hoc modification to the 1D finite element inverse analysis.

Isotherms↗

Pterodactyl: Effects of 3D Thermal Analysis on Thermal Protection System Design for a Flap Control System

NASA’s Pterodactyl project has investigated the use of a novel multi-flap control system to facilitate precision targeting of Deployable Entry Vehicles (DEVs) during atmospheric re-entry [1]. DEVs can be folded to fit within the limiting cross-sectional area of current launch systems. Once deployed, the vehicle expands and settles into a pre-determined blunt body shape. While DEVs provide a more efficient solution to increased payload sizes, the absence of a back shell does not allow for easy integration of reaction control systems, which have historically been used for guidance and control (G&C) of rigid aeroshells during entry. One DEV solution, called the Adaptable, Deployable Entry Placement Technology (ADEPT), employs mechanically deployed gores. This provided the Pterodactyl project with the opportunity to incorporate a rib-mounted, 8-flap control system for G&C. Each flap can deflect independently in and out of the hypersonic flow, requiring TPS for the flaps. Previous work within the Pterodactyl project utilized 1D thermal analysis to design the TPS. However, the Pterodactyl project was concerned that the base level tools for 1D thermal analysis were not accounting for the 3D effects of the large heating gradients along and across the flaps, the in-depth in-plane conductivity of the TPS and internal structure, and the effects of the small edge radii at the neck of the flaps. This paper discusses the methodology and results of a 3D thermal analysis of the flap control system. Additionally, the results from the 1D and 3D thermal analyses are compared. It is found that elements of the original design that resulted from the 1D analysis may be overly conservative, and implementation of a 3D thermal analysis indicated a reduction in TPS thickness is feasible. This result helps to reduce the mechanical integration complexity of the flap at the rib tip and realizes potential mass savings.

Sarah N D'Souza↗

Measurement of tropospheric 300 nm solar ultraviolet flux for determination of O/1D/ photoproduction rate

The tropospheric importance of the OH radical, and the reaction scheme that leads to its formation, are now being widely investigated. Ozone photolysis at wavelengths no greater than 318 nm produces O(1D), a small fraction of which then reacts with water vapor to yield OH. Although experimental data are available for the O(1D) quantum yield, as well as the O3 absorption cross section, all previous tropospheric photochemical models have had to use theoretical calculations to determine the UV flux. Discussed in this paper are aircraft spectral measurements of the solar UV flux at two altitudes - 2 and 6 km. These results have been compared with three theoretical approaches. The measured experimental fluxes have been combined here with recent quantum yield data to calculate the O(1D) photoproduction rate for various albedo values. This rate is larger than that used in models by about a factor of 2 for reasonable values of assumed albedo.

Sellers, B.↗

The reaction of N/2D/ with O2 as a source of O/1D/ atoms in aurorae

The source of O(1D) atoms in the auroral ionosphere is investigated using sounding rocket data. Previously, it has been shown that the conventional sources of O(1D) atoms in the aurora, dissociative recombination of O2(plus) and electron impact excitation of atomic oxygen, fail to explain the measured 6300 A volume emission rate profile. It is suggested that the atom-atom interchange reaction of N(2D) with O2 can be the major source of auroral 6300 A emission if O(1D) is created with high efficiency.

Rusch, D. W.↗

Fabry-Perot ground-based observations of comets and the Jupiter plasma torus

The Wisconsin 150 mm dual etalon Fabry-Perot spectrometer is a powerful instrument for the study of diffuse emission sources such as cometary atmospheres, the Jupiter plasma torus, and various emission nebulae. Since 1985, researchers have concentrated their efforts on extensive observations of Comet Halley and the analysis of the data. Images of Comet Halley in (OI)6300 Angstrom emission were analyzed to obtain the spatial distribution of O(1D) in the cometary atmosphere. The narrow spectral bandpass of the Fabry-Perot (0.2 Angstrom) eliminated contamination from terrestrial airglow (OI)6300 and cometary NH2 lines in the nearby spectrum. The results were modelled to provide photodestruction lifetimes of cometary Water abd OH, the predominant parents of O(1D). The Fabry-Perot was also used in the scanning mode to obtain measurements of (OI)6300 and Balmer alpha emissions which were used to determine the H, O(1D) and water production rates as a function of heliocentric distance, both pre-perihelion and post-perihelion. Researchers also analyzed high resolution spectra of the NH2 (0,8,0) band in the 6300 Angstrom region to obtain preliminary values of the NH2 production rate. Assuming NH3 is the major parent of NH2, researchers found that the abundance ratio NH3/water is about (0.12 plus or minus 0.04 percent), assuming thermal equilibrium for the level populations of NH2.

Scherb, Frank↗

The 630 nm dayglow

The daytime thermospheric emission at 630 nm from the (3P-1D) transition of atomic oxygen is examined using data from the Atmosphere Explorer C and E spacecraft. Observed altitude distributions of the emission rate measured using the Visible Airglow Experiment are compared with those calculated from in situ measurements of ion and neutral densities and temperatures, and from a model of the photon and photoelectron flux. Good agreement is obtained for most orbits with photoelectron impact on O, photodissociation of O2, and dissociative recombination of O2(+) providing most of the production. Implications for some of the controversial points of O(1D) chemistry, such as the solar EUV and Schumann-Runge continuum flux, the yield of O(1D) from the reaction of N(2D) with O2, the value of spontaneous transition coefficients, and the rate of quenching by O(3P) are discussed.

Solomon, Stanley C.↗

Protostellar formation in rotating interstellar clouds. VIII - Inner core formation

The results are presented of a variety of spherically symmetric one-dimensional (1D) calculations intended to determine the robustness of the dynamical hiccup phenomenon in protostellar cores. The 1D models show that the phenomenon is relatively insensitive to changes in the equations of state, numerical resolution, initial density and temperature, and the radiative transfer approximation. In 1D, the hiccup results in an explosive destruction of the entire inner protostellar core. Inner core formation is studied with a sequence of three-dimensional models which show that rapid inner core rotation stabilizes the hiccup instability. Instead, the inner core becomes quite flat and undergoes a cycle of binary fragmentation, binary decay into a single object surrounded by a bar, breakup of the bar into a binary, etc. When lesser amounts of rotation are involved, the inner core does hiccup somewhat, but mass is ejected in only a few directions, leading to several broad streams of ejecta.

Boss, Alan P.↗

High-resolution spectra of the 6300-A region of Comet P/Halley

Echelle/reticon high resolution spectra have been obtained for the 6300-A region of P/Halley which show a clear separation in the relative contributions of the various rotational lines of the (0,8,0) band of NH2 and of the cometary and airglow contributions of O(1D). An analysis of these data indicates that the vibrational structure of the band could be useful as a diagnostic for coma temperatures and/or outflow kinematics. The inner radial brightness distribution for O(1D) is found to be in keeping with production by H2O parent-molecule dissociation; O(1D) also exhibited a detectable deviation from circular symmetry.

Combi, Michael R.↗

Spectrographic observation at wavelengths near 630 nm of the interaction between the atmosphere and the Space Shuttle exhaust

The interaction between the Space Shuttle exhaust and the ambient atmosphere was studied using spectra in the wavelength region near 630 nm, obtained from the Air Force Maui Optical Station were the temporal, spatial, and spectral distribution of the emission in this region was recorded. The results show that, when the Space Shuttle exhaust gases interact with the atmosphere in the ram direction, an intense long-lasting emission is generated at 630 nm due to O(1D - 3P). A substantial amount of O(1D) is swept back onto the orbiter. Two processes responsible for the formation of O(1D) are proposed.

Broadfoot, A. L.↗

Influence of Subpixel Scale Cloud Top Structure on Reflectances from Overcast Stratiform Cloud Layers

Recent observational studies have shown that satellite retrievals of cloud optical depth based on plane-parallel model theory suffer from systematic biases that depend on viewing geometry, even when observations are restricted to overcast marine stratus layers, arguably the closest to plane parallel in nature. At moderate to low sun elevations, the plane-parallel model significantly overestimates the reflectance dependence on view angle in the forward-scattering direction but shows a similar dependence in the backscattering direction. Theoretical simulations are performed that show that the likely cause for this discrepancy is because the plane-parallel model assumption does not account for subpixel, scale variations in cloud-top height (i.e., "cloud bumps"). Monte Carlo simulation, comparing ID model radiances to radiances from overcast cloud field with 1) cloud-top height variation, but constant cloud volume extinction; 2) flat tops but horizontal variations in cloud volume extinction; and 3) variations in both cloud top height and cloud extinction are performed over a approximately equal to 4 km x 4 km domain (roughly the size of an individual GAC AVHRR pixel). The comparisons show that when cloud-top height variations are included, departures from 1D theory are remarkably similar (qualitatively) to those obtained observationally. In contrast, when clouds are assumed flat and only cloud extinction is variable, reflectance differences are much smaller and do not show any view-angle dependence. When both cloud-top height and cloud extinction variations are included, however, large increases in cloud extinction variability can enhance reflectance difference. The reason 3D-1D reflectance differences are more sensitive to cloud-top height variations in the forward-scattering direction (at moderate to low, sun elevations) is because photons leaving the cloud field in that direction experience fewer scattering events (low-order scattering) and are restricted to the topmost portions of the cloud. While reflectance deviations from 1D theory are much larger for bumpy clouds than for flat clouds with variable cloud extinction, differences in cloud albedo are comparable for these two cases.

Loeb, N. G.↗