A new strategy for efficient solar energy conversion - Parallel-processing with surface plasmons
(Previously announced in STAR as N82-29354)
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(Previously announced in STAR as N82-29354)
A lightweight, high performance nuclear reactor power system can offer significant advantages for many space missions. Conceptual design has been completed for the SP-100, a system which utilizes many thermoelectric converters and is capable of delivering 100 kilowatts of electrical power. A reference design, using thermoelectric materials with an average figure of merit of 0.001/K and a reactor heat pipe temperature of 1500 K, is presented which has a mass of 2280 kg not including contingency. The sensitivity of system mass to changes in the configuration and thermoelectric material properties are presented
In combination with a reactor for a coal utilization system, a pressure letdown device accepts from a reactor, a polyphase fluid at an entrance pressure and an entrance velocity, and discharges the fluid from the device at a discharge pressure substantially lower than the entrance pressure and at a discharge temperature and a discharge velocity substantially equal to the entrance temperature and entrance velocity. The device is characterized by a series of pressure letdown stages including several symmetrical baffles, disposed in coaxially nested alignment. In each baffle several ports or apertures of uniform dimensions are defined. The number of ports or apertures for each baffle plate is unique with respect to the number of ports or apertures defined in each of the other baffles. The mass rate of flow for each port is a function of the area of the port, the pressure of the fluid as applied to the port, and a common pressure ratio established across the ports.
Planned research efforts and reorganization of the Project as the Biocatalysis Research Activity are described, including the following topics: electrocatalysts, fluid extraction, ammonia synthesis, biocatalysis, membrane fouling, energy and economic analysis, decarboxylation, microscopic reaction models, plasmid monitoring, and reaction kinetics.
Insufficient theoretical definition of heterogeneous catalysts is the major difficulty confronting industrial suppliers who seek catalyst systems which are more active, selective, and stable than those currently available. In contrast, progress was made in tailoring homogeneous catalysts to specific reactions because more is known about the reaction intermediates promoted and/or stabilized by these catalysts during the course of reaction. However, modeling heterogeneous catalysts on a microscopic scale requires compiling and verifying complex information on reaction intermediates and pathways. This can be achieved by adapting homogeneous catalyzed reaction intermediate species, applying theoretical quantum chemistry and computer technology, and developing a better understanding of heterogeneous catalyst system environments. Research in microscopic reaction modeling is now at a stage where computer modeling, supported by physical experimental verification, could provide information about the dynamics of the reactions that will lead to designing supported catalysts with improved selectivity and stability.
Documentation describing software differences between two general purpose computers for scientific applications is presented. Descriptions of the use of the FORTRAN and FORTRAN 77 high level programming language on a CDC 7600 under SCOPE and a CRAY XMP under COS are offered. Itemized differences of the FORTRAN language sets of the two machines are also included. The material is accompanied by numerous examples of preferred programming techniques for the two machines.
The activities of the Biocatalysis Research Activity are organized into the Biocatalysis and Molecular Modeling work elements and a supporting planning and analysis function. In the Biocatalysis work element, progress is made in developing a method for stabilizing genetically engineered traits in microorganisms, refining a technique for monitoring cells that are genetically engineered, and identifying strains of fungi for highly efficient preprocessing of biomass for optimizing the efficiency of bioreactors. In the Molecular Modeling work element, a preliminary model of the behavior of enzymes is developed. A preliminary investigation of the potential for synthesizing enzymes for use in electrochemical processes is completed. Contact with industry and universities is made to define key biocatalysis technical issues and to broaden the range of potential participants in the activity. Analyses are conducted to identify and evaluate potential concepts for future research funding.
Applying vortex generators from 20 to 100 percent span of the Mod-2 rotor resulted in a projected increase in annual energy capture of 20 percent and reduced the wind speed at which rated power is reached by nearly 3 m/sec. Application of vortex generators from 20 to 70 percent span, the fixed portion of the Mod-2 rotor, resulted in a projected increase in annual energy capture of about half this. This improved performance came at the cost of a small increase in cyclic blade loads in below rated power conditions. Cyclic blade loads were found to correlate well with the change in wind speed during one rotor revolution.
The general field of electrocatalysis, from both the technical and business standpoints is accessed and research areas and approaches most likely to lead to substantial energy/cost savings are identified. The overall approach was to compile and evaluate available information, relying heavily on inputs/recommendations of research managers and technical personnel in responsible positions in industry and at universities. Some promising approaches identified to date include the use of transition metal compounds as electrocatalysts and the use of the new electrochemical photocapacitance spectroscopy (EPS) technique for electrocatalyst characterization/development. For the first time, an oxygen electrocatalyst based on the K2NiF4 structure was synthesized, investigated and compared with a perovskite analog. Results show that this class of materials, based on Ni(3+), forms very efficient and stable O2 anodes in basic solution and suggest that other structure-types be examined in this regard. The very difficult problem of dinitrogen and carbon dioxide electroreductions is addressed through the use of biological model systems which can mimic the enzyme processes in nature.
Technical problems and their solutions comprise by far the majority of work involved in space simulation engineering. Fixed price contracts with schedule award fees are becoming more and more prevalent. Accurate estimation of these jobs is critical to maintain costs within limits and to predict realistic contract schedule dates. Computerized estimating may hold the answer to these new problems, though up to now computerized estimating has been complex, expensive, and geared to the business world, not to technical people. The objective of this effort was to provide a simple program on a desk top computer capable of providing a Rough Order of Magnitude (ROM) estimate in a short time. This program is not intended to provide a highly detailed breakdown of costs to a customer, but to provide a number which can be used as a rough estimate on short notice. With more debugging and fine tuning, a more detailed estimate can be made.
Previously cited in issue 02, p. 237, Accession no. A82-11710
Previously cited in issue 05, p. 686, Accession no. A83-16735
The impact of efficiency on the power system and how efficiency is affected by component types is discussed. Some ac and dc bus configurations are described along with prototype systems.
Applied research and technology efforts in thermoelectric and thermionic programs were recommended that will enable space power systems for the nation's future space missions. Specifically it was argued that the effort in thermoelectric materials technology be broadened with the objective of obtaining a material with a Figure of Merit greater than 1.0 x 10(-3)/K for hot junction temperatures of 1100 to 1500 K. The recommended effort in thermionics is to pursue technology programs that will result in an understanding and lifetime prediction methodologies for fuel-emitter and sheath-insulator behavior as a function of operating time and temperature. Also it is recommended that an effort be initiated that combines the thermoelectric, thermionic and power electronic technologies into a program to develop the technology for high temperature, high radiation resistant, and high current electronic switches.
The prototype intermediate frequency video down converter of the Deep Space Network (BLK 1) Very Long Base Interferometry system, a hybrid of analog and digital circuits, was completed and tested. The initial results met all design specifications, establishing a milestone in new design technology for such devices. This device has uses in other similar applications and can form the basis for expanded design and applications.
Successful fabrication of bismuth bolometers led to the observation of antenna action rom array elements. Fabrication of the best antennas arrays was made more facile with finding that increased argon flow during the dc sputtering produced more uniform bismuth films and bonding to antennas must be done with the substrate temperaure below 100 C. Higher temperatures damaged the bolometers. During the testing of the antennas, it was found that the use of a quasi-optical system provided a uniform radiation field. Groups of antennas were bonded in series and in parallel with the parallel configuration showing the greater response.
A number of spectral signals associated with forest cover were selected in order to test the usefulness of adjustments to Landsat MSS digital count values. The signatures were taken from 26 independent regional land cover inventories in the northeastern US. A regression analysis was conducted which revealed a significant relationship between digital count values and variation in the solar elevation angles in MSS bands four, six, and seven for deciduous forests and in all MSS bands for conifers. When signatures were adjusted for solar elevation angles and MSS sensor calibration differences, the dependence on solar elevation angle was reduced. The adjustments also significantly reduced the variance with Level II forest categories among scenes.
A formula is derived for combining effects of successive hysteresis loops in the creep range of materials when one loop has excess tensile creep, while the other contains excess compressive creep. The resultant effect resembles single loops involving balanced tensile and compressive creep. The attempt to use the Interaction Damage Rule as a tool in combining loops of non-equal size and complex strainrange content has led to important new concepts useful in future studies of creep-fatigue. It turns out that the Interaction Damage Rule is basically an expression of how a set of hysteresis loops involving only single generic strains can combine to produce the same micromechanistic damage as the loop containing the combined strainranges which it analyzes. Making use of the underlying concept of Strainrange Partitioning that only the strainrange content of a hysteresis loop governs fatigue life, not order of introducing strainranges, a rational derivation of the Interaction Damage Rule is provided, showing also how it can effectively be used to synthesize independent loops and determine both damaging and healing effects.