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At least 883 records · Page 49
All sourcesNASA NTRSDOE OSTI
NASA NTRS1998

An Assessment of Molten Metal Detachment Hazards for Electron Beam Welding in the Space Environment: Analysis and Test Results

Conditions under which molten metal detachments might occur in a space welding environment are analyzed. A weld pool detachment parameter specifying conditions for pool detachment by impact is derived and corroborated by experimental evidence. Impact detachment for the pool is unlikely. Impact detachment for a drop of metal on the end of the weld wire may be possible under extreme conditions. Other potential causes of molten metal detachment considered, vaporization pressure forces and wire flickout from the pool, did not appear to present significant detachment threats.

Nunes, A. C., Jr.↗
NASA NTRS1961

Effect of Inert, Reducing, and Oxidizing Atmospheres on Friction and Wear of Metals to 1000 F

Experiments were conducted in inert, reducing, and oxidizing atmospheres to determine their influence on the friction and wear properties of various metals. Nitrogen, argon, forming gas (10 volume percent H2, 90 volume percent N2), and various concentrations of oxygen in nitrogen were used. A 3/16-inch-radius hemispherical rider under a load of 1000 grams contacted the flat surface of a rotating disk. The surface speed employed was 35 feet per minute. The presence of surface oxides is vitally important to the protection of metals in sliding contact. Extremely high friction and excessive wear were encountered in the absence of these oxides. In some instances (electrolytically pure copper), the removal of the surface oxides resulted in mass welding of the specimens in sliding contact. Extremely small quantities of oxygen are sufficient to provide protection of metal surfaces; for example, with 440-C stainless steel, 0.03 volume percent oxygen was found to be adequate.

Buckley, Donald H.↗
NASA NTRS1999

Ignition and Combustion of Bulk Metals in a Microgravity Environment

Results of a study of heterogeneous and homogeneous combustion of metals in reduced gravity are presented. Cylindrical titanium and magnesium samples are radiatively ignited in pure-oxygen at 1 atm. Qualitative observations, propagation rates, and burning times are extracted from high-speed cinematography. Time-resolved emission spectra of gas-phase reactions are acquired with an imaging spectrograph. Lower propagation rates of the reacting mass on titanium and of ignition waves on magnesium are obtained at reduced gravity. These rates are compared to theoretical results from fire-spread analyses with a diffusion/convection controlled reaction. The close agreement found between experimental and theoretical propagation rates indicates the strong influence of natural-convection-enhanced oxygen transp6rt on burning rates. Lower oxygen flux and lack of condensed product removal appear to be responsible for longer burning times of magnesium gas-phase diffusion flames in reduced gravity. Spherically symmetric explosions in magnesium flames at reduced gravity (termed radiation-induced metal explosions, or RIME) may be driven by increased radiation heat transfer from accumulated condensed products to an evaporating metal core covered by a porous, flexible oxide coating. In titanium specimens, predominantly heterogeneous burning characterizes the initial steady propagation of the molten mass, while homogeneous gas-phase reactions are detected around particles ejected from the molten mixture. In magnesium specimens, band and line reversal of all the UV spectral systems of Mg and MgO are attributed to the interaction between small oxide particles and the principal gaseous emitters.

Branch, Melvyn C.↗
NASA NTRS1999

Friction Stir Welding of SiC/Aluminum Metal Matrix Composites

Friction Stir Welding (FSW) is a new solid state process for joining metals by plasticizing and consolidating materials around the bond line using thermal energy producing from frictional forces. A feasibility study for FSW of Metal Matrix Composites (MMC) was investigated using aluminum 6092 alloy reinforced with 17% SiC particulates. FSW process consists of a special rotating pin tool that is positioned to plunge into the MMC surface at the bond line. As the tool rotates and move forward along the bond line, the material at the bond line is heated up and forced to flow around the rotating tip to consolidate on the tip's backside to form a solid state joint. FSW has the potential for producing sound welds with MMC because the processing temperature occurs well below the melting point of the metal matrix; thereby eliminating the reinforcement-to-matrix solidification defects, reducing the undesirable chemical reactions and porosity problems.

Lee, Jonathan A.↗
NASA NTRS1999

The Second-Parameter Effect in Metal-Rich Globular Clusters

Recent Hubble Space Telescope (HST) observations have shown that the metal-rich globular clusters (GCs) NGC 6388 and NGC 6441 exhibit a pronounced 2nd parameter effect. Ordinarily metal-rich GCs have only a red horizontal-branch (HB) clump. However, NGC 6388 and NGC 6441 also possess an unexpected population of blue HB stars, indicating that some 2nd parameter is operating in these clusters. Quite remarkably, the HBs in both clusters slope upward with decreasing B -V from the red clump to the top of the blue tail. We review the results of ongoing stellar evolution calculations which indicate (1) that NGC 6388 and NGC 6441 might provide a crucial diagnostic for understanding the origin of the 2nd parameter effect, (2) that differences in age or mass loss along the red-giant branch (RGB) - the two most prominent 2nd parameter candidates - cannot explain the HB morphology of these GCs, and (3) that noncanonical effects involving an enhanced helium abundance or rotation can produce upward sloping HBs. Finally we suggest a new metal-depletion scenario which might help to resolve a baffling conundrum concerning the surface gravities of the blue HB stars in these clusters.

Sweigart, Allen V.↗
NASA NTRS1998

In situ Resource Utilization for Processing of Metal Alloys on Lunar and Mars Bases

Current plans for practical missions leading to a sustained human presence on our Moon and Mars rely on utilizing their in situ resources. Initially, resource availability must be assessed followed by the development of economically acceptable and technically feasible extractive processes. In regard to metals processing and fabrication, the lower gravity level on the Moon (0.125 g) and Mars (0.369 g) will dramatically change the presently accepted hierarchy of materials in terms of specific properties, a factor which must be understood and exploited. Furthermore, significant changes are expected in the behavior of liquid metals during processing. In metal casting, for example, mold filling and associated solidification processes have to be reevaluated. Finally, microstructural development and therefore material properties, presently being documented through ongoing research in microgravity science and applications, needs to be understood and scaled to the reduced gravity environments. These and other issues are addressed in this paper.

Stefanescu, D. M.↗
NASA NTRS1999

Source of Global Scale Variations in the Midday Vertical Content of Ionospheric Metal Ions

An analysis of long baseline NIMBUS 7 SBUV (Solar Backscatter UV Spectrometer) observations of the latitudinal variation of the noontime vertical Mg' content above approx. 70 km have revealed seasonal, solar activity and magnetic activity dependencies in the Mg+ content. The distributions were categorized in terms of magnetic coordinates partially because transport processes lifting metallic ions from the main meteor ionization layer below 100 km up into the F- region and down again are controlled by electrodynamical processes. Alternatively, the Nimbus Mg+ distributions may simply be a result of ion/neutral chemistry changes resulting from atmospheric changes and not dynamics. In such a case magnetic control would not dominate the distributions. Using in situ satellite measurements of metal ions from the Atmosphere Explorer satellites in the region above the main meteor layer and published sounding rocket measurements of the main metallic ion layers, the effects of the dynamics on the vertical content are delineated. The consequences of atmospheric changes on the vertical content are explored by separating the Nimbus measurements in a geodetic frame of reference.

Joiner, J.↗
NASA NTRS1999

[Observations in the Outer Galaxy of Metal Abundances]

This project involved observations of far-infrared (FIR) fine-structure lines of [S III] (19,33 microns), [O III] (52,99 microns), and [N III] (57 microns) in the outer Galaxy (galactocentric radius R = 11-18 kpc), in order to study the variation of metal abundances with radius in the Galaxy. The metal abundance gradient is a fundamental input into models of galaxy evolution, and greatly constrains theories of galaxy evolution, stellar structure and evolution, and star formation. In addition, we observed the [C III (158 microns) and [O I] (63 microns) lines in these same regions to study molecular cloud structure in the low metallicity outer Galaxy. These observations were carried out over two weeks in August 1995 aboard the Kuiper Airborne Observatory, which was stationed at Hickam AFB at the time. Two Harvey Mudd students worked with me planning the observations and accompanied me on the flights. These students, and two other Harvey Mudd students, worked with me during the remaining time of the grant period analyzing these data and preparing them for publication These data have formed the basis for two journal articles in a professional astronomical journal. The first off these articles has been published (Rudolph et al. 1997, "Far-Infrared Abundance Measurements in the Outer Galaxy", The Astrophysical Journal, 489, 94-101). The second article is in preparation (Rudolph et al. 1999, "The Abundance Gradient in the Galaxy", in preparation for The Astrophysical Journal).

Source record↗
NASA NTRS2000

Parametric Weight Comparison of Advanced Metallic, Ceramic Tile, and Ceramic Blanket Thermal Protection Systems

A parametric weight assessment of advanced metallic panel, ceramic blanket, and ceramic tile thermal protection systems (TPS) was conducted using an implicit, one-dimensional (I-D) finite element sizing code. This sizing code contained models to account for coatings fasteners, adhesives, and strain isolation pads. Atmospheric entry heating profiles for two vehicles, the Access to Space (ATS) vehicle and a proposed Reusable Launch Vehicle (RLV), were used to ensure that the trends were not unique to a certain trajectory. Ten TPS concepts were compared for a range of applied heat loads and substructural heat capacities to identify general trends. This study found the blanket TPS concepts have the lightest weights over the majority of their applicable ranges, and current technology ceramic tiles and metallic TPS concepts have similar weights. A proposed, state-of-the-art metallic system which uses a higher temperature alloy and efficient multilayer insulation was predicted to be significantly lighter than the ceramic tile stems and approaches blanket TPS weights for higher integrated heat loads.

Myers, David E.↗
NASA NTRS2000

Thermodynamic Analysis of the Combustion of Metallic Materials

Two types of computer codes are available to assist in the thermodynamic analysis of metallic materials combustion. One type of code calculates phase equilibrium data and is represented by CALPHAD. The other type of code calculates chemical reaction by the Gordon-McBride code. The first has seen significant application for alloy-phase diagrams, but only recently has it been considered for oxidation systems. The Gordon-McBride code has been applied to the combustion of metallic materials. Both codes are limited by their treatment of non-ideal solutions and the fact they are limited to treating volatile and gaseous species as ideal. This paper examines the significance of these limitations for combustion of metallic materials. In addition, the applicability of linear-free energy relationships for solid-phase oxidation and their possible extension to liquid-phase systems is examined.

Wilson, D. Bruce↗
NASA NTRS2000

Examples of Unsteady Combustion in Non-Metallized Propellants

For over thirty years the T-Burner has been the de facto standard for determining the unstable response of solid propellants. This paper reviews some of the different approaches that have been used, and briefly summarizes advantages and disadvantages of the different techniques. Data from a variety of sources have been reviewed and summarized showing the effect of various test conditions and propellant formulation variations. Much of the data taken in the 60's and early 70's were with so-called research propellants, with relatively low solids loading and usually monomodal AP as the oxidizer. Later data were obtained with propellants containing solids loading more typical and practical propellants. Several distinct differences were observed in the data for the different types of propellants. Data varying AP particle size distributions indicate that either additional fine AP or finer AP usually increases the propellant response. A significant reduction in the response can be achieved by reducing the amount of fine AP, while holding burning rate constant either by adding a catalyst or by varying the overall AP size distribution. A significant amount of data has been obtained for reduced smoke propellants containing stability additives. The data indicate that the additives provide significant particle damping, and most often, also reduce the propellant response. Data from double base propellants indicate a much broader response over a wide frequency range. This implies that double base propellants should be more unstable in tangential modes than composite propellants. This trend seems to be consistent with observed motor data. Measuring the response of metallized propellants has been a challenge due to the large damping due to metal oxide particles in the gas. Data from metallized propellants are not presented here, but will be summarized in a future paper.

Beckstead, M. W.↗
NASA NTRS2000

Development of Metal Casting Molds By Sol-Gel Technology Using Planetary Resources

Metals extracted from planetary soils will eventually need to be casted and shaped in-situ to produce useful products. In response to this challenge, we propose to develop and demonstrate the manufacturing of a specific product using Lunar and Martian soil simulants, i.e. a mold for the casting of metal and alloy parts, which will be an indispensable tool for the survival of outposts on the Moon and Mars. Drawing from our combined knowledge of sol-gel and metal casting technologies, we set out to demonstrate the extraordinary potential of mesoporous materials such as aerogels to serve as efficient casting molds as well as fulfilling numerous other needs of an autonomous planetary outpost.

Sibille, L.↗
NASA NTRS2001

Metal Matrix Composite LOX Turbopump Housing Via Novel Tool-Less Net-Shape Pressure Infiltration Casting Technology

Metal matrix composites (MMC) offer relatively higher specific strength, specific stiffness, lower coefficient of thermal expansion (CTE) and lower density as compared with conventional alloys. These unique properties make them very attractive for aerospace turbomachinery applications where there is ever increasing emphasis to reduce weight and cost, and to increase engine performance. Through a joint effort between NASA and Metal Matrix Cast Composites, Inc., a complex liquid oxygen (LOX) compatible turbopump housing is being redesigned and manufactured from hybrid (particulate and fibers) Aluminum MMC. To this end, a revolutionary tool-less pressure infiltration casting technology is being perfected. Ceramic preforms for the composite are 3-dimensionally printed using a stereolithography file, acquired from a CAD model. The preforms are then invested into a refractory material and pressure infiltrated with liquid metal. After casting, the refractory material is washed away leaving behind a near net-shape composite part. Benefits of this process include increased composite uniformity, no mold machining, short time from design to part, properties matching traditional methods, ability to make previously impossible to manufacture parts and no size limitations with a newly developed joining technology. The results of materials, manufacturing and design optimizations, preform joining, and sub-element tests will be presented.

Shah, Sandeep↗
NASA NTRS2000

Metal Nanoparticle Aerogel Composites

We have fabricated sol-gels containing gold and silver nanoparticles. Formation of an aerogel produces a blue shift in the surface plasmon resonance as a result of the decrease in the dielectric constant of the matrix upon supercritical extraction of the solvent. However, as a result of chemical interface damping this blue shift does not obey effective medium theories. Annealing the samples in a reducing atmosphere at 400 C eliminates this discrepancy and results in narrowing and further blue shifting of the plasmon resonance. Metal particle aggregation also results in a deviation from the predictions of effective medium theories, but can be controlled through careful handling and by avoiding the use of alcohol. By applying effective medium theories to the heterogeneous interlayer surrounding each metal particle, we extend the technique of immersion spectroscopy to inhomogeneous materials characterized by spatially dependent dielectric constants, such as aerogels. We demonstrate that the shift in the surface plasmon wavelength provides the average fractional composition of each component (air and silica) in this inhomogeneous layer, i.e. the porosity of the aerogel or equivalently, for these materials, the catalytic dispersion. Additionally, the kinetics suggest that collective particle interactions in coagulated metal clusters are perturbed during silica gelation resulting in a change in the aggregate geometry.

Smith, David D.↗
NASA NTRS2000

Heat Transfer Performances of Pool Boiling on Metal-Graphite Composite Surfaces

Nucleate boiling, especially near the critical heat flux (CHF), can provide excellent economy along with high efficiency of heat transfer. However, the performance of nucleate boiling may deteriorate in a reduced gravity environment and the nucleate boiling usually has a potentially dangerous characteristic in CHF regime. That is, any slight overload can result in burnout of the boiling surface because the heat transfer will suddenly move into the film-boiling regime. Therefore, enhancement of nucleate boiling heat transfer becomes more important in reduced gravity environments. Enhancing nucleate boiling and critical heat flux can be reached using micro-configured metal-graphite composites as the boiling surface. Thermocapillary force induced by temperature difference between the graphite-fiber tips and the metal matrix, which is independent of gravity, will play an important role in bubble detachment. Thus boiling heat transfer performance does not deteriorate in a reduced-gravity environment. Based on the existing experimental data, and a two-tier theoretical model, correlation formulas are derived for nucleate boiling on the copper-graphite and aluminum-graphite composite surfaces, in both the isolated and coalesced bubble regimes. Experimental studies were performed on nucleate pool boiling of pentane on cooper-graphite (Cu-Gr) and aluminum-graphite (Al-Gr) composite surfaces with various fiber volume concentrations for heat fluxes up to 35 W per square centimeter. It is revealed that a significant enhancement in boiling heat transfer performance on the composite surfaces is achieved, due to the presence of micro-graphite fibers embedded in the matrix. The onset of nucleate boiling (the isolated bubble regime) occurs at wall superheat of about 10 C for the Cu-Gr surface and 15 C for the Al-Gr surface, much lower than their respective pure metal surfaces. Transition from an isolated bubble regime to a coalesced bubble regime in boiling occurs at a superheat of about 14 C on Cu-Gr surface and 19 C on Al-Gr surface.

Zhang, Nengli↗
NASA NTRS2001

Metal Matrix Composite LOX Turbopump Housing Via Novel Tool-Less Net-Shape Pressure Infiltration Casting Technology

Metal matrix composites (MMC) offer relatively higher specific strength, specific stiffness, lower coefficient of thermal expansion (CTE) and lower density as compared with conventional alloys. These unique properties make them very attractive for aerospace turbomachinery applications where there is ever increasing emphasis to reduce weight and cost, and to increase engine performance. Through a joint effort between NASA and Metal Matrix Cast Composites, Inc., a complex liquid oxygen (LOX) compatible turbopump housing is being redesigned and manufactured from hybrid (particulate and Fibers) Aluminum MMC. To this end, a revolutionary tool-less pressure infiltration casting technology is being perfected. Ceramic preforms for the composite are 3-dimensionally printed using a stereolithography file, acquired from a CAD model. The preforms are then invested into a refractory material and pressure infiltrated with liquid metal. After casting, the refractory material is washed away leaving behind a near net-shape composite part. Benefits of this process include increased composite uniformity, no mold machining, short time from design to part properties matching traditional methods, ability to make previously impossible to manufacture parts and no size limitations with a newly developed joining technology. The results of materials, manufacturing and design optimizations, preform joining, and sub element tests will be presented.

Shah, Sandeep↗
NASA NTRS2001

Metallic Electrode: Semiconducting Nanotube Junction Model

A model is proposed for two observed current-voltage (I-V) patterns in an experiment with a scanning tunneling microscope tip and a carbon nanotube [Collins et al., Science 278, 100 ('97)]. We claim that there are two contact modes for a tip (metal) -nanotube semi conductor) junction depending whether the alignment of the metal and semiconductor band structure is (1) variable (vacuum-gap) or (2) fixed (touching) with V. With the tip grounded, the tunneling case in (1) would produce large dI/dV with V > 0, small dI/dV with V < 0, and I = 0 near V = 0 for an either n- or p-nanotube. However, the Schottky mechanism in (2) would result in forward current with V < 0 for an n-nanotube, while with V > 0 for an p-nanotube. The two observed I-V patterns are thus entirely explained by a tip-nanotube contact of the two types, where the nanotube must be n-type. We apply this picture to the source-drain I-V characteristics in a long nanotube-channel field-effect-transistor (Zhou et al., Appl. Phys. Lett. 76, 1597 ('00)], and show that two independent metal-semiconductor junctions connected in series are responsible for the observed behavior.

Yamada, Toshishige↗
NASA NTRS2001

Variable Stars in the Unusual, Metal-Rich Globular Cluster NGC-6441

We have undertaken a search for variable stars in the metal-rich globular cluster NGC 6441 using time-series BV photometry. The total number of variables found near NGC 6441 has been increased to approx. 104, with 48 new variables being found in this survey. A significant number of the variables are RR Lyrae stars (approx. 46), most of which are probable cluster members. As was noted by Layden et al. (1999), the periods of the fundamental mode RR Lyrae are unusually long compared to field stars of similar metallicity. The existence of these long period RRab stars is consistent with Sweigart & Catelan's (1998) prediction that the horizontal branch of NGC 6441 is unusually bright. This result implies that the metallicity-luminosity relationship for RR Lyrae stars is not universal. We discuss the difficulty in determining the Oosterhoff classification of NGC 6441 due to the unusual nature of its RR Lyrae. A number of ab-type RR Lyrae are found to be both brighter and redder than the other probable RRab found along the horizontal branch, which may be a result of blending with stars of redder color. A smaller than usual gap is found between the shortest period fundamental mode and the longest period first-overtone mode RR Lyrae. We determine the reddening of the cluster to be E(B - V) = 0.51 +/- 0.02 mag, with substantial differential reddening across the face of the cluster. The mean V magnitude of the RR Lyrae is found to be 17.51 +/- 0.02 resulting in a distance of 10.4 to 11.9 kpc, for a range of assumed values of < M(sub V)> for RR Lyrae stars. The possibility that stars in NGC 6441 may span a range in [Fe/H] is also discussed.

Pritzl, Barton J.↗