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At least 883 records · Page 49

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NASA NTRS1989

Early shaping of asymmetrical planetary nebulae

It is suggested that the shape of a young asymmetrical planetary nebulae may be influenced by a close binary-star located at its center. This binary is a relic of the common envelope phase, presumably through which the asymmetrical planetary nebula evolved. It is assumed that, for a short period of time, shortly after the cessation of the slow wind and long before the fast wind becomes effective, the binary ejects a small amount of mass, mainly in the equatorial plane. By using two-dimensional hydrodynamics it is found that, at late times, the high-density region has a 'horsehoe' shape, as viewed in the symmetry plane. There is an instability in the maximum density region, which shows up as a high-density knot. The exact scale of the knot is determined by the numerics. The applications of the results to observations are discussed.

Soker, Noam↗

NASA NTRS1999

MHD Streamer Structure, Slow Solar Wind, and the Streamer Brightness Boundary

Flow tubes adjacent to closed magnetic field lines on the boundaries of streamers can have extremely large geometric spreading factors. Numerical models in this thin layer are subject to grid definition uncertainties. Therefore, we compute flow tube geometry using the analytic model of streamer structure described by Pneuman. This model has been found to be more widely applicable than commonly believed as a consequence of observations made with SOHO/UVCS and YOKHOH/SXT. We use the model to compute the radial dependence of flow tube geometry (the "spreading factors") for several different streamer models. The results are used to analyze the hypothesis that extremely slow flows in these open flow tubes may cause high densities relative to adjacent coronal hole flow. Such high density could mean that the streamer brightness boundary is defined by the open flow tubes adjacent to streamers rather than closed field lines.

Suess, Steven T.↗

NASA NTRS2012

SOFIA Observations of S106: Dynamics of the Warm Gas

Context The H II region/PDR/molecular cloud complex S106 is excited by a single O-star. The full extent of the warm and dense gas close to the star has not been mapped in spectrally resolved high-J CO or [C II] lines, so the kinematics of the warm. partially ionized gas, are unknown. Whether the prominent dark lane bisecting the hourglass-shaped nebula is due solely to the shadow cast by a small disk around the exciting star or also to extinction in high column foreground gas was an open question until now. Aims. To disentangle the morphology and kinematics of warm neutral and ionized gas close to the star, study their relation to the bulk of the molecular gas. and to investigate the nature of the dark lane. Methods. We use the heterodyne receiver GREAT on board SOFIA to observe velocity resolved spectral lines of [C II] and CO 11 yields 10 in comparison with so far unpublished submm continuum data at 350 micron (8HARC-Il) and complementary molecular line data. Results. The high angular and spectral resolution observations show a very complex morphology and kinematics of the inner S106 region, with many different components at different excitation conditions contributing to the observed emission. The [C II] lines are found to be bright and very broad. tracing high velocity gas close to the interface of molecular cloud and H II region. CO 11 yields 10 emission is more confined.. both spatially and in velocity, to the immediate surroundings of S 106 IR showing the presence of warm, high density (clumpy) gas. Our high angular resolution submm continuum observations rule out the scenario where the dark lane separating the two lobes is due solely to the shadow cast by a small disk close to the star. The lane is clearly seen also as warm, high column density gas at the boundary of the molecular cloud and H II region.

Simon, R.↗

DOE OSTI2025

Molecular Design Considerations for Azobenzene Anolytes

Realization of high-density batteries requires the development of anolytes that display highly negative reduction potentials, solubility, and persistence in the charged state. Azobenzenes have garnered interest as potential anolytes for redox flow batteries. Here, we report the synthesis of a family of substituted azobenzene derivatives and evaluation of their solution-phase electrochemical properties. Systematic synthetic derivatization of this scaffold allows (1) access to anolytes of varying solubility, including intrinsically liquid derivatives that represent potential high-density charge carriers; (2) systematic variation of the reduction potential, and in some cases redox inventory, that provides azobenzenes with highly negative reduction potentials; and (3) control of the lifetime of the azobenzene radical anions that result from one-electron reduction. Electrokinetic experiments demonstrated that fast electron transfer occurs for all derivatives examined. Spectroscopic characterization of monoreduced azobenzene derivatives establishes that decomposition of the azobenzene radical anion proceeds via bimolecular disproportionation. Together, these results provide an experimental basis for the optimization of azobenzene anolytes for electrochemical storage applications, including redox flow batteries.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2024

High Power Density Thermal Energy Storage With Phase Change Material in Enhanced Compact Heat Exchangers

Abstract Performance of a novel ultracompact thermal energy storage (TES) heat exchanger, designed as a microchannel finned-tube exchanger is presented. With water as the heating–cooling fluid in the microchannels, a salt hydrate phase change material (PCM), lithium nitrate trihydrate (LiNO3 · 3H2O), was encased on the fin side. To establish the hypothesis that small-length-scale encasement (<3 mm) of PCM substantially enhances heat transfer to yield very high power-density energy storage, heat exchanger designs with 10 and 24 fins/inch were considered. They were subjected to thermal cycling, or repeated heating (melting) and cooling (freezing), with inlet fluid flow mimicking diurnal variation between 42 °C and 25 °C (representing typical arid-region conditions) over an accelerated time period. By employing salt self-seeding to obviate subcooling during cooling or recrystallization, the TES was found to exhibit stable long-term (100 heating–cooling cycles) operation with very high PCM-side heat transfer coefficients (∼100–500 W/m2 K) and storage power density (∼160–175 kW/m3). In fact, with optimization of heating–cooling fluid flowrate for given charging–discharging time period and exchanger size, power density >300 kW/m3 can be achieved. The results clearly establish that highly compact heat exchangers used as TES units can provide very high-performance alternatives to conventional ones.

Engineering↗

NASA NTRS1994

Effects of the Venusian atmosphere on incoming meteoroids and the impact crater population

The dense atmosphere on Venus prevents craters smaller than about 2 km in daimater from forming and also causes formation of several crater fields and multiple-floored craters (collectively referred to as multiple impacts). A model has been constructed that simulates the behavior of a meteoroid in a dense planetary atmosphere. This model was then combined with an assumed flux of incoming meteoroids in an effort to reproduce the size-frequency distribution of impact craters and several aspects of the population of the crater fields and multiple-floored craters on Venus. The modeling indicates that it is plausible that the observed rollover in the size-frequency curve for Venus is due entirely to atmospheric effects on incoming meteoroids. However, there must be substantial variation in the density and behavior of incoming meteoroids in the atmosphere. Lower-density meteoroids must be less likely to survive atmospheric passage than simple density differences can account for. Consequently, it is likely that the percentage of craters formed by high-density meteoroids is very high at small crater diameters, and this percentage decreases substantially with increasing crater diameter. Overall, high-density meteoroids created a disproportionately large percentage of the impact craters on Venus. Also, our results indicate that a process such as meteoroid flattening or atmospheric explosion of meteoroids must be invoked to prevent craters smaller than the observed minimum diameter (2 km) from forming. In terms of using the size-frequency distribution to age-date the surface, the model indicates that the observed population has at least 75% of the craters over 32 km in diameter that would be expected on an atmosphereless Venus; thus, this part of the curve is most suitable for comparison with calibrated curves for the Moon.

Herrick, Robert R.↗

DOE OSTI2022

Dual Protective Mechanism of AlPO 4 Coating on High-Nickel Cathode Material for High Energy Density and Long Cycle Life Lithium-Ion Batteries

Cathode material with high nickel content is a promising candidate for the future generation of Li-ion batteries (LIBs). However, severe structural degradation during cycling limits its practical use, especially for electric vehicles. Herein, AlPO 4 nanoparticles were synthesized and then coated onto the surface of a high-nickel layer-structured cathode via a dry coating method. The AlPO 4 nanoparticles coating significantly improved the cycling stability from 69.2% to over 80% capacity retention after 140 cycles. Furthermore, the structure and chemical composition of the AlPO 4 -coated cathode was investigated by XRD, SEM, XPS, and STEM. Compared with the non-coated cathode, we revealed a dual protective mechanism for enhanced cycling stability, where Al doping and Li 3 PO 4 coating play synergistic roles in protecting cathode material through long-term cycling. This work demonstrates a facile and environmentally friendly approach toward improving the performance of high-nickel LIB cathodes, which can be easily scaled up for industrial applications.

25 ENERGY STORAGE↗

NASA NTRS1993

Spacecraft computer technology at Southwest Research Institute

Southwest Research Institute (SwRI) has developed and delivered spacecraft computers for a number of different near-Earth-orbit spacecraft including shuttle experiments and SDIO free-flyer experiments. We describe the evolution of the basic SwRI spacecraft computer design from those weighing in at 20 to 25 lb and using 20 to 30 W to newer models weighing less than 5 lb and using only about 5 W, yet delivering twice the processing throughput. Because of their reduced size, weight, and power, these newer designs are especially applicable to planetary instrument requirements. The basis of our design evolution has been the availability of more powerful processor chip sets and the development of higher density packaging technology, coupled with more aggressive design strategies in incorporating high-density FPGA technology and use of high-density memory chips. In addition to reductions in size, weight, and power, the newer designs also address the necessity of survival in the harsh radiation environment of space. Spurred by participation in such programs as MSTI, LACE, RME, Delta 181, Delta Star, and RADARSAT, our designs have evolved in response to program demands to be small, low-powered units, radiation tolerant enough to be suitable for both Earth-orbit microsats and for planetary instruments. Present designs already include MIL-STD-1750 and Multi-Chip Module (MCM) technology with near-term plans to include RISC processors and higher-density MCM's. Long term plans include development of whole-core processors on one or two MCM's.

Shirley, D. J.↗

NASA NTRS2009

Orion Landing Simulation Eight Soil Model Comparison

LS-DYNA finite element simulations of a rigid Orion Crew Module (CM) were used to investigate the CM impact behavior on eight different soil models. Ten different landing conditions, characterized by the combination of CM vertical and horizontal velocity, hang angle, and roll angle were simulated on the eight different soils. The CM center of gravity accelerations, pitch angle, kinetic energy, and soil contact forces were the outputs of interest. The simulation results are presented, with comparisons of the CM behavior on the different soils. The soils analyzed in this study can be roughly categorized as soft, medium, or hard, according to the CM accelerations that occur when landing on them. The soft group is comprised of the Carson Sink Wet soil and the Kennedy Space Center (KSC) Low Density Dry Sand. The medium group includes Carson Sink Dry, the KSC High Density In-Situ Moisture Sand and High Density Flooded Sand, and Cuddeback B. The hard soils are Cuddeback A and the Gantry Unwashed Sand. The softer soils were found to produce lower peak accelerations, have more stable pitch behavior, and to be less sensitive to the landing conditions. This investigation found that the Cuddeback A soil produced the highest peak accelerations and worst stability conditions, and that the best landing performance was achieved on the KSC Low Density Dry Sand.

Mark, Stephen D.↗

DOE OSTI2021

Passive high-power-density grid interface device

A hybrid switched capacitor power converter for high-power applications is provided. The converter has a transistor-switched input-stage boost converter followed by a capacitor-and-diode ladder circuit. The converter is adapted to produce an output voltage of at least 5 kV at a power level of at least 0.5 kW. The ladder circuit includes one or more multi-stage rails.

Brocato, Robert W.↗

NASA NTRS1993

High energy density aluminum-oxygen cell

An alternative to a secondary battery as the power source for vehicle propulsion is a fuel cell. An example of this is the metal-air fuel cell using metals such as aluminum, zinc, or iron. Aluminum is a particularly attractive candidate, having high energy and power densities, being environmentally acceptable, and having a large, established industrial base for production and distribution. An aluminum-oxygen system is currently under development for a UUV test vehicle, and recent work has focussed upon low corrosion aluminum alloys and an electrolyte management system for processing the by-products of the energy-producing reactions. This paper summarizes the progress made in both areas. Anode materials capable of providing high utilization factors over current densities ranging from S to 150 mA/sq cm have been identified. These materials are essential to realizing an acceptable mission life for the UUV. With respect to the electrolyte management system, a filter/precipitator unit has been successfully operated for over 250 hours in a large scale, half-cell system.

Rudd, E. J.↗

DOE OSTI2021

Advances in physics understanding of high poloidal beta regime toward steady-state operation of CFETR

Experimental and modeling investigations of the high βp scenarios on the DIII-D and EAST tokamaks show advantages in high energy confinement, avoidance of n = 1 MHD, and core-edge integration with reduced heat flux, making this scenario an attractive option for CFETR steady-state operation. Experiments show that plasmas with high confinement and high density can be achieved with neutral beam injection on DIII-D (β p ~ 2.2, β N ~ 3.5, f BS ~ 50%, f Gw ~ 1.0, H 98y2 ~ 1.5) and pure RF power on EAST (β P ~ 2.0, β N ~ 1.6, f BS ~ 50%, f Gw ~ 0.8, H 98y2 > 1.3). By tailoring the current density profile, a q-profile with local (off-axis) negative shear is achieved that yields improved confinement and MHD stability. Transport analysis and simulation suggest that the combination of high density gradient and high Shafranov shift allows turbulence stabilization and higher confinement. Using on-axis ECH injection, tungsten accumulation is avoided on EAST, and this is reproduced in modeling. Reduced heat flux (by >40%) and maintenance of high core confinement is achieved with active feedback control of the radiated divertor, an important result for long pulse operation in tokamaks. In conclusion, the improved physics understanding and validated modeling tools are used to design a 1GW steady-state scenario for CFETR.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

DOE OSTI2023

The need for ion-exchange membranes with high charge densities

Ion-exchange membranes (IEMs) are essential for controlling ion transport in electrochemical membrane-based technologies for water purification, energy generation, and energy storage. In general, IEMs must exhibit high ionic conductivity and selectivity, both of which are significantly influenced by the charge and water content of the hydrated membrane. In this perspective, we compiled the charge and water contents of approximately 1,000 IEMs reported over the past several decades to assess their range and variability, as well as to reveal gaps and set clear targets for future membrane design. We compared the charge and water content of negatively and positively charged membranes, as well as membranes developed for desalination and energy applications. The majority of IEMs, regardless of structure or intended application, have volumetric charge densities below 3 mol/L[membrane]. This narrow range of charge densities limits the performance of IEMs and contributes to the observed tradeoff between ion throughput and selectivity. It is critical to develop IEMs with higher charge densities to overcome this performance limitation. Further, we highlighted several design strategies that yielded IEMs with fixed charge densities higher than 3 mol/L[membrane]. These strategies provide valuable insights and can guide the design of next-generation IEMs with high charge densities.

36 MATERIALS SCIENCE↗

DOE OSTI2026

Synthesis, Characterization, and Testing of High-Lithium-Density Composite Breeders

Solid tritium breeder materials must first and foremost have sufficiently high concentrations of lithium to enable a plant-scale tritium breeding ratio greater than 1:1. However, in addition to lithium content, such breeder materials must also meet other performance metrics including high tritium release rates, thermal conductivities, and irradiation damage tolerance. Perhaps most importantly, tritium breeders must maintain their mechanical integrity during reactor operation so as to avoid degradation which can jeopardize the functionality of the tritium breeder blanket module, which in most designs takes the form of a pebble bed geometry. Unfortunately, the mechanical robustness of most lithium-bearing ceramics under investigation for fusion applications is often inversely related to the lithium atom density. For example, a material such as lithium oxide (Li2O), which has one of the highest lithium atom densities, has a much lower mechanical splitting strength than lithium metatitanate (Li2TiO3), though Li2TiO3 has less than half the lithium atom density of Li2O. This work seeks to provide an alternative to monolithic ceramic tritium breeders, in the form of metal-reinforced composite tritium breeders. Specifically, composite tritium breeders have been synthesized combining Li2O with various ferrous metal reinforcements via electric field assisted sintering (EFAS), also known as spark plasma sintering (SPS). As the metal reinforcement content is increased, metallic networks are observed, via electron microscopy and X-ray computed tomography, to form throughout the composite material. Through destructive mechanical testing, even dilute metal reinforcement loading enables drastic mechanical strength improvements over pure Li2O while higher loadings give rise to quasi-ductile behavior and higher ultimate strengths than Li2TiO3 – while still maintaining a higher density of lithium atoms than Li2TiO3 and many other breeder candidates. In addition to microstructural characterization and mechanical testing, thermal property measurements and hydrogen permeability testing are underway to further assess the suitability of such composites for fusion reactor applications.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

DOE OSTI2020

Experimental study on a novel three-phase absorption thermal battery with high energy density applied to buildings

Buildings contribute to 75% of total electricity consumption and 80% of peak electricity demand in the United States. A significant portion of building electricity consumption goes to space conditioning. Therefore, using thermal energy storage (TES) to decouple the building electricity consumption and the fluctuating space-conditioning load has significant potential to shift peak electricity demand and improve the stability of the grid. To provide effective TES within the spatial constraints in buildings, a three-phase absorption thermal battery (TATB) system with very high energy storage density was designed and studied. The TATB stores low-temperature heat in hydrate crystals of salts and supports space conditioning through absorption systems. In this study, a benchtop TATB using lithium chloride (LiCl) hydrate crystals as the storage material was tested under practical operating conditions for its energy storage density and discharge rate. We report the TATB successfully generated LiCl hydrate crystals during charging mode and then dissolved the crystals during discharging mode. A material-based energy storage density of 300 kWh/m 3 (specific energy of 903 kJ/kg) was achieved with a discharge rate of up to 1.3 kW thermal energy. The test results verified the high performance of the TATB and encouraged further development of this technology.

25 ENERGY STORAGE↗

NASA NTRS1993

From bipolar to quadrupolar - The collimation processes of the Cepheus A outflow

Results of new K-band observations of the (1, 1) and (2, 2) ammonia lines toward Cepheus A are reported. The lines are mapped with approximately 2 arcsec of angular resolution and 0.3 km/s of velocity resolution. A sensitivity of 10 mJy has been achieved. The observations reveal details of the spatial and kinematics structure of the ambient high-density gas. It is suggested that the interstellar high-density gas is diverting and redirecting the outflow in the sense that the quadrupolar structure of the molecular outflow is produced by the interaction with the ammonia condensationss, with Cep A-1 and Cep A-3 splitting in two halves, respectively the blue- and redshifted lobes of an east-west bipolar molecular outflow.

Torrelles, Jose M.↗

DOE OSTI2022

High resolution density pedestal measurements during edge localized modes by short-pulse reflectometry in the TCV tokamak

This publication presents high spatio-temporal resolution (mm/μs) density profile measurements of the pedestal top during type I, III, and small edge localized mode (ELM) H-mode plasmas in the Tokamak à Configuration Variable (TCV). These measurements were performed using a novel short-pulse reflectometer. Average inter-ELM density profiles are obtained via conditional averaging using the Dα trace as ELM indicator. Changes to the pedestal density profile gradients prior to type-III ELMs reveal unique pedestal dynamics leading to the ELM crash which can provide important experimental data for validation of non-linear MHD ELM simulations. The small-ELM scenario is found to feature a ∼25-35 kHz quasi-coherent density fluctuation near the separatrix rho_psi ∼0.993-1.05 not observed during a similar type-I ELM discharge. This oscillation is also found in low-field-side magnetic pick- up probes displaying a ballooning character and n=+1 toroidal mode number. This oscillation could help explain the markedly different pedestal dynamics observed in the small-ELM regime.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

DOE OSTI2023

Motor with Advanced Concepts for High power density and INtegrated cooling for Efficiency (MACHINE)

Raytheon Technologies Research Center (RTRC) is the central research and development (R&D) organization for RTX, and has extensive expertise in the design, modeling and analysis of high-performance electrical machines and thermal management for all its business units. The proposing team consists of researchers from RTRC and John Deere (JD), will be referred as “Team”. Each organization a has long track record of successful R&D of materials, manufacturing, components, and systems for energy efficiency applications. Motor power density and efficiency are limited by fundamental physical trade-offs between electromagnetics, thermal management, and structural design considerations. The team is proposing to utilize novel technologies and multi-physics design methods to develop a Motor with Advanced Concepts for High power density and INtegrated cooling for Efficiency (MACHINE), demonstrating an 8X improvement in power density.

33 ADVANCED PROPULSION SYSTEMS↗