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At least 883 records · Page 49

Fluorescent air leakage detection system for enclosures

Provided is a Fluorescent Air Leakage Detection (FALD) system and method for locating a defect in an enclosure that uses a nontoxic fluorescent solution as a marker. The solution is aerosolized with an atomizing device and guided to defects by a gas pressure modifying device. Defects are visually located by surveying the enclosure with an ultraviolet or visible light source and identifying a location where accumulated solution fluoresces.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Efficiency Improvement Progress in Green, Yellow and Red III Nitride LEDs

Large improvements in the efficiencies of visible light emitting diodes (LEDs) have been realized over the last decade. Extending the range of wavelengths over which efficient emission can be realized continues to be a goal of active research. Efficiency droop refers to a non-thermal decrease in internal quantum efficiency with increasing current density that affects III-nitride LEDs in general, but more severely those with longer emission wavelengths. The so-called green gap is mainly related to the wavelength dependence of efficiency droop. The peak EQE in commercial green LEDs exceeds 60% but corresponds to a current density that is an order of magnitude lower than required for applications. In this presentation, we will review some of the underlying physics that contribute to the wavelength dependence of droop. We will discuss some challenges in the development of long wavelength III-nitride LEDs and possible strategies to mitigate efficiency droop based on the understanding that nonradiative Auger recombination is the root cause. One general strategy is to engineer the multi-quantum well active region to minimize the average carrier density. Another approach is to design wells with a more favorable balance between the radiative and Auger coefficients. Finally, we will present the current status of the performance of green, yellow and red III-Nitride LEDs.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Neutron Scattering (NS) Spectroscopy

A wide range of advanced experimental methods has been used in catalysis science to understand chemical transformations at molecular level. Among these, neutron scattering not only gives catalytic information that is highly complementary to other microscopic scattering techniques such as electrons (microscopy and diffraction) and photons from visible light to synchrotron X-rays but also often provides unique insights into catalysis. This chapter aims to provide a general overview of neutron scattering and its applications for heterogeneous catalysis, emphasizing chemistry at the gas/solid interface. It starts with an introduction to the theory of neutron scattering, with pros and cons for catalyst research, followed by a description of three main neutron scattering techniques: neutron diffraction (ND), inelastic neutron spectroscopy (INS), and quasi-elastic neutron scattering (QENS). It includes recent applications in each technique and then a short introduction of other neutron techniques that are less frequently used in the catalysis field. It ends with a summary and a future outlook.

Braatz, Jisue↗

Compositions with doped titanium dioxide nanoparticles and methods of use

A dental composition comprising doped T1O2 nanoparticles, and a curable resin material, wherein the curable resin material comprises a polymer precursor component, and wherein the dopant may be one or more of, for example, N (nitrogen), Ag (silver), F (fluorine), P (phosphorus), and P04 (phosphate). A method of using the dental composition in a dental application. The dental composition may be antibacterial in the absence of visible light or UV light.

Florez, Fernando Luis Esteban↗

Transmissive concentrated photovoltaic module with cooling system

A spectrum splitting, transmissive concentrating photovoltaic (tCPV) module is proposed and designed for a hybrid photovoltaic-solar thermal (PV/T) system. The system may be able to fully utilize the full spectrum of incoming sunlight. By utilizing III-V triple junction solar cells with bandgaps of approximately 2.1 eV, 1.7 eV, and 1.4 eV in the module, ultraviolet (UV) and visible light (in-band light) are absorbed and converted to electricity, while infrared (IR) light (out-of-band light) passes through and is captured by a solar thermal receiver and stored as heat. The stored heat energy may be dispatched as electricity or process heat as needed. The tCPV module may have an overall power conversion efficiency exceeding 43.5% for above bandgap (in-band) light under a standard AM1.5D solar spectrum with an average concentration ratio of 400 suns. Passive and/or active cooling methods may be used to keep cells below 110° C. while transmitting >75% of out-of-band light to the thermal receiver, which may attain thermal energy capture at temperatures as high as 500° C. or more. A transparent active cooling system may improve the CPV module efficiency by about 1% (absolute) relative to a passive cooling system by reducing the maximum cell working temperature by about 16° C.

Escarra, Matthew David↗

Temporal light modulation: A phantom array visibility measure

At temporal light modulation (TLM) frequencies between 80 Hz and 20 000 Hz observers may perceive a series of repeated images called the phantom array effect (PAE) when they move their eyes in large saccades across a modulating light source or across a scene lit by the modulating light source. To date, there is no well-established measure for quantifying PAE visibility, but there is growing awareness of the need for one among design professionals and sensitive populations. This paper documents a new measure, the phantom array visibility measure (PAVM), which is based on the results of recent human factors experiments. The measure follows the mathematical underpinning used by the flicker visibility measure and the stroboscopic visibility measure, where the time-domain TLM waveform is converted into its Fourier frequency components; each component is evaluated through a threshold curve of modulation depth, then summed through an equation employing a Minkowski exponent. This scales the PAVM so that a value of 1 indicates a waveform at a threshold visibility in the conditions of the underlying experiment.

Tan, J.↗

Systems and Methods for Automated Water Detection Using Visible Sensors

Systems and methods are disclosed that include automated machine vision that can utilize images of scenes captured by a 3D imaging system configured to image light within the visible light spectrum to detect water. One embodiment includes autonomously detecting water bodies within a scene including capturing at least one 3D image of a scene using a sensor system configured to detect visible light and to measure distance from points within the scene to the sensor system, and detecting water within the scene using a processor configured to detect regions within each of the at least one 3D images that possess at least one characteristic indicative of the presence of water.

Rankin, Arturo L.↗

Differences in visible and near-infrared light reflectance between orange fruit and leaves

The objective was to find the best time during the season (April 26, 1972 to January 8, 1973) to distinguish orange fruit from leaves by spectrophotometrically determining at 10-day intervals when the difference in visible (550- and 650-nm wavelengths) and near-infrared (850-nm wavelength) light reflectance between fruit and nearby leaves was largest. December 5 to January 8 was the best time to distinguish fruit from leaves. During this period the fruit's color was rapidly changing from green to yellow, and the difference in visible light reflectance between fruit and leaves was largest. The difference in near-infrared reflectance between leaves and fruit remained essentially constant during ripening when the difference in visible light reflectance between leaves and fruit was largest.

Gausman, H. W.↗

Design of 3D Oxide–Metal Hybrid Metamaterial for Tailorable Light–Matter Interactions in Visible and Near-Infrared Region

Dielectric–metallic hybrid metamaterials exhibit extraordinary optical properties due to the light–matter interactions at the dielectric–metallic interfaces. The ability in precision control of the light–matter interactions in nanoscale is key to tailor the optical properties of hybrid metamaterials. In this work, a complex 3D framework of multilayered self-assembled BaTiO 3 (BTO)-Au hybrid thin films is demonstrated with such precision control of the light–matter interaction in nanoscale. Here, unique “bamboo-like” Au nanostructures are formed via the bilayer and trilayer stacking of BTO-Au hybrid layers with interlayers of SrTiO 3 , CeO 2 , or MgO. Different film strain states introduced by the three interlayers result in variable diameter and density of Au nanopillars. Both simulated and experimental optical data demonstrate the localized surface plasmon resonance change and hyperbolic dispersion wavelength shift in visible to near-infrared because of the effective tuning of the Au nanopillar aspect ratio and free electron density. The highly tunable optical properties along with the ferroelectric behavior and thermal robustness of the 3D hybrid film enable it to be a great candidate for multifunctional applications. This study demonstrates a unique 3D approach for precision optical property tuning and combined functionalities in oxide–metal metamaterial systems toward future integrated photonic and electronic devices.

36 MATERIALS SCIENCE↗

UV–Visible reflectance of common light reflectors and their degradation after an ionization dose up to 100 Mrad

We report light reflectors are widely used to enhance scintillation light collection. Their enhancement level depends on the reflector’s reflectance at the scintillator’s emission wavelength. We report UV–Visible reflectance spectra, relative to BaSO 4 , for several common reflectors. Also reported is their radiation hardness against an ionization dose up to 100 Mrad. The results of this investigation provide a reference for applications of these reflectors in a severe radiation environment.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Countrywide LED Lighting Retrofit for Safety, Visibility, and Energy Efficiency (Final Technical Report)

The project supported national clean energy goals by reducing electricity demand and improving energy efficiency in public infrastructure. Tasks defined in the Statement of Project Objectives included site assessments, retrofit planning, lighting design optimization, installation, monitoring, and reporting. All milestones and go/no-go decision points were successfully met.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Lighting factors affecting the visibility of a moving display.

Compensatory tracking performance was shown to be substantially degraded by oscillation of the visual display at both 1.0 and 2.0 Hz. The severity of this decrement was altered significantly by changes in both the color and the intensity of the display illumination. Performance was significantly better with red light illuminating the display at 0.05 mL than with blue light at the equivalent luminance. This improvement in performance was similar in magnitude to that found for an increase in broad-band illumination of the display where luminance was increased from 1/2 log unit below to 1/2 log unit above 0.05 mL. Visual mechanisms that may have been responsible for these findings are suggested.

Gilson, R. D.↗

Surface Tagging of Al 6061-T6 using Photoluminescent Oxides

The goal of tagging nuclear fuels (or related materials, such as fuel cladding) is to provide a persistent marker, traceable to the fuel manufacturer, that can be detected after some length of time, likely after the fuel has been lost, rerouted, or partially destroyed. Ideally, the tag is complicated enough to encode data pertaining to the provenance (manufacturer, date or time, constituents, etc.) and robust enough to survive in-pile exposure and/or further destruction. The taggant should not change the behavior or performance of the fuel in any meaningful way. Photoluminescent tagging was an attractive solution to many of these challenges, as it is undetectable under normal lighting conditions, visible to the naked eye under specific lighting conditions, does not require a significant quantity of material to be photoluminescent, observable with simple commercial detection tools, and is versatile and robust in application. In FY23, the team focused on embedding photoluminescent taggants onto the replicate fuel cladding surface using welding. From a welding standpoint, photoluminescent taggants, in the form of oxides, are a viable option for tagging because the taggants have high melting points, and thus likely to survive welding temperatures (i.e., remain as a secondary phase particle and maintain luminescent properties). Additionally, these taggants have the potential to act as a metal matrix composite which may increase the strength-to-weight ratio, stiffness, and ductility of the base material, all beneficial to cladding and fuel performance.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

Wavelength independent interferometer

A polychromatic interferometer utilizing a plurality of parabolic reflective surfaces to properly preserve the fidelity of light wavefronts irrespective of their wavelengths as they pass through the instrument is disclosed. A preferred embodiment of the invention utilizes an optical train which comprises three off-axis parabolas arranged in conjunction with a beam-splitter and a reference mirror to form a Twyman-Green interferometer. An illumination subsystem is provided and comprises a pair of lasers at different preselected wavelengths in the visible spectrum. The output light of the two lasers is coaxially combined by means of a plurality of reflectors and a grating beam combiner to form a single light source at the focal point of the first parabolic reflection surface which acts as a beam collimator for the rest of the optical train. By using visible light having two distinct wavelengths, the present invention provides a long equivalent wavelength interferogram which operates at visible light wherein the effective wavelength is equal to the product of the wavelengths of the two laser sources divided by their difference in wavelength. As a result, the invention provides the advantages of what amounts to long wavelength interferometry but without incurring the disadvantage of the negligible reflection coefficient of the human eye to long wavelength frequencies which would otherwise defeat any attempt to form an interferogram at that low frequency using only one light source.

Hochberg, Eric B.↗

Infrared Light-Emitting Devices from Antenna-Coupled Luttinger Liquid Plasmons In Carbon Nanotubes

Electrically driven light-emitting devices provide highly energy-efficient lighting at visible wavelengths, and they have transformed photonic and electronic lighting applications. Efficient infrared light-emitting devices, however, have been challenging because band gap emission from semiconductors becomes inefficient in the mid-infrared to far-infrared spectral range. Here, in this paper, we investigate infrared light-emitting devices (IRLEDs) based on Luttinger liquid (LL) plasmons in one-dimensional (1D) metallic carbon nanotubes. Elementary excitations in LL are characterized by collective charge and spin excitations, i.e., plasmons and spinons. Consequently, electrons injected into the nanotubes transform efficiently into LL plasmons, a hybrid excitation of electromagnetic fields and electrons. We design nanoantennas coupled to the carbon nanotube to radiate LL plasmons into the far field. LL-based IRLEDs can be designed to selectively emit at wavelengths across the far- and mid-infrared spectra. An electrical-to-optical power conversion efficiency up to 3.2% may be achieved. Such efficient and narrowband LL-based IRLEDs can enable novel infrared nanophotonic applications.

36 MATERIALS SCIENCE↗

A Deeper Look at the Fundamentals of Heterodyne Detection Requirements

We generally accept the experimentally observed criteria for heterodyne detections that the two waves that are mixed must (i) be collinear, (ii) have matched wave fronts and (iii) cannot be orthogonally polarized. We have not found in the literature adequate physical explanations for these requirements. The purpose of this paper is to find deeper physical understanding of the coherent heterodyne detection processes that could lead to better coherent laser radar system designs1. We find that there are a number of unresolved paradoxes in classical and quantum optics regarding the definitions and understanding of the "interference" and "coherence" properties of light, which are attributed as essentially due to inherent properties of the EM waves. A deeper exploration indicates that it is the various quantum mechanical properties of the detecting material dipoles that make light detectable (visible, or measurable) to us. Accordingly, all the properties that we generally attribute to only light, are in reality manifestations of collective properties of dipole-light interactions. "Interference" and "coherence" can be better understood in terms of this mutual interaction, followed by energy absorption by the dipoles from EM wave fields, manifesting in some measurable transformation of the detecting dipoles. Light beams do not interfere by themselves. The superposition effects due to light beams become manifest through the response characteristics of the detecting dipoles. In this paper, we will show some preliminary expe rimental results that clearly demonstrate that the heterodyning wave fronts have quantitative degradation in signal generation as the angle between them deviates from perfect collinearity. Subsequently, we will propose a hypothesis for this behavior. We will present experimental data establishing that the so called incoherent light can be detected through heterodyne mixing as long as the pulse length contained in the "incoherent" light is longer than the response time of the detector. We will also present a correspondingly better interpretation of two distinguishable coherence properties, temporal coherence and spectral coherence. Our investigation provides a deeper insight into how to rela x various system requirements for heterodyne detection and accordingly develop systems that are simpler, more reliable and lower in cost. Also, we believe that engineering of detector architecture by appropriately modifying dipole behavior using emerging nanotechnology to optimize heterodyne efficiency will be advantageous.

Roychoudhuri, Chandrasekhar↗