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At least 883 records · Page 49

Flood warnings, flood disaster assessments, and flood hazard reduction : the roles of orbital remote sensing

Orbital remote sensing is now poised to make three fundamental contributions towards reducing the detrimental effects of extreme floods. Effective Flood warning requires frequent (near-daily) radar observation of the Earth's surface through cloud cover. In contrast, both optical and radar wavelengths will increasingly be used for disaster assessment and hazard reduction. These latter tasks are accomplished, in part, by accurate mapping of flooded lands and commonly over periods of several days or more. We use radar scatterometer data from QuikSCAT to detect changes in surface water area and with a full global coverage every 2.5 days. Also, MODIS, RADARSAT, and other higher spatial resolution data are used for flood mapping and other flood measurements. These records are preserved in a global flood hazard atlas at http://www.dartmouth.edu/-floods/Atlas.html.

Shabaneh, Tamer B.↗

Estimating groundwater use and demand in arid Kenya through assimilation of satellite data and in-situ sensors with machine learning toward drought early action

Groundwater is an important source of water for people, livestock, and agriculture during drought in the Horn of Africa. In this work, areas of high groundwater use and demand in drought-prone Kenya were identified and forecasted prior to the dry season. Estimates of groundwater use were extended from a sentinel network of 69 in-situ sensored mechanical boreholes to the region with satellite data and a machine learning model. The sensors contributed 756 site-month observations from June 2017 to September 2021 for model building and validation at a density of approximately one sensor per 3700 sq.km. An ensemble of 19 parameterized algorithms was informed by features including satellite-derived precipitation, surface water availability, vegetation indices, hydrologic land surface modeling, and site characteristics to dichotomize high groundwater pump utilization. Three operational definitions of high demand on groundwater infrastructure were considered: 1) mechanical runtime of pumps greater than a quarter of a day (6+ hr) and daily per capita volume extractions indicative of 2) domestic water needs (35+ L), and 3) intermediate needs including livestock (75+ L). Gridded interpolation of localized groundwater use and demand was provided from 2017 to 2020 and forecasted for the 2021 dry season, June–September 2021. Cross-validated skill for contemporary estimates of daily pump runtime and daily volume extraction to meet domestic and intermediate water needs was 68%, 69%, and 75%, respectively. Forecasts were externally validated with an accuracy of at least 56%, 70%, or 72% for each groundwater use definition. The groundwater maps are accessible to stakeholders including the Kenya National Drought Management Authority (NDMA) and the Famine Early Warning Systems Network (FEWS NET). These maps represent the first operational spatially-explicit sub-seasonal to seasonal (S2S) estimates of groundwater use and demand in the literature. Knowledge of historical and forecasted groundwater use is anticipated to improve decision-making and resource allocation for a range of early warning early action applications.

Katie Fankhauser↗

SatCORPS Global Cloud Composite (GCC): the Design and Delivery of A High Quality, High Resolution, Global Cloud Product Available in Near-Real Time

The NASA Satellite ClOud and Radiation Property retrieval System (SatCORPS) supports the development of an analysis ready and cloud-optimized data transformation pipeline and geospatial service enablement of a global cloud composite (GCC) product derived from global geostationary satellite imagery. This geospatial service will be available at high temporal and spatial resolution via the SatCORPS web mapping application for visualization and analysis as well as direct ingestion to common geospatial software and custom programming. The resulting global cloud composite products from the processing pipeline can then be geospatially-service enabled as ArcGIS Image Services and Open Geospatial Consortium (OGC) Web Mapping/Coverage Services for visualization and analysis via a web mapping application and common geospatial software. Near real time global observations are created through the composition of five geostationary satellites that provides modelling and forecasting communities with the capability to provide high quality and timely information to start the projection process. The Global Cloud Composite product combines information from geostationary satellites, GOES-16, GOES-17, Himawari-8, Meteosat-11 and Meteosat-9 to create a single global composite netcdf file and images using the different products within the netcdf file. The SatCORPS team, though our Global Cloud Composite (GCC) product and web-based visualization tools including Geographical Information System (GIS) services provide near real time global cloud product information to both automated processes and traditional web users that is timely and high quality derived from geostationary satellites. The Global Cloud Composite product takes advantage of the scalable processing resources provided by the AWS batch service to provide new composites every thirty minutes. Because information from each of the low earth orbiting satellites is available on schedules tuned to the specific satellite, the processing algorithm temporally composites the final dataset as each satellite’s information becomes available. The SatCORPS team has leveraged our experience using Amazon Web Services (AWS) to build a low latency high availability tool that allows end users both human and automated to acquire high quality and high-resolution Geostationary Earth Orbiting (GEO) information at zero cost to the end user. This presentation will describe how we architected and implemented the service as well as lessons learned based on our experiences both developing and operating the system. The lessons learned include how we integrated multiple services including Amazon Batch, Amazon S3 and Amazon Lambda service to create a low cost but high-performance processing system that is capable of identifying and processing the most appropriate satellite overpass information into global cloud composites. We will also describe our web-based tools including our Geographic Information System that can be used for visualization and analysis. The products from the processing can be geospatially-service enabled as ArcGIS Image Services and Open Geospatial Consortium (OGC) Web Mapping/Coverage Services for visualization and analysis via a web mapping application and common geospatial software. The SatCORPS Global Composite Cloud product provides sophisticated global composited cloud research products with very low latency that we see that as filling a rapidly growing need in the research and modelling community with no up-front nor ongoing costs associated with downloading or using the information.

AWS AMCE SMCE GCC SATCORPS GLOBAL CLOUD COMPOSITE ↗

Quantitative Species Measurements in Microgravity Combustion Flames using Near-Infrared Diode Lasers

Understanding the physical phenomena controlling the ignition and spread of flames in microgravity has importance for space safety as well as for characterizing dynamical and chemical combustion processes which are normally masked by buoyancy and other gravity-related effects. Unfortunately, combustion is highly complicated by fluid mechanical and chemical kinetic processes, requiring the use of numerical modeling to compare with carefully designed experiments. More sophisticated diagnostic methods are needed to provide the kind of quantitative data necessary to characterize the properties of microgravity combustion as well as provide accurate feedback to improve the predictive capabilities of the models. Diode lasers are a natural choice for use under the severe conditions of low gravity experiments. Reliable, simple solid state operation at low power satisfies the operational restrictions imposed by drop towers, aircraft and space-based studies. Modulation wavelength absorption spectroscopy (WMS) provides a means to make highly sensitive and quantitative measurements of local gas concentration and, in certain cases, temperature. With near-infrared diode lasers, detection of virtually all major combustion species with extremely rapid response time is possible in an inexpensive package. Advancements in near-infrared diode laser fabrication technology and concurrent development of optical fibers for these lasers led to their use in drop towers. Since near-infrared absorption line strengths for overtone and combination vibrational transitions are weaker than the mid-infrared fundamental bands, WMS techniques are applied to increase detection sensitivity and allow measurement of the major combustion gases. In the first microgravity species measurement, Silver et al. mounted a fiber-coupled laser at the top of the NASA 2.2-sec drop tower and piped the light through a single-mode fiber to the drop rig. A fiber splitter divided the light into eight channels that directed the laser beam across a methane or propane diffusion jet flame. The light beams were recaptured by a set of gradient index lenses, coupled back into separate fiber optic lines, and transmitted back to detectors and electronics in the instrument package. In these experiments a 6-mm od fiber cable (containing the nine optical fibers) fell with the drop rig. Using separate detection and demodulation channels, spatial and temporal (up to 20 Hz) maps of water vapor and methane concentrations were obtained at differing heights in the flames. While this apparatus was useful from a demonstration standpoint, several drawbacks needed attention before useful scientific measurements could be obtained. First, eight lines of sight are somewhat insufficient for detailing the spatial profiles of the gas. Second, multiple detection channels operating in parallel are both expensive and present a challenge for accurate calibration. As a result, a newer scanning system was developed in our first contract under this program. The primary characteristic of this system is that it contains a single detection channel and achieves "continuous" spatial resolution by scanning the laser beam across the flame region, then directing this beam onto a single detector. Thus spatial measurements are converted to a temporal series of data. The true spatial resolution is limited only by the beam diameter and width of the sweep. In these experiments the beam is focused to about 1-mm diameter and scans across a region up to 4-cm wide.

Silver, Joel A.↗

Geospatial Modeling of Asthma Population in Relation to Air Pollution

Current observations indicate that asthma is growing every year in the United States, specific reasons for this are not well understood. This study stems from an ongoing research effort to investigate the spatio-temporal behavior of asthma and its relatedness to air pollution. The association between environmental variables such as air quality and asthma related health issues over Mississippi State are investigated using Geographic Information Systems (GIS) tools and applications. Health data concerning asthma obtained from Mississippi State Department of Health (MSDH) for 9-year period of 2003-2011, and data of air pollutant concentrations (PM2.5) collected from USEPA web resources, and are analyzed geospatially to establish the impacts of air quality on human health specifically related to asthma. Disease mapping using geospatial techniques provides valuable insights into the spatial nature, variability, and association of asthma to air pollution. Asthma patient hospitalization data of Mississippi has been analyzed and mapped using quantitative Choropleth techniques in ArcGIS. Patients have been geocoded to their respective zip codes. Potential air pollutant sources of Interstate highways, Industries, and other land use data have been integrated in common geospatial platform to understand their adverse contribution on human health. Existing hospitals and emergency clinics are being injected into analysis to further understand their proximity and easy access to patient locations. At the current level of analysis and understanding, spatial distribution of Asthma is observed in the populations of Zip code regions in gulf coast, along the interstates of south, and in counties of Northeast Mississippi. It is also found that asthma is prevalent in most of the urban population. This GIS based project would be useful to make health risk assessment and provide information support to the administrators and decision makers for establishing satellite clinics in future.

Kethireddy, Swatantra R.↗

Spatial variability of outgoing longwave radiation

Data from the Earth Radiation Budget Experiment scanning radiometer aboard the NOAA-9 operational meteorological satellite are used to investigate the spatial variability of Outgoing Longwave Radiation (OLR). Daily and monthly radiation maps at 2.5 deg latitude-longitude scale are used as a basis for the study. The regions of greatest variability are in the tropics and subtropics. Storm tracks such as the South Pacific convergence zone appear as regions of high OLR variability. Spatial spectra in longitude show two regimes of OLR. At large scales (wavenumbers less than 6), the spatial spectrum is flat. For wavenumbers greater than 10, the spectra decrease as wavenumber to the -3 power. The spatial spectrum of daily anomalies from the mean is a strong function of latitude and season, with interesting features. Correlations of daily anomalies from the monthly mean decrease exponentially in latitude but have a damped-wave structure in longitude. The spatial variability of the daily maps, as measured by degree variance, have 10 times the power at degree 24 than the monthly maps, but at scales between 1 and 10, the degree variance is practically the same for daily as for monthly.

Smith, G. Louis↗

Preliminary Correlations of Gravity and Topography from Mars Global Surveyor

The Mars Global Surveyor (MGS) spacecraft is currently in a 400-km altitude polar mapping orbit and scheduled to begin global mapping of Mars in March of 1999. Doppler tracking data collected in this Gravity Calibration Orbit prior to the nominal mapping mission combined with observations from the MGS Science Phasing Orbit in Spring - Summer 1999 and the Viking and mariner 9 orbiters has led to preliminary high resolution gravity fields. Spherical harmonic expansions have been performed to degree and order 70 and are characterized by the first high spatial resolution coverage of high latitudes. Topographic mapping by the Mars Orbiter Laser Altimeter on MGS is providing measurements of the height of the martian surface with sub-meter vertical resolution and 5-30 m absolute accuracy. Data obtained during the circular mapping phase are expected to provide the first high resolution measurements of surface heights in the southern hemisphere. The combination of gravity and topography measurements provides information on the structure of the planetary interior, i.e. the rigidity and distribution of internal density. The observations can also be used to address the mechanisms of support of surface topography. Preliminary results of correlations of gravity and topography at long planetary wavelengths will be presented and the implications for internal structure will be addressed.

Zuber, M. T.↗

The global distribution on total ozone - Toms satellite measurements

The general behavior of total ozone by season and latitude was known before 1930 through the pioneering observations by Dobson. The ozone record at Oxford and other European stations was dominated by an annual cycle and by irregular short term fluctuations. The amplitude and phase of the annual cycle were determined at representative latitudes in both hemispheres. However, the short term variations appeared to be meteorological origin, although the specific cause could not be identified. Data from the Total Ozone Mapping Spectrometer (TOMS) on the Nimbus 7 spacecraft, with global coverage at an average spatial resolution of 66 km, can now be used to completely map the total ozone field. These maps demonstrate that troughs and ridges in the upper troposphere are responsible for the large, short term ozone variations found at middle latitudes, while in the tropics, the steady, low ozone levels show broad scale structure associated with the Hadley circulation.

Krueger, Arlin J.↗

Comparison of Image Restoration Methods for Lunar Epithermal Neutron Emission Mapping

Orbital measurements of neutrons by the Lunar Exploring Neutron Detector (LEND) onboard the Lunar Reconnaissance Orbiter are being used to quantify the spatial distribution of near surface hydrogen (H). Inferred H concentration maps have low signal-to-noise (SN) and image restoration (IR) techniques are being studied to enhance results. A single-blind. two-phase study is described in which four teams of researchers independently developed image restoration techniques optimized for LEND data. Synthetic lunar epithermal neutron emission maps were derived from LEND simulations. These data were used as ground truth to determine the relative quantitative performance of the IR methods vs. a default denoising (smoothing) technique. We review and used factors influencing orbital remote sensing of neutrons emitted from the lunar surface to develop a database of synthetic "true" maps for performance evaluation. A prior independent training phase was implemented for each technique to assure methods were optimized before the blind trial. Method performance was determined using several regional root-mean-square error metrics specific to epithermal signals of interest. Results indicate unbiased IR methods realize only small signal gains in most of the tested metrics. This suggests other physically based modeling assumptions are required to produce appreciable signal gains in similar low SN IR applications.

McClanahan, T. P.↗

Contrasting landform perception with varied radar illumination geometries and at simulated resolutions of Venera and Magellan

The high sensitivity of imaging radars to slope at moderate to low incidence angles enhances the perception of linear topography on images. It reveals broad spatial patterns that are essential to landform mapping and interpretation. As radar responses are strongly directional, the ability to discriminate linear features on images varies with their orientation. Landforms that appear prominent on images where they are transverse to the illumination may be obscure to indistinguishable on images where they are parallel to it. Landform detection is also influenced by the spatial resolution in radar images. Seasat radar images of the Gran Desierto Dunes complex, Sonora, Mexico; the Appalachian Valley and Ridge Province; and accreted terranes in eastern interior Alaska were processed to simulate both Venera 15 and 16 images (1000 to 3000 km resolution) and image data expected from the Magellan mission (120 to 300 m resolution. The Gran Desierto Dunes are not discernable in the Venera simulation, whereas the higher resolution Magellan simulation shows dominant dune patterns produced from differential erosion of the rocks. The Magellan simulation also shows that fluvial processes have dominated erosion and exposure of the folds.

Ford, J. P.↗

Estimation of Orbital Neutron Detector Spatial Resolution by Systematic Shifting of Differential Topographic Masks

We present a method and preliminary results related to determining the spatial resolution of orbital neutron detectors using epithermal maps and differential topographic masks. Our technique is similar to coded aperture imaging methods for optimizing photonic signals in telescopes [I]. In that approach photon masks with known spatial patterns in a telescope aperature are used to systematically restrict incoming photons which minimizes interference and enhances photon signal to noise. Three orbital neutron detector systems with different stated spatial resolutions are evaluated. The differing spatial resolutions arise due different orbital altitudes and the use of neutron collimation techniques. 1) The uncollimated Lunar Prospector Neutron Spectrometer (LPNS) system has spatial resolution of 45km FWHM from approx. 30km altitude mission phase [2]. The Lunar Rennaissance Orbiter (LRO) Lunar Exploration Neutron Detector (LEND) with two detectors at 50km altitude evaluated here: 2) the collimated 10km FWHM spatial resolution detector CSETN and 3) LEND's collimated Sensor for Epithermal Neutrons (SETN). Thus providing two orbital altitudes to study factors of: uncollimated vs collimated and two average altitudes for their effect on fields-of-view.

McClanahan, T. P.↗

Rapid Identification of Synthetic Routes to Functional Metastable Phases Using X-ray Probed Laser Anneal Mapping (XPLAM) Time-Temperature Quench Maps

Many material systems have known or predicted functional phases that are metastable at standard temperature and pressure. While substantial advances have been made in the high-throughput and combinatorial synthesis of materials with a range of stoichiometries, investigation of thermal processing remains largely the domain of iterative uniform anneals or static gradients. Here we develop X-ray probed laser anneal mapping (XPLAM), a high throughput technique coupling spatially resolved X-ray diffraction with microsecond to millisecond laser gradient anneals to produce temperature–dwell–transformation (TDT) diagrams of the phase as a function of quench time and temperature. In addition to showing regimes where specific metastable phases form preferentially, TDT diagrams provide insight into the submillisecond kinetics of solid–solid phase transitions. This is a unique tool for mapping reaction pathways for metastable phases. As a first demonstration of XPLAM, we study Bi2O3, which has a rich set of polytypes, including the d-phase with an exceptionally high oxygen ion conductivity. We demonstrate the first annealing-driven synthesis of room temperature d-Bi2O3. We expect XPLAM to prove a powerful technique for rapid identification of synthetic routes to metastable phases and to generate the exhaustive data sets required for machine learning-guided exploration of materials processing.

36 MATERIALS SCIENCE↗

Arctic Sea Ice Motion from Wavelet Analysis of Satellite Data

Wavelet analysis of DMSP SSM/I (Special Sensor Microwave/Imager) 85 GHz and 37 GHz radiance data, SMMR (Scanning Multichannel Microwave Radiometer) 37 GHz, and NSCAT (NASA Scatterometer) 13.9 GHZ data can be used to obtain daily sea ice drift information for both the northern and southern polar regions. The derived maps of sea ice drift provide both improved spatial coverage over the existing array of Arctic Ocean buoys and better temporal resolution over techniques utilizing data from satellite synthetic aperture radars (SAR). Examples of derived ice-drift maps in the Arctic illustrate large-scale circulation reversals within a period of a couple weeks. Comparisons with ice displacements derived from buoys show good quantitative agreement. NASA Scatterometer (NSCAT) 13.9 GHZ data have been also used for wavelet analysis to derive sea-ice drift. First, the 40' incidence-angle, sigma-zero (surface roughness) daily map of whole Arctic region with 25 km of pixel size from satellite's 600 km swath has been constructed. Then, the similar wavelet transform procedure to SSM/I data can be applied. Various scales of wavelet transform and threshold have been tested. By overlaying , neighbor filtering, and block-averaging the results of multiscale wavelet transforms, the final sea ice drift vectors are much smooth and representative to the sea ice motion. This wavelet analysis procedure is robust and can make a major contribution to the understanding of ice motion over large areas at relatively high temporal resolutions. The results of wavelet analysis of SSM/I and NSCAT images and buoy data can be merged by some data fusion techniques and will help to improve our current knowledge of sea ice drift and related processes through the data assimilation of ocean-ice numerical model.

Liu, Antony K.↗

Mapping Inundation from Hurricane Florence (2018) with L-Band Synthetic Aperture Radar, Commercial Imagery, and Ancillary Data via Machine Learning Classification

During and after flooding events, mapping the extent of floodwaters aids in the distribution of resources, recovery efforts, and damage assessment practices. Development of a land cover classification system focused on mapping inundation after major hurricane events using synthetic aperture radar (SAR) data could allow for the production of near-real-time inundation mapping, enabling government and emergency response entities to get a preliminary idea of a developing situation. Complimentary optical and SAR images from domestic and foreign entities are brought together through activations of the International Charter: Space and Major Disasters to support response efforts, from true-color, near-infrared, and thermal remote sensing data obtained by NASA, NOAA, and international satellites to the collection of high-resolution true color aerial photography by NOAA and the National Geodetic Survey. In response to Hurricane Florence of 2018, NASA JPL collected numerous swaths of quad-pol L-band SAR data with the Uninhabited Aerial Vehicle Synthetic Aperture Radar (UAVSAR) instrument observing the record-setting river stages across North and South Carolina. The resulting fully-polarized SAR images allow for mapping of inundation extent at a high spatial resolution with a unique advantage over optical imaging stemming from the sensor’s ability to penetrate cloud cover and dense vegetation. In this study, true-color NOAA aerial and commercial satellite imagery are used in conjunction with four UAVSAR data swaths centered on the Lumberton and Cape Fear River basins in southeastern North Carolina to develop a Random Forest classification model focused on mapping open water and floodwater otherwise obscured by vegetation or lingering cloud cover. Ancillary building footprint, transportation route, and population data will also be incorporated into the classification scheme to estimate the societal impacts of flooding based on the proximity of features to detected inundation. Preliminary results from the Hurricane Florence case study will be discussed in addition to the limitations of available validation data for assessment of the classifier’s accuracy.

Alexander M Melancon↗

Path planning using optically computed potential fields

An algorithm for the optical computation of potential field maps suitable for mobile robot navigation is described and experimentally produced maps and paths are presented. The parallel analog optical computation employs a two-dimensional spatial light modulator on which an image of the potential field map is generated. Optically calculated fields contain no local minima, tend to produce paths centered in gaps between obstacles, and produce paths which give preference to wide gaps. Calculation of 128 x 128 pixel fields at a few hertz are possible with current technology, and calculation time vs. map size scales favorably in comparison to digital electronic computation.

Reid, Max B.↗

The GOES-R Geostationary Lightning Mapper (GLM) and the Global Observing System for Total Lightning

for the existing GOES system currently operating over the Western Hemisphere. New and improved instrument technology will support expanded detection of environmental phenomena, resulting in more timely and accurate forecasts and warnings. Advancements over current GOES include a new capability for total lightning detection (cloud and cloud-to-ground flashes) from the Geostationary Lightning Mapper (GLM), and improved temporal, spatial, and spectral resolution for the next generation Advanced Baseline Imager (ABI). The GLM will map total lightning continuously day and night with near-uniform spatial resolution of 8 km with a product latency of less than 20 sec over the Americas and adjacent oceanic regions. This will aid in forecasting severe storms and tornado activity, and convective weather impacts on aviation safety and efficiency among a number of potential applications. The GLM will help address the National Weather Service requirement for total lightning observations globally to support warning decision-making and forecast services. Science and application development along with pre-operational product demonstrations and evaluations at NWS national centers, forecast offices, and NOAA testbeds will prepare the forecasters to use GLM as soon as possible after the planned launch and check-out of GOES-R in 2016. New applications will use GLM alone, in combination with the ABI, or integrated (fused) with other available tools (weather radar and ground strike networks, nowcasting systems, mesoscale analysis, and numerical weather prediction models) in the hands of the forecaster responsible for issuing more timely and accurate forecasts and warnings.

Goodman, Steven J.↗

Issues in Defining Software Architectures in a GIS Environment

The primary mission of the Pan-American Center for Earth and Environmental Studies (PACES) is to advance the research areas that are relevant to NASA's Mission to Planet Earth program. One of the activities at PACES is the establishment of a repository for geographical, geological and environmental information that covers various regions of Mexico and the southwest region of the U.S. and that is acquired from NASA and other sources through remote sensing, ground studies or paper-based maps. The center will be providing access of this information to other government entities in the U.S. and Mexico, and research groups from universities, national laboratories and industry. Geographical Information Systems(GIS) provide the means to manage, manipulate, analyze and display geographically referenced information that will be managed by PACES. Excellent off-the-shelf software exists for a complete GIS as well as software for storing and managing spatial databases, processing images, networking and viewing maps with layered information. This allows the user flexibility in combining systems to create a GIS or to mix these software packages with custom-built application programs. Software architectural languages provide the ability to specify the computational components and interactions among these components, an important topic in the domain of GIS because of the need to integrate numerous software packages. This paper discusses the characteristics that architectural languages address with respect to the issues relating to the data that must be communicated between software systems and components when systems interact. The paper presents a background on GIS in section 2. Section 3 gives an overview of software architecture and architectural languages. Section 4 suggests issues that may be of concern when defining the software architecture of a GIS. The last section discusses the future research effort and finishes with a summary.

Acosta, Jesus↗

Spatially Resolved Persistent Photoconductivity in MoS2–WS2 Lateral Heterostructures

The optical and electronic properties of 2D semiconductors are intrinsically linked via the strong interactions between optically excited bound species and free carriers. Here we use near-field scanning microwave microscopy (SMM) to image spatial variations in photoconductivity in MoS 2 –WS 2 lateral multijunction heterostructures using photon energy-resolved narrowband illumination. We find that the onset of photoconductivity in individual domains corresponds to the optical absorption onset, confirming that the tightly bound excitons in transition metal dichalcogenides can nonetheless dissociate into free carriers. These photogenerated carriers are most likely n-type and are seen to persist for up to days. Informed by finite element modeling we reveal that they can increase the carrier density by up to 200 times. This persistent photoconductivity appears to be dominated by contributions from the multilayer MoS 2 domains, and we attribute the flake-wide response in part to charge transfer across the heterointerface. Spatial correlation of our SMM imaging with photoluminescence (PL) mapping confirms the strong link between PL peak emission photon energy, PL intensity, and the local accumulated charge. This work reveals the spatially and temporally complex optoelectronic response of these systems and cautions that properties measured during or after illumination may not reflect the true dark state of these materials but rather a metastable charged state.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗