Elastic and Piezoelectric Properties of Boron Nitride Nanotube Composites: Molecular Dynamics of a Single Wall BNNT - I
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Yamakov, V. I.↗
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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X-Ray Amorphous Phases in Terrestrial Analog Volcanic Sediments: Implications for Amorphous Phases in Gale Crater, Mars
X-ray diffraction (XRD) amorphous phases have been found as major components (approx.15-60 wt%) of all rock and soil samples measured by the CheMin XRD instrument in Gale Crater, Mars. The nature of these phases is not well understood and could be any combination of primary (e.g., glass) and secondary (e.g., allophane) phases. Amorphous phases form in abundance during surface weathering on Earth. Yet, these materials are poorly characterized, and it is not certain how properties like composition and structure change with formation environment. The presence of poorly crystalline phases can be inferred from XRD patterns by the appearance of a low angle rise (< or approx.10deg 2(theta)) or broad peaks in the background at low to moderate 2(theta) angles (amorphous humps). CheMin mineral abundances combined with bulk chemical composition measurements from the Alpha Particle X-ray Spectrometer (APXS) have been used to estimate the abundance and composition of the XRD amorphous materials in soil and rock samples on Mars. Here we apply a similar approach to a diverse suite of terrestrial samples - modern soils, glacial sediments, and paleosols - in order to determine how formation environment, climate, and diagenesis affect the abundance and composition of X-ray amorphous phases.
Smith, R. J.↗
Connecting the Interstellar Gas and Dust Properties in Distant Galaxies Using Quasar Absorption Systems
Gas and dust grains are fundamental components of the interstellar medium and significantly impact many of the physical processes driving galaxy evolution, such as star-formation, and the heating, cooling, and ionization of the interstellar material. Quasar absorption systems (QASs), which trace intervening galaxies along the sightlines to luminous quasars, provide a valuable tool to directly study the properties of the interstellar gas and dust in distant, normal galaxies. We have established the presence of silicate dust grains in at least some gas-rich QASs, and find that they exist at higher optical depths than expected for diffuse gas in the Milky Way. Differences in the absorption feature shapes additionally suggest variations in the silicate dust grain properties, such as in the level of grain crystallinity, from system-to-system. We present results from a study of the gas and dust properties of QASs with adequate archival IR data to probe the silicate dust grain properties. We discuss our measurements of the strengths of the 10 and 18 micron silicate dust absorption features in the QASs, and constraints on the grain properties (e.g., composition, shape, crystallinity) based on fitted silicate profile templates. We investigate correlations between silicate dust abundance, reddening, and gas metallicity, which will yield valuable insights into the history of star formation and chemical enrichment in galaxies.
Aller, Monique C.↗
Single Object & Time Series Spectroscopy with JWST NIRCam
JWST will enable high signal-to-noise spectroscopic observations of the atmospheres of transiting planets with high sensitivity at wavelengths that are inaccessible with HST or other existing facilities. We plan to exploit this by measuring abundances, chemical compositions, cloud properties, and temperature-pressure parameters of a set of mostly warm (T 600 - 1200 K) and low mass (14 -200 Earth mass) planets in our guaranteed time program. These planets are expected to have significant molecular absorptions of H2O, CH4, CO2, CO, and other molecules that are key for determining these parameters and illuminating how and where the planets formed. We describe how we will use the NIRCam grisms to observe slitless transmission and emission spectra of these planets over 2.4 - 5.0 microns wavelength and how well these observations can measure our desired parameters. This will include how we set integration times, exposure parameters, and obtain simultaneous shorter wavelength images to track telescope pointing and stellar variability. We will illustrate this with specific examples showing model spectra, simulated observations, expected information retrieval results, completed Astronomer's Proposal Tools observing templates, target visibility, and other considerations.
NIRCam↗
Synergies Between the Kepler, K2 and TESS Missions with the PLATO Mission (Revised)
Two transit survey missions will have been flown by NASA prior to the launch of ESA's PLATO Mission in 2026, laying the groundwork for exoplanet discovery via the transit method. The Kepler Mission, which launched in 2009, collected data on its 100+ square degree field of view for four years before failure of a reaction wheel ended its primary mission. The results from Kepler include 2300+ confirmed or validated exoplanets, 2200+ planetary candidates, 2100+ eclipsing binaries. Kepler also revolutionized the field of asteroseismology by measuring the pressure mode oscillations of over 15000 solar-like stars spanning the lifecycle of such stars from hydrogen-burning dwarfs to helium-burning red giants. The re-purposed Kepler Mission, dubbed K2, continues to observe fields of view in and near the ecliptic plane for 80 days each, significantly broadening the scope of the astrophysical investigations as well as discovering an additional 156 exoplanets to date. The TESS mission will launch in 2017 to conduct an all-sky survey for small exoplanets orbiting stars 10X closer and 100X brighter than Kepler exoplanet host stars, allowing for far greater follow-up and characterization of their masses as well as their sizes for at least 50 small planets. Future assets such as James Webb Space Telescope, and ground-based assets such as ESOs Very Large Telescope (VLT) array, the Exremely Large Telescope (ELT), and the Thirty Meter Telescope (TMT) will be able to characterize the atmospheric composition and properties of these small planets. TESS will observe each 24 X 96 field of view for 30 days and thereby cover first the southern and then the northern hemisphere over 13 pointings during each year of the primary mission. The pole-most camera will observe the James Webb continuous viewing zone for one year in each hemisphere, permitting much longer period planets to be detected in this region. The PLATO mission will seek to detect habitable Earth-like planets with an instrument composed of 26 small telescopes in several 2232 square deg FOVs with a range of observation durations over a mission lifetime of up to eight years. This paper summarizes the findings of the KeplerK2 missions, previews the likely results from the TESS mission, and explores the lessons learned and to be learned from these prior missions that can be incorporated into the observation and data reduction strategy for the PLATO Mission so as to maximize the science return.
exoplanet detection↗
Incorporation of Functionalized Polyhedral Oligomeric Silsesquioxane Nanomaterials as Reinforcing Agents for Impact Ice Mitigating Coatings
In-flight, aircraft are exposed to a wide range of environments. One commonly exposed environment are clouds containing super-cooled water droplets. These water drop- lets exist in a metastable state below the freezing point of water, in the range of 0 to -20°C. As the vehicle impacts the droplets, latent heat is released and within milliseconds the droplets convert to ice. This process is referred to as impact icing or in-flight icing.1 Impact icing is a major concern for aircraft since it can lead to degraded aerodynamic performance and, if left un- treated, can lead to loss of the vehicle. Active approaches (i.e., pneumatic boots, heated air ducts) typically utilized in mitigating in-flight ice accretion significantly increases vehicle weight and cannot be applied to all aircraft.1-3 A passive approach based on coatings is desired, but durability issues are a concern, especially on the wing leading edge.3 Nanomaterials have been shown to afford significant improvement in coating and composite physical properties at low loading levels.4 In this study, Polyhedral Oligomeric Silsesquioxane (POSS) nanomaterials have been shown to increase coating durability. Also, with wide variety of functionalities present on the arm structure, POSS nanomaterials have been shown to readily alter coating surface chemistry to mitigate impact ice adhesion from -16 to -8°C in a simulated in-flight icing environment.
Beck, Devon M.↗
Widespread carbon-bearing materials on near-Earth asteroid (101955) Bennu
(101955) Bennu is a dark, Earth orbit-crossing, asteroid thought to be assembled from the fragments of an ancient collision. Spatially-resolved visible and near-infrared spectra of Bennu provide details about its surface properties and composition. In addition to a hydrated phyllosilicate band, we detect a ubiquitous 3.4-micron absorption feature, which we attribute to a mix of organic and carbonate materials. The shape and depth of this absorption feature vary across Bennu’s surface, spanning the range seen among similar main-belt asteroids. Its distribution does not correlate with the temperature, reflectance, spectral slope, or hydrated minerals although those characteristics correlate with each other in some cases. The deepest 3.4-micron absorptions occur on individual boulders. The variations may be due to differences in abundance, recent exposure, or space weathering.
Amy A. Simon↗
Multiscale Simulation of Deployable Composite Structures
In this paper, a multiscale simulation method for analyzing deployable composite structures is presented. Effective shell properties of the composites are obtained based on Mechanics of Structure Genome (MSG) homogenization, and then implemented into a user-subroutine UGENS for structural simulation with shell elements in Abaqus. The column bending test(CBT) of a flat thin flexure and lenticular composite boom in a simplified deployer structure are studied for demonstration. A viscoelastic material model with direct integration is adopted in this paper. The CBT simulation shows good agreement with experiments during relaxation, while errors are observed when comparing residual deformation. It is shown that this CBT model can be calibrated to CBT test results. For the lenticular boom analysis, the complete process of flattening, coiling, stowage, deployment and recovery is simulated with the viscoelastic shell model.
Finite element analysis↗
Identifying Meteorological Influences on Marine Low Cloud Mesoscale Morphology Using Satellite Classifications
Marine low cloud mesoscale morphology in the southeastern Pacific Ocean is analyzed using a large dataset of machine-learning generated classifications spanning three years. Meteorological variables and cloud properties are composited 10by mesoscale cloud type, showing distinct meteorological regimes of marine low cloud organization from the tropics to the midlatitudes. The presentation of mesoscale cellular convection, with respect to geographic distribution, boundary layer structure, and large-scale environmental conditions, agrees with prior knowledge. Two tropical and subtropical cumuliform boundary layer regimes, suppressed cumulus and clustered cumulus, are studied in detail. The patterns in precipitation, circulation, column water vapor, and cloudiness are consistent with the representation of marine shallow mesoscale convective 15 self-aggregation by large eddy simulations of the boundary layer. Although they occur under similar large-scale conditions, the suppressed and clustered low cloud types are found to be well-separated by variables associated with low-level mesoscale circulation, with surface wind divergence being the clearest discriminator between them, whether reanalysis or satellite observations are used. Clustered regimes are associated with surface convergence and suppressed regimes are associated with surface divergence.
Johannes Mohrmann↗
Ongoing Progress Toward NASA's Surface Biology and Geology Mission
Pursuant to recommendations by the National Academies of Science, Engineering and Medicine's Earth Science Decadal Survey, the National Aeronautics and Space Administration (NASA) has announced the development of an Earth System Observatory (ESO), a series of missions designed to observe processes across the Earth's interior, surface and atmosphere. A key component of this system is the Surface Biology and Geology (SBG) investigation. SBG will measure the composition and properties of Earth's land, inland waters, and coastal oceans. The notional architecture consists of multiple spacecraft slated for launch in the 2027–2028 timeframe (Figure 1). Target science questions and geophysical variables span diverse disciplines including terrestrial and aquatic ecology, geology, vulcanology, hydrology and cryospheric sciences (Figure 2). Beyond simply measuring geophysical variables for each discipline, SBG will provide information about the links between the different domains, enabling a more comprehensive understanding of the Earth as a connected system. SBG measurements will also benefit a wide range of societal applications including agriculture, terrestrial and aquatic biodiversity, natural hazards, public health, and management of water and other natural resources. SBG will also coordinate measurements, data products, and analyses with other ESO elements to deliver an integrated Earth System perspective of Earth and its changing climate.
David R. Thompson↗
Role of Small-Scale Impulsive Events in Heating the X-Ray Bright Points of the Quiet Sun
Small-scale impulsive events, known as nanoflares, are thought to be one of the prime candidates that can keep the solar corona hot at its multimillion-Kelvin temperature. Individual nanoflares are difficult to detect with the current generation of instruments; however, their presence can be inferred through indirect techniques such as Differential Emission Measure (DEM) analysis. Here, we employ this technique to investigate the possibility of nanoflare heating of the quiet corona during the minimum of solar cycle 24. We estimate the DEM of disk-integrated quiet Sun and X-ray bright points (XBP) using the observations from XSM on board the Chandrayaan-2 orbiter and AIA on board the Solar Dynamic Observatory. XBPs are found to be the dominant contributor to disk-integrated X-rays, with a radiative flux of ∼2 × 10 5 erg cm −2 s −1 . XBPs consist of small-scale loops associated with bipolar magnetic fields. We simulate such XBP loops using the EBTEL hydrodynamic code. The lengths and magnetic field strengths of these loops are obtained through a potential field extrapolation of the photospheric magnetogram. Each loop is assumed to be heated by random nanoflares having an energy that depends on the loop properties. The composite nanoflare energy distribution for all the loops has a power-law slope close to −2.5. The simulation output is then used to obtain the integrated DEM. It agrees remarkably well with the observed DEM at temperatures above 1 MK, suggesting that the nanoflare distribution, as predicted by our model, can explain the XBP heating.
Solar coronal heating↗
Characterizing the Unique Properties of Natural-Fiber Composites Nondestructively
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Nondestructive Evaluation↗
Engineered Polymer Composites Through Electrospun Nanofiber Coating of Fiber Tows
Toughening and other property enhancements of composite materials are typically implemented by-modifying the bulk properties of the constituents, either the fiber or matrix materials. This often leads to difficulties in processing and higher material costs. Many composites consist of tows or yarns (thousands of individual fibers) that are either filament wound or processed into a fabric by weaving or braiding. The matrix material can be added to the tow or fabric before final processing, resulting in a prepreg material, or infused into the fiber material during final processing by a variety of methods. By using a direct electrospun deposition method to apply thermoplastic nanofiber to the surface of the tows, the tow-tow interface in the resulting composite can be modified while using otherwise conventional materials and handling processes. Other materials of interest could also be incorporated into the electrospun precursor.
toughening↗
Thermodynamic and transport combustion properties of hydrocarbons with air. Part 4: Compositions corresponding to Rankine temperature schedules in part 3
The equilibrium compositions corresponding to the thermodynamic and transport combustion properties for a wide range of conditions for the reaction of hydrocarbons with air are presented. The compositions presented correspond to Rankine temperature schedules.
Gordon, S.↗
High Volume Fraction Carbon Nanotube Composites for Aerospace Applications
Reported nanoscale mechanical properties of carbon nanotubes (CNTs) suggest that their use may enable the fabrication of significantly lighter structures for use in space applications. To be useful in the fabrication of large structures, however, their attractive nanoscale properties must be retained as they are scaled up to bulk materials and converted into practically useful forms. Advances in CNT production have significantly increased the quantities available for use in manufacturing processes, but challenges remain with the retention of nanoscale properties in larger assemblies of CNTs. This work summarizes recent progress in producing carbon nanotube composites with tensile properties approaching those of carbon fiber reinforced polymer composites. These advances were achieved in nanocomposites with CNT content of ~70% by weight. The processing methods explored to yield these CNT composite properties will be discussed, as will the characterization and test methods that were developed to provide insight into the factors that contribute to the enhanced tensile properties. Technology maturation was guided by parallel advancements in computational modeling tools that aided in the interpretation of experimental data.
Siochi, Emilie J.↗
Composite materials for structures on planetary surfaces
The physical and mechanical properties of advanced composite materials as related to their use in structures on planetary surfaces are reviewed. Polymer matrix composites are recommended as the best materials in the first exploration stages. Achievement of mechanical properties, physical properties, improved processability, and ease of assembly required on planetary surfaces depends on the tailorability of composites.
Radford, Donald W.↗
Simulating the Effects of Carbon Nanotube Continuity and Interfacial Bonding on Composite Strength and Stiffness
Molecular dynamics simulations of carbon nanotube (CNT) composites, in which the CNTs are continuous across the periodic boundary, overestimate the experimentally measured mechanical properties of CNT composites along the fiber direction. Since the CNTs in these composites are much shorter than the composite dimensions, load must be transferred either directly between CNTs or through the matrix, a mechanism that is absent in simulations of effectively continuous CNTs. In this study, the elastic and fracture properties of high volume fraction discontinuous carbon nanotube/amorphous carbon composite systems were compared to those of otherwise equivalent continuous CNT composites using ReaxFF reactive molecular dynamics simulations. These simulations were used to show how the number of nanotube-matrix interfacial covalent bonds affect composite mechanical properties. Furthermore, the mechanical impact of interfacial bonding was decomposed to reveal its effect on the properties of the CNTs, the interfacial layer of matrix, and the bulk matrix. For the composites with continuous reinforcement, it was found that any degree of interfacial bonding has a negative impact on axial tensile strength and stiffness. This is due to disruption of the structure of the CNTs and interfacial matrix layer by the interfacial bonds. For the discontinuous composites, the modulus was maximized between 4%-7% interfacial bonding and the strength continues to increase up to the highest levels of interfacial bonding studied. Areas of low stress and voids were observed in the simulated discontinuous composites at the ends of the tubes, from which fracture was observed to initiate. Experimental carbon nanotube yarn composites were fabricated and tested. The results were used to illustrate knockdown factors relative to the mechanical performance of the tubes themselves.
Benjamin D Jensen↗
Tunable Optical Properties of Metal Nanoparticle Sol-Gel Composites
We demonstrate that the linear and non-linear optical properties of sol-gels containing metal nanoparticles are highly tunable with porosity. Moreover, we extend the technique of immersion spectroscopy to inhomogeneous hosts, such as aerogels, and determine rigorous bounds for the average fractional composition of each component, i.e., the porosity of the aerogel, or equivalently, for these materials, the catalytic dispersion. Sol-gels containing noble metal nanoparticles were fabricated and a significant blue-shift in the surface plasmon resonance (SPR) was observed upon formation of an aerogel, as a result of the decrease in the dielectric constant of the matrix upon supercritical extraction of the solvent. However, as a result of chemical interface damping and aggregation this blue-shift does not strictly obey standard effective medium theories. Mitigation of these complications is achieved by avoiding the use of alcohol and by annealing the samples in a reducing atmosphere.
Smith, David D.↗