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At least 883 records · Page 49

Why HOC+ is detectable in interstellar clouds: the rate of the reaction between HOC+ and H2

The recent confirmation by Ziurys and Apponi of the detection of HOC+ toward Sgr B2 (OH), and their identification of the ion in Orion-KL and several other sources show that HOC+ is far more abundant than predicted by previous ion-molecule models. In these models, the reaction HOC(+) + H2 --> HCO(+) + H2 is assumed to rapidly destroy HOC+, based on the results of a prior calculation. We have recalculated the rate of this reaction as a function of temperature using a new ab initio potential surface and a phase space approach to the dynamics which includes tunneling. The newly calculated rate is small (< or = 1 x 10(-10) cm3 s-1) at temperatures under 100 K.

Non-NASA Center↗

Response of the middle atmosphere to solar UV and dynamical perturbations

Recent studies of solar UV related changes of ozone and temperature have considerably improved the understanding of the solar UV and ozone relationship in the middle atmosphere on time scales of a solar rotation. These studies have shown that during periods of high solar activity, ozone in the upper stratosphere has a measurable response to changes in the solar UV flux in accordance with theoretical predictions. The problem of measuring solar response of the stratospheric ozone and temperature on time scales of a solar cycle is more difficult. In the altitude range of 2 mb, the model based calculations, based on plausible scenarios of solar UV variation, suggest a change of less than 4 percent in ozone mixing ratio and 1 to 2 K in temperature. The relative response was studied of the middle atmosphere to solar forcing at 155 and 27 day periods as indicated from the spectral analyses of a number of solar indices.

Chandra, S.↗

Central Plasma Sheet Ion Properties as Inferred from Ionospheric Observations

A method of inferring central plasma sheet (CPS) temperature, density, and pressure from ionospheric observations is developed. The advantage of this method over in situ measurements is that the CPS can be studied in its entirely, rather than only in fragments. As a result, for the first time, comprehensive two-dimensional equatorial maps of CPS pressure, density, and temperature within the isotropic plasma sheet are produced. These particle properties are calculated from data taken by the Special Sensor for Precipitating Particles, version 4 (SSJ4) particle instruments onboard DMSP F8, F9, F10, and F11 satellites during the entire year of 1992. Ion spectra occurring in conjunction with electron acceleration events are specifically excluded. Because of the variability of magnetotail stretching, the mapping to the plasma sheet is done using a modified Tsyganenko [1989] magnetic field model (T89) adjusted to agree with the actual magnetotail stretch at observation time. The latter is inferred with a high degree of accuracy (correlation coefficient -0.9) from the latitude of the DMSP b2i boundary (equivalent to the ion isotropy boundary). The results show that temperature, pressure, and density all exhibit dawn-dusk asymmetries unresolved with previous measurements. The ion temperature peaks near the midnight meridian. This peak, which has been associated with bursty bulk flow events, widens in the Y direction with increased activity. The temperature is higher at dusk than at dawn, and this asymmetry increases with decreasing distance from the Earth. In contrast, the density is higher at dawn than at dusk, and there appears to be a density enhancement in the low-latitude boundary layer regions which increases with decreasing magnetic activity. In the near-Earth regions, the pressure is higher at dusk than at dawn, but this asymmetry weakens with increasing distance from the Earth and may even reverse so that at distances X less than approx. 10 to -12 R(sub E), depending on magnetic activity, the dawn sector has slightly higher pressure. The temperature and density asymmetries in the near-Earth region are consistent with the ion westward gradient/curvature drift as the ions ExB convect earthward. When the solar wind dynamic pressure increases, CPS density and pressure appear to increase, but the temperature remains relatively constant. Comparison with previously published work indicates good agreement between the inferred pressure, temperature, and density and those obtained from in situ data. This new method should provide a continuous mechanism to monitor the pressure, temperature, and density in the magnetotail with unprecedented comprehensiveness.

Wing, Simon↗

On the coupled nature of atmospheric phenomena

The interactions that take place in the stratosphere and the troposphere which are important to the maintenance of the chemical, dynamic, and thermal state and of the middle atmosphere, and which may be important in the determination of the state of the lower atmosphere are reviewed. Examples of these interactions due to either natural or anthropogenic processes are discussed, and promising areas for future research are indicated. Specific topics include: (1) coupling between temperature and chemistry via temperature dependent rate constants; (2) the effect of latitudinal temperature variations on zonal winds; (3) the effect of clouds, surface albedo, and the lower atmosphere on stratospheric chemistry due to the scattering and reflection of solar radiation; (4) the effect of trace constituents on thermal structure and thermal balance; (5) the effect of the stratosphere on tropospheric climate; (6) the effect of solar UV variability on stratospheric chemistry and temperature; and (7) the effect of trace constituents on stratospheric dynamics.

Callis, L. B.↗

Chemical and Thermal Analysis

During the past six months we have conducted significant research in several domains in order to clarify and understanding the aging and chemical failure mechanism of thermoplastics (PVDF or Tefzel) for pipes. We organized numerous analytical studies with methods including Fourier Transform Infrared Spectroscopy, Dynamic Mechanical Analysis, Differential Scanning Calorimetry, and Stress Relaxation experiments. In addition we have reanalyzed previous thermogravimetric data concerning the rate of deplasticization of Coflon pipe. We investigated a number of aged samples of both Tefzel and Coflon that were forwarded from MERL. We conducted stress relaxation experiments of Coflon pipe at several temperatures and determined an activation energy. We also examined the dynamic mechanical response PVDF during deplasticization and during methanol plasticization. We performed numerous DSC analyses to research the changing crystalline morphology. We have noted significant changes in crystallinity upon aging for both PVDF and Tefzel. Little variation in elemental composition was noted for many of the aged Coflon and Tefzel samples tested.

Bulluck, J. W.↗

Materials testing of the IUS techroll seal material

As a part of the investigation of the control system failure Inertial Upper Stage on IUS-1 flight to position a Tracking and Data Relay Satellite (TDRS) in geosynchronous orbit, the materials utilized in the techroll seal are evaluated for possible failure models. Studies undertaken included effect of temperature on the strength of the system, effect of fatigue on the strength of the system, thermogravimetric analysis, thermomechanical analysis, differential scanning calorimeter analysis, dynamic mechanical analysis, and peel test. The most likely failure mode is excessive temperature in the seal. In addition, the seal material is susceptible to fatigue damage which could be a contributing factor.

Nichols, R. L.↗

On the interconnection of dynamic processes in the lower thermosphere with meteorological phenomena in the tropostratosphere

Nowadays the atmosphere is considered a single dynamic system governed by inner and other factors, the separate layers (troposphere, strato-mesosphere, thermosphere) of which are in a state of interaction though they differ physically from one another in thermal stratification and energetic processes. Observational data of thermodynamic parameter connections in these layers height range are presented. The interconnection between the temperature field disturbances in the tropo-stratosphere and the dynamic regime in the lower thermosphere in winter and summer is defined as revealed by observational data.

Fakhrutdinova, A. N.↗

Numerical simulations of microflare evolution in the solar transition region and corona

Several observers report transient ultraviolet brightenings, often referred to as microflares, in the solar atmosphere. In this paper, the results are presented of a series of one-dimensional numerical simulations examining possible relationships between microflares and the generation of dynamical chromospheric and transition region features. Low-energy and medium-energy microflares eject long-lived cool, dense gas plugs into the corona, with the gas plug traversing the loop apex in the medium energy case. In the case of high-energy microflares, the gas plug is rapidly heated to the temperature of the surrounding corona, and the results resemble the dynamics occurring in standard solar flare thick-target electron beam models.

Sterling, Alphonse C.↗

Characterization of MOCVD fluid dynamics by laser velocimetry

Three-component laser velocimetry techniques are applied to characterize the fluid dynamics of an MOCVD reactor. These methods provide three-dimensional quantitative measurements of the gas velocities inside the reactor at typical growth temperatures. The effects of buoyancy-induced convection are examined by comparing data from the hot reactor with cold reactor results. It was found that thermal convection dominated the fluid dynamics of the reactor at growth temperatures. Cold reactor tests showed unstable flow patterns that were subject to fluidic switching effects.

Johnson, E. J.↗

Analysis of Two-Phase Flow in Damper Seals for Cryogenic Turbopumps

Cryogenic damper seals operating close to the liquid-vapor region (near the critical point or slightly su-cooled) are likely to present two-phase flow conditions. Under single phase flow conditions the mechanical energy conveyed to the fluid increases its temperature and causes a phase change when the fluid temperature reaches the saturation value. A bulk-flow analysis for the prediction of the dynamic force response of damper seals operating under two-phase conditions is presented as: all-liquid, liquid-vapor, and all-vapor, i.e. a 'continuous vaporization' model. The two phase region is considered as a homogeneous saturated mixture in thermodynamic equilibrium. Th flow in each region is described by continuity, momentum and energy transport equations. The interdependency of fluid temperatures and pressure in the two-phase region (saturated mixture) does not allow the use of an energy equation in terms of fluid temperature. Instead, the energy transport is expressed in terms of fluid enthalpy. Temperature in the single phase regions, or mixture composition in the two phase region are determined based on the fluid enthalpy. The flow is also regarded as adiabatic since the large axial velocities typical of the seal application determine small levels of heat conduction to the walls as compared to the heat carried by fluid advection. Static and dynamic force characteristics for the seal are obtained from a perturbation analysis of the governing equations. The solution expressed in terms of zeroth and first order fields provide the static (leakage, torque, velocity, pressure, temperature, and mixture composition fields) and dynamic (rotordynamic force coefficients) seal parameters. Theoretical predictions show good agreement with experimental leakage pressure profiles, available from a Nitrogen at cryogenic temperatures. Force coefficient predictions for two phase flow conditions show significant fluid compressibility effects, particularly for mixtures with low mass content of vapor. Under these conditions, an increase on direct stiffness and reduction of whirl frequency ratio are shown to occur. Prediction of such important effects will motivate experimental studies as well as a more judicious selection of the operating conditions for seals used in cryogenic turbomachinery.

Arauz, Grigory L.↗

Molecular Dynamics Simulations of the Thermal Conductivity of Single-Wall Carbon Nanotubes

Carbon nanotubes (CNT) have very attractive electronic, mechanical. and thermal properties. Recently, measurements of thermal conductivity in single wall CNT mats showed estimated thermal conductivity magnitudes ranging from 17.5 to 58 W/cm-K at room temperature. which are better than bulk graphite. The cylinderical symmetry of CNT leads to large thermal conductivity along the tube axis, additionally, unlike graphite. CNTs can be made into ropes that can be used as heat conducting pipes for nanoscale applications. The thermal conductivity of several single wall carbon nanotubes has been calculated over temperature range from l00 K to 600 K using non-equilibrium molecular dynamics using Tersoff-Brenner potential for C-C interactions. Thermal conductivity of single wall CNTs shows a peaking behavior as a function of temperature. Dependence of the peak position on the chirality and radius of the tube will be discussed and explained in this presentation.

Osman, M.↗

Temperature Dependent Modal Test/Analysis Correlation of X-34 Fastrac Composite Rocket Nozzle

A unique high temperature modal test and model correlation/update program has been performed on the composite nozzle of the FASTRAC engine for the NASA X-34 Reusable Launch Vehicle. The program was required to provide an accurate high temperature model of the nozzle for incorporation into the engine system structural dynamics model for loads calculation; this model is significantly different from the ambient case due to the large decrease in composite stiffness properties due to heating. The high-temperature modal test was performed during a hot-fire test of the nozzle. Previously, a series of high fidelity modal tests and finite element model correlation of the nozzle in a free-free configuration had been performed. This model was then attached to a modal-test verified model of the engine hot-fire test stand and the ambient system mode shapes were identified. A reduced set of accelerometers was then attached to the nozzle, the engine fired full-duration, and the frequency peaks corresponding to the ambient nozzle modes individually isolated and tracked as they decreased during the test. To update the finite-element model of the nozzle to these frequency curves, the percentage differences of the anisotropic composite moduli due to temperature variation from ambient, which had been used in the initial modeling and which were obtained by small sample coupon testing, were multiplied by an iteratively determined constant factor. These new properties were used to create high-temperature nozzle models corresponding to 10 second engine operation increments and tied into the engine system model for loads determination.

Brown, Andrew M.↗

Dynamic recrystallization and grain boundary migration in B2 FeAl

Transmission electron microscopy and optical microscopy were used to examine polycrystalline specimens of the B2-structured alloy FeAl strained under tension to fracture at elevated temperature. Strain-induced grain boundary migration was observed above 900 K and dynamic recrystallization was found at 1000 K and 1100 K. Little evidence of dynamic recovery was evident but some networks were formed at 1100 K.

Baker, I.↗

Energy dynamics in stressed magnetic fields - The filamentation and flare instabilities

The thermal and tearing instabilities are believed to be the two primary temperature modification mechanisms in sheared astrophysical magnetic fields. The former gives rise to the formation of cool filaments and the latter to the release of magnetic energy. It has long been known that these processes are interrelated, most conspicuously in the case of the solar corona where prominences often precede flares within the same magnetic structure. It is also clear, from first principles, that the energy transport underlying the thermal instability should have a strong effect on the resistivity which facilitates magnetic tearing, and that the energy release of the latter should affect the temperature drop of the former. This paper describes some results of the first calculations which attempt to unify the dynamic treatment of these two coexisting instabilities. Growth rates as a function of resistivity, and examples of the primary mode structures are provided, along with a discussion of some critical aspects of the interaction of these two astrophysical energy flux mechanisms.

Van Hoven, G.↗

Dynamical response of the dayside ionosphere of Venus to the solar wind

Dayside ion composition measurements made by the orbiter ion mass spectrometer and the orbiter electron temperature probe on the Pioneer Venus orbiter are used to infer the dominant processes involved in the dynamic response of the Venus ionosphere to the solar wind. The analysis is confined to the topside ionosphere in the vicinity of the subsolar point, where the ionosphere-solar wind interaction is expected to be maximized. Height profiles of the ion composition and plasma temperatures in the main body of the topside ionosphere, lying between the ionopause and chemical equilibrium regions, reveal that the ionosphere is in a compressed state. This region of the ionosphere is interpreted in terms of a stationary equilibrium where the compression is derived from the ponderomotive force j x B. The estimated magnitude of this force is confirmed by the magnetic field measurements made by the orbiter magnetometer.

Hartle, R. E.↗

Thin film strain gage development program

Sputtered thin-film dynamic strain gages of 2 millimeter (0.08 in) gage length and 10 micrometer (0.0004 in) thickness were fabricated on turbojet engine blades and tested in a simulated compressor environment. Four designs were developed, two for service to 600 K (600 F) and two for service to 900 K (1200 F). The program included a detailed study of guidelines for formulating strain-gage alloys to achieve superior dynamic and static gage performance. The tests included gage factor, fatigue, temperature cycling, spin to 100,000 G, and erosion. Since the installations are 30 times thinner than conventional wire strain gage installations, and any alteration of the aerodynamic, thermal, or structural performance of the blade is correspondingly reduced, dynamic strain measurement accuracy higher than that attained with conventional gages is expected. The low profile and good adherence of the thin film elements is expected to result in improved durability over conventional gage elements in engine tests.

Grant, H. P.↗

Performance of a mullite reusable surface insulation system in a hypersonic stream

The thermal and structural performance of a large panel of mullite reusable surface insulation (RSI) tiles was determined by a series of aerothermal tests in the Langley 8-foot high-temperature structures tunnel. The test panel was designed to represent a portion of the surface structure on a space shuttle orbiter fuselage along a 1,150 K isotherm with the mullite tile system bonded directly to the primary structure. Aerothermal tests were conducted at a free-stream Mach number of 6.7, a total temperature of 1,880 K, a unit Reynolds number of 4.6 million per meter, and dynamic pressure of 62 kPa. The thermal response of the mullite tile was as predicted, and the bond-line temperature did not exceed the design level of 570 K during a typical entry-heat cycle. Geometric irregularities of the tile gaps affected the tile edge temperatures when exposed to hypersonic flow. The tile coating demonstrated good toughness to particle impacts, but the coating cracked and flaked with thermal cycles. The gap filler of woven silica fibers appeared to hinder flow penetration into the gaps and withstood the flow shear of the present tests.

Hunt, L. R.↗