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At least 883 records · Page 49

NH3 in IRC plus 10216

Ammonia was detected in the circumstellar envelope of IRC +10216 by means of three infrared absorption lines in the nu sup 2 band around 950/cm. The lines are fully resolved at a resolution of 0.22 km/sec and indicate that most of the circumstellar gas is accelerated to expansion velocities around 14 km/sec within a few stellar radii. The NH3 profiles indicate a rotational temperature between 400 and 700 K, and H2 density between 10 to the 8th power/cu cm and 10 to the 10th power/cu cm, and NH3 column density of 10 to the 17th power/sq cm. The H2 density indicates that the mass of the circumstellar envelope within a 1 arcsec radius is approximately 0.1 solar masses.

Betz, A. L.↗

NH3 in IRC +10216

Ammonia has been detected in the circumstellar envelope of IRC +10216 by means of three infrared absorption lines in the nu-2 band around 950 kaysers. The profiles are well resolved at a resolution of 0.22 km/s and show that most of the circumstellar gas is accelerated to expansion velocities around 14 km/s within a few stellar radii. The observed ammonia requires a rotational temperature between 400 and 700 K, an H2 density between 100 million and 10 billion per cu cm, and an NH3 column density of 10 to the 17th per sq cm. The H2 density indicates that the mass of the circumstellar envelope within a 1 arcsec radius is about 0.1 solar mass.

Betz, A. L.↗

The 12- to 20-micron spectrum of Venus - Implications for temperature and cloud structure

The spectrum of Venus was measured between approximately 500 and 800 kaysers (12 to 20 microns) at a resolution of 3.12 kaysers from the NASA C141 G. P. Kuiper Airborne Observatory on 22 and 24 February 1977. The spectrum clearly shows the detailed structure of CO2 absorption in the vicinity of the nu-2 fundamental band at 667 kaysers. In addition, details of model fitting demonstrate the possibility for a cold and thin haze of sulfuric acid droplets along with an optically opaque cloud top near 250 K. Such clouds represent major differences from other H2SO4 main cloud deck models in the recent literature and may be indicative of changes in the vertical distribution of aerosols on a global scale. The temperatures retrieved for pressures at or below 10 mbar are largely independent of the cloud model assumed and they are some 16 to 20 K warmer than the 1972 NASA model. All retrieved temperatures lie within the range of Mariner 5 and Mariner 10 radio occultation inversion results.

Aumann, H. H.↗

Velocity profiles of the 2.1 micron H2 emission line in the Orion molecular cloud

Spectra of the H2 nu = 1-0 S(1) emission line in Orion, observed at various positions with a resolution of 20 km/s, are presented. The intrinsic full width at half-maximum of the line ranges from 18 to 58 km/s over the observed positions. Analysis of the line profiles shows that the emitting gas is probably expanding from a region near the BN and KL infrared sources at velocities typically of 40 km/s but as high as 100 km/s, and that it is associated with the source of the broad lines seen in the spectra of many other molecules. Strong constraints are placed on models of the physical processes responsible for the broad emission lines.

Nadeau, D.↗

Ultraviolet and X-ray observations of Seyfert galaxies and low z QSOs

An analysis of IUE observations of Seyfert galaxies and QSOs indicates that they have the same energy source and heating mechanisms. Neither collisional de-excitation nor simple dust models are sufficient to explain the small L alpha/H beta ratio of Seyfert galaxies and low z QSOs, which is below the recombination value. For Seyfert galaxies, the Log nu (1450) correlates well with Log W lambda (C IV), with a slope similar to that of QSOs. Regarding X-ray fluxes, which were obtained by the A2 experiment onboard the HEAO-1 satellite, the L alpha luminosity correlates well with the continuum luminosity at 1450 A, and there is a positive correlation between the X-ray luminosity and the full line width at zero intensity.

Wu, C.-C.↗

Influence of gravity wave activity on lower thermospheric photochemistry and composition

The wind and temperature oscillations of internal gravity waves can cause horizontal variations of a factor of two in minor gas number densities in the lower thermosphere over length scales of several hundred kilometers. The variations are due both to vertical transport of constituents whose lifetimes are long compared to the wave period and to chemical activity driven by temperature dependent reaction rate coefficients. The nightglow emission of the hydroxyl radical provides a remote sensor of wave activity between 80 and 90 km. Theoretical calculations show that the horizontal variations in the atomic hydrogen distribution are the largest single contributor to wave structure in the nightglow followed by the effects of temperature fluctuations on the rate coefficient of the reaction H + O3 yields O2 + OH (nu prime is greater than 0).

Frederick, J. E.↗

Production of OH from photolysis of HOCl at 307-309 nm

Laser-induced fluorescence has been used to measure the amount of OH produced in the laser photolysis of HOCl at 310 nm. The HOCl was generated by the Cl2O + H2O and by the HCl + Cl2O reactions. The laser technique samples OH on a microsecond time scale so that secondary radical reactions cannot contribute significantly to the observed signals. The fluorescence signals were calibrated with O3-H2O mixtures, the reactions O3 + h(nu) yields O(1D) + O2 and O(1D) + H2O yields 2OH yielding known amounts of OH. The value for the absorption cross section of HOCl at 310 nm has been determined to be 6 x 10 to the -20th sq cm, assuming K(eq) = 0.082 for the Cl2O + H2O yields 2HOCl system and assuming unit quantum yield for the production of OH. The present investigation further supports earlier experimental work concluding that HOCl will photodissociate rapidly and will not be an important holding tank for chlorine in the stratosphere. These results are in disagreement with theoretical calculations of the UV absorption spectrum of HOCl in the 300-350-nm wavelength region.

Molina, M. J.↗

Ground-state rotational constants of /C-13/H3D

Rotational constants for the vibrational ground state of (C-13)H3D, which has been detected in the atmospheres of Jupiter and Saturn, are reported. High-resolution spectra of monodeuteromethane were obtained in the region 1800 to 2500 kaysers by a vacuum Fourier interferometer, and the values of the rotational constants B0, D0J, D0JK, H0JJJ, H0JJK and H0JKK were calculated by an analysis of ground-state combination differences in the nu 2(A1) band. The calculated frequency and intensity of this transition are found to be in agreement with the observed values.

Chackerian, C., Jr.↗

High-resolution laser absorption spectroscopy of ozone near 1129.4 cm (-1)

A Beer's Law experiment was performed with a tunable diode laser to determine self broadened line shape parameters of one infrared absorption ozone line in the nu1 band for ten pressures from 0.26 to 6.29 torr at 285 K. The SO2 line positions were used for wavelength calibration. Line shapes were iteratively fitted to the Voigt function at a Doppler width of 29.54 MHz (HWHM) resulting in values for the integrated line strength, (S), of (0.144 +/- 0.007) x 10 to the minus 20th/cm molecule/cu cm, line center frequency, nu sub o, of 1129.426/cm and the Lorentzian contributions to halfwidth. A linear least squares fit of (alpha sub L)5 as a function of pressure yielded a zero intercept of 15.27 +/- 0.29 MHz (rho = 0.99) and a broadening parameter, (alpha sub L)5, of 5.71 +/- 0.29 MHz/Torr. This results in a line width (FWHM) of 0.144 +/- .007/cm at 760 torr and 285 K.

Majorana, L. N.↗

Acceleration wave breakup of liquid jets with airstreams

Characteristic mean drop diameters were determined for downstream and upstream injection into nonswirling and swirling airflows. The effects of the aerodynamic and liquid surface forces on the mean drop size were obtained with a scanning radiometer. Water jet breakup was studied primarily in the acceleration wave regime with values of WeRe 10 to the 6th power and the following empirical expression was obtained: D(o)/D(m) =C (WeRe) to the 0.4, power where D(o) and D(m) are the orifice and mean drop diameters, respectively. We and Re are the Weber and Reynolds numbers defined as repectively, We = rho(a)D(o)V(r)/sigma and Re = D(o)V(r)/nu, where V(r) and rho(a) are airstream relative velocity and density, respectively, and sigma and nu are surface tension and kinematic viscosity of the liquid, respectively. The proportionally constant C was evaluated as follows: for downstream injection, C = 0.023 with nonswirling airflow, and C = 0.027 with swirling airflow. For upstream injection, the empirical expression D(o)/D(m) = 0.0045 (WeRe) to the 0.5 power was obtained with nonswirling airflow. Experimental conditions included a water flow rate of 68 liter per hour and an airflow rate per unit area range of 4.6 to 25.2 gm/sq cm sec at 293 K and atmospheric pressure.

Ingebo, R. D.↗

Photoexcitation of lasers and chemical reactions for NASA missions: A theoretical study

The possibility of obtaining CW laser oscillation by optical pumping in the infrared at an elevated gas pressure is reviewed. A specific example utilizing a mixture of CO and NO gases is included. The gas pressures considered are in excess of several atmospheres. Laser frequency tuning over a broad region becomes possible at such elevated gas pressures due to collisional broadening of the amplifying transitions. The prior-rate and surprisal analysis are applied to obtain detailed VV and VT rates for CO and NO molecules and the transfer rates in a CO-NO gas mixture. The analysis is capable of giving temperature dependence of the rate constants. Computer estimates of the rates are presented for vibrational levels up to v = 50. The results show that in the high-lying vibrational states the VV transfer rates with Delta nu = 2 become appreciable.

Javan, A.↗

Influence of thermal boundary conditions on heat transfer from a cylinder in cross flow

Local heat transfer data over the leading surface of a cylinder in crossflow were obtained for a Reynolds number range of 50,000. The cylinder was operated at both uniform-wall-temperature and uniform-heat-flux thermal ance of 80 deg from the front stagnation point, the uniform-wall-temperature heat transfer coefficients were as much as 66 percent lower than the uniform-heat-flux data. Between the stagnation point and 60 deg around the cylinder, there were no significant differences in the data. This region of the cylinder is within the cylindrical curvature region of the front end of a real turbine so it was concluded that either thermal boundary condition could be used to model turbine flow over that region of the blade. Results of evaluating the exponent x in the fundamental relationship Nu=f(Re) sup x, which is used in data correlation show the exponent varies as a function of local position on the cylinder even in the laminar flow region. The value of x increases linearly from 0.50 at the stagnation point to 0.59 at 60 deg around the cylinder. This linear trend continued into the separation region at 80 deg for the uniform-wall-temperature data, but x increased markedly in the separation region for the uniform-heat-flux data.

Papell, S. S.↗

Infrared observations of circumstellar ammonia in OH/IR supergiants

Ammonia has been detected in the circumstellar envelopes of VY Canis Majoris, VX Sagittarii, and IRC +10420 by means of several absorption lines in the nu-2 vibration-rotation band near 950 kaysers. The line profiles are well resolved (0.2 km/sec resolution) and show the gas being accelerated to terminal expansion velocities near 30 km/sec. The observations reveal a method for determining the position of the central star on VLBI maps of OH maser emission to an accuracy of approximately 0.2 arcsec. A firm lower limit of 2 x 10 to the 15th/sq cm is obtained for the NH3 column density in VY Canis Majoris.

Mclaren, R. A.↗

Infrared heterodyne spectroscopy of circumstellar molecules

Ammonia has been detected in the circumstellar envelopes of IRC+10216, VY CMa, VX Sgr, and IRC+10420. A number of absorption lines of (N-14)H3 in the nu sub 2 vibration-rotation band around 28 THz (950 per cm) have been observed at a velocity resolution of 0.2 km/s. Typical linewidths are 1 to 4 km/s, and the details of the line profiles provide additional insights on the process of mass loss in these stars.

Betz, A. L.↗

Ethylene in IRC +10216

Ethylene has been detected in the circumstellar gas surrounding the supergiant star IRC +10216. Two lines of the nu sub 7 vibration-rotation band near 28 THz (949/cm) have been seen in absorption at an expansion velocity of 14 km/sec relative to the central star. The line intensities indicate a rotational temperature of T greater than 400 K and a radial C2H4 column density of 10 to the 16th to 10 to the 17th per sq cm.

Betz, A. L.↗

N2 pressure - broadened O3 line widths and strengths near 1129.4 cm-1

A Beer's Law experiment was performed with a tunable diode laser to find the N2 pressure broadening characteristics of a single 03 absorption line at 1129.426 cm for N2 pressures from 10 to 100 torr (O3 pressure = 3.16 torr). SO2 line positions were used for wavelength calibration. Line shapes were interatively fitted to a Lorentz function. Results were delta (HWHM in MHz) = 47.44 (+ or - 5.34) MHz + 1.730 (+ or - 0.088) MHz/torr *p(torr) with sigma = 0.9897. This intercept compares well with the Doppler O3 - O3 broadened (at 3.16 torr) width of 44.52 Hz. This result in a HWHM line width of 0.44 cm atm at 760 torr and 285 K. The line strengths integrated over delta nu = 0.55 cm were found to be N2 pressure dependent.

Copeland, G. E.↗

The peculiar UV extinction of Herschel 36

The differential extinction curve of Herschel 36 was determined from International Ultraviolet Explorer data. It is quite unusual, characterized by a distinct 2200 A peak with a very low far blue end at 5 to 7 mu to the -1 power. The star appears to be an extreme member of the group Savage drew attention to, previously consisting only of theta Ori, NU Ori, sigma Sco, and rho Oph. It appears that multiple scattering effects are needed to explain the observations.

Hecht, J.↗

The resonance line of B II in IUE spectra of chemically peculiar stars

A description is presented of high-dispersion spectroscopic observations of eight chemically peculiar stars including Kappa Cnc and Mu Lep, and of one normal comparison star, Nu Cap, in the vicinity of 1362 A. The reported data were obtained with the International Ultraviolet Explorer during the first 15 months of its operation. The initial reduction of the data, which were originally described in a qualitative summary by Leckrone (1980), was affected by a serious error in the calibration of the instrument's intensity transfer function. This error has been corrected in the currently presented data. The results of spectrum syntheses of the 1362 A feature are also described for several of the stars.

Leckrone, D. S.↗