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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 883 records · Page 49

Renewable low-Z wall for fusion reactors with built-in tritium recovery (Final Technical Report)

This project pursued development of a novel renewable plasma-facing wall technology for fusion reactors. The technology is based on a slurry which can be easily delivered by delivery tubes to the reactor wall. The slurry dries at the hot reactor wall into pebble rods which are extruded out into the hot plasma, where the pebbles break off and fall along the reactor wall and can be recovered by gravity and re-used. The falling pebbles carry away heat and tritium and also protect the wall against large scale erosion or redeposition of material. The research focused on carbon-based pebble rods and demonstrated that pebble rods could be produced from slurry with tolerable levels of outgassing on a reactor-relevant timescale (< 5 minutes). Steady-state handling of reactor relevant (up to 50 MW/m 2 ) normal-incidence heat loads was demonstrated. Pebble release velocities were found to be sufficiently small (< 1 m/s) to allow recovery below the vacuum chamber. Tunability of the pebble rod breaking rate was demonstrated by changing the fill fraction of the interpebble matrix which binds the pebbles together. This work could benefit the public by helping move forward the design of commercially viable fusion energy reactors. Designing a first wall for magnetic fusion reactors which can handle the huge heat loads present and also avoid buildup of tritium-containing deposits is extremely challenging and requires novel approaches like the one being investigated here.

36 MATERIALS SCIENCE↗

Scalable Fabrication of a Fibrous Amine-functionalized Matrix (FAM) Sorbent for Critical Mineral Recovery

We report a novel flat sheet Fibrous Amine-functionalized Matrix (FAM) sorbent platform designed for efficient and selective capture of CM from dilute solutions. The FAM sorbent features crosslinked amine microfilms coated onto/within a glass fiber matrix, providing fast mass transfer and excellent mechanical stability. Systematic batch and flow-through tests with FAM revealed rapid metal uptake kinetics and high capacity for representative species, achieving ~90 mg/g of Gallium, ~100 mg/g of Cobalt, and ~90 mg/g for Neodymium. Moreover, multiple eluents, including mineral acids and complexing agents, enabled highly effective desorption of adsorbed metals, demonstrating the feasibility of regenerating FAM sorbents. Importantly, tests with authentic coal ash leachate demonstrated strong selectivity toward U.S. Department of Energy (DOE)-listed CM and rare earth elements over abundant base cations, confirming the robustness of FAM in realistic complex solutions. The flat sheet geometry was amenable to scaling into durable spiral wound modules, highlighting the potential for future regeneration and reuse. This work establishes FAM sorbents as a promising platform for the recovery of CM from wastewaters, advancing both resource sustainability and environmental stewardship.

critical mineral recovery↗

Chemically Enabled CO 2 -Enhanced Oil Recovery in Multi-Porosity, Hydrothermally Altered Carbonates in the Southern Michigan Basin - Task 2 Topical Report

This attachment A is a detailed Topical Report for Task 2 (Advanced Field Characterization and Machine Learning Based Data Integration) under the project "Chemically Enabled CO 2 -Enhanced Oil Recovery in Multi-Porosity, Hydrothermally Altered Carbonates in the Southern Michigan Basin." The overall project activity and finding, including the field pilot testing of CO 2 injection are summarized in the companion Final Technical Report The Advanced Field Characterization and Machine Learning Based Data Integration task (Task 2) involved a systematic geologic characterization of the Trenton-Black River (TBR) play in the SMB which included the development of comprehensive datasets, advanced data analytics, risk assessment, and piggyback field characterization. These activities aimed to address the complex carbonate systems by evaluating the extent of fractures, dolomitization, facies, and reservoir properties with the primary objective of informing the static and dynamic modeling, field injection test, and providing input into the development strategy plan. The task was divided into four subtasks: • Subtask 2.1 – Data compilation, review, and analysis • Subtask 2.2 – Risk Assessment • Subtask 2.3 – Advanced Field Characterization • Subtask 2.4 – Integrated Physics-Based Machine Learning and Advanced Data Analytics

02 PETROLEUM↗

Post-Closure Report for Closed Resource Conservation and Recovery Act Corrective Action Units, Nevada National Security Site, Nevada, For Calendar Year 2019, Revision 0

This report serves as the combined annual report for post-closure activities in compliance with the requirements listed in Resource Conservation and Recovery Act Permit Number NEV HW0101 associated with the following closed corrective action units (CAUs): • CAU 90, Area 2 Bitcutter Containment • CAU 91, Area 3 U-3fi Injection Well • CAU 92, Area 6 Decon Pond Facility • CAU 110, Area 3 WMD U-3ax/bl Crater • CAU 111, Area 5 WMD Retired Mixed Waste Pits • CAU 112, Area 23 Hazardous Waste Trenches

54 ENVIRONMENTAL SCIENCES↗

Recycling of Lithium-Ion Batteries via Electrochemical Recovery: A Mini-Review

With the rising demand for lithium-ion batteries (LIBs), it is crucial to develop recycling methods that minimize environmental impacts and ensure resource sustainability. The focus of this short review is on the electrochemical techniques used in LIB recycling, particularly electrochemical leaching and electrodeposition. Our summary covers the latest research, highlighting the principles, progress, and challenges tied to these methods. By examining the current state of electrochemical recovery, this review intends to provide guidance for future advancements and enhance LIB recycling efficiency.

25 ENERGY STORAGE↗

Studies toward the Use of Ionic Liquids and Supercritical CO 2 for the Recovery and Separation of Praseodymium from Waste Streams

Waste streams from the incineration of metal-containing materials like such as computer processor boards and batteries may contain critical rare earth elements like praseodymium. Data on the solubility of Pr compounds and on their distribution coefficients in supercritical CO 2 /ionic liquid two-phase systems are important to determine if an ionic liquid/supercritical CO 2 two-phase approach is feasible toward the recovery of a particular metal. This work provides data on the solubility of various praseodymium compounds in butyl-methyl-pyrrolidinium bis(trifluoromethylsulfonyl)imide (BMPyTf2N) ionic liquid and on the distribution coefficients of these praseodymium compounds in the supercritical CO 2 phase of the two-phase BMPyTf2N ionic liquid/supercritical CO 2 system, with and without a tributyl phosphate additive.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Restoration Insights Gained from a Field Deployment of Dithionite and Acetate at a Uranium In Situ Recovery Mine

Mining uranium by in situ recovery (ISR) typically involves injecting an oxidant and a complexing agent to mobilize and extract uranium in a saturated ore zone. This strategy involves less infrastructure and invasive techniques than traditional mining, but ISR often results in persistently elevated concentrations of U and other contaminants of concern in groundwater after mining. These concentrations may remain elevated for an extended period without remediation. Here, we describe a field experiment at an ISR facility in which both a chemical reductant (sodium dithionite) and a biostimulant (sodium acetate) were sequentially introduced into a previously mined ore zone in an attempt to establish reducing geochemical conditions that, in principle, should decrease and stabilize aqueous U concentrations. While several lines of evidence indicated that reducing conditions were established, U concentrations did not decrease, and in fact increased after the amendment deployments. We discuss likely reasons for this behavior, and we also discuss how the results provide insights into improvements that could be made to the restoration process to benefit from the seemingly detrimental behavior.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗