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At least 883 records · Page 49

Global asymptotic stability of dynamic dissipative compensators for multibody flexible space structures

The stability characteristics of dynamic dissipative compensators are investigated for multibody flexible space structures having nonlinear dynamics. The problem addressed is that of proving asymptotic stability of dynamic dissipative compensators. The stability proof uses the Liapunov approach and exploits the inherent passivity of such systems. For such systems these compensators are shown to be robust to parametric uncertainties and unmodeled dynamics. The results are applicable to a large class of structures such as flexible space structures with articulated flexible appendages.

Kelkar, Atul G.↗

Optimizing aluminum oxide passivation layers—Laser-induced plasmas for layer formation, real-time diagnostics, and layer evaluation

Molten salts have beneficial thermophysical and electrolytic properties, but the aggressive nature of molten salts requires corrosion mitigation strategies, such as structural material surface treatment. In this study, a laser-induced breakdown spectroscopy (LIBS) system was used to simultaneously ablate and monitor de-excitation spectra to form and identify dense alumina passivation layers. Additionally, high-frequency (kHz) LIBS imaging allowed rapid elemental mapping and depth profiling for surface O/Al ratios via minimally destructive analysis. The paired t-test rejected the null hypothesis that air and Ar cover gases were equivalent (p = 0.00012), and the analysis of variance (ANOVA) showed that overlap between shots (p = 0.03112) and cover gas flow rate (p = 0.02729) were statistically significant. At 75% overlap, the O/Al ratio increased to 10% ± 2%, and 90% overlap rose further to 31% ± 2%. Regardless of overlap, tuning the gas flow from 0.5 to 2.5 L min −1 enhanced the O/Al ratio by 24% ± 4%. LIBS depth profiling showed a 3× increase in layer thickness from 75% to 90% overlap. Molecular band peaks of AlO, a precursor to Al 2 O 3 found during treatment, suggest that band intensity could be used for real-time Al 2 O 3 optimization. Ultimately, by adjusting laser spot overlap and cover gas flow rate, a 266 nm laser was shown to form Al 2 O 3 layers on an Al6061 sample, with cover gas flow rate primarily affecting the O/Al ratio and layer thickness correlating with laser spot overlap. This combination of molecular spectra collection, imaging, and depth profiling demonstrated the robust layer analysis capabilities of LIBS.

Corrosion↗

Degradation of HT9 under simultaneous ion beam irradiation and liquid metal corrosion

A potentially promising coolant/structural material pair for a liquid-metal-cooled fast reactors is lead bismuth eutectic (LBE) coolant with the ferritic/martensitic steel HT9. The challenge of deploying LBE, however, is the corrosive environment it creates for structural materials. This corrosion can be mitigated with precise oxygen content control in the LBE to allow for the growth of passive protective oxide layers on the surface of the steel. In this paper, results are reported from the Irradiation Corrosion Experiment II (ICE-II), which allowed the simultaneous irradiation of a sample while in contact with LBE. It was found that a characteristic multilayer structure with an outer Fe 3 O 4 oxide and inner FeCr 2 O 4 spinel was grown and the oxidation was significantly larger in the irradiated region when compared to the region that was only exposed to LBE corrosion. As a result, a possible mechanisms are discussed to help understand this irradiation enhanced corrosion behavior.

36 MATERIALS SCIENCE↗

Defect state passivation at III-V oxide interfaces for complementary metal–oxide–semiconductor devices

The paper describes the reasons for the greater difficulty in the passivation of interface defects of III–V semiconductors like GaAs. These include the more complex reconstructions of the starting surface which already possess defect configurations, the possibility of injecting As antisites into the substrate which give rise to gap states, and the need to avoid As-As bonds and As dangling bonds which give rise to gap states. The nature of likely defect configurations in terms of their electronic structure is described. The benefits of diffusion barriers and surface nitridation are discussed.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Achieving Accuracy Requirements for Forest Biomass Mapping: A Spaceborne Data Fusion Method for Estimating Forest Biomass and Lidar Sampling Error

The synergistic use of active and passive remote sensing (i.e., data fusion) demonstrates the ability of spaceborne light detection and ranging (LiDAR), synthetic aperture radar (SAR) and multispectral imagery for achieving the accuracy requirements of a global forest biomass mapping mission (+/-20 Mg/ha or 20%, the greater of the two, for at least 80% of grid cells). A data fusion approach also provides a means to extend 3D information from discrete spaceborne LiDAR measurements of forest structure across scales much larger than that of the LiDAR footprint. For estimating biomass, these measurements mix a number of errors including those associated with LiDAR footprint sampling over regional-global extents. A general framework for mapping above ground live forest biomass density (AGB) with a data fusion approach is presented and verified using data from NASA field campaigns near Howland, ME, USA, to assess AGB and LiDAR sampling errors across a regionally representative landscape. We combined SAR and Landsat-derived optical (passive optical) image data to identify contiguous areas (>0.5 ha) that are relatively homogenous in remote sensing metrics (forest patches). We used this image-derived data with simulated spaceborne LiDAR derived from orbit and cloud cover simulations and airborne data from NASA's Laser Vegetation Imaging Sensor (LVIS) to compute AGB and estimate LiDAR sampling error for forest patches and 100 m, 250 m, 500 m, and 1 km grid cells. At both the patch and grid scales, we evaluated differences in AGB estimation and sampling error from the combined use of LiDAR with both SAR and passive optical and with either SAR or passive optical alone. First, this data fusion approach demonstrates that incorporating forest patches into the AGB mapping framework can provide sub-grid forest information for coarser grid-level AGB reporting. Second, a data fusion approach for estimating AGB using simulated spaceborne LiDAR with SAR and passive optical image combinations reduced forest AGB sampling errors 12%-38% from those where LiDAR is used with SAR or passive optical alone. In absolute terms, sampling errors were reduced from 14-40 Mg/ha to 11-28 Mg/ha across all grid scales and prediction methods, where minimum sampling errors were 11, 15, 18, and 22 Mg/ha for 1 km, 500 m, 250 m, and 100 m grid scales, respectively. Third, spaceborne global scale accuracy requirements were achieved whereby at least 80% of the grid cells at 100 m, 250 m, 500 m, and 1 km grid levels met AGB accuracy requirements using a combination of passive optical and SAR along with machine learning methods to predict vegetation structure metrics for forested areas without LiDAR samples. Finally, using either passive optical or SAR, accuracy requirements were met at the 500 m and 250 m grid level, respectively..

LiDAR↗

Robust control of nonlinear flexible multibody systems using quaternion feedback and dissipative compensation

Global asymptotic stability of a class of nonlinear multibody flexible space structures under dissipative compensation is established. Two cases are considered. The first case allows unlimited nonlinear motions of the entire system and uses quaternion feedback. The second case assumes that the central body motion is in the linear range although the other bodies can undergo unrestricted nonlinear motion. The stability is proved to be robust to the inherent modeling nonlinearities and uncertainties. Furthermore, for the second case, the stability is also shown to be robust to certain actuator and sensor nonlinearities. The stability proofs use the Lyapunov approach and exploit the inherent passivity of such systems. The results are applicable to a wide class of systems, including flexible space structures with articulated flexible appendages.

Kelkar, Atul G.↗

Bayesian Estimation of Precipitation from Satellite Passive Microwave Observations Using Combined Radar-Radiometer Retrievals

Precipitation estimation from satellite passive microwave radiometer observations is a problem that does not have a unique solution that is insensitive to errors in the input data. Traditionally, to make this problem well posed, a priori information derived from physical models or independent, high-quality observations is incorporated into the solution. In the present study, a database of precipitation profiles and associated brightness temperatures is constructed to serve as a priori information in a passive microwave radiometer algorithm. The precipitation profiles are derived from a Tropical Rainfall Measuring Mission (TRMM) combined radar radiometer algorithm, and the brightness temperatures are TRMM Microwave Imager (TMI) observed. Because the observed brightness temperatures are consistent with those derived from a radiative transfer model embedded in the combined algorithm, the precipitation brightness temperature database is considered to be physically consistent. The database examined here is derived from the analysis of a month-long record of TRMM data that yields more than a million profiles of precipitation and associated brightness temperatures. These profiles are clustered into a tractable number of classes based on the local sea surface temperature, a radiometer-based estimate of the echo-top height (the height beyond which the reflectivity drops below 17 dBZ), and brightness temperature principal components. For each class, the mean precipitation profile, brightness temperature principal components, and probability of occurrence are determined. The precipitation brightness temperature database supports a radiometer-only algorithm that incorporates a Bayesian estimation methodology. In the Bayesian framework, precipitation estimates are weighted averages of the mean precipitation values corresponding to the classes in the database, with the weights being determined according to the similarity between the observed brightness temperature principal components and the brightness temperature principal components of the classes. Because the classes are stratified by the sea surface temperature and the echo-top-height estimator, the number of classes that are considered for retrieval is significantly smaller than the total number of classes, making the algorithm computationally efficient. The radiometer-only algorithm is applied to TMI observations, and precipitation estimates are compared with combined TRMM precipitation radar (PR) TMI reference estimates. The TMI-only algorithm, supported by the empirically derived database, produces estimates that are more consistent with the reference values than the precipitation estimates from the version-6 TRMM facility TMI algorithm. Cloud-resolving model simulations are used to assign a latent heating profile to each precipitation profile in the empirically derived database, making it possible to estimate latent heating using the radiometer-only algorithm. Although the evaluation of latent heating estimates in this study is preliminary, because realistic conditional probability distribution functions are attached to latent heating structures in the algorithm s database, a generally positive impact on latent heating estimation from passive microwave observations is expected.

Grecu, Mircea↗

WE-F-16A-03: 3D Printer Application in Proton Therapy: A Novel Method to Deliver Passive-Scattering Proton Beams with a Fixed Range and Modulation for SRS and SRT

Purpose: To present a novel technique to deliver passive-scattering proton beam with fixed range and modulation using a 3D printed patient-specific bolus for proton stereotactic radiosurgery and radiotherapy. Methods: A CIRS head phantom was used to simulate a patient with a small brain lesion. A custom bolus was created in the Eclipse Treatment Planning System (TPS) to compensate for the different water equivalent depths from the patient surface to the target from multiple beam directions. To simulate arc therapy, a plan was created on the initial CT using three passive-scattering proton beams with a fixed range and modulations irradiating from different angles. The DICOM-RT structure file of the bolus was exported from the TPS and converted to STL format for 3D printing. The phantom was rescanned with the printed custom bolus and head cup to verify the dose distribution comparing to the initial plan. EBT3 films were placed in the sagital plane of the target to verify the delivered dose distribution. The relative stopping power of the printing material(ABSplus-P430) was measured using the Zebra multi-plate ion chamber. Results: The relative stopping power of the 3D printing material, ABSplus-P430 was 1.05 which is almost water equivalent. The dose difference between verification CT and Initial CT is almost negligible. Film measurement also confirmed the accuracy for this new proton delivery technique. Conclusion: Our method using 3D printed range modifiers simplify the treatment delivery of multiple passive-scattering beams in treatment of small lesion in brain. This technique makes delivery of multiple beam more efficient and can be extended to allow arc therapy with proton beams. The ability to create and construct complex patient specific bolus structures provides a new dimension in creating optimized quality treatment plans not only for proton therapy but also for electron and photon therapy.

60 APPLIED LIFE SCIENCES↗

Characterization of the Pulsed Radiation Environment in FREC-II at the ACRR

Ongoing tests at the Annular Core Research Reactor (ACRR) at Sandia National Laboratories aim to measure temperature and strain in materials exposed to a transient neutron-photon environment. Radiation transport and finite element analysis codes are used to predict the thermal-structural response of test articles exposed in the reactor. Strain and temperature sensors fielded on test articles provide validation data for finite element models, while active and passive radiation dosimetry provides data for MCNP models. The ACRR is able to provide pulse energies of 40 - 300 MJ per pulse with pulse times of 7 - 100 milliseconds. The pulse power is higher than many of the other research reactors due to its unique high heat capacity UO{sub 2}-BeO fuel in the central reactor. Additionally, the Fuel Ringed External Cavity (FREC-II) contains U-ZrH fuel. Future tests at the ACRR plan to field test assemblies in the Fuel Ringed External Cavity (FREC-II) and expose the test articles to the transient anisotropic radiation field experienced in the cavity. The FREC-II is coupled with the ACRR core and is used to test larger specimens, and the radiation environment can be shaped/modified to the needs of the experiment. The FREC-II was designed to provide an irradiation cavity with a strong flux gradient favoring the central cavity side. Neutron fluence also varies by height in the cavity, with a peak level slightly below the fuel rod vertical centerline. Tests were conducted in 2014 to measure the thermal-structural response of test articles exposed in the central cavity. Those tests in the central cavity fielded Nickel activation foils to record the neutron fluence at various locations around the test assembly. Foil data was later used to highlight uncertainties between thermo-structural response models and the measured temperature and strain. Studies performed in 2015 exposed large arrays of activation foils and thermo-luminescent dosimeters (TLD) in the FREC-II cavity in order to map out the neutron and photon spectrum at many locations. This type of passive measurement was shown to be too simple for performing thermo-structural simulations of a test article in response to multiple pulsed-reactor exposures. The Depleted Uranium Strain and Temperature - Enhanced Response (DUSTER-II) experiments will expose test assemblies to reactor pulses in the FREC-II cavity. To prepare for these experiments, the MCNP model will be compared with June 2016 experimental results from the pulses with the FREC-II coupled with the ACRR. These comparisons will provide an accurate model to be implemented in further studies. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Engineering Polymers as Structural Materials in Spacecraft Water Systems

The novel application of structural materials, surface treatments, and barrier coatings is desired to mitigate the rapid loss of ionic silver (Ag+) biocide observed with passive metal alloys, improve reliability, and reduce system mass. In this work, we provide an initial look at the potential replacement of these heritage alloys in spacecraft water systems with high-performance thermoplastic engineering polymers, including PEEK, PEI, and PVDF. Such materials have found increasing use as structural materials in a broad array of performance-critical applications, including in the aerospace, medical implant, and chemical processing fields. We selected a number of promising materials for investigation, compiled mechanical behavior data, and conducted theoretical performance analyses. We also identified and began to address numerous material suitability concerns as well as design requirements for pressurized components in human-rated spacecraft hardware. These include material flammability, offgassing, leaching, chemical resistance, radiation tolerance, prevention of fracture/yielding, and others. We find that there is significant potential for use of engineering polymers in spacecraft water systems, and suggest some directions for future research.

Lance Dean Delzeit↗

Additive Engineering for Efficient and Stable Perovskite Solar Cells

Perovskite solar cells (PSCs) have reached a certified 25.2% efficiency in 2019 due to their high absorption coefficient, high carrier mobility, long diffusion length, and tunable direct bandgap. However, due to the nature of solution processing and rapid crystal growth of perovskite thin films, a variety of defects can form as a result of the precursor compositions and processing conditions. The use of additives can affect perovskite crystallization and film formation, defect passivation in the bulk and/or at the surface, as well as influence the interface tuning of structure and energetics. Here, recent progress in additive engineering during perovskite film formation is discussed according to the following common categories: Lewis acid (e.g., metal cations, fullerene derivatives), Lewis base based on the donor type (e.g., O-donor, S-donor, and N-donor), ammonium salts, low-dimensional perovskites, and ionic liquid. Various additive-assisted strategies for interface optimization are then summarized; additives include modifiers to improve electron- and hole-transport layers as well as those to modify perovskite surface properties. To conclude, an outlook is provided on research trends with respect to additive engineering in PSC development.

14 SOLAR ENERGY↗

A digital computer program for the dynamic interaction simulation of controls and structure (DISCOS), volume 1

A theoretical development and associated digital computer program system for the dynamic simulation and stability analysis of passive and actively controlled spacecraft are presented. The dynamic system (spacecraft) is modeled as an assembly of rigid and/or flexible bodies not necessarily in a topological tree configuration. The computer program system is used to investigate total system dynamic characteristics, including interaction effects between rigid and/or flexible bodies, control systems, and a wide range of environmental loadings. In addition, the program system is used for designing attitude control systems and for evaluating total dynamic system performance, including time domain response and frequency domain stability analyses.

Bodley, C. S.↗

Design of ground test suspension systems for verification of flexible space structures

A simple model demonstrates the frequency-increasing effects of a simple cable suspension on flexible test article/suspension systems. Two passive suspension designs, namely a negative spring mechanism and a rolling cart mechanism, are presented to alleviate the undesirable frequency-increasing effects. Analysis methods are provided for systems in which the augmentations are applied to both discrete and continuous representations of test articles. The damping analyses are based on friction equivalent viscous damping. Numerical examples are given for comparing the two augmentations with respect to minimizing frequency and damping increases.

Cooley, V. M.↗

Significant electrical control of amorphous oxide thin film transistors by an ultrathin Ti surface polarity modifier

We demonstrate an enhanced electrical stability through a Ti oxide (TiO{sub x}) layer on the amorphous InGaZnO (a-IGZO) back-channel; this layer acts as a surface polarity modifier. Ultrathin Ti deposited on the a-IGZO existed as a TiO{sub x} thin film, resulting in oxygen cross-binding with a-IGZO surface. The electrical properties of a-IGZO thin film transistors (TFTs) with TiO{sub x} depend on the surface polarity change and electronic band structure evolution. This result indicates that TiO{sub x} on the back-channel serves as not only a passivation layer protecting the channel from ambient molecules or process variables but also a control layer of TFT device parameters.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Corrosion evaluation of Ti–6Al–4V manufactured by electron beam melting in Ringer’s physiological solution: an in vitro study of the passive film

We report that electrochemical characteristics and semiconducting behavior of additively manufactured electron beam melted (EBM) and wrought (WR) Ti–6Al–4V (Ti-G5) are compared in Ringer’s physiological solution. X-ray diffraction (XRD) and field emission scanning electron microscopy (FE-SEM) confirmed the α+β structure of the tested materials, with two different microstructure types of “bimodal” and “basket-weave” for WR and EBM, respectively. Potentiodynamic polarization (PDP) revealed that the corrosion current density for EBM (i corr =0.27±0.06 μA cm -2 ) is less than the WR (i corr =0.70±0.05 μA cm -2 ). Moreover, potentiostatic polarization (PS) that was employed to form the passive layers at three different potentials of 300, 500, and 700 mV Ag/AgCl , showed that the passive films on the EBM sample are thinner. This finding was confirmed by electrochemical impedance spectroscopy (EIS). Furthermore, through Mott–Schottky (M–S) analysis, donor densities on WR passive films were found to be ~1.5 times larger than EBM. Although PS and EIS confirmed that the passive layer on EBM is thinner, it provides higher corrosion resistance than WR. The passive layer on both samples were found to have n-type characteristics with a duplex structure.

36 MATERIALS SCIENCE↗

Electroactive ZnO: Mechanisms, Conductivity, and Advances in Zn Alkaline Battery Cycling

Zinc oxide is of great interest for advanced energy devices because of its low cost, wide direct bandgap, non-toxicity, and facile electrochemistry. In zinc alkaline batteries, ZnO plays a critical role in electrode passivation, a process that hinders commercialization and remains poorly understood. Here, novel observations of an electroactive type of ZnO formed in Zn-metal alkaline electrodes are disclosed. The electrical conductivity of battery-formed ZnO is measured and found to vary by factors of up to 10 4 , which provides a first-principles-based understanding of Zn passivation in industrial alkaline batteries. Simultaneous with this conductivity change, protons are inserted into the crystal structure and electrons are inserted into the conduction band in quantities up to ≈10 20 cm –3 and ≈1 mAh gZnO –1 . Electron insertion causes blue electrochromic coloration with efficiencies and rates competitive with leading electrochromic materials. The electroactivity of ZnO is evidently enabled by rapid crystal growth, which forms defects that complex with inserted cations, charge-balanced by the increase of conduction band electrons. Furthermore, this property distinguishes electroactive ZnO from inactive classical ZnO. Knowledge of this phenomenon is applied to improve cycling performance of industrial-design electrodes at 50% zinc utilization and the authors propose other uses for ZnO such as electrochromic devices.

36 MATERIALS SCIENCE↗

Columbia County Habitat for Humanity Passive Townhomes

Columbia County (New York) Habitat for Humanity built a pair of townhomes to Passive House criteria with the purpose of exploring approaches for achieving Passive House performance and to eventually develop a prototype design for future projects. The project utilized a 2x6 frame wall with a structural insulated panel curtain wall and a ventilated attic over a sealed OSB ceiling air barrier. Mechanical systems include a single head, wall mounted ductless mini-split heat pump in each unit and a heat recovery ventilator. Costs were $26,000 per unit higher for Passive House construction compared with the same home built to ENERGY STAR version 3 specifications, representing about 18% of total construction cost. This report discusses the cost components, energy modeling results and lessons from construction. Two alternative ventilation systems are analyzed: a central system; and, a point-source system with small through-wall units distributed throughout the house. The report includes a design and cost analysis of these two approaches.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Building America Case Study: Columbia County Habitat for Humanity Passive Townhomes, Hudson, New York

Columbia County (New York) Habitat for Humanity built a pair of townhomes to Passive House criteria with the purpose of exploring approaches for achieving Passive House performance and to eventually develop a prototype design for future projects. The project utilized a 2x6 frame wall with a structural insulated panel curtain wall and a ventilated attic over a sealed OSB ceiling air barrier. Mechanical systems include a single head, wall mounted ductless mini-split heat pump in each unit and a heat recovery ventilator. Costs were $26,000 per unit higher for Passive House construction compared with the same home built to ENERGY STAR version 3 specifications, representing about 18 percent of total construction cost. This report discusses the cost components, energy modeling results and lessons from construction. Two alternative ventilation systems are analyzed: a central system; and, a point-source system with small through-wall units distributed throughout the house. The report includes a design and cost analysis of these two approaches.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗