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At least 883 records · Page 49

Time evolution of off-state degradation of AlGaN/GaN high electron mobility transistors

The evolution of AlGaN/GaN high electron mobility transistors under off-state stress conditions is studied by gate leakage current (I{sub g}) monitoring, electroluminescence (EL), and atomic force microscope (AFM) imaging at room temperature. It is found that the number of off-state failure sites as identified by EL increases over time during stress until it reaches a saturation value. I{sub g} increases accordingly during stress until this saturation number of failure sites is reached. AFM scanning of the device surface stripped of metal contacts and passivation reveals surface pits corresponding to the location of the EL spots. These pits have an elongated shape oriented towards the drain contact whose length is correlated with the distance to the adjacent pits and with the time since their appearance during the stress experiment. A model for the generation and evolution of the off-state stress-related failure sites is proposed consistent with the experimental results, bringing together surface migration of electrochemical species with trap-based leakage mechanisms and resulting in the formation of an exclusion zone around each failure site.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Plasma and radiation detection via fiber interferometry

Photonic Doppler velocimetry tracks motion during high-speed, single-event experiments using telecommunication fiber components. The same technology can be applied in situations where there is no actual motion, but rather a change in the optical path length. Migration of plasma into vacuum alters the refractive index near a fiber probe, while intense radiation modifies the refractive index of the fiber itself. Lastly, these changes can diagnose extreme environments in a flexible, time-resolved manner.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

GLOBAL DRAG-INDUCED INSTABILITIES IN PROTOPLANETARY DISKS

We use the Fokker-Planck equation and model the dispersive dynamics of solid particles in annular protoplanetary disks whose gas component is more massive than the particle phase. We model particle-gas interactions as hard sphere collisions, determine the functional form of diffusion coefficients, and show the existence of two global unstable modes in the particle phase. These modes have spiral patterns with the azimuthal wavenumber m = 1 and rotate slowly. We show that in ring-shaped disks, the phase-space density of solid particles increases linearly in time toward an accumulation point near the location of pressure maximum, while instabilities grow exponentially. Therefore, planetesimals and planetary cores can be efficiently produced near the peaks of unstable density waves. In this mechanism, particles migrating toward the accumulation point will not participate in the formation of planets, and should eventually form a debris ring like the main asteroid belt or classical Kuiper Belt objects. We present the implications of global instabilities to the formation of ice giants and terrestrial planets in the solar system.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

The nature of Hα-selected galaxies at z > 2. II. Clumpy galaxies and compact star-forming galaxies

We present the morphological properties of Hα-selected galaxies at z > 2 in SXDF-UDS-CANDELS field. With high-resolution optical/near-infrared images obtained by the Hubble Space Telescope, we identify giant clumps within the Hα emitters (HAEs). We find that at least 41% of our sample shows clumpy structures in the underlying disks. The color gradient of clumps is commonly seen in the sense that the clumps near the galactic center tend to be redder than those in the outer regions. The mid-infrared detection in galaxies with red clumps and the spatial distribution of Hα emission suggest that dusty star-formation activity is probably occurring in the nuclear red clumps. A gas supply to a bulge component through clump migration is one of the most potent physical processes for producing such dusty star-forming clumps and forming massive bulges in local early-type galaxies. They would become large quiescent galaxies at later times just by consumption or blowout of remaining gas. Also, while most of the HAEs have extended disks, we observe two massive, compact HAEs whose stellar surface densities are significantly higher. They are likely to be the direct progenitors of massive, compact quiescent galaxies at z = 1.5-2.0. Two evolutionary paths to massive quiescent galaxies are devised to account for both the size growth of quiescent galaxies and their increased number density from z ∼ 2 to z = 0.

79 ASTRONOMY AND ASTROPHYSICS↗

Mobility of Source Zone Heavy Metals and Radionuclides: The Mixed Roles of Fermentative Activity on Fate and Transport of U and Cr. Final Report

Various U. S. Department of Energy (DOE) low and medium-level radioactive waste sites contain mixtures of heavy metals, radionuclides and assorted organic materials. In addition, there are numerous sites around the world that are contaminated with a mixture of organic and inorganic contaminants. In most sites, over time, water infiltrates the wastes, and releases metals, radionuclides and other contaminants causing transport into the surrounding environment. We investigated the role of fermentative microorganisms in such sites that may control metal, radionuclide and organics migration from source zones. The project was initiated based on the following overarching hypothesis: Metals, radionuclides and other contaminants can be mobilized by infiltration of water into waste storage sites. Microbial communities of lignocellulose degrading and fermenting microorganisms present in the subsurface of contaminated DOE sites can significantly impact migration by directly reducing and immobilizing metals and radionuclides while degrading complex organic matter to low molecular weight organic compounds. These low molecular weight organic acids and alcohols can increase metal and radionuclide mobility by chelation (i.e., certain organic acids) or decrease mobility by stimulating respiratory metal reducing microorganisms. We demonstrated that fermentative organisms capable of affecting the fate of Cr6+, U6+ and trinitrotoluene can be isolated from organic-rich low level waste sites as well as from less organic rich subsurface environments. The mechanisms, pathways and extent of contaminant transformation depend on a variety of factors related to the type of organisms present, the aqueous chemistry as well as the geochemistry and mineralogy. This work provides observations and quantitative data across multiple scales that identify and predict the coupled effects of fermentative carbon and electron flow on the transport of radionuclides, heavy metals and organic contaminants in the subsurface; a primary concern of the DOE Environmental Remediation Science Division (ERSD) and Subsurface Geochemical Research (SBR) Program.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Real-time Microseismic Processing for Induced Seismicity Hazard Detection

Induced seismicity is inherently associated with underground fluid injections. If fluids are injected in proximity to a pre-existing fault or fracture system, the resulting elevated pressures can trigger dynamic earthquake slip, which could both damage surface structures and create new migration pathways. The goal of this research is to develop a fundamentally better approach to geological site characterization and early hazard detection. We combine innovative techniques for analyzing microseismic data with a physics-based inversion model to forecast microseismic cloud evolution. The key challenge is that faults at risk of slipping are often too small to detect during the site characterization phase. Our objective is to devise fast-running methodologies that will allow field operators to respond quickly to changing subsurface conditions.

15 GEOTHERMAL ENERGY↗

Report on in-situ studies of flash sintering of uranium dioxide

Flash sintering is a novel type of field assisted sintering that uses an electric field and current to provide densification of materials on very short time scales. The potential for field assisted sintering techniques to be used in producing nuclear fuel is gaining recognition due to the potential economic benefits and improvements in material properties. The flash sintering behavior has so far been linked to applied and material parameters, but the underlying mechanisms active during flash sintering have yet to be identified. This report summarizes the efforts to investigate flash sintering of uranium dioxide using dilatometer studies at Los Alamos National Laboratory and two separate sets of in-situ studies at Brookhaven National Laboratory’s NSLS-II XPD-1 beamline. The purpose of the dilatometer studies was to understand individual parameter (applied and material) effects on the flash behavior and the purpose of the in-situ studies was to better understand the mechanisms active during flash sintering. As far as applied parameters, it was found that stoichiometry, or oxygen-to-metal ratio, has a significant effect on the flash behavior (time to flash and speed of flash). Composite systems were found to have degraded sintering behavior relative to pure UO 2 . The critical field studies are complete for UO 2.00 and will be analyzed against an existing model for comparison. The in-situ studies showed that the strength of the field and current are directly related to the sample temperature, with temperature-driven phase changes occurring at high values. The existence of an ‘incubation time’ has been questioned, due to a continuous change in lattice parameter values from the moment that the field is applied. Some results from the in-situ experiments, which should provide evidence regarding ion migration, are still being analyzed. Some preliminary conclusions can be made from these results with regard to using field assisted sintering to fabricate nuclear fuel. First, the pure UO 2 -based system shows promising behavior with flash sintering, but composite systems are likely to show better sintering behavior with spark plasma sintering. Efforts to develop these methods should therefore be tailored towards the likelihood of success. Additionally, modeling is a rapidly developing aspect of current flash sintering research and should be used in parallel with experiments. Ultimately, ongoing flash sintering studies on various materials, like those summarized in this report, are rapidly contributing to the feasibility of controlling this method for use in the future.

##CAI suggestions##↗

Harnessing Uncertainty through Functional Data Analysis in Gas Breakthrough Data

Detecting subsurface explosions from radionuclide gas migration through rock fractures is an effective way to identify nuclear activity. Los Alamos National Laboratory (LANL) has developed simulation methods, based on data from the 1962 Hardhat underground nuclear test, to predict gas breakthrough times at the surface. However, these methods rely on an imperfect understanding of the relationship between rock damage and fracture permeability. Our clinic project studies methods for predicting breakthrough curves that characterize total mass produced as a function of time, as well as quantifying the uncertainty associated with these predictions. The model that is currently employed to relate damage to permeability uses an empirically motivated power-law expression, with a range of parameter values that are compatible with the experimental Hardhat data. We develop emulators, built from functional data analysis techniques and trained on simulation data, that rapidly predict the gas breakthrough curve given a damage field and given the parameter values of the power-law equation. Using Bayesian regression, we address the problem of uncertainty quantification in our emulators. Finally, in order to test the robustness of the model, we further validate it on a damage field representing different physical conditions.

58 GEOSCIENCES↗

Operando X-ray Nanocharacterization of Polycrystalline Thin Film Modules

Non-destructive measurement techniques, with high spatial resolution, capable of correlating composition and structure with device properties, are few and far between. For the case of polycrystalline and inhomogeneous materials, the added challenge is that large sampling areas are necessary in order to have a statistical representation of the specimen under study. For the study of grain cores and grain boundaries in polycrystalline solar absorbers this is of particular importance since their dissimilar behavior and variability throughout the samples makes it difficult to draw conclusions and ultimately optimize the materials and devices. Our approach to use state-of-the-art x-ray microscopy to study full module stacks under operating conditions is unique. Understanding the effects of elemental and charge migration under full encapsulation and operating conditions will allow CIGS and CdTe manufactures and in particular our partners in this proposal to modify materials, stacks, architectures, and processing steps to minimize the performance losses through time.

14 SOLAR ENERGY↗

Advanced digital SAR processing study

A highly programmable, land based, real time synthetic aperture radar (SAR) processor requiring a processed pixel rate of 2.75 MHz or more in a four look system was designed. Variations in range and azimuth compression, number of looks, range swath, range migration and SR mode were specified. Alternative range and azimuth processing algorithms were examined in conjunction with projected integrated circuit, digital architecture, and software technologies. The advaced digital SAR processor (ADSP) employs an FFT convolver algorithm for both range and azimuth processing in a parallel architecture configuration. Algorithm performace comparisons, design system design, implementation tradeoffs and the results of a supporting survey of integrated circuit and digital architecture technologies are reported. Cost tradeoffs and projections with alternate implementation plans are presented.

Martinson, L. W.↗

Tectonic wedging in the forearc basin - Accretionary prism transition, Lesser Antilles forearc

This paper describes regional structure of the inner forearc of the southern Lesser Antilles, which contains an extensive 50-70 km wide inner forearc deformation belt (IFDB) developed above crystalline basement of the undeformed forearc basin (FAB), close to and perhaps above its probable subduction trace with Atlantic lithosphere. The IFDB is analyzed, with emphasis placed on five transects across the belt, using mainly migrated seismic sections and balanced model cross sections. The IFDB features and its evolution are discussed, with special attention given to the major structures divided by early and late stages of development, paleobathymetric history, event timing, displacement and strain, and alternative tectonic explanations.

Torrini, Rudolph, Jr.↗

A Third Exoplanetary System with Misaligned Orbital and Stellar Spin Axes

We presented evidence that the WASP-14 exoplanetary system has misaligned orbital and stellar-rotational axes, with an angle of 33.1 plus or minus 7.4 degrees between their sky projections. At the time of this publication, WASP-14 was the third system known to have a significant spin-orbit misalignment, and all three systems had super- Jupiter planets and eccentric orbits. Therefore we hypothesized that the migration and subsequent orbital evolution of massive, eccentric exoplanets is somehow different from that of less massive close-in Jupiters, the majority of which have well-aligned orbits.

Johnosn, John A.↗

Impact of sub-core scale heterogeneity on CO2/brine multiphase flow for geological carbon storage in the Minnelusa sandstone

CO2 geological storage in deep saline aquifers is a mitigation option for CO2 emissions due to its large storage capacity and immediate accessibility. Accurately determining the CO2-brine relative permeability curves is key to the evaluation of CO2 injectivity and sweep efficiency in reservoir simulation as well as the CO2 injection in the field. This study highlights the remarkable effects of sub-core scale heterogeneity on the CO2-brine multiphase flow properties of the Minnelusa Sandstone in Wyoming. Two unsteady state CO2-brine drainage experiments were performed on the two samples. The first sample exhibits slanted laminated structure, while the second one represents a more homogeneous sandstone system. The CO2 saturation distributions during drainage reveals that the main variation in multiphase flow properties of two core samples were attributed to the porosity distribution that leads to the capillary pressure heterogeneity. Assisted history matching was used to obtain the respective relative permeability curves, which suggests heterogeneity-dependent behavior. In addition, sensitive and uncertainty analyses indicate that physical and petro-physical properties of low-porosity and low-permeability bedding layers exert marked effects on CO2 front breakthrough time and brine production. The results presented in this study help to gain insight into the CO2-brine multiphase flow properties in heterogeneous sandstones and can pave the way for the upscaling of CO2 migration and field-scale simulation accurately. This work is funded under the Department of Energy CarbonSAFE program (awards DE-FE0031624 DE0031891).

Kou, Zuhao↗

Target Tracking with Distributed Sensing and Optimal Data Migration

The paper presents an Extended Kalman Filter based framework for airborne target tracking using adaptive information fusion from multi-modal multi-rate distributed sensors network. First, the tracking algorithm execution location is determined using an optimal data migration strategy, which also computes the associated delays for each sensor data to arrive at the computing location. Next, the fast (zero-delay) sensors information is dynamically fused in the filter correction procedure at the arrival instance of each valid sensor reading. Finally, the target estimation is updated based on the valid slow (delayed) data, which are grouped according to the delay-time steps before application of the Larsen's method. This approach is applied to the synthetic sensor data generated by means of the ground based radar and camera models for the simulated target flight in Reflection simulation environment.

Distributed sensing↗

Evaluation of micromilling/conventional isotope ratio mass spectrometry and secondary ion mass spectrometry of δ 18 O values in fish otoliths for sclerochronology

Stable oxygen isotope ratios (δ 18 O values) measured in fish otoliths can provide valuable detailed information on fish life history, fish age determination, and ocean thermography. Traditionally, otoliths are sampled by micromilling followed by isotope ratio mass spectrometry (IRMS), but direct analysis by secondary ion mass spectrometry (SIMS) is becoming more common. However, these two methods have not been compared to determine which, if either, is better for fish age validation studies. Hence, the goals were to: (1) determine if the δ 18 O signatures from the two different methods are similar, (2) determine which method is better for fish age validation studies, and (3) examine biogeographic and migration history. Both analytical techniques, micromilling/IRMS and SIMS, were used to measure δ 18 O values in six Pacific cod (Gadus macrocephalus) otoliths. A series of measurements was made from the center of each otolith to its edge to develop a life-history δ 18 O signature for each fish. The sampling resolution of SIMS analyses was 2–3 times greater than that obtained by micromilling/IRMS. We found an offset between SIMS and micromilling/IRMS δ 18 O values, about 0.5‰ on average, with SIMS yielding lower values. However, the δ 18 O patterns from both methods (i.e., the number of δ 18 O maxima) correspond to the estimated age determined by otolith growth-zone counts, validating fish age determination methods. Both techniques resolved δ 18 O life-history signatures and showed patterns consistent with seasonal variation in temperatures and changes due to fish migration. When otoliths are large, micromilling/IRMS can provide adequate resolution for fish age validation. Finally, SIMS is the better option if greater sampling resolution is required, such as when otoliths are small or specimens are longer lived and have compact growth zones.

54 ENVIRONMENTAL SCIENCES↗

In situ study on low-k interconnect time-dependent-dielectric-breakdown mechanisms

An in situ transmission-electron-microscopy methodology is developed to observe time-dependent dielectric breakdown (TDDB) in an advanced Cu/ultra-low-k interconnect stack. A test structure, namely a “tip-to-tip” structure, was designed to localize the TDDB degradation in small dielectrics regions. A constant voltage is applied at 25 °C to the “tip-to-tip” structure, while structural changes are observed at nanoscale. Cu nanoparticle formation, agglomeration, and migration processes are observed after dielectric breakdown. The Cu nanoparticles are positively charged, since they move in opposite direction to the electron flow. Measurements of ionic current, using the Triangular-Voltage-Stress method, suggest that Cu migration is not possible before dielectric breakdown, unless the Cu/ultra-low-k interconnect stacks are heated to 200 °C and above.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Role of Decomposition Product Ions in Hysteretic Behavior of Metal Halide Perovskite

Ion migration is one of the most debated mechanisms and credited with multiple observed phenomena and performance in metal halide perovskites (MHPs) semiconductor devices. However, to date, the migration of ions and their effects on MHPs are not still fully understood, largely due to a lack of direct observations of temporal ion migration. In this work, using direct observation of ion migration in-operando, we observe the hysteretic migration behavior of intrinsic ions (i.e., CH 3 NH 3 + and I – ) as well as reveal the migration behavior of CH 3 NH 3 + decomposition ions. We find that CH 3 NH 3 + decomposition products can be affected by light and accumulate at the interfaces under bias. These MHP decomposition products are tightly related to the device performance and stability. Complementary results of time-resolved Kelvin probe force microscopy (tr-KPFM) demonstrate a correlation between dynamics of these interfacial ions and charge carriers. Overall, we find that there are a number of mobile ions including CH 3 NH 3 + decomposition products in MHPs that need to be taken into account when measuring MHP device responses (e.g., charge dynamics) and should be considered in future optimization studies of MHP semiconductor devices.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Influences of Mg Ions and Al Ions on Deposition Behavior of Supersaturated Silicic Acid - 20261

Silicic acid can change into various species such as deposit, colloidal, and soluble form under certain conditions: for example, gradual pH changes around geological disposal repositories. In particular, silicic acid deposits narrow groundwater flow paths, thereby restricting the flow of groundwater. Such effects may contribute to a delay in radionuclide migration. Previous studies have reported that silicic acid supersaturated in sodium and calcium ions can narrow the flow paths. This study examined the effect of magnesium (Mg) and aluminum (Al) ions on the deposition of supersaturated silicic acid on the solid phase. The deposition behavior of supersaturated silicic acid on the solid phase was investigated in a batch system while changing the initial supersaturation concentration, the coexisting ion concentration, and the amount of added solid phase. In the presence of Mg ions, silicic acid precipitation increased with increasing Mg ion concentration due to the influence of the electrolyte, and crosslinking reactions. The coexistence of Al ions significantly suppressed silicic acid deposition due to the formation of a covering on the solid surface during Al ion hydrolysis under conditions of high Al concentration (1.4 mM). On the basis of these experimental results, the apparent deposition rate constant of silicic acid was estimated to be in the range from 10{sup -11} to 10{sup -10} m/s. The Damkoehler number (the dimensionless number expressed by the ratio of the characteristic time of mass transfer and the chemical reaction constant) was sufficient to cause the clogging of the host rock by deposition. This suggests that supersaturated silicic acid deposition, regardless of the presence of Mg ions (and Al ions), contributes to improving barrier performance against radionuclide migration in the host rock. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗