Transforming large-scale industrially produced carbon nanotubes to high-performance electrode materials for lithium-ion batteries
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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These slides present work jointly completed by Tasks in PrOMMiS. The first half of the presentation motivates the importance of critical materials for national security and how the recovery of critical minerals via membrane separations can be more cost effective than currently used technology. The second half of the presentation presents cost-optimal results for the custom cost model for diafiltration using the superstructure flowsheet developed by CMU. These results highlight how PSE can inform process targets (i.e., product purity targets) and suitable design strategies for scaled-up membrane cascades.
The project has two primary objectives: (1) down select three-dimensional (3D) printing and post-processing approaches for solid-state electrolyte (SSE) / cathode integration, and (2) understand battery failure mechanisms via ex situ and in situ characterization.
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Visible absorption bands of alkali metals in molten alkali chlorides
The abundance of the following elements in the L 16-19 No. 118 regolith sample, zone V was determined by isotopic dilution using a mass spectrometer equipped with a scattering ion source: Li -- 9.8, Be -- 1.2, Be -- 2.6, and Ti -- 1.92 percent. For comparison, these same elements were measured in samples of surface material returned by Apollo 11, Apollo 12, and Apollo 14, and in the terrestrial reference standard diabase W-1. The content of Li, Be, and B in the Luna 16 sample is nearly the same as in the Apollo 11 surface material. The surface material returned by Apollo 12 and Apollo 14 contains two to four times more of these elements. However, the abundance ratios of Li, Be, and B are remarkably similar in the surface materials from the four different lunar regions. With respect to basaltic achondrites and especially with respect to chondrites, the lunar basalts are enriched in Li, Be, and B up to 100 times.
In open clusters, late-F stars exhibit a Li maximum (the Li 'peak' region) at lower abundance with age, which could be due either to stellar depletion or Galactic Li enrichment (or some other cause). We have observed a short-period tidally locked binary (SPTLB) on the Li peak region in the old cluster M67 to distinguish between alternatives. SPTLBs which synchronized in the early pre-main sequence would avoid the rotational mixing which, according to Yale models, may be responsible for depleting Li with age in open cluster dwarfs. We find that both components of the M67 SPTLB have a Li abundance lying about a factor of 2 or more above any other M67 single star and about a factor of 3 or more above the mean Li peak region abundance in M67. Our results suggest that the initial Li abundance in M67 is at least as high as approximately 3.0 = 12 + log (N(sub Li)/N(sub H)). Our high M67 SPTLB Li abundance and those in other clusters support the combination of Zahn's tidal circularization and the Yale rotational mixing theories and may indicate that the halo Li plateau (analogous to the cluster Li peak region) abundance has been depleted from a higher primordial value. Implications are discussed.
This NASA Aerospace Flight Battery Systems Working Group was chartered within the NASA Engineering and Safety Center (NESC). The Battery Working Group was tasked to complete tasks and to propose proactive work to address battery related, agency-wide issues on an annual basis. In its first year of operation, this proactive program addressed various aspects of the validation and verification of aerospace battery systems for NASA missions. Studies were performed, issues were discussed and in many cases, test programs were executed to generate recommendations and guidelines to reduce risk associated with various aspects of implementing battery technology in the aerospace industry. This report contains the Appendices to the findings from the first year of the program's operations.
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