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At least 883 records · Page 49

NASA Environmental Control and Life Support Technology Development for Exploration: 2020 to 2021 Overview

This paper provides an overview of NASA supported activities developing Environmental Control and Life Support (ECLSS) technologies in the following capability areas: life support, environmental monitoring, fire safety, and logistics. NASA has been refining technology needs for deep space missions including Gateway, lunar surface, Mars transit, and Mars surface missions. Validating technologies in relevant environments, both in low earth orbit (LEO) and ground tests is critical in understanding technology performance and long duration performance. On-orbit and ground tests inform NASA’s technology decisions to fill exploration gaps. NASA has multiple technology projects across the technology readiness spectrum with potential to fill or partially fill exploration gaps. For each capability area, this paper will describe select capability gaps, NASA technology project maturation over the past year, and how key performance parameters (KPPs) are being used to measure the degree of capability gap closure. KPPs are evolving but they still provide a useful measure in communicating progress and identifying development needs to fill exploration gaps. The intent is to provide a very high-level overview describing the strategic approach to gap closure and provide references to additional technical details, progress, and KPPs.

Life Support↗

Impacts of Snow and Cloud Covers on Satellite-Derived PM 2.5 Levels

Satellite aerosol optical depth (AOD) has been widely employed to evaluate ground fine particle (PM 2.5 ) levels, whereas snow/cloud covers often lead to a large proportion of non-random missing AOD. As a result, the fully covered and unbiased PM 2.5 estimates will be hard to generate. Among the current approaches to deal with the data gap issue, few have considered the cloud-AOD relationship and none of them have considered the snow-AOD relationship. This study examined the impacts of snow and cloud covers on AOD and PM 2.5 and made full-coverage PM 2.5 predictions with the consideration of these impacts. To estimate the missing AOD, daily gap-filling models with snow/cloud fractions and meteorological covariates were developed using the random forest algorithm. By using these models in New York State, a daily AOD data set with a 1-km resolution was generated with a complete coverage. The“out-of-bag” R 2 of the gap-filling models averaged 0.93 with an interquartile range from 0.90 to 0.95. Subsequently, a random forest-based PM 2.5 prediction model with the gap-filled AOD and covariates was built to predict fully covered PM 2.5 estimates. A ten-fold cross-validation for the prediction model showed a good performance with an R 2 of 0.82. In the gap-filling models, the snow fraction was of higher significance in the snow season compared with the rest of the year. The prediction models fitted with/without the snow fraction also suggested the discernible changes in PM 2.5 patterns, further confirming the significance of this parameter. Compared with the methods without considering snow and cloud covers, our PM 2.5 prediction surfaces showed more spatial details and reflected small-scale terrain-driven PM 2.5 patterns. The proposed methods can be generalized to the areas with extensive snow/cloud covers and large proportions of missing satellite AOD for predicting PM 2.5 levels with high resolutions and complete coverage.

AOD↗

NASA Environmental Control and Life Support Technology Development for Exploration: 2020 to 2021 Overview

This paper provides an overview of NASA supported activities developing Environmental Control and Life Support (ECLSS) technologies in the following capability areas: life support, environmental monitoring, fire safety, and logistics. NASA has been refining technology needs for deep space missions including Gateway, lunar surface, Mars transit, and Mars surface missions. Validating technologies in relevant environments, both in low earth orbit (LEO) and ground tests is critical in understanding technology performance and long duration performance. On-orbit and ground tests inform NASA’s technology decisions to fill exploration gaps. NASA has multiple technology projects across the technology readiness spectrum with potential to fill or partially fill exploration gaps. For each capability area, this paper will describe select capability gaps, NASA technology project maturation over the past year, and key performance parameters (KPPs). KPPs are evolving but they still provide a useful measure in communicating progress and identifying development needs to fill exploration gaps. The intent is to provide a very high-level overview describing the projects that are supporting gap closure and provide references to additional technical details, progress, and KPPs.

James Lee Broyan↗

NASA Environmental Control and Life Support Technology Development for Exploration: 2020 to 2021 Overview

This PowerPoint presentation supports the following paper submission's abstract (STRIVES 20210015025). This paper provides an overview of NASA supported activities developing Environmental Control and Life Support (ECLSS) technologies in the following capability areas: life support, environmental monitoring, fire safety, and logistics. NASA has been refining technology needs for deep space missions including Gateway, lunar surface, Mars transit, and Mars surface missions. Validating technologies in relevant environments, both in low earth orbit (LEO) and ground tests is critical in understanding technology performance and long duration performance. On-orbit and ground tests inform NASA’s technology decisions to fill exploration gaps. NASA has multiple technology projects across the technology readiness spectrum with potential to fill or partially fill exploration gaps. For each capability area, this paper will describe select capability gaps, NASA technology project maturation over the past year, and key performance parameters (KPPs). KPPs are evolving but they still provide a useful measure in communicating progress and identifying development needs to fill exploration gaps. The intent is to provide a very high-level overview describing the projects that are supporting gap closure and provide references to additional technical details, progress, and KPPs.

Life Support↗

Loci/STREAM Sharp Interface Model Validation of Cryogenic Propellant Tank Self-Pressurization

This paper documents a model validation effort for the prediction of cryogenic propellant tank selfpressurization physics using the Loci/STREAM sharp interface CFD model developed at NASA MSFC. Cryogenic fluid management (CFM) applications for long duration spaceflight missions require accurate modeling of heat transfer and thermodynamics. Therefore, detailed validation of those physics is important to ensure simulation accuracy. In the past, the MSFC Propulsion Fluid Dynamics Branch has validated and used the Loci/STREAM Volume of Fluid (VOF) module extensively for propellant slosh applications, which are dominated by fluid motion. For cases where the interface gas/liquid interface is essentially static, the Loci/STREAM sharp interface was developed for more rapid and efficient CFM analysis. In the present study, Loci/STREAM sharp interface simulations were compared with the NASA K-site self-pressurization experiment of a flight weight, partially full, LH2 tank in normal gravity. This study investigated several parametric effects and made a number of important observations on the performance of the Loci/STREAM sharp interface method: - First, a homogeneous model was derived to verify the CFD model. The homogeneous model assumes both gas and liquid phases are uniform and are at saturation temperature. The predicted pressure rise rates at 3.5 W/m2 and 2.0 W/m2 with a 49% fill level are all lower than the experimental measurement. This is expected due to the observed temperature stratification near the gas-liquid interface during testing. - The k-w and k-e turbulence models predict comparable pressurization rates, which are much lower than the experiment measurement. On the other hand, the pressure values and pressurization rates from both models are almost the same as those of the homogeneous model. The current turbulence model is too diffusive and is not capable of capturing the thermal stratification in the liquid and ullage. - When using the laminar flow model, the pressurization rate is found to be very close to the experimental value when a quasi-steady flow field is allowed to develop by continuously venting the tank prior to pressurization as was done during testing. On the other hand, without initial venting, the rate is not constant. Additionally, the development time to reach a quasi-steady flow field differed from the experiment due to the lack of turbulent mixing away from the gas-liquid interface that is expected in reality. - Using the laminar flow model and appropriate initial conditioning, the pressurization rate is within 15% of the experimental value for 49% fill level at 3.5 W/m 2 and is within 18% for 2.0 W/m 2 heat loading. - Using the laminar flow model and appropriate initial conditioning, the pressurization rate is within 18% of the experimental value for a 29% fill level and within 15% for an 83% fill level.

H. Q. Yang↗

Investigation of Radiological Contamination at Parks in the Gateway National Recreation Area - 20350

In 2005, the National Park Service was notified that elevated radiation levels were detected at Great Kills Park during a baseline radiological mapping effort conducted by the Counter Terrorism Bureau of the New York City Police Department and the United States Department of Energy. Great Kills Park is in the Staten Island Unit of the Gateway National Recreation Area. A records search determined that approximately 280 acres of the park was established over an area in which the New York City Department of Sanitation placed approximately 15.1 million cubic yards of waste fill from 1944 to 1948. Since 2005, a series of response actions and investigations were conducted on behalf of the National Park Service to mitigate risk to human health and the environment and to determine the nature of radiological contamination at Great Kills Park. The findings support that radiological contamination is related to certain components of waste fill, including incinerator residue from both on and offsite incinerators, coal ash from the historical use of coal-fired boilers for heating, and incidental radiological artifacts in the waste fill due to their historical use and subsequent disposal. A majority of the radiological artifacts were determined to contain radium-226 and included radioluminescent markers, radium impregnated switch board buttons, radium paint containers, and brachytherapy devices. The National Park Service has several other Parks in the Gateway National Recreation Area that were established in areas with a similar history to Great Kills Park, and overlie waste fill historically placed during landfilling operations, including Spring Creek Park and Dead Horse Bay. Over the last year, the National Park Service has performed additional radiological investigations at Great Kills Park as part of the ongoing Remedial Investigation under the Comprehensive Environmental Response, Compensation, and Liability Act. In addition, preliminary radiological investigations were performed at Spring Creek Park and Dead Horse Bay Park in the Jamaica Bay Unit of Gateway National Recreation Area. These investigation activities identified gamma radiation levels above the ambient level, several of which were attributable to radiological artifacts similar in nature to those recovered at Great Kills Park. Ongoing investigations at Parks in the Gateway National Recreation Area support an association between radiological contamination and historical landfilling practices that were common prior to the regulation and control of radioactive materials. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

A Novel Technique for Distributed Measuring of Strain in the Vadose Zone

Characterizing water content and pressure changes in the vadose zone is important to understanding a variety of geologic processes, ranging from permeability, to evapotranspiration, and aquifer recharge. Changes in water content, or pressure, cause strain in the solid porous medium of the vadose zone, and it is possible that measuring those strains could be used a characterization tool. The Coherence-length-gated Microwave Photonics Interferometry (CMPI) technique measures strain at high resolution along many intervals defined by pairs of reflectors distributed along an optical fiber. This technique has recently been developed at Clemson University, and it has the spatial, and temporal resolution to characterize the strains that are expected to occur with hydrologic changes in the vadose zone. However, the technique has never been used to measure strain in porous media, so its capabilities remain uncertain. The objective of this thesis is to evaluate the ability of using CMPI to measure strain changes in the vadose zone. The research approach consists of conducting laboratory tests using a column filled with sand that was subjected to changes in water content and pressure. An optical fiber with CMPI reflectors was deployed in a high surface area ribbon and used to measure strain along the axis of the column. The column was made from 8-inch, Schedule 40 PVC pipe (75 cm tall, 20 cm inner diameter) and filled with medium-grained sand (K = 2.5x10-6 m/s, porosity = 0.28, Coefficient of Uniformity = 2, van Genuchten (n = 4.34 and  = 0.00039 m-1), Young’s Modulus = 18 – 47 MPa). Five pressure and four temperature sensors attached to probes inserted into the wall. The optical fiber includes five reflectors spaced 10 cm apart on the inside and outside of the column along the vertical axis. Strain measurements are made between pairs of reflectors. The reflectors are created in 250-micron-diameter acrylate-coated single mode Corning SMF28e+ optical fiber using a femtosecond laser. The optical fiber was laminated between two pieces of polyester film creating a large surface area to transfer strain from the porous media to the optical fiber. The experiments were conducted by filling the column from the bottom or infiltrating water from the top. The water was allowed to equilibrate to room temperature prior to each test in order to limit thermoelastic strain. Five injection tests with a rate of 250 ml/min and three infiltration tests at varying rates were conducted, and the results show patterns of strain and pressure are generally similar. Hydrologic conditions define three zones based on the pressure magnitude and distribution. 1.) Ambient Zone where the pressure heads are quasi-static and the pressure gradient is roughly unity (head gradient of zero). This is the uppermost zone and is characterized by negative pressures. 2.) Transition Zone where the pressures increase from ambient to zero, are changing relatively rapidly and the pressure gradient is relatively steep (pressure head gradients of 2). The Transition zone is 10 to 15 cm thick. 3.) Positive Pressure Zone where the pressure is positive, the rate of change is slower than in the transition zone and the gradient is flatter (pressure head gradient 1.1 to 1.2). This is the lowest zone in the column. Injection of water causes the pressure to increase and the three zones to move upward. The Transition zone moves at a rate of approximately 0.0002 m/s +/- .00005, according to analyses of pressure profiles. This is the same as the average velocity of the water calculated as volumetric flux/effective porosity =5.4x10-5 m/s/0.28. Strain signals in the range of 10s  were observed with a noise level of generally less than 0.1  (signal to noise ratio of greater than 100) during injection and drainage. The spatial and temporal distributions of strain caused by injection depend on the location of the moving pressure zones. The locations of the different pressure zones were determined from pressure profiles at different times and these data were transferred to strain time series. This showed that strain in the Ambient pressure zone is either unchanged or slightly compressive, whereas strain in Transition zone is tensile and roughly proportional to the pressure change, and strain ranges from tensile to compressive in the Positive Pressure zone. In general, the strain is variable at the top of the Positive Pressure zone, but it appears to be consistently tensile lower in the zone. The spatial distribution of strain causes three distinct stages in the strain times series measured between pairs of CMPI reflectors. The strain is unchanged or slightly compressive during Stage 1, it increases (positive strain is tensile) approximately linearly at a rate of 0.02 to 0.03 μ/s during the Stage 2, and then flattens out in Stage 3. The strain increases again during Stage 4 of the time series. The pressure also changes in stages. It is unchanged during Stage 1 and then increases relatively rapidly at a rate of between 4 and 10 Pa/s during Stage 2 and continues to increase during Stages 3 and 4, but at a rate slightly slower than during Stage 2 (from 2.5 to 3.5 Pa/s). The rates of pressure and strain change are consistent with basic analyses. The rate of pressurization is similar to the calculated velocity of flow in the saturated zone, and this is similar to the measured velocity of the strain increase. The ratio of the pressurization rate and strain rate during Stage 2 (2.5 (Pa/s) /0.03 (μ/s)) is 80 MPa, which is approximately equal to the upper range expected considering the uniaxial compression and the Young’s Modulus of the sand. An interesting effect occurs when the upper surface of the sand becomes saturated. Significant compression (several 10s of ) occurs as the pressure and saturation increase at the upper surface. Compression occurs throughout the column, but the effect is greatest at the top of the column. The rate of compression is fastest slightly before ponding occurs, but it slows markedly and nearly stops when water starts to accumulate at the surface (ponding). This effect reverses when the surface of the sand is drained, resulting in tension throughout the column. The compression caused by this effect can be as large or larger than the tensile strain that accumulated during filling. This effect was unexpected because increasing pressure is normally associated with tensile strain. Nevertheless, this effect was observed consistently in all tests where the pressure changes at the upper surface, including tests where water was injected from below or infiltrated from above. This effect behaves as if the pore pressure at the upper surface of the sand exerts a normal force on the boundary (increasing pore pressure exerts a downward compression on the boundary). The results of these laboratory experiments indicate that CMPI can measure strain caused by fluid pressure changes in the vadose zone with a signal to noise ratio of 100 or more. Injection and drainage cause a strain signal that is complex, but repeatable. The magnitudes of the strain signal are consistent with magnitudes that are expected based on poroelastic calculations using independently measured properties of the sand. These results indicate that the CMPI technique with an optical fiber laminated in a polyester ribbon generates data that represent the strain distribution during hydrologic processes of imbibition and drainage in variably saturated sand. This suggests that distributed strain measurements using CMPI could be a viable approach for evaluating processes in the vadose zone, laying the groundwork for future field implementation.

47 OTHER INSTRUMENTATION↗

Methodology to determine printability criteria of highly concentrated pastes through rheological characterization

Material extrusion is an additive manufacturing technique that enables the creation of reproducible and complex hardware by depositing a viscous, shear-thinning ink onto a substrate in a custom-pattern via extrusion through a syringe. Here, the ability of an ink to be extruded onto a substrate in many layers, and maintain the desired shape is what defines the printability. Printability is often investigated by formulating, printing, and postmortem analysis of final parts in an iterative manner. Investigations of printability through rheological characterization have often been concerned with inks that straddle the line between printable and too thin, leaving out an entire class of inks that are highly-filled pastes, where extrudability is the limiting factor. Highly-filled pastes continue to pose issues for researchers as the effect of filler morphology, size, loading, and packing fraction on the ink rheology and corresponding printability is not understood. While traditional rheological characterizations may be useful for some inks, we show that protocols utilizing steady-shear, or large-amplitude oscillatory shear are difficult and unreliable for highly-filled pastes. Through transient rheology paired with real-time images we show that each traditional protocol produces inhomogeneous deformations that violate the assumptions that underly common rheological definitions. Instead, we demonstrate metrics measured with small-amplitude oscillatory shear that are correlated to the printability of various ink formulations ranging in loading. The rheological measures that accurately predict the printability of the inks are the axial stress measured at small amplitudes, and the critical stress amplitude above which rheological characterizations become impossible. In addition, we estimate the maximum packing fraction for each filler, based on the exponent common to hard sphere models, and show that the printability of each ink can be predicted by the ratio of the packing fraction to the theoretical maximum. We show how small-amplitude oscillatory shear allows users to develop printability criteria for any ink to enhance the workflow in the development of new inks, increase the performance of material extrusion printing, and improve the stability of printed parts, with less wasted time and materials.

36 MATERIALS SCIENCE↗

Coal Ash Beneficial Use at Savannah River Site

The Savannah River Site (SRS) has over 1.4 million cubic meters of coal ash and coal fines left over from coal-burning power plants that operated on site. Currently, the coal ash must be disposed of in an approved landfill or the coal ash-containing basins must be closed in place (i.e. consolidation, appropriate cover and liner system). Potential beneficial uses of the coal ash include geotechnical fill, such as backfill needed in the closure cap of the Z-area Saltstone Disposal Units (SDU), and use in cementitious material applications like thermal beneficiation or cement kiln feed, thereby reducing the environmental footprint of SRS. In this study, samples of coal ash from SRS were obtained and characterized for chemical and physical properties. Coal ash samples did not leach sulfates or heavy metals, so the coal ash is a candidate for geotechnical fill use. The samples also did not increase the acidity of the leachate during leaching tests, so it would not be detrimental to use as geotechnical fill near cementitious materials. The composition and energy potential of the coal ash makes it favorable for use as feed for external/off-site cement kilns or thermal beneficiation plants

01 COAL, LIGNITE, AND PEAT↗

Development, verification, and validation of comprehensive acoustic fluid-structure interaction capabilities in an open-source computational platform

The acoustic fluid-structure interaction (FSI) formulation is a practical numerical approach for the seismic analysis of fluid-filled tanks. However, there are no verification and validation studies reported in the literature that demonstrate the ability of an acoustic FSI numerical model to predict responses important to structural and mechanical design for intense translational and rotational earthquake inputs. Herein, an acoustic FSI formulation is implemented in the open-source Multiphysics Object-Oriented Simulation Environment (MOOSE), and is formally verified and validated using analytical solutions and code-to-code verification, and experimental data, respectively. The analytical solutions are for small amplitude, unidirectional seismic inputs. The code-to-code verification utilizes a previously verified and validated Arbitrary Lagrangian-Eulerian (ALE) numerical model in the commercial finite element code LS-DYNA. The validation studies utilize a comprehensive data set assembled from results of 3D earthquake-simulator tests of a fluid-filled vessel. The acoustic numerical model in MOOSE is verified and validated for hydrodynamic pressures and support reactions except for cases that involve significant convective response. For small amplitude inputs, numerically predicted wave heights match those of the analytical solutions. The numerical model is not verified and validated for wave height calculations under intense 3D seismic inputs. The run times for the acoustic FSI simulations in MOOSE are an order of magnitude, or more, shorter than for the corresponding ALE simulations in LS-DYNA. The utility of the MOOSE acoustic FSI implementation is demonstrated by seismic analysis of a building equipped with a fluid-filled, advanced nuclear reactor.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Radial storage efficiency for CO 2 injection: Quantifying effectiveness of local flow control methods

Basin-scale geologic carbon sequestration will require hundreds of injection wells, each of which has costs related to property rights and regulatory requirements that correlate with the areal size of the carbon dioxide plume. These surface-footprint-related issues motivate maximizing storage efficiency radially away from each well. Radial storage efficiency (RSE) is defined here as the ratio of the volumetrically weighted carbon dioxide free-phase saturation within a given radius away from the injection well to the available pore space within that same radius. Maximizing RSE effectively minimizes the radial extent of the CO 2 plume. Optimizing RSE around individual wells requires local flow control injection strategies that can increase the uniformity of the filling of pore space around the well over the entire length of the perforated injection interval despite differences in local formation transmissivity. The goal of uniform filling of the storage reservoir starting from the well outward is to maximize carbon dioxide sweep and trapping locally outward from the well in all of the layers of the storage region before buoyancy forces predominate and drive carbon dioxide upward where it will spread laterally under lower-permeability layers. Example simulations of carbon dioxide injection into a layered storage system with and without local flow control are presented to show the advantage of uniformly filling all layers and how RSE can be used to quantify storage efficiency for the two different injection approaches. Published 2021. This article is a U.S. Government work and is in the public domain in the USA.

03 NATURAL GAS↗

Genetic variation in nitrogen‐use efficiency and its associated traits in dryland winter wheat ( Triticum aestivum L.) cultivars released from the 1940s to the 2010s in Shaanxi Province, China

Abstract BACKGROUND Improving the nitrogen‐use efficiency (NUE) of wheat can help mitigate the problems of poor soil fertility under dryland conditions. We conducted field experiments using three nitrogen (N) fertilization levels (0, 120, and 180 kg ha −1 ) applied to eight dryland wheat cultivars to assess NUE and its associated traits. RESULTS The grain yield significantly increased with the improvement in variety, mainly as a result of a substantial increase in 1000‐grain weight and harvest index. Modern wheat varieties have stabilized at an optimal plant height and exhibited improved performance in terms of NUE, partial N productivity, N harvest index, and grain protein content compared to older varieties. The NUE of wheat gradually increased with variety replacement. The net photosynthesis rate of the flag leaves in the filling stage improved with the year of cultivar release; Increasing soil–plant analysis development (SPAD) values of flag leaves in the flowering and filling stages were observed over time, with the flag leaves of modern varieties showing a high chlorophyll content in the filling stage. Additionally, the principal component analysis showed that the SPAD value, grain number per unit area, transpiration rate, leaf area, and grain protein content positively contributed to the clustering of the N180 and modern cultivars (from the 2000s to 2010s). CONCLUSION Overall, high levels of N application did not significantly improve the NUE of wheat. However, modern wheat varieties can optimize N distribution, increase flag leaf photosynthetic capacity, and improve photosynthesis ability, thus enhancing NUE to achieve high yields under a suitable level of N supply. © 2022 Society of Chemical Industry.

Lian, Huida↗

Optical leakage mitigation in ortho-mode transducer detectors for microwave applications

Ortho-mode transducers (OMT) are a commonly used method of coupling opti-cal signals between waveguides and on-chip circuitry and detectors. While the ideal OMT-waveguide coupling requires minimal disturbance to the waveguide, when used for mm-wave applications the waveguide is often slide though and the OMT probes inserted on a thin support membrane. This interface is a potential source of signal leakage and can lead to signal loss and experimental systematics (e.g. in CMB polarization experiments where lost signal can result in temperature to polarization leakage). Here we report on the development of new OMT- waveguide coupling structures with the goal of reducing leakage at the horn-to-detector-wafer interface. The pixel to pixel optical leakage due to the gap be-tween the coupling waveguide and the backshort is reduced by means of a protrusion that passes through the OMT membrane and connects the waveguide sections on each side of the wafer. High frequency electromagnetic simulations indicate that these protrusions can reduce optical leakage in the gap by ~80% percent, with a ~60% filling factor, respect to an ordinary OMT coupling without protrusion, using designs that are compatible with current fabrication processes. We describe the design of the new coupling structure including the impact of varying two key parameters: wafer to optical coupling gap and protrusion fill factor. Prototype devices have been designed that will characterize the performance of the new design using a relative measurement with varying filling factors. We describe the simulation setup and results, and present a chip layout and sample box designed to perform an initial measurement.

Detectors↗

Evidence of redox cycling as a sub-mechanism in hydrogen production during ethanol steam reforming over La 0.7 Sr 0.3 MnO 3-x perovskite oxide catalysts

Ethanol steam reforming (ESR) is of societal interest. Here, in this work, experiments were conducted to ascertain if some of the H 2 is produced by a redox cycle involving H 2 O filling oxygen vacancies over reducible oxide catalysts. Redox cycling experiments were performed over La 0.7 Sr 0.3 MnO 3-x (100) in ultra-high vacuum. It was found that H 2 was produced from redox cycling with alternating ethanol and water exposures over La 0.7 Sr 0.3 MnO 3-x (100), with both half-cycles occurring at temperatures ≤800 K. In the first half-cycle, ethanol ‘directly’ reduced the surface to create oxygen vacancies (not by a CO intermediate), and in the second half-cycle water filled oxygen vacancies to make H 2 . The H 2 production during the water exposure has a half-cycle turnover frequency of >3.2 × 10 -2 molecules site -1 s -1 in the temperature range of 700–800 K, which is fast enough to be part of the ESR full catalytic cycle. Flowing both reactant gases together, ethanol and water, over La 0.7 Sr 0.3 MnO 3-x (100) and La 0.7 Sr 0.3 MnO 3-x powders significantly increases hydrogen production compared to pure ethanol. The results suggest that steady state ESR includes a sub-mechanism of ethanol ‘directly’ reducing the surface to create oxygen vacancy, and water filling oxygen vacancy to make some of the H 2 by a Mars van Krevelen type mechanism.

08 HYDROGEN↗

Understanding of the factors slowing down metakaolin reaction in limestone calcined clay cement (LC3) at late ages

Factors which could explain the slowing down of the metakaolin reaction in LC{sup 3} blends are investigated. Portlandite availability and the presence of aluminium ions in the pore solution are shown not to be limiting factors. Hydrates can only precipitate in solution filled pores. Internal relative humidity measurements indicate that at 28 days solution is present only in pores with radii below 13 nm. An enhancement of metakaolin reaction was obtained at late ages when the larger capillaries are filled with solution. The lower limit of the water filled pores was more difficult to analyse since there is a lack of precision in determining interfacial energies of hydrates and pore solution of the system. However, this study gives an indication of order of magnitude where the growth of hydrates could be slowed down.

36 MATERIALS SCIENCE↗

Autogenous healing of Engineered Cementitious Composites (ECC) based on MgO-fly ash binary system activated by carbonation curing

Developing self-healing of concrete cracks represents a critical approach for extending material longevity. If demonstrated on concretes with CO 2 stored through carbonation curing, self-healing can further mitigate infrastructure lifecycle emissions. In this study, the self-healing process is investigated on novel Engineered Cementitious Composites (ECC) based on binary blends of reactive MgO cement and siliceous fly ash activated by carbonation. The self-healing was observed under cyclic wetting and drying exposures and was characterized by measurements of resonance frequency, optical microscopy and X-ray computed microtomography (XCT). Thermogravimetric analysis, X-ray powder diffraction and scanning electron microscopy were employed to assist in identifying healing products and mechanisms. It was found that micro-cracks could be autogenously filled in 7 wet-dry cycles, as evidenced by over 95% recovery of resonance frequency and healed crack appearance under optical microscopic observation. Nevertheless, the composite mechanical performance, particularly tensile strength and ductility, did not fully recover with respect to the uncracked specimens. The inadequate post-healing mechanical properties were consistent with XCT observations that indicated low material densities in the cracked area. Based on the chemical and microstructural characterizations, it was determined that nesquehonite crystallites were responsible for the crack filling. Although the nesquehonite filled cracks will be less permeable to invasion of reactive fluids, novel strategies are needed to establish more robust healing capability to completely restore the crack bridging and composite tensile performance.

36 MATERIALS SCIENCE↗

Exploring capabilities of Micro-Fabricated 3D-printed capsules for studying effects of material mix on thermonuclear burn

The introduction of a high-precision, 3D-printing method, known as two-photon polymerization (2PP), has created a new means of producing novel targets to study inertial confinement fusion (ICF). Here, this work aims to explore if 2PP fabricated capsules can meet ICF requirements such as size, uniformity, deuteration degree, and ability to maintain gas fill. Two types of capsules with 3D-printed lattices were evaluated on the Omega-60 Laser Facility: (1) carbon-deuterium-oxygen (CDO) lattice with a H 2 gas fill and (2) carbon-hydrogen-oxygen (CHO) lattice with a D 2 gas fill. Experimental results and numerical simulations, which assumed complete mixing of capsule materials, reasonably agreed for both target types. A further study into the effects of capsule preheat or 2PP geometry on material mix is underway. Our work demonstrates that the unique capabilities of customizable, 3D-printed capsules present promising opportunities for further investigation into more sophisticated mix and burn experiments in ICF.

2PP↗

Simulation-driven design optimization of reaction injection molding (RIM) process for polydicyclopentadiene (pDCPD): Minimizing cycle time, defects, and warpage

Replacing metal components in trucks, trailers, and buses with lightweight polymer composites is challenging due to high temperatures and complex manufacturing. The Reaction Injection Molding (RIM) process using Dicyclopentadiene (DCPD) resin offers a solution by producing robust parts with excellent stiffness, impact strength, and resistance properties. Simulations are essential for optimizing this process, predicting defects, and improving quality. However, most commercial software is tailored for thermoplastics, requiring thermoset users to generate their own datasets. In this study, a material data card for DCPD was developed to perform RIM simulations. Design of Experiments (DOE) was used to identify key factors affecting filling, curing, and warpage, aiming to minimize cycle time and defects. The simulations explored varying injection gate parameters (size, location, number) and process conditions (mold/resin temperature, injection/curing pressure). Results showed that gate design significantly impacts filling behavior and defects. A single central gate provided balanced flow with fewer defects, while two corner gates led to more defects. Additionally, lower injection pressure increased filling time, while higher mold temperature accelerated curing but led to more warpage. In conclusion, this optimization framework aims to enhance DCPD part performance and promote sustainable manufacturing by reducing waste and energy consumption.

42 ENGINEERING↗