Polypeptides from the condensation of amino acid adenylates
Polymerized and hydrolyzed polypeptides from condensed amino acid adenylates for prebiological synthesis model
Banda, P. W.↗
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Results for “condensation”
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Selective condensation of aminoacyl adenylates by nucleoproteinoid microparticles.
Microparticles composed of each of four enzymically synthesized homopolynucleotides and the same lysine-rich proteinoid have been found to influence the condensation of the AMP-anhydrides of each of four amino acids. The conditions of preparation of the particles and other variables of the experiments control the types of reaction. When a period set of conditions was identified empirically, the incorporation favored the amino acids whose present-day codons are related to the homopolynucleotide in the particle.
Nakashima, T.↗
Condensate-removal device for heat exchangers
Device comprises array of perforated tubes manifolded together and connected to a vacuum suction device. Vacuum applied to these tubes pulls mixture of condensate and effluent gas through perforations and along length of tubes to discharge device. Discharge device may be a separator which separates water vapor from effluent air and allows recirculation of both of them.
Trusch, R. B.↗
Continuous dependence of fixed points of condensing maps
Many problems in analysis are concerned with the dependence upon parameters of fixed points of maps. For contraction mappings, criteria are relatively easy to obtain and have been known for some time. In the study of solutions of functional differential equations, more general results were needed. It is the purpose of this paper to give a rather general fixed-point theorem for condensing maps depending on a parameter, to prove continuous dependence and to indicate how many of the previous results are special cases.
Hale, J. K.↗
Electrical conductivity of condensed molecular hydrogen in the giant planets
Theoretical interpretation of several phenomena concerning Jupiter and Saturn depends upon the electrical conductivity of molecular hydrogen which, according to present models, forms the outermost layer of both planets. The layer starts at the transition pressure between the metallic and the molecular form of hydrogen, that is around 1 Mbar, and extends to the outside limits of the atmosphere. Whether at the highest pressures (and temperatures) this layer is a solid or a dense fluid is not certain. In any case, the fluid is in supercritical condition so that there is only a gradual transition from dense liquid to a gaseous form. The two theories which require specific values of the conductivity of the condensed molecular hydrogen are those pertaining to the generation of a magnetic field in the liquid hydrogen rather than in the deep metallic interior (HIDE, 1967), and those concerned with the electromagnetic coupling and exchange of angular momentum between the liquid core and the solid molecular hydrogen mantle.
Smoluchowski, R.↗
Scattering from condensates in turbulent jets
An analysis is made of the scattering signal levels to be expected from condensed water vapor droplets for crossed-beam instruments operating in the wavelength region. 18 to 4.3 microns. The results show that scattering should not present a problem for the infrared system operating under conditions typical of the IITRI jet facility. Actual measurements made for comparison indicate that scattering levels are appreciable, and presumably result from oil mist added by the facility air compressors.
Wilson, L. N.↗
User's manual for the TRW gaspipe 2 program: A vapor-gas front analysis program for heat pipes containing non-condensible gas
A digital computer program for design and analysis of heat pipes which contain non-condensible gases, either for temperature control or to aid in start-up from the frozen state, is presented. Some of the calculations which are possible with the program are: (1) wall temperature profile along a gas-loaded heat pipe, (2) amount of gas loading necessary to obtain desired evaporator temperature at a desired heat load, (3) heat load versus evaporator temperature for a fixed amount of gas in the pipe, and (4) heat and mass transfer along the pipe, including the vapor-gas front region.
Edwards, D. K.↗
On the primordial condensation and accretion environment and the remanent magnetization of meteorites
In the context of various models for the early evolution of a solar nebula, the possible roles assigned to ambient magnetic fields and the paleointensities required to establish the stable natural remanent magnetization observed in meteorites, are discussed. It is suggested that the record of paleofields present during condensation, growth, and accumulation of grains is likely to have been preserved as chemical or thermochemical remanence in unaltered meteoritic material. Fine particle theories appear adequate for treating meteoritic remanence, if models based on corresponding types of permanent magnet materials, e.g., powder ferrites for chondrites and diffusion hardened alloys for iron meteorites, are adopted.
Brecher, A.↗
Laboratory simulation of processes of evaporation, condensation, and sputtering taking place on the surface of the moon
Study of evaporation, condensation and sputtering on the Moon can provide information on the same processes on other planets, and reveal details of the formation of the lunar regolith. Simulation methods include vacuum evaporation, laser evaporation, and bubbling gas through melts.
M D Nusinov↗
Condensed phase details in the time-independent combustion of AP/composite propellants
The problem of nonmetallized ammonium perchlorate (AP)/composite propellant combustion is studied with the aim of coherently interpreting apparently diverse experimental data. Three fundamental hypotheses are introduced: the extent of propellant degradation at the vaporization step has to be specified through a scientific criterion; condensed phase degradation of AP to vaporizable fragments is the overall rate-limiting reaction; the rate of combustion in the gas phase is controlled by diffusive-mixing processes. Theoretical predictions of the regression rates of AP are seen to match well with experimental observations. Theoretical curves of regression rate are presented for a typical composite propellant. It is seen through analyses that either of the two familiar models for the gas phase (flame sheet approximation and uniform combustion) describes the general behavior adequately, hence de-emphasizing the role of gas phase details in propellant combustion.
Kumar, R. N.↗
Adsorption and condensation of Cu on W single-crystal surfaces
The adsorption and condensation of Cu up to several monolayers in thickness on tungsten 110 and 100 single-crystal surfaces are studied by combining low-energy electron diffraction, Auger electron spectroscopy, thermal desorption spectroscopy, work-function measurements, and quartz microbalance thickness measurements in one experimental system. The results show drastic differences in the evolution of the structure, work function, and desorption behavior between 110 and 100 surfaces. These differences are understandable in terms of the atomic roughness of the surfaces.
Bauer, E.↗
Kinetic approach to the evaporation and condensation problem
In the paper, the Boltzmann equation governing the evaporation and condensation phenomena is solved by the Monte Carlo method. Based on the kinetic theory of gas the role of the non-equilibrium Knudsen layer and the growth of the hydrodynamic region outside the layer as time proceeds are simulated. Results show two possible types of transient developments in the vapor phase. The effects of the molecular absorption coefficient of the phase surface are examined. Except in the case of very strong evaporation the kinematic effects of binary collisions among vapor molecules on the mass flux rate are not serious. The limiting case of the quasi-steady evaporation and the maximal value of the evaporation rate are obtained.
Murakami, M.↗
Analysis of nitrogen condensation in an expanding nozzle flow
Condensation of nitrogen flow in an expanding nozzle flow is analyzed using one-dimensional gas dynamic equations and the equations for nucleation and droplet growth. Effects of variations in the Tolman constant and the mass accommodation factor are discussed as well as the effect of foreign nuclei. Comparisons are made with experimental data obtained from a small, contoured nozzle.
Wang, F. C.↗
The time dependent growth of H2O-H2SO4 aerosols by heteromolecular condensation
A theory for the time-dependent growth of solution droplets by heteromolecular condensation is presented. The theory is applied to the growth of H2O-H2SO4 aerosols for relative humidities less than 100 per cent. Growth curves (droplet radius as a function of time) for different values of relative humidity are evaluated.
Hamill, P.↗
The prebiotic synthesis of deoxythymidine oligonucleotides. II - Comparison of condensing agents
A reaction which oligomerizes nucleotides under possible prebiotic conditions has been characterized. Nucleoside monophosphate in the presence of cyanamide at acid pH condenses to form dithymidine pyrophosphate and phosphodiester bonded compounds. Imidazole compounds and activated precursors such as nucleoside triphosphate are not necessary for this oligomerization reaction which produces primarily cyclic oligonucleotides.
Odom, D. G.↗
Can the ordinary chondrites have condensed from a gas phase
The conditions under which ordinary chondrites containing iron in three different chemical states can form in thermodynamic equilibrium with a gas phase are calculated. Hydrogen depletion factors of 100-1000 are obtained and the formation of liquid condensates from residual gases occurs at pressures (prior to hydrogen depletion) of roughly equal to or greater than 1 atm.
Herndon, J. M.↗
'Mysterite' - A late condensate from the solar nebula
An attempt is made to clarify the nature of 'mysterite', a material that had been postulated to explain the overabundance of Tl, Bi, and Ag in certain chondrites. Four dark clasts and a vein sample from the H6 chondrite Supuhee were analyzed by radiochemical neutron activation analysis for Ag, Au, Bi, Br, Cd, Cs, Ge, In, Ir, Ni, Os, Rb, Re, Sb, Se, Te, Tl, and Zn. One of the clasts is enriched in all volatile elements, while the other four samples are enriched only in the siderophile volatiles Ag, Bi, and Tl. The enrichments range up to 100 times typical H6 chondrite abundances. The proportions of Ag, Bi, and Tl suggest the presence of at least two, Tl-rich and Tl-poor, varieties of mysterite. The former seems to dominate in Supuhee and Krymka, and the latter in Mezo-Madaras. Apparently mysterite is a late condensate from the solar nebula that collected volatiles left behind by earlier generations of chondrites. It was incorporated in Supuhee and perhaps in other chondrites (mainly of low petrologic types) during brecciation events.
Higuchi, H.↗
The adsorption and early stages of condensation of Ag and Au on W single-crystal surfaces
Silver and gold were evaporated up to several monolayers in thickness onto W single-crystal surfaces of the 110 and 100 plane types in the temperature range between 300 and 1300 K. The mode of growth and the structure of the layers were studied by Auger electron spectroscopy and low-energy electron diffraction. The results are compared with thermal desorption spectroscopy data and work-function change measurements. They show certain similarities but also some striking differences between the two systems Ag/W and Au/W as well as a strong crystallographic anisotropy of adsorption and condensation.
Bauer, E.↗