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NASA NTRS1989

Chemical evolution of primitive solar system bodies

Observations on organic molecules and compounds containing biogenic elements in the interstellar medium and in the primitive bodies of the solar system are reviewed. The discovery of phosphorus molecular species in dense interstellar clouds, the existence of organic ions in the dust and gas phase of the comas of Comet Halley, and the presence of presolar, deuterium-hydrogen ratios in the amino acids of carbonaceous chondrites are discussed. The relationships between comets, dark asteroids, and carbonaceous chondrites are examined. Also, consideration is given to the chemical evolution of Titan, the primitive earth, and early Mars.

Oro, J.↗
NASA NTRS1989

Infrared photometry and spectroscopy of Comet P/Encke 1987

New IR observations in the 2.3-18.5 micron range are presented which demonstrate that P/Encke exhibited very little continuum superheat and very weak silicate emission when near perihelion, at a heliocentric distance of 0.37 AU. It is inferred on the basis of this finding that the grains in P/Encke are large; also, no evidence is found for a 3.4-micron feature associable with hydrocarbon emissions. While there is evidence of jet-like coma activity on the P/Encke nucleus near perihelion, the total IR flux at heliocentric distances near 1 AU may be from a bare, rotating nucleus with a radius in the 2.5-6.4 km range.

Gehrz, R. D.↗
NASA NTRS1989

The in-situ cometary particulate size distribution measured for one comet: P/Halley

The close approach of Giotto to comet Halley during its 1986 apparition offered an opportunity to study the particulate mass distribution to masses of up to one gram. Data acquired by the front end channels of the highly sensitive mass spectrometer PIA and the dust shield detector system, DIDSY, provide definition to the detected distribution as close as 1000 km to the nucleus. Dynamic motion of the particulates after emission leads to a spatial differentiation affecting the size distribution in several forms: (1) ejecta velocity dispersion; (2) radiation pressure; (3) varying heliocentric distance; and (4) anisotropic nucleus emission. Transformation of the in-situ distribution from PIA and DIDSY weighted heavily by the near-nucleus fluxes leads to a presumed nucleus distribution. The data lead to a puzzling distribution at large masses, not readily explained in an otherwise monotonous power law distribution. Although temporal changes in nucleus activity could and do modify the in-situ size distribution, such an explanation is not wholly possible, because the same form is observed at differing locations in the coma where the time of flight from the nucleus greatly varies. Thus neither a general change in comet activity nor spatial variations lead to a satisfactory explanation.

Mcdonnell, J. A. M.↗
NASA NTRS1989

The comet rendezvous asteroid flyby mission

The Comet Rendezvous Asteroid Flyby (CRAF) mission is designed to answer the many questions raised by the Halley missions by exploring a cometary nucleus in detail, following it around its orbit and studying its changing activity as it moves closer to and then away from the Sun. In addition, on its way to rendezvous with the comet, CRAF will fly by a large, primitive class main belt asteroid and will return valuable data for comparison with the comet results. The selected asteroid is 449 Hamburga with a diameter of 88 km and a surface composition of carbonaceous chondrite meteorites. The expected flyby date is January, 1998. The CRAF spacecraft will continue to make measurements in orbit around the cometary nucleus as they both move closer to the Sun, until the dust and gas hazard becomes unsafe. At that point the spacecraft will move in and out between 50 and 2,500 kilometers to study the inner coma and the cometary ionosphere, and to collect dust and gas samples for onboard analysis. Following perihelion, the spacecraft will make a 50,000 km excursion down the comet's tail, further investigating the solar wind interaction with the cometary atmosphere. The spacecraft will return to the vicinity of the nucleus about four months after perihelion to observe the changes that have taken place. If the spacecraft remains healthy and adequate fuel is still onboard, an extended mission to follow the comet nucleus out to aphelion is anticipated.

Morrison, David↗
NASA NTRS1990

Carbon-rich particles in Comet Halley

The majority of particles detected in the coma of Comet Halley contain carbon atoms; many of these grains appear to consist preponderately or only of light elements. These light-element particles may be composed of organic compounds. Of the possible combinations of the elements hydrogen, carbon, nitrogen, and oxygen, numerous examples are found of particles containing the combinations (H,C,O,N), (H,C,N), (H,C,O), and (H,C). These results may bear on the recent detection of polyoxymethylene fragments, the observation of cyanojets (CN patterns consistent with release from solid particles), the possible presence of cyanopolyacetylenes or HCN polymer and the make-up of the CHON particles. If cometary matter could reach the surface of the earth without complete disruption, these diverse organic and mixed particles could create unique microenvironments, possibly with significant or even pivotal prebiotic chemical activity. Here a speculative insight into possible relationships between carbon in comets and carbon in life is given, as well as a brief overview of on-going analysis of data from the highly successful Particle Impact Analyzer (PIA) experiment flown on the Giotto spacecraft for the flyby of Comet Halley (development and implementation of PIA was under the direction of J. Kissel of the Max Planck Institute for Kernphysik, Heidelberg). PIA is a time-of-flight analyzer which obtains mass spectra of ions from individual particles impacting on a Pt-Ag foil target within the instrument.

Clark, Benton C.↗
NASA NTRS1990

Laboratory simulation of interstellar grain chemistry and the production of complex organic molecules

During the past 15 years considerable progress in observational techniques has been achieved in the middle infrared (5000 to 500 cm(-1), 2 to 20 microns m), the spectral region most diagnostic of molecular vibrations. Spectra of many different astronomical infrared sources, some deeply embedded in dark molecular clouds, are now available. These spectra provide a powerful probe, not only for the identification of interstellar molecules in both the gas solid phases, but also of the physical and chemical conditions which prevail in these two very different domains. By comparing these astronomical spectra with the spectra of laboratory ices one can determine the composition and abundance of the icy materials frozen on the cold (10K) dust grains present in the interior of molecular clouds. These grains and their ice mantles may well be the building blocks from which comets are made. As an illustration of the processes which can take place as an ice is irradiated and subsequently warmed, researchers present the infrared spectra of the mixture H2O:CH3OH:CO:NH3:C6H14 (100:50:10:10:10). Apart from the last species, the ratio of these compounds is representative of the simplest ices found in interstellar clouds. The last component was incorporated into this particular experiment as a tracer of the behavior of a non-aromatic hydrocarbon. The change in the composition that results from ultraviolet photolysis of this ice mixture using a UV lamp to simulate the interstellar radiation field is shown. Photolysis produces CO, CO2, CH4, HCO, H2CO, as well as a family of moderately volatile hydrocarbons. Less volatile carbonaceous materials are also produced. The evolution of the infrared spectrum of the ice as the sample is warmed up to room temperature is illustrated. Researchers believe that the changes are similar to those which occur as ice is ejected from a comet and warmed up by solar radiation. The warm-up sequence shows that the nitrile or iso-nitrile bearing compound produced during photolysis evaporates between 200 and 250K, suggesting that it is carried by a small molecular species. These molecules could be similar to the source material in Comet Halley that is ejected in grains into the coma, freed by sublimation, and photolyzed by solar radiation to produce the observed jets.

Allamandola, L. J.↗
NASA NTRS1988

Design of an imaging microscope for soft X-ray applications

An imaging soft X-ray microscope with a spatial resolution of 0.1 micron and normal incidence multilayer optics is discussed. The microscope has a Schwarzschild configuration, which consists of two concentric spherical mirrors with radii of curvature which minimize third-order spherical aberration, coma, and astigmatism. The performance of the Stanford/MSFC Cassegrain X-ray telescope and its relevance to the present microscope are addressed. A ray tracing analysis of the optical system indicates that diffraction-limited performance can be expected for an object height of 0.2 mm.

Hoover, Richard B.↗
NASA NTRS1989

Nuclei of two earth-grazing comets of fan-shaped appearance

The conceptual model of a collimated particle flow from isolated sources on the nucleus formulated for comets displaying a persisting sunward fanlike coma is successfully applied to two short-period comets, Pons-Winnecke (PW) and Schwassmann-Wachmann 3 (SW3), observed respectively in 1927 and 1930. For PW, the interpretation of fan-orientation pattern is compatible with the spin axis inertially fixed in May-June 1927, but for SW3 the interpretation requires rapid nucleus precession at a peak rate of about 1.4 deg/day. Both comets satisfy the basic conditions for displaying a fan in the time span covered by the fan observations. The emission sources are situated within 35 deg of the sunlit rotation pole of PW and within 19 deg of the pole of SW 3. A rotation period of 8.2 hr is suggested for PW if the rotation sense is prograde or 5.8 hr if it is retrograde. Water production rates and global loss and erosion rates for the comets are estimated.

Sekanina, Z.↗
NASA NTRS1989

5- to 13-micron airborne observations of Comet Wilson 1986l

Comet Wilson was observed from the Kuiper Airborne Observatory approximately 23.6 and 25.7 Apr. 1987, UT (approx. 3 to 5 days after perihelion) using the NASA-Ames Faint Object Grating Spectrometer. Spectrophotometric data were observed with a 21 inch aperture between 5 and 13 micrometer and with a spectral resolution of 50 to 100. Spectra of the inner coma and nucleus reveal a fairly smooth continuum with little evidence of silicate emission. The 5 to 8 micrometer color temperature of the comet was 300 + or - 15 K, approx. 15 percent higher than the equilibrium blackbody temperature. All three spectra of the nucleus show a new emission feature at approx. 12.25 micrometer approx. two channels (.22 micrometer) wide. Visual and photographic observations made during the time of these observations showed a broad faint, possible two component tail. No outburst activity was observed.

Lynch, D. K.↗
NASA NTRS1990

The CfA redshift survey - Data for the NGP + 30 zone

Redshifts and morphological types are presented for a complete sample of 1093 galaxies with m(pg) less than or equal to 15.5 mag in a 6-deg-wide strip crossing the north Galactic pole. Also presented are redshifts for an additional 92 fainter galaxies in the same strip. Outside of the core of the Coma Cluster, both early- and late-type galaxies trace essentially the same structures in redshift space. Thinner slices illustrate the small velocity dispersion perpendicular to the surfaces in the survey.

Huchra, John P.↗
NASA NTRS1990

Rotation of Comet P/Tempel 2 from CCD and photoelectric photometry

Two lightcurves have been obtained of the periodic comet Tempel 2 during May and June 1988, using a CCD camera, as well as five photoelastic photometer lightcurves. On each observational occasion, two uneven maxima were observed which suggest that the lightcurves in question are not products of an active spot on the comet, but rather are true reflections from an elongated rotating nucleus that are being observed through a transparent coma. A comparison of CCD and photoelectric photometry leads to an encouragement of users of the latter to sustain their efforts with such instruments.

Wisniewski, W. Z.↗
NASA NTRS1990

Comparison of water production rates from UV spectroscopy and visual magnitudes for some recent comets

IUE data on the UV and visible coma emissions of the comets Bradfield, P/Tempel 2, Wilson, and P/Halley, are presently compared with the visual lightcurves from magnitudes reported in the IAU circulars to consider the temporal evolution of these comets. While the water-production rates obtainable from visual magnitudes on the basis of Newburn's (1984) method are consistent with OH-derived rates to first order, they are sometimes either displaced or unable to exhibit the same pre/postperihelion asymmetry. The best agreement is obtained for the relatively dust-free Comet P/Tempel 2. IUE Fine Error Sensor lightcurves are generally in agreement with curves based on total visual magnitude.

Roettger, E. E.↗
NASA NTRS1990

Ground-based thermal IR images of Comet Tempel 2

The 10.8-micron images of Comet Tempel 2 obtained on the four days from September 21 to 24, 1988, indicate that the dust coma contributed about half of the nuclear pixel brightness. The nuclear condensation brightness exhibited a temporal variability slightly larger than observational uncertainty. The structure of the observed extended dust emission is interpretable as (1) a large grain tail primarily generated by cm-scaled particles, (2) the result of an outburst near 2.5-3.0 AU perihelion, and (3) a sunward emission of dust in a fanlike pattern.

Campins, Humberto↗
NASA NTRS1989

VUV-visible measurements on different samples of amorphous carbon

Among various candidate materials for interstellar dust, amorphous carbon (AC) is playing an increasingly important role (Greenstein, 1981; Hecht et al., 1984; Jura, 1983, 1986). Furthermore, recent in situ measurements have clearly shown the presence of carbonaceous grains in the coma of comet Halley (Kissel et al., 1986). Laboratory investigations on AC grains may be very useful to better interpret observations and to support theoretical elaborations. Recently, the authors started an international research program which also includes UV extinction analyses on AC samples, by using synchrotron light. Preliminary results obtained in a first shift of measurements, last June, are given. At the present stage of the data analysis, the authors can only draw some preliminary considerations. A wide band falling at around 240 nm is detected in all the analyzed samples. It intensity seems to decrease with increasing the dust collecting distance. A peak at 150 nm decreases in intensity with increasing the collecting distance. The band seems absent in the samples characterized by a larger amount of dust. A feature at about 200 nm is detected in some samples. At the moment the authors tend to attribute it to the transmission properties of the LiF substrates at the wavelength and/or to some problems in the experimental setup. It is unclear if a hump at 120 nm is real or due to instrumental effects. The profile of the spectra does not show substantial changes when the samples are cooled down to about 100 K. The present results appear to be in general agreement with previous findings, but their analysis is in progress and the interpretation is still on the way.

Blanco, A.↗
NASA NTRS1990

The H I content of non-isolated galaxies

It seems obvious that the evolution of star formation rate and hence of gas content in galaxies strongly depends on their environment. It reveals itself in particular in enhanced star formation or even in a strong burst of activity of massive stars often observed in interacting galaxies. Nevertheless it should be noted that the time scale for the gas to be exhausted in these galaxies is unknown even approximately. To clarify a role of surroundings in the evolution of disk galaxies we should compare the H I content of isolated and non-isolated galaxies otherwise similar by their properties. It is concluded that there are no systematic differences between H I content in isolated and non-isolated late-type galaxies; in spite of the differences of star formation rates their hydrogen mass is determined by slowly evolving kinematic parameters of the disk. Enhanced star formation in interacting galaxies, if it lasts long enough, must have an initial mass function enriched in massive stars in order not to significantly reduce the supply of gas. Certainly these conclusions are not valid for galaxies which are members of rich clusters such as Virgo or Coma, where H I-deficiency really exists, possibly due to the interaction of interstellar H I with hot intergalactic gas.

Zasov, Anatoli V.↗
NASA NTRS1990

Results from the comet Giacobini-Zinner and Halley campaigns

The spacecraft flybys of Comets Giacobini-Zinner and Halley were highly successful. Many untested theories were confirmed and additional clues provided to decide between competing models, but without leading to a clear preference. New questions were also raised. Based on the improved knowledge, research efforts will now be much better focused than was possible before the encounters. Moreover, interpretation of the Earth-based (ground-based, airborne, rocket-borne, and Earth satellite) observations should be improved. The goals of the workshop are defined in terms of the results from spacecraft measurements and Earth-based observations of Comets Giacobini-Zinner and Halley. A summary is presented of the new knowledge about the nucleus, the coma gas and dust, and the plasma. It is realized that extreme caution must be used when generalizing results from the Comet Giacobini-Zinner and Halley investigations to comets universally. The many surprises of the successful missions, the dangers inherent in generalizations to other comets, and the many still open and new questions are the reasons for the need of further spacecraft investigations. However, an unquestionably successful start was made in expanding the knowledge about the physics and chemistry of comets and all the related implications, and the question about the similarities of and differences between comets can now be explored further.

Huebner, Walter F.↗
NASA NTRS1990

Simultaneous imaging of optical CN lines and radio HCN lines in comet Austin

The parent molecule of cometary CN has been the subject of speculation for a long time. When HCN was detected at 3.4 mm in Comet Kohoutek, the problem seemed to be resolved, but much more detailed work on Comet Halley raised the quantitative question of whether HCN could be the only parent. Therefore, comparative CN/HCN studies are vital for understanding the origin of cometary CN. The striking observation of CN jets in Comet Halley raised another very interesting question about the origin of CN. Traditional theory permits only dust features to remain well defined far from the nucleus. The CN jets were interpreted as arising from submicron sized dust particles, perhaps CHON particles. An estimated 10 to 50 percent of the CN in the comet was in the jets in the Halley observations. Several hypotheses can be made: (1) some of the CN originates from the dust and has nothing to do with HCN; or, (2) at least some of the HCN is also produced from the dust in the coma rather than directly from the nucleus. (In the second hypothesis, whether CHN is or is not the parent of the CN associated with the dust would need to be established.) The extended scalelengths found for CO by Eberhardt et. al. (1987) and for H2CO by Snyder et. al. (1989) also support ideas like hypothesis (2). A third hypothesis should be mentioned; contrary to the usual theory, the gas flow does not become isotropic (Combi 1987). For all of the reasons mentioned, it is essential to make a detailed comparison of the spatial distributions of CN and HCN. Furthermore, because of the variability of cometary emissions, it is necessary to make measurements simultaneously.

Palmer, Patrick↗
NASA NTRS1991

Chiron: Evidence for historic cometary activity

The non-asteroidal brightening of (2060) Chiron, first noted by Tholen in 1988 is now ascribed to cometary activity. Photometry since 1988 has revealed a broad surge in brightness that peaked in 1989 about 1.0 mag above the brightness in the mid-1980s. The surge is evidently due to sporatic formation of dust coma, which is itself driven by the presence of extremely volatile ices at or near the surface. CN emission was recently reported. Since Chiron is now nearing perihelion, there is interest in determining whether it has exhibited anomalous brightening in the past, particularly at greater heliocentric distances. Photographic plates dating back to 1895 are known to contain images of Chiron. Using some of these archival material, the initial results are presented for a project to determine Chiron's brightness history over orbital timescales. A particularly homogeneous and high-quality set of plates taken prior to and around the time of Chiron's discovery in Oct. 1977 at the 1.2 m Oschin Schmidt telescope at Mt. Palomar Observatory were examined. Images of Chiron were identified and digitized using a PDS microdensitometer, and images of field stars around Chiron were both similarly digitized and photometrically calibrated using recently acquired B and V band CCD frames. As a result of the present work, eleven new data, including estimated errors, were added between 1969 and 1977. The implications that Chiron can be active at any heliocentric distance in its present orbit suggest that the active volatile is either N2, CH4, or CO, and that a substantial degree of mantling may have developed. Further historical data is presented, the error bars discussed, and possible mechanisms suggested for the observed activity.

Bus, Schelte J.↗