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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 883 records · Page 49
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Color as a tool for quantitative analysis of heterogeneous polymer degradation

Polymers are widely used industry, but degrade due to environmental conditions, such as elevated temperature or radiation. The degradation of polymers is dominated oxidation in oxygenated environments. Such oxidation is commonly referred to as thermal-oxidation or photo-oxidation and in many situations is heterogeneous through thickness of the polymer. While heterogeneous oxidation of polymers is a common phenomenon, the effect on the lifetime of polymers is not well understood as methods to evaluate such oxidation are time consuming and challenging to implement. Here we show a novel method for quantitative evaluation of heterogeneous oxidation in polymers using a fast and accurate color approach. The proposed color approach was observed to improve the efficiency of obtaining heterogenous oxidation profiles in half the time of common approaches, such as indention or Fourier transform infrared spectroscopy. Furthermore, the method was found to produce trends similar to that observed using common approaches and the applicability of the method was verified by mapping oxygen concentration through thickness using energy dispersive X-ray spectroscopy. Lastly, the utility of the proposed method was demonstrated through the generation of an oxidation design space, which is envisioned to assist with designing experiments towards estimation of polymer lifetime. Finally, we anticipate this work to be a starting point for further evaluation of heterogeneous oxidation in polymers using optical properties.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Arctic shrub size and leaf traits, northern Alaska, summer 2017 (Version 2.0)

This data package contains leaf and size trait and environmental data collected from 170 plots of rapidly expanding shrub genera (Alnus, Betula, and Salix) and a widespread sedge (Eriophorum vaginatum) along a latitudinal and climate gradient in northern Alaska. The trait data were collected in summer 2017 and include leaf area, specific leaf area, leaf nitrogen concentration, leaf delta 15N, leaf delta 13C, shrub height, aboveground biomass, and the ratio of root biomass to aboveground biomass. These raw data support a submitted manuscript that examines the intraspecific variations of size, leaf and root traits of shrubs across the graminoid-dominated nutrient-poor arctic tundra and reveals the environmental drivers of deciduous shrub traits in tundra ecosystems (Fraterrigo et al., submitted). Data are presented by site (n=5) and patch (shrub or sedge plot) in separate csv files. The location data are provided in the “plot coordinates” file; all other files contain the data in the file title. Detailed methods are in the submitted manuscript. A companion data package contains root trait data collected simultaneously from the same plots (Fraterrigo and Chen, 2020). See the "Related references" section for more information.2023/07/20 Update: The latest version of this dataset publication is version 2.0. The latest version of the data package was updated to correct the leaf size trait.csv file.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Available land for cellulosic biofuel production: a supply chain centered comparison

The land that is potentially available to produce dedicated cellulosic bioenergy crops, often referred to as 'marginal' land, depends heavily on the underlying assumptions used to classify and identify it. In this study we compare three definitions and types of marginal land to identify the interactions between the bioenergy landscape and the logistics networks needed for the biofuel supply chain. Typical studies of the scale, cost, and greenhouse gas (GHG) mitigation potential of cellulosic biofuel take a land-centered approach which may neglect to account for the trade-offs between establishing bioenergy crops and the supply chain design decisions needed to allow those crops to be converted to liquid fuel. A mathematical programming approach is used to minimize the total annualized cost of a large-scale field-to-product system producing bioethanol in the USA midwest. Results show that a high concentration of marginal land leads to efficient systems and that the bioenergy landscape design becomes increasingly important with a higher emphasis on GHG mitigation. Additionally, targeted landscape design (including fertilization) with a focus on fields with high soil carbon sequestration potential can greatly reduce the system-wide GHG emissions for only a small increase in the unit cost of biofuel.

09 BIOMASS FUELS↗
DOE OSTI2021

High-Entropy Ceramic Coatings: Transformative New Materials for Environmentally-Compatible Thin-Film Insulators against High-T Molten Salts

An emerging new class of promising materials, High-Entropy Ceramics (HECs) or Compositionally-Complex Ceramics (CCCs), have been successfully fabricated in the last three years. This project evaluates HECs/CCCs in the concentrated solar power (CSP) context. In this project, we have identified a couple of simple, and key descriptors governing thermal conductivity in HECs. Size disorder among the cations was found to have a strong influence on the thermal conductivity across multiple systems and throughout a vast compositional space. Since identifying this, we have optimized previous compositions to achieve low thermal conductivities of $k$~$1-1.4Wm{-1}K{-1}$. We have further reduced our selection of promising compositions based on project guidelines and applied a theory that can potentially predict reactivity with molten salts to identify a small set of HECs that are suitable for further molten salt heat transfer media (HTM) stability testing. Many compositions reveal poor resistance to molten chloride salt after being exposed for 24 h compared to the reference structural alloy, Haynes 230. However, after 100 h, a few HECs/CCCs show strong parabolic rate constant effects and provide greater resistance to chloride salt compared to Haynes 230 alloy, which shows more linear kinetics. Postmortem characterization of the microstructure reveals the parabolic rate constant originates from a dense reaction layer form at the interface. This feature is absent in Haynes 230, which only shows grain boundary infiltration. The HECs/CCCs were also put in contact with the metal alloy under Ar for 800 h at 800°C and show negligible interaction. Lastly, parabolic rate constant HECs/CCCs also have low thermal conductivity $(<2 Wm^{-1} K^{-1})$ at 800°C. These specimens satisfy all project requirements and demonstrate their promising application in next-generation CSP.

14 SOLAR ENERGY↗
NASA NTRS1999

An Evaluation of Oceanographic Optical Instruments and Deployment Methodologies

The primary objective of the Sea-viewing, Wide Field-of-view Sensor (SeaWiFS) Project is to produce water- leaving radiances with an uncertainty of 5% in clear-water regions and chlorophyll a concentrations within +/- 35% over the range of 0.05-50 mg/cu m. Any global mission, like SeaWiFS, requires validation data be submitted from a wide variety of investigators which places a significant challenge on quantifying the total uncertainty associated with the in situ measurements, because each investigator follows slightly different practices when it comes to implementing all of the steps associated with collecting field data, even those with a prescribed set of protocols. This study uses data from multiple cruises to quantify the uncertainties associated with implementing data collection procedures while utilizing differing in-water optical instruments and deployment methods. A comprehensive approach is undertaken and includes: (1) the use of a portable light source and in-water intercomparisons to monitor the stability of the field radiometers, (2) alternative methods for acquiring reference measurements, and (3) different techniques for making in-water profiles. The only system to meet the 5% radiometric objective of the SeaWiFS Project was a free-fall profiler using (relatively inexpensive) modular components, although a more sophisticated (and comparatively expensive) profiler using integral components was very close and only 1% higher. A relatively inexpensive system deployed with a winch and crane was also close, but the ship shadow contamination problem increased the total uncertainty to approximately 6.5%.

Hooker, Stanford B.↗
NASA NTRS2000

Effect of Jet Injection Angle and Number of Jets on Mixing and Emissions From a Reacting Crossflow at Atmospheric Pressure

The mixing of air jets into hot, fuel-rich products of a gas turbine primary zone is an important step in staged combustion. Often referred to as "quick quench," the mixing occurs with chemical conversion and substantial heat release. An experiment has been designed to simulate and study this process, and the effect of varying the entry angle (0 deg, 22.5 deg and 45 deg from normal) and number of the air jets (7, 9, and 11) into the main flow, while holding the jet-to-crossflow mass-low ratio, MR, and momentum-flux ratio, J, constant (MR = 2.5;J = 25). The geometry is a crossflow confined in a cylindrical duct with side-wall injection of jets issuing from orifices equally spaced around the perimeter. A specially designed reactor, operating on propane, presents a uniform mixture to a module containing air jet injection tubes that can be changed to vary orifice geometry. Species concentrations of O2, CO, CO2, NO(x) and HC were obtained one duct diameter upstream (in the rich zone), and primarily one duct radius downstream. From this information, penetration of the jet, the spatial extent of chemical reaction, mixing, and the optimum jet injection angle and number of jets can be deduced.

St.John, D.↗
DOE OSTI2023

Counterion Control and the Spectral Signatures of Polarons, Coupled Polarons, and Bipolarons in Doped P3HT Films

When an electron is removed from a conjugated polymer, such as poly(3-hexylthiophene-2,5-diyl) (P3HT), the remaining hole and associated change in the polymer backbone structure from aromatic to quinoidal are referred to as a polaron. Bipolarons are created by removing the unpaired electron from an already-oxidized polymer segment. In electrochemically-doped P3HT films, polarons, and bipolarons are readily observed, but in chemically-doped P3HT films, bipolarons rarely form. This is explained by studying the effects of counterion position on the formation of polarons, strongly coupled polarons, and bipolarons using both spectroscopic and X-ray diffraction experiments and time-dependent density functional theory calculations. The counterion positions control whether two polarons spin-pair to form a bipolaron or whether they strongly couple without spin-pairing are found. When two counterions lie close to the same polymer segment, bipolarons can form, with an absorption spectrum that is blueshifted from that of a single polaron. Otherwise, polarons at high concentrations do not spin-pair, but instead J-couple, leading to a redshifted absorption spectrum. The counterion location needed for bipolaron formation is accompanied by a loss of polymer crystallinity. Finally, these results explain the observed formation order of single polarons, coupled single polarons, and singlet bipolarons in electrochemically- and chemically-doped conjugated polymers.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Design Methods, Tools, and Data for Ceramic Solar Receivers Year 1 Continuation Report

This report describes the first year of work on a project to develop the methods, tools, and data required to analyze high temperature ceramic Concentrating Solar Power (CSP) components. This first year focused on developing the methods and data required for a time-independent assessment of potential components, focusing in particular on ceramic solar receivers. The report describes both model development and testing work focused on accomplishing this goal. Our overall conclusion is that high temperature ceramic CSP components are viable and could provide a means to overcome the expected low reliability and short service life for equivalent components constructed from Ni-based superalloys. Based on the results reported here, we recommend the project continue to Phase II which will develop more sophisticated, realistic models for time-dependent failure of ceramics operating in expected CSP component conditions and develop the time-dependent ceramic test data needed to parameterize these models, using commercial SiC as a reference material.

14 SOLAR ENERGY↗
NASA NTRS2022

Alignment of Optical Backscatter Measurements from the EXPORTS Northeast Pacific Field Deployment

Backscattering of light is commonly measured by ocean observing systems, including ships and autonomous platforms, and is used as a proxy for the concentration of water column constituents such as phytoplankton and particulate carbon. Multiple on-going projects involve large numbers of independent measurements of backscatter, as well as other biologically relevant parameters, to understand how biology is changing in time and space throughout the global ocean. Rarely are there sufficient measurements to test how well these instruments are inter-calibrated in real-world deployment conditions. This paper develops a procedure to align multiple independently calibrated backscatter instruments to each other using nearby profiling casts and applies this method to nine instruments deployed during a recent field campaign in the North Pacific during August–September of 2018. This process revealed several incorrect calibrations; post-alignment, all nine instruments aligned extremely well with each other. We also tested an alignment to a deep-water reference and found that this method is generally sufficient but has significant limitations; this procedure lacks the ability to correct instruments measuring only shallow profiles and can only account for additive offsets, not multiplicative changes. These findings highlight the utility of process studies involving several independent measurements of similar parameters in the same area.

North Pacific↗
DOE OSTI2021

Approaching disorder-tolerant semiconducting polymers

Doping has been widely used to control the charge carrier concentration in organic semiconductors. However, in conjugated polymers, n-doping is often limited by the tradeoff between doping efficiency and charge carrier mobilities, since dopants often randomly distribute within polymers, leading to significant structural and energetic disorder. Here, we screen a large number of polymer building block combinations and explore the possibility of designing n-type conjugated polymers with good tolerance to dopant-induced disorder. We show that a carefully designed conjugated polymer with a single dominant planar backbone conformation, high torsional barrier at each dihedral angle, and zigzag backbone curvature is highly dopable and can tolerate dopant-induced disorder. With these features, the designed diketopyrrolopyrrole (DPP)-based polymer can be efficiently n-doped and exhibit high n-type electrical conductivities over 120 S cm -1 , much higher than the reference polymers with similar chemical structures. This work provides a polymer design concept for highly dopable and highly conductive polymeric semiconductors.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Genome reduction improves octanoic acid production in scale down bioreactors

Microorganisms in large-scale bioreactors are exposed to heterogeneous environmental conditions due to physical mixing constraints. Nutritional gradients can lead to transient expression of energetically wasteful stress responses and as a result, can reduce the titres, rates and yields of a bioprocess at larger scales. To what extent these process parameters are impacted is often unknown and therefore bioprocess scale-up comes with major risk. Designing platform strains to account for these intermittent stresses before introducing synthesis pathways is one strategy for de-risking bioprocess development. For example, Escherichia coli strain RM214 is a derivative of wild-type MG1655 that has had several genes and whole operons removed from its genome based on their metabolic cost. In this study, we engineered E. coli strain RM214 (referred to as WG02) to produce octanoic acid from glycerol in batch-flask and fed-batch bioreactor cultivations and compared it to an octanoic acid-producing E. coli MG1655 (WG01). In batch flask cultivations, the two strains performed similarly. However, in carbon limited fed-batch bioreactor cultivations, WG02 provided a greater than 22% boost to biomass compared to WG01 while maintaining similar titres of octanoic acid. Reducing the biomass accumulation of WG02 with nitrogen limited fed-batch cultivation resulted in a 16% improvement in octanoic acid titre over WG01. Finally, in a scale-down system consisting of a stirred tank reactor (representing a well-mixed zone) and plug flow reactor (representing an intermittent carbon starvation zone), WG02 again improved octanoic acid titre by almost 18% while maintaining similar biomass concentrations as WG01.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS2001

Understanding of Jupiter's Atmosphere After the Galileo Probe Entry

Instruments on the Galileo probe measured composition, cloud properties, thermal structure. winds, radiative energy balance, and electrical properties of the Jovian atmosphere. As expected the probe results confirm some expectations about Jupiter's atmosphere, refute others, and raise new questions which still remain unanswered. This talk will concentrate on those aspects of the probe observations which either raised new questions or remain unresolved. The Galileo probe observations of composition and clouds provided some of the biggest surprises of the mission. Helium abundance measured by the probe differed significantly from the remote sensing derivations from Voyager. discrepancy between the Voyager helium abundance determinations for Jupiter and the Galileo probe value have now led to a considerably increased helium determination for Saturn. Global abundance of N in the form of ammonia was observed to be supersolar by approximately the same factor as carbon, in contrast to expectations that C/N would be significantly larger than solar. This has implications for the formation and evolution of Jupiter. The cloud structure was not what was generally anticipated, even though most previous remote sensing results below the uppermost cloud referred to 5 micron hot spots, local regions with reduced cloud opacity. The Galileo probe descended in one of these hot spots. Only a tenuous, presumed ammonium hydrosulfide, cloud was detected, and no significant water cloud or super-solar water abundance was measured. The mixing ratios as a function of depth for the condensibles ammonia, hydrogen sulfide, and water, exhibited no apparent correlation with either condensation levels or with each other, an observation that is still a puzzle, although there are now dynamical models of hot spots which show promise in being able to explain such behavior. Probe tracked zonal winds show that wind magnitude increases with depth to pressures of about 4 bars, with the winds extending to at least as deep as the probe made measurements, 22 bars. Models of hot spot dynamics raise the possibility that the variation with depth of the probe measured zonal winds between 0.4 and 4 bars reflect the dynamics of the hot spot rather than the global wind pattern. Galileo upper atmosphere measurements established that there is a sharp temperature rise with altitude between about 350 and 800 km above the 1 bar pressure level, with the upper atmosphere reaching, temperatures near 900 K. The energy sources for this upper atmosphere heating are not clearly established, but various mechanisms have been proposed. These and other aspects of the Galileo probe data will be discussed.

Young, Richard E.↗
DOE OSTI2020

Ultra-thin passivation layers in Cu(In,Ga)Se 2 thin-film solar cells: full-area passivated front contacts and their impact on bulk doping

In the search for highly transparent and non-toxic alternative front layers replacing state-of-the-art CdS in Cu(In,Ga)Se 2 thin-film solar cells, alternatives rarely exceed reference devices in terms of efficiency. Full-area ultra-thin aluminium oxide tunnelling layers do not require any contact patterning and thus overcome the main drawback of insulating passivation layers. Even a few monolayers of aluminium oxide can be deposited in a controlled manner by atomic layer deposition, they show excellent interface passivation properties, low absorption, and suitable current transport characteristics on test devices. Depositing a ZnO-based transparent front contact, however, results in extremely poor solar cell performance. The issue is not necessarily a low quality of the alternative front layer, but rather the intricate relation between front layer processing and electronic bulk properties in the absorber layer. We identify three challenges critical for the development of novel front passivation approaches:(i) both Cd and Zn impurities beneficially reduce the high native net dopant concentration in the space charge region, (ii) sputter deposition of ZnO damages the passivation layer resulting in increased interface recombination, (iii) thermal treatments of devices with ZnO layer result in substantial Zn diffusion, which can penetrate the full absorber thickness already at moderate temperatures.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS2003

Understanding of Jupiter's Atmosphere after the Galileo Probe Entry

Instruments on the Galileo probe measured composition, cloud properties, thermal structure, winds, radiative energy balance, and electrical properties of the Jovian atmosphere. As expected the probe results confirm some expectations about Jupiter's atmosphere, refute others, and raise new questions which still remain unanswered. This talk will concentrate on those aspects of the probe observations which either raised new questions or remain unresolved. The Galileo probe observations of composition and clouds provided some of the biggest surprises of the mission. Helium abundance measured by the probe differed significantly from the remote sensing derivations from Voyager. Discrepancy between the Voyager helium abundance determinations for Jupiter and the Galileo probe value have now led to a considerably increased helium determination for Saturn. Global abundance of N in the form of ammonia was observed to be super-solar by approximately the same factor as carbon, in contrast to expectations that C/N would be significantly larger than solar. This has implications for the formation and evolution of Jupiter. The cloud structure was not what was generally anticipated, even though most previous remote sensing results below the uppermost cloud referred to 5 micron hot spots, local regions with reduced cloud opacity. The Galileo probe descended in one of these hot spots. Only a tenuous, presumed ammomium hydrosulfide, cloud was detected, and no significant water cloud or super-solar water abundance was measured. The mixing ratios as a function of depth for the condensibles ammonia, hydrogen sulfide, and water, exhibited no apparent correlation with either condensation levels or with each other, an observation that is still a puzzle, although there are now dynamical models of hot spots which show promise in being able to explain such behavior. Probe tracked zonal winds show that wind magnitude increases with depth to pressures of about 4 bars, with the winds extending to at least as deep as the probe made measurements, 22 bars. Models of hot spot dynamics raise the possibility that the variation with depth of the probe measured zonal winds between 0.4 and 4 bars reflect the dynamics of the hot spot rather than the global wind pattern. Galileo upper atmosphere measurements established that there is a sharp temperature rise with altitude between about 350 and 800 km above the 1 bar pressure level, with the upper atmosphere reaching temperatures near 900 K. The energy sources for this upper atmosphere heating are not clearly established, but various mechanisms have been proposed. These and other aspects of the Galileo probe data will be discussed.

Fonda, Mark↗
DOE OSTI2020

An Unobstructive Sensing Method for Indoor Air Quality Optimization and Metabolic Assessment within Vehicles

This work investigates the use of an intelligent and unobstructive sensing technique for maintaining vehicle cabin’s indoor air quality while simultaneously assessing the driver metabolic rate. CO 2 accumulation patterns are of great interest because CO 2 can have negative cognitive effects at higher concentrations and also since CO 2 accumulation rate can potentially be used to determine a person’s metabolic rate. The management of the vehicle’s ventilation system was controlled by periodically alternating the air recirculation mode within the cabin, which was actuated based on the CO 2 levels inside the vehicle’s cabin. The CO 2 accumulation periods were used to assess the driver’s metabolic rate, using a model that considered the vehicle’s air exchange rate. In the process of the method optimization, it was found that the vehicle’s air exchange rate (λ [h –1 ]) depends on the vehicle speeds, following the relationship: λ = 0.060 × (speed) – 0.88 when driving faster than 17 MPH. An accuracy level of 95% was found between the new method to assess the driver’s metabolic rate (1620 ± 140 kcal/day) and the reference method of indirect calorimetry (1550 ± 150 kcal/day) for a total of N = 16 metabolic assessments at various vehicle speeds. The new sensing method represents a novel approach for unobstructive assessment of driver metabolic rate while maintaining indoor air quality within the vehicle cabin.

passive sensing↗
NASA NTRS2004

The Southern Hemisphere Additional Ozonesondes (SHADOZ) 1998-2002 Tropical Ozone Climatology: Instrumentation and Station-to-Station Variability - 3

Abstract: Since 1998 the Southern Hemisphere ADditional OZonesondes (SHADOZ) project has collected more than 2000 ozone profiles from a dozen tropical and subtropical sites using balloon-borne electrochemical concentration cell (ECC) ozonesondes. The data (with accompanying pressure-temperature-humidity soundings) are archived. Analysis of ozonesonde imprecision within the SHADOZ dataset revealed that variations in ozonesonde technique could lead to station-to-station biases in the measurements. In this paper imprecisions and accuracy in the SHADOZ dataset are examined in light of new data. When SHADOZ total ozone column amounts are compared to version 8 TOMS (2004 release), discrepancies between sonde and satellite datasets decline 1-2 percentage points on average, compared to version 7 TOMS. Variability among stations is evaluated using total ozone normalized to TOMS and results of laboratory tests on ozonesondes (JOSE-2O00, Julich Ozonesonde Intercomparison Experiment). Ozone deviations from a standard instrument in the JOSE flight simulation chamber resemble those of SHADOZ station data relative to a SHADOZ-defined climatological reference. Certain systematic variations in SHADOZ ozone profiles are accounted for by differences in solution composition, data processing and instrument (manufacturer). Instrument bias leads to a greater ozone measurement above 25 km over Nairobi and to lower total column ozone at three Pacific sites compared to other SHADOZ stations at 0-20 deg.S.

Thompson, Anne M.↗
DOE OSTI2024

Helium metastable density determination in the COST reference source by absolutely calibrated optical emission spectroscopy

Helium metastable densities in the COST Reference Microplasma Jet are estimated for a variety of He/N2 admixtures and dissipated powers by applying a collisional-radiative model to absolutely calibrated optical emission spectroscopy measurements. This is accomplished by delineating the excitation mechanisms that result in the N2(C–B) and N2+(B–X) emission bands, the latter of which is strongly coupled to the presence of helium metastables. A number of other plasma parameters are established and discussed for each operating condition including the electron energy distribution function, reduced electric field, rate constants, and electron density. With these parameters, the reaction rates for the primary ionization pathways are also calculated, emphasizing the importance of helium metastables for discharge sustainment. Good agreement with the existing literature is found for most plasma parameters and for helium metastable densities, in particular. A clear [N2]−1 relationship between the nitrogen concentration and density of helium metastables is demonstrated, as has been identified in previous studies in analogous atmospheric pressure plasma jets. This validates the efficacy of this optical technique for determining helium metastable densities and establishes it as a viable, and in many cases, more accessible alternative to other means of quantifying helium metastables in low-temperature plasmas.

Physics↗
NASA NTRS1950

Linear theory of boundary effects in open wind tunnels with finite jet lengths

In the first part, the boundary conditions for an open wind tunnel (incompressible flow) are examined with special reference to the effects of the closed entrance and exit sections. Basic conditions are that the velocity must be continuous at the entrance lip and that the velocities in the upstream and downstream closed portions must be equal. In the second part, solutions are derived for four types of two-dimensional open tunnels, including one in which the pressures on the two free surfaces are not equal. Numerical results are given for every case. In general, if the lifting element is more than half the tunnel height from the inlet, the boundary effect at the lifting element is the same as for an infinitely long open tunnel. In the third part, a general method is given for calculating the boundary effect in an open circular wind tunnel of finite jet length. Numerical results are given for a lifting element concentrate at a point on the axis.

Katzoff, S↗