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At least 883 records · Page 49

Positron sources: from conventional to advanced accelerator concepts-based colliders

Positron sources are the key elements for the future and current lepton collider projects such as ILC, CLIC, SuperKEKB, FCC-ee, Muon Collider/LEMMA, etc., introducing challenging critical requirements for high intensity and low emittance beams in order to achieve high luminosity. In fact, due to their large production emittance and constraints given by the target thermal load, the main collider parameters such as the peak and average current, the emittances, the damping time, the repetition frequency and consequently the luminosity are determined by the positron beam characteristics. In this work, the conventional positron sources and their main properties are explored for giving an indication to the challenges that apply during the design of the advanced accelerator concepts. The photon-driven positron sources as the novel approach proposed, primarily for the future linear colliders, are described highlighting their variety and problematic.

47 OTHER INSTRUMENTATION↗

Status and future plans for C 3 R&D

C 3 is an opportunity to realize an e + e - collider for the study of the Higgs boson at √s = 250 GeV, with a well defined upgrade path to 550 GeV while staying on the same short facility footprint. C 3 is based on a fundamentally new approach to normal conducting linear accelerators that achieves both high gradient and high efficiency at relatively low cost. Given the advanced state of linear collider designs, the key system that requires technical maturation for C 3 is the main linac. This paper presents the staged approach towards a facility to demonstrate C 3 technology with both Direct (source and main linac) and Parallel (beam delivery, damping ring, ancillary component) R&D. The primary goal of the C 3 Demonstration R&D Plan is to reduce technical and cost risk by building and operating the key components of C 3 at an adequate scale. This R&D plan starts with the engineering design, and demonstration of one cryomodule and will culminate in the construction of a 3 cryomodule linac with pre-production prototypes. This R&D program would also demonstrate the linac rf fundamentals including achievable gradient and gradient stability over a full electron bunch train and breakdown rates. It will also investigate beam dynamics including energy spread, wakefields, and emittance growth. This work will be critical to confirm the suitability of the C 3 beam parameters for the physics reach and detector performance in preparation for a Conceptual Design Report (CDR), as well as for follow-on technology development and industrialization. The C 3 Demonstration R&D Plan will open up significant new scientific and technical opportunities based on development of high-gradient and high-efficiency accelerator technology. It will push this technology to operate both at the GeV scale and mature the technology to be reliable and provide high-brightness electron beams. The timeline for progressing with C 3 technology development will be governed by practical limitations on both the technical progress and resource availability. It consists of four stages: Stage 0) Ongoing fundamental R&D on structure prototypes, damping and vibrations. Stage 1) Advancing the engineering maturity of the design and developing start-to-end simulations including space-charge and wakefield effects. This stage will include testing of strucutres operating at cryogenic temperatures. Beam tests would be performed with high beam current to test full beam loading. Stage 2) Production and testing of the first cryomodule at cryogenic temperatures. This would provide sufficient experimental data to compile a CDR and it is anticipated for Stage 2 to last 3 years and to culminate with the transport of photo-electrons through the first cryomodule. Stage 3) Updates to the engineering design of the cryomodules, production of the second and third cryomodule and their installation. Lower charge and lower emittance beams will be used to investigate emittance growth. The successful full demonstration of the 3 cryomodules to deliver up to a 3 GeV beam and achieve the C 3 five gradient will allow a comprehensive and robust evaluation of the technical design of C 3 as well as mitigate technical, schedule, and cost risks required to proceed with a Technical Design Report (TDR).

radiation hardened magnets↗

Characteristics of 1D ordered arrays of optical centers in solid-state photonics

Abstract Collective interaction of emitter arrays has lately attracted significant attention due to its role in controlling directionality of radiation, spontaneous emission and coherence. We focus on light interactions with engineered arrays of solid-state emitters in photonic resonators. We theoretically study light interaction with an array of emitters or optical centers embedded inside a microring resonator and discuss its application in the context of solid-state photonic systems. We discuss how such arrays can be experimentally realized and how the inhomogeneous broadening of mesoscopic atomic arrays can be leveraged to study broadband collective excitations in the array.

Kling, Trevor (ORCID:0000000314967717)↗

Do blue galaxy-clusters have hot intracluster gas?

Abstract We present herein a systematic X-ray analysis of blue galaxy clusters at z = 0.84 discovered by the Subaru telescope. The sample consisted of 43 clusters identified by combining red-sequence and blue-cloud surveys, covering a wide range of emitter fractions (i.e., 0.3–0.8). The spatial extent of the over-density region of emitter galaxies was approximately 1 Mpc in radius. The average cluster mass was estimated as 0.6(<1.5) × 1014 M⊙ from the stacked weak-lensing measurement. We analyzed the XMM-Newton archival data, and measured the X-ray luminosity of the hot intracluster medium. As a result, diffuse X-ray emission was marginally detected in 14 clusters, yielding an average luminosity of 5 × 1042 erg s−1. To the contrary, it was not significant in 29 clusters. The blue clusters were significantly fainter than the red-dominated clusters, and the X-ray luminosity did not show any meaningful correlation either with emitter fraction or richness. The X-ray surface brightness was low, but the amount of gas mass was estimated to be comparable to that observed in the 1013–1014 M⊙ cluster. Based on the results, we suggest that the blue clusters are at the early formation stage, and the gas is yet to be compressed and heated up to produce appreciable X-rays. Follow-up spectroscopic measurements are essential to clarify the dynamical status and co-evolution of galaxies and hot gas in the blue clusters.

Misato, Rana↗

Reverse Heterojunction (Al)GaInP Solar Cells for Improved Efficiency at Concentration

Mitigating series resistance is crucial to the efficiency of concentrator solar cells at high current density. Conventional AlGaInP junction designs for the top junction of III-V multijunction cells present a challenging tradeoff between series resistance on the one hand and current collection and voltage on the other hand. In this article we discuss the physics of a reverse heterojunction solar cell that aims to improve on this tradeoff by combining a high bandgap Al 0.18 Ga 0.33 In 0.49 P base and a lower bandgap (Al)GaInP emitter. The high mobility of the emitter leads to a relatively low series resistance, compared with a high bandgap homojunction cell. Furthermore, the electroluminescence spectrum shows emission peaks from both the emitter and base, leading to an open-circuit voltage that is not strictly dominated by either layer. The reverse heterojunction design is increasingly beneficial as the one-sun voltage increases.

14 SOLAR ENERGY↗

Electroluminescence Characterization of Recombination in Back Junction Silicon Heterojunction Test Structures: Role of the Inversion Layer

Electroluminescence (EL) characterization technique is used to quantify recombination properties in back junction silicon (Si) heterojunction (HJ) solar cell test structures with interdigitated back contact (IBC) emitters and metal contacts. These test structures are three terminal devices that allow the selective biasing and injection of minority carriers into spatially isolated emitter strips having different widths. This allows the study of minority carriers' current transport, flow, and recombination in these regions, which can, then, be applied to full IBC cells. EL is used to verify that emission is proportional to the minority carriers' concentration in the corresponding regions of the device, thus providing information relevant to minority carriers' collection when compared with laser beam induced current technique in considerably less time and with a higher spatial resolution. Current transport through the inversion layer that occurs due to the band bending at the n crystalline Si and p amorphous Si interface is discussed relying on the distance that minority carriers travel in different configurations and on their diffusion length. Laser defect spots (LDS) were, then, introduced in the emitter regions to analyze the spatial profile of minority carriers as they recombine at the LDS due to their high surface recombination velocity. Ideality factors in different configurations are spatially mapped from EL before and after introducing LDS and are used to show the effect of the inversion layer on the different recombination mechanisms. Current transport through the inversion layer is studied at different biasing conditions and correlated with current transport after LDS.

42 ENGINEERING↗

Light-Induced Al Plating on Si for Fabrication of an Ag-Free All-Al Solar Cell

Light-induced electroplating of Al as the front electrode on the n-type emitter of Si solar cells is proposed as a substitute for screen-printed Ag. The advantages and disadvantages of Al over Cu as the front electrode are discussed. The power of a green laser used for patterning of the SiN x antireflection coating is optimized. Conditions for removal of laser damage and contamination on the laser-patterned surface are identified. The effect of plating temperature and post-annealing temperature on Al morphology and resistivity are investigated. Several plating additives are explored to improve the morphology and resistivity of the Al film. Nicotinic acid produces the lowest resistivity of 3.1 μ Ω-cm. However, the lowest contact resistivity between light-induced Al and Si is 69 mΩ-cm 2 due to laser-induced damage to the emitter. The Al film spikes through the thin n-type emitter when annealed at 500 °C causing cell failure. The process reproducibility is also poor due to atmospheric moisture.

14 SOLAR ENERGY↗

Maximal nighttime electrical power generation via optimal radiative cooling

We present a systematic optimization of nighttime thermoelectric power generation system utilizing radiative cooling. We show that an electrical power density >2 W/m 2 , two orders of magnitude higher than the previously reported experimental result, is achievable using existing technologies. This system combines radiative cooling and thermoelectric power generation and operates at night when solar energy harvesting is unavailable. The thermoelectric power generator (TEG) itself covers less than 1 percent of the system footprint area when achieving this optimal power generation, showing economic feasibility. We study the influence of emissivity spectra, thermal convection, thermoelectric figure of merit and the area ratio between the TEG and the radiative cooler on the power generation performance. We optimize the thermal radiation emitter attached to the cold side and propose practical material implementation. The importance of the optimal emitter is elucidated by the gain of 153% in power density compared to regular blackbody emitters.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Lifetime-resolved photon-correlation Fourier spectroscopy

The excited state population of single solid-state emitters is subjected to energy fluctuations around the equilibrium driven by the bath and relaxation through the emission of phonons or photons. Simultaneous measurement of the associated spectral dynamics requires a technique with a high spectral and temporal resolution with an additionally high temporal dynamic range. We propose a pulsed excitation-laser analog of photon-correlation Fourier spectroscopy (PCFS), which extracts the linewidth and spectral diffusion dynamics along the emission lifetime trajectory of the emitter, effectively discriminating spectral dynamics from relaxation and bath fluctuations . This lifetime-resolved PCFS correlates photon-pairs at the output arm of a Michelson interferometer in both their time-delay between laser-excitation and photon-detection T and the time-delay between two photons τ . We propose the utility of the technique for systems with changing relative contributions to the emission from multiple states, for example, quantum emitters exhibiting phonon-mediated exchange between different fine-structure states.

36 MATERIALS SCIENCE↗

Multiple Synchrotron Light Monitors for Transverse Matching and Monitoring at CEBAF

Beam setup at the Continuous Electron Beam Accelerator Facility (CEBAF) involves threading beam through the machine and monitoring global transfer functions to identify and address cumulative lattice errors. Transverse beam emittance may grow by as much as two orders of magnitude, mediated by synchrotron radiation. Re-matching the enlarged beam phase space into successive re-circulation arcs minimizes this emittance growth but requires knowledge of the actual beam distribution. This is now accomplished through quadrupole scans using wire profile monitors, the most time-consuming activity in our setup process. We propose to use Synchrotron Light Monitors (SLMs) to image the beam at homologous points in the four super-period recirculation arc lattices. Benefits include real-time monitoring of beam parameters and reduced elapsed time for initial setup.These SLMs will be installed in Arc 7 of the CEBAF machine, where Synchrotron Radiation contributes moderately to emittance growth. One of four required SLMs will be installed and commissioned this year, with the rest being installed next year.

Freeman, B.↗

Observation of Long-Range Wakefield Effects Generated in an Off-Resonance Tesla-Type Cavity

The interest in controlling emittance dilution effects due to off-axis beam transport in accelerator cavities and the resulting dipolar modes is especially important for the facilities with lower emittance beams. The Fermilab Accelerator Science and Technology (FAST) facility has a unique configuration of two single cavities after the photocathode rf gun followed by a cryomodule. The second capture cavity (CC2) was run 15 kHz off resonance and without rf power while a 25-MeV beam was injected into it. The beam centroid effects were tracked by 10 rf button BPMs with bunch-by-bunch position readout capability downstream in a 12-m drift. Possible LRW effects seemed to dominate our previously observed near-resonant HOM effects at mode 14 in this cavity. This mode also shifted in frequency compared to that of the tuned case based on direct measurements. Submacropulse vertical position slewing of 1400 microns at 11 m downstream was observed with a 125 pC/bunch, 50 bunches per macropulse, and 25-MeV beam. The y-position slew amplitudes as a function of z were also measured. Horizontal positions also showed a slew effect. Both are emittance-dilution effects which one wants to mitigate.

Lumpkin, Alex H.↗

Investigations of Long-Range Wakefield Effects in a TESLA-type Cryomodule at FAST

The preservation of low emittance of electron beams during transport in the accelerating structures of large facilities is an ongoing challenge. In the cases of the TESLA-type superconducting rf cavities currently used in the European X-ray Free-electron Laser (XFEL) and the under-construction Linac Coherent Light Source upgrade (LCLS-II), off-axis beam transport may result in emittance dilution due to transverse long-range wakefields (LRWs) and short-range wakefields (SRW)***. To investigate such effects, experiments were performed at the Fermilab Accelerator Science and Technology (FAST) facility with its unique configuration of two TESLA-type cavities after the photocathode rf gun followed by an 8-cavity cryomodule CM). We generated beam trajectory changes with the H/V125 corrector set located 4 m upstream of the cryomodule. At 125 pC/bunch, 50 bunches, 25-MeV input, and 100-MeV exit energy, we observed for the first time submacropulse position slews of up to 500 microns at locations ~3 m after the CM and a centroid oscillation at a difference frequency of 240 kHz further downstream. Both are emittance-dilution effects which we mitigated with selective upstream beam steering.

43 PARTICLE ACCELERATORS↗

Final cooling with thick wedges for a muon collider

In the final cooling stages for a muon collider, the transverse emittances are reduced while the longitudinal emittance is allowed to increase. In previous studies, Final 4-D cooling used absorbers within very high field solenoids to cool low-momentum muons. Simulations of the systems did not reach the desired cooling design goals. In this study, we develop and optimize a different conceptual design for the final 4D cooling channel, which is based on using dense wedge absorbers. We used G4Beamline to simulate the channel and Python to generate and analyze particle distributions. We optimized the design parameters of the cooling channel and produced conceptual designs (corresponding to possible starting points for the input beam) which achieve transverse cooling in both x and y by a factor of ~3.5. These channels achieve a lower transverse and longitudinal emittance than the best design previously published.

43 PARTICLE ACCELERATORS↗

Experimental investigation of longitudinal scraping of H- bunches via photo-detachment

Longitudinal emittance growth is a significant challenge in RF linacs, especially for poorly bunched beams. This stems from particles occupying outer synchrotron oscillation orbits in the LBET, causing unwanted bunch-bunch interactions and degraded beam quality. To address this, we proposed using temporally spaced laser pulses to selectively photo-detach electrons from the longitudinal head and tail regions of H- ion bunches. This approach aims to reduce particle density in extreme orbits, enhancing beam uniformity and limiting emittance growth. Our experiments employed Fermilab's 'LaserNotcher' system at the font end of the linac, delivering 1.6 MW peak power with sub-nanosecond precision. By neutralizing the first and last half-nanosecond of several H- bunches, we measured their propagation injection into the booster. Measurements of pulse width, average height, and temporal spacing over booster cycles were compared between the scraped and unscraped bunches. Statistical analysis evaluated the results’ significance, highlighting the feasibility of laser-based scraping for future linac designs to achieve higher beam energies with improved emittance control.

Landon, Parker [Boston U.]↗

Changes in SSL Device Efficiency and Optical Performance Under Accelerated Aging Conditions

Lighting application efficiency (LAE) describes the efficient delivery of light from the light source to the lighted task and is viewed as a new frontier—increasing energy savings with solid-state lighting (SSL) technologies. The framework for LAE that is proposed by the U.S. Department of Energy (DOE) consists of four major elements: light source efficiency, optical delivery efficiency, spectral efficiency, and intensity effectiveness. This report focuses on a sampling of the available SSL products that can be broadly defined as having modified spectral output because the method of spectra modification has a significant impact on light source efficiency and long-term optical delivery and spectral efficiencies. This report focused on the changes in light source, optical delivery, and spectral efficiencies that occur during aging of SSL devices. An accelerated stress test (AST) regiment was developed for the devices under test (DUTs) examined in this report to provide insights into how the performance of SSL devices change with aging. The AST protocols demonstrate that the SSL products discussed in this report often reduce light source efficiency to achieve different spectral characteristics. In addition, aging of the optical components (e.g., lenses, solder masks) in SSL devices can produce increased light absorption, which negatively impacts optical delivery efficiency and light source efficiency. The modified spectral outputs of the selected SSL products discussed in this report come in a variety of form factors and achieve enhanced optical performance by using a variety of methods. All of the products examined in this study use mid-power light-emitting diodes (MP-LEDs), although the number, configuration, phosphor content, and light-emitting diode (LED) pump of the MP-LEDs differ. Product MS-1 is a 60-watt (W) replacement A19 lamp with a hermetically sealed glass globe, which contains an embedded optical filter to absorb green and yellow emissions, thereby creating a “sunlike” modified spectrum. Product MS-2 is a 60-W replacement A19 lamp with 30 MP-LEDs, and it uses a violet LED pump, along with green and red phosphor emissions, to produce a “healthy” spectrum. This spectrum omits blue emissions in an effort to reduce melanopic lux. Product MS-3 is an LED module consisting of 21 MP-LEDs that use a violet LED pump, along with blue, green, and red phosphors, to produce a “sunlike” spectrum. Products MS-4 and MS-5 are both 6-inch (in) downlights that use a manual switching mechanism so that users can select application-specific correlated color temperatures before installation. Products MS-4 and MS-5 both contain two LED primaries (2,700 Kelvin [K] and 5,000 K) for spectral tuning. Product MS-4 contains 12 MP-LEDs for each LED primary, and Product MS-5 contains 10 MP-LEDs for each LED primary. This report summarizes the overall findings from up to 8,000 hours (hrs) of AST on the lamp DUTs (Products MS-1 and MS-2); up to 5,000 hrs of AST on the LED light engine DUTs (Product MS-3); and up to 7,000 hrs of AST on the downlight DUTs (Products MS-4 and MS-5). The AST procedures used in this study included a room temperature operational life (RTOL) test, an operational life test conducted at 45 degrees Celsius (°C; 45OL) test, an operational life test conducted at 75°C (75OL), a wet high-temperature operational life test performed at 65°C and 90% relative humidity (6590), and a wet high-temperature operational life test performed at 75°C and 75% relative humidity (7575). The AST procedures used for Products MS-1 and MS-2 were RTOL, 45OL, and 6590. The AST procedures used for Products MS-3, MS-4, and MS-5 were RTOL, 75OL, and 7575. During the ASTs described herein, separate populations of each product (three DUTs in each population for Products MS-1, MS-2, MS-4, and MS-5; four DUTs in each population for Product MS-3) were subjected to power cycling of 1 hr on and 1 hr off. The key findings from this study include the following. Enhanced optical performance came at the cost of reduced light source efficiency for the lamps and light engines examined in this study. The optical filter used to produce a “sunlike” spectrum for Product MS-1 reduced light source efficiency by 26%, from 113 lumens per watt (lm/W) to 85 lm/W. Products MS-2 and MS-3 that used a violet-pumped LED to achieve “healthy” and “sunlike” enhanced optical performance, respectively, suffered the largest reduction in initial light source efficiency (49 lm/W for Product MS-2 and 68 lm/W for Products MS-3) perhaps because of the use of violet LED as the optical pump. Product MS-2 also had the poorest color fidelity because of undersaturation of blues and oversaturation of greens and yellows. Chromaticity maintenance of the products in this study was generally good, with parametric failure only occurring for one product at one AST condition (i.e., Product MS-3 at 7575). The chromaticity shift for Product MS-3 in 7575 test conditions resulted from reduced emissions of the broad green and red phosphors used to mimic sunlight in the 500–750 nanometer (nm) range. As a result of these phosphor emission losses, chromaticity shifted toward the more stable violet-pumped LED and blue phosphor. Although chromaticity maintenance was acceptable for most products tested, different chromaticity shift mechanisms were observed for temperature and humidity tests compared with temperature alone for Products MS-1, MS-2, and MS-3. For Product MS-1, a relative increase in green emissions was observed with humidity, which may indicate humidity-accelerated degradation of the optical filter at green wavelengths (optical delivery efficiency reduction) or degradation of the emitters in the red region (spectral efficiency reduction). The violet-pumped products (i.e., MS-2 and MS-3) exhibited different chromaticity shift behavior in the temperature-humidity environments, with Product MS-2 shifting generally yellow because of photo-induced oxidation of the plastic globe (i.e., a reduction of optical delivery efficiency) and Product MS-3 shifting toward violet and blue emitters because of faster loss of emission from green and red phosphors (i.e., a reduction in spectral efficiency). Because of an initial drop in power consumption, the light source efficiency of downlights (Products MS-4 and MS-5) increased at RTOL throughout the test duration. The light source efficiency initially increased during 75OL until a decay in luminous flux maintenance (LFM) dominated light source efficiency, whereas the light source efficiency decreased for the entire 7575 test duration. It was found that increasing the ambient environment of an SSL device from 25°C to 75°C decreases the LFM by 2.7 to 5.5, depending on design of the SSL device. Adding humidity to the system (75OL to 7575) was found to decrease LFM by another factor of approximately 3.0. A common location of failure was identified for the downlights (Products MS-4 and MS-5) operated in the 7575 environment. This failure abruptly occurred between 3,000 to 5,000 hrs of testing on the film capacitor of the electromagnetic interference (EMI) filter near the diode bridge for 11 of the 12 downlights. It is likely that this failure was caused by a combination of the high electrical voltage across the capacitor, the location of the capacitor near the heat sources (e.g., transformers, diode bridges, power resistors), and the high stress environment of 7575. Longer test times are needed to fully understand the LFM, luminous efficacy changes, and chromaticity shifts for some of the products. Because of the high reliability, light source efficiency, and spectral tuning capabilities of LEDs, the expectations of LAE for SSL products are greatly increased over traditional lighting products. The data gathered in this report begin to provide an understanding of the tradeoffs that current SSL products undergo when optimizing the different efficiency elements of LAE. As discussed in this report, the findings from the tests conducted show that the optimization of spectral efficiency can come at the cost of initial light source efficiency. Furthermore, the introduction of violet LEDs can promote long-term optical delivery efficiency degradation, and the introduction of optical filters or new phosphors can lead to unwanted spectral efficiency changes because the ratio of phosphor emitters changes with aging. The data presented in this report also identified a common failure location in 6-in downlights. The results regarding long-term behavior of the modified spectra devices studied provide valuable information about changes to the light source, spectral, and optical delivery efficiencies as the devices age. This information can be used to improve future SSL designs.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

High-Luminance LED Platform for Improved Efficacy in Directional Applications (Final Technical Report)

In this project, Lumileds developed a platform of high-luminance LEDs and LED light engines to increase efficacy and reduce energy consumption of directional lighting applications. The platform was developed through innovations in three key areas: (1) epi and device architectures optimized for high drive current density, breaking through the tradeoff in efficacy (lm/W) vs. emittance (lm/mm 2 ) exhibited by state-of-the-art products; (2) a compact chip-scale package allowing high packing density and thus high overall luminance in multi-emitter arrays; and (3) phosphor technology to enable correlated color temperature (CCT) tuning in multi-emitter arrays with optimized LED utilization, efficacy, color uniformity and color quality. Directional indoor and outdoor lighting applications make up a major portion of the total lighting energy consumption in the U.S, accounting for >40% of the energy savings potential of solid-state lighting. Success of this project helps accelerate the realization of these energy savings both through higher system efficacy and adoption due to new functionality, and thus contributes significantly to realizing the DOE Lighting program goals.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Controlled Injection of Electrons for Improved Performance of Laser-Wakefield Acceleration

Our lab performed a series of experiments on controlled injection of LWFA with two extreme laser pulses: one laser pulse was used to drive LWFA. In contrast, the other precisely controls the injection of electrons into the wakefield plasma wave. We have demonstrated an efficient reduction of electron beam emittance by optical injection and novel spatio-temporal manipulation of the electron beam by the extreme laser-plasma waves. Moreover, the optical injection process involves unprecedented new physics, which will benefit studies in astrophysics, inertial confinement fusion, laser-driven x-ray light sources, and ultrafast science. We further improved the performance of LWFA by a better understanding and control of the extreme laser-plasma wave dynamics for optical injection. Three novel mechanisms were identified in the optical injection process: (1) collision of two laser pulses, (2) collision of a laser pulse with a wakefield plasma wave, and (3) collision of two laser wakefields. All three methods improved electron-beam energy spread, emittance, stability, and reproducibility. First, we identified, compared, and independently controlled these different injection mechanisms by controlling the polarization of the injector laser pulse. Second, we manipulated the spatiotemporal splitting of LWFA electron beams to reduce their emittance. Third, we applied the same laser-plasma-wave dynamics and the same experimental setup for improved performance of ion acceleration, which has also been predicted by the recent simulations.

43 PARTICLE ACCELERATORS↗

Novel and effective surface passivation for high efficiency n- and p-type Silicon solar cell

The project objective was to develop a novel Si surface passivation method using chalcogens, sulfur (S) and/or selenium (Se), as passivating elements, to withstand industry-standard high temperature contacting and metallization schemes for p-type Si based passivated emitter and rear contact (p-PERC) solar cells. The back surface passivation of PERC cells has been improved drastically with the invention and successful application of an Al 2 O 3 passivation layer. However, the front n + diffused junction surface is still poorly passivated by the standard amorphous silicon nitride (SiNx) anti-reflection coating (ARC) layer. This project sought to address the passivation challenges of both front n+ emitter and undiffused p-Si back surface. Improved p-PERC solar cell performance with open circuit voltage (V OC ) > 680 mV and efficiency of 22% were targeted to validate superior defect passivation properties as compared to standard SiO 2 / Al 2 O 3 passivation. During this project, we systematically investigated process-structure-properties-performance relationships of this novel advanced defect passivation approach. The S/Se passivation was carried out by reacting industrial Czochralski (Cz) Si wafers in H 2 S and H 2 Se gases in a chemical vapor deposition (CVD) reactor at temperatures up to 700°C. After an exhaustive optimization of the process parameters (temperature, time, and gas concentration), we established an optimized process and demonstrated extremely low surface recombination velocities (SRVs) of 1.5 cm/s and 8 cm/s on n-type and p-type Si, respectively, by S-passivation. In-depth surface and interface characterization were performed using soft x-ray and photoelectron spectroscopies (XPS, UPS, XES), combined with capacitance-voltage-frequency (C-V-f) measurements, to decipher the surface chemical/electronic structure and interface defect state densities. These measurements provided critical understanding of the defect passivation mechanism and elucidated the presence of surface S-Si bonds, a reduction of surface dipoles, and low interface state densities (D it ) < 10 11 cm -2 ev -1 . We also found that the Se-passivation is inferior to the S-passivation (by at least one order of magnitude in SRV). Application of the optimized S-passivation to the n+ diffused emitter surface led to a low surface recombination current density, J0 ≈ 40 fA/cm 2 (~ 1/4 of the industry-standard SiNx-passivation), and high implied V OC (686 mV) in p-PERC solar cell structures. The S-passivation process also was found to improve the bulk quality of the p-type Si, better than the SiO 2 or Al 2 O 3 passivation processes. After successful demonstration of efficient passivation of Si surface defects by S, we extensively studied the air, thermal, and illumination stability of the passivation structure. S-passivation itself degrades in air due to competing reactions with moisture and oxygen to form oxides, which can be eliminated by a SiNx capping layer (also acting as a anti-reflective coating). After SiNx process optimization, we demonstrated illumination and thermally stable S-passivation with SRV < 5 cm/s and J 0 < 80 fA/cm 2 . These enhancements in Si passivation, incorporated into p-PERC cells, achieved an efficiency of 19.93% with V OC = 649 mV, using manufacturing metallization and contacting schemes. The low cell performance (cell V OC is much less than the implied V OC = 686 mV, anticipated from surface passivation) was identified due to degradation of S-passivation during the metal firing step (out-diffusion of S from the Si interface to the SiNx surface). The S-passivation of Si surfaces shows significant promise with excellent passivation quality, essential for high performance (high V OC , high efficiency) solar cells. Integration of this innovative defect passivation into devices, however, demands further development of the capping layer, low temperature (<700°C) metallization process, and/or engineering of advanced device structures. Surface passivation-dominated advanced Si solar cells, such as tunnel oxide passivated contacts and Si heterojunctions, are increasingly of interest due to their high-performance potential and will have a growing photovoltaic market share in the near future.

14 SOLAR ENERGY↗