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At least 883 records · Page 49

Dielectronic recombination rates, ionization equilibrium, and radiative emission rates for Mn ions in low-density high-temperature plasmas

The analysis of optically-thin far-ultraviolet and X-ray emission lines of multiply-charged ions is one of the basic methods for determining the temperatures and densities of laboratory and astrophysical plasmas. In addition, the energy balance in these plasmas can be significantly influenced by the emission of radiation from relatively low concentrations of multiple-charged atomic ions. Because the populations of the excited levels are expected to depart substantially from their local thermodynamic equilibrium values a detailed treatment of the elementary collisional and radiative processes must be employed in order to predict the emission line intensities. In this investigation the authors present the results of calculations based on a corona equilibrium model in which a detailed evaluation is made of the dielectronic recombination rate coefficients. The ionization and autoionization following inner-shell electron excitation from each ground state are balanced by direct radiative and dielectronic recombination. The spectral line intensities emitted by the low-lying excited states, which are assumed to undergo spontaneous radiative decay in times that are short compared with the collision time, are evaluated in terms of the corona ionization equilibrium distributions of the ground states and their electron-impact excitation states.

Jacobs, V. L.↗

Multiorder etalon sounder (MOES) development and test for balloon experiment

The Fabry-Perot interferometer (FPI), with its high throughput and high spectral resolution has been used in the remote-sensing measurements of the earth's atmospheric composition, winds, and temperatures. The most recent satellite instruments include the Fabry-Perot interferometer flown on the Dynamics Explorer-2 (DE-2), the High Resolution Doppler Imager (HRDI), and the Cryogenic Limb Array Etalon Spectrometer (CLAES) flown on the Upper Atmosphere Research Satellite (UARS). These instruments measure the Doppler line profiles of the emission and absorption of certain atmospheric species (such as atomic oxygen) in the visible and infrared spectral region. The successful space flight of DE-FPI, HRDI, and CLAES on UARS demonstrated the extremely high spectral resolution and ruggedness of the etalon system for the remote sensing of earth and planetary atmospheres. Recently, an innovative FPI focal plane detection technique called the Circle-to-Line Interferometer Optical (CLIO) system was invented at the Space Physics Research Laboratory. The CLIO simplifies the FPI focal plane detection process by converting the circular rings or fringes into a linear pattern similar to that produced by a conventional spectrometer, while retaining the throughput advantage of the etalon interferometer. The combination of FPI and CLIO allows the development of more sensitive Fabry-Perot interferometers in the infrared for the remote sensing of the lower atmospheres of Earth and possibly other planets. The Multiorder Etalon Sounder (MOES), a combination of the rugged etalon and the CLIO, compares very favorably to other space-borne optical instruments in terms of performance versus complexity. The new instrument is expected to be rugged, compact, and very suitable for an operational temperature and moisture sounder. With this technique, the contamination of radiance measurements by emissions of other gases is also minimized. At the Space Physics Research Laboratory (SPRL), the MOES concept and laboratory experiments were worked on for the past several years. Both theoretical studies and laboratory prototype experiments showed that MOES is very competitive compared with other high resolution sounders in terms of complexity and performance and has great potential as a compact and rugged high resolution atmospheric temperature and trace species sounder from the polar platform or the geostationary platform. The logical next step is to convert our laboratory prototype to a balloon instrument, so that field test of MOES can be carried out to prove the feasibility and capability of this new technology. Some of the activities related to the development of MOES for a possible balloon flight demonstration are described. Those research activities include the imaging quality study on the CLIO, the design and construction of a MOES laboratory prototype, the test and calibration of the MOES prototype, and the design of the balloon flight gondola.

Hays, Paul B.↗

Space environmental effects on coated optics

Several multilayer coated mirror designs developed for potential space applications were tested on the Long Duration Exposure Facility (LDEF) along with single layer witness coatings deposited on fused silica and a coated CaF2 window. Performance requirements included high mirror reflectivity, low absorption, low scatter, environmental durability, and radiation hardness. The designs were selected in screening tests using combined electron, proton, and simulated solar UV radiation. The purpose of the space test was to validate the above test results and determine the effects of atomic oxygen and contamination on mirror performance.

Donovan, T. M.↗

A laboratory study on the dissociative recombination of vibrationally excited O2/+/ions

The dissociative recombination of vibrationally excited O2(+) ions is studied in light of the possible importance of this reaction in upper atmospheric chemistry. A plasma spectroscopy experiment was performed in a microwave cavity filled by an argon-oxygen mixture, with O(1S) production monitored by measurements of the 5577-A afterglow, the O2(+) density and the electron concentration. Plasma and optical data reveal the predominant afterglow ions to be Ar2(+) and O2(+), with an effective O(1S) dissociative recombination coefficient of 2.1 x 10 to the -8th cu cm/sec, corresponding to a quantum yield of 10%. Experiments with an argon-krypton-oxygen mixture reveal that vibrationally excited O2(+) ions are the chief source of the O(1S) atoms, with a specific recombination coefficient for the dissociation of O2(+)(2 pi g) into O(1S) and O(1D) of 4.2 x 10 to the -9th cu cm/sec. A comparison of the laboratory results with Atmospheric Explorer data on the 5577-A airglow implies that O2(+) ions in the sunlit ionosphere are vibrationally excited to the same degree as in the laboratory, with the vibrational relaxation of these ions much slower than dissociative recombination. Results also predict a dawn-twilight asymmetry in the effective O(1S) yield due to the normal variation of electron content.

Zipf, E. C.↗

Progress of the LASSO experiment

The LASSO (Later Synchronisation from Stationary Orbit) experiment, designed to demonstrate the feasibility of achieving time synchronization between remote atomic clocks with an accuracy of one nanosecond or better by using laser techniques for the first time is described. The experiment uses groundbased laser stations and the SIRIO-2 geostationary satellite to be launched towards the end of 1981. The qualification of the LASSO on-board equipment is discussed with a brief description of the electrical and optical test equipment used. The progress of the operational organization is included.

Serene, B. E. H.↗

Thermal control paints on LDEF: Results of M0003 sub-experiment 18

Several thermal control paints were flown on the Long Duration Exposure Facility (LDEF), including the white paints Chemglaze A276, S13GLO, and YB-71, and the black paint D-111. The effects of low earth orbit, which includes those induced by UV radiation and atomic oxygen, varied significantly with each paint and its location on LDEF. For example, samples of Chemglaze A276 located on the trailing edge of LDEF darkened significantly due to UV-induced degradation of the paint's binder, while leading edge samples remained white but exhibited severe atomic oxygen erosion of the binder. Although the response of S13GLO to low earth orbit is much more complicated, it also exhibited greater darkening on trailing edge samples as compared to leading edge samples. In contrast, YB-71 and D-111 remained relatively stable and showed minimal degradation. The performance of these paints as determined by changes in their optical and physical properties, including solar absorptance as well as surface chemical changes and changes in surface morphology is examined. It will also provide a correlation of these optical and physical property changes to the physical phenomena that occurred in these materials during the LDEF mission.

Jaggers, C. H.↗

Spectroscopy-Based Characterization of Single Wall Carbon Nanotubes

We present the initial results of our combined investigation of Raman scattering and optical absorption spectroscopy in a batch of single wall carbon nanotubes (SWNTs). The SWNT diameters are first estimated from the four radial breathing mode (RBM) peaks using a simple relation of omega(sub RBM) = 248/cm nm/d(sub t)(nm). The calculated diameter values are related to the optical absorption peaks through the expressions of first interband transition energies, i.e., E(sup S)(sub 11) = 2a gamma/d(sub t) for semiconducting and E(sup S)(sub 11) = 6a gamma/d(sub t) for metallic SWNTs, respectively, where a is the carbon-carbon bond length (0.144 nm) and gamma is the energy of overlapping electrons from nearest neighbor atoms, which is 2.9 eV for a SWNT. This analysis indicates that three RBM peaks are from semiconducting tubes, and the remaining one is from metallic tubes. The detailed analysis in the present study is focused on these three peaks of the first absorption band by determining the values of the representative (n,m) pairs. The first step of analysis is to construct a list of possible (n,m) pairs from the diameters calculated from the positions of the RBM peaks. The second step is to compute the first interband transition energy, E(sub 11), by substituting the constructed list of (n,m) into the expression of Reich and Thomsen, and Saito et al. Finally, the pairs with the energies closest to the experimental values are selected.

Namkung, Min↗

Optical Magnetometer Incorporating Photonic Crystals

According to a proposal, photonic crystals would be used to greatly increase the sensitivities of optical magnetometers that are already regarded as ultrasensitive. The proposal applies, more specifically, to a state-of-the-art type of quantum coherent magnetometer that exploits the electromagnetically-induced-transparency (EIT) method for determining a small change in a magnetic field indirectly via measurement of the shift, induced by that change, in the hyperfine levels of resonant atoms exposed to the field.

Kulikov, Igor↗

The extreme ultraviolet /750-1230 A/ spectrum of an aurora

Extreme ultraviolet auroral spectra have been obtained in the wavelength range of 750-1230 A resolution with a rocket-borne grating spectrometer. Atomic emissions of N I, N II, O I and O II are the dominant features along with geocoronal H I Lyman alpha. N2 emission bands, which appear strongly in laboratory electron impact spectra, appear only as a modest background continuum between 900 to 1100 A. The observed intensities are consistent with electron impact excitation of O and N2. For optically thick emissions, such as N I at 1200 A, radiation transport along the arc results in an intensity enhancement when viewed through the arc towards the zenith.

Park, H.↗

Two new advanced forms of spectrometry for space and commercial applications

Reagentless ultraviolet absorption spectrometry (UVAS) and Liquid Atomic Emission Spectrometry (LAES) represent new forms of spectrometry with extensive potential in both space and commercial applications. Originally developed under KSC sponsorship for monitoring nutrient solutions for the Controlled Ecological Life Support System (CELSS), both UVAS and LAES have extensive analytical capabilities for both organic and inorganic chemical compounds. Both forms of instrumentation involve the use of remote fiber optic probes and real-time measurements for on-line process monitoring. Commercial applications exist primarily in environmental analysis and for process control in the chemical, pulp and paper, food processing, metal plating, and water/wastewater treatment industries.

Schlager, Kenneth J.↗

Remote sounding of tropospheric minor constituents

The etalon interferometer, or Fabry-Perot interferometer (FPI), with its high throughput and high spectral resolution was widely used in the remote-sensing measurements of the earth's atmospheric composition, winds, and temperatures. The most recent satellite instruments include the Fabry-Perot interferometer flown on the Dynamics Explorer-2 (DE-2) and the High Resolution Doppler Imager (HRDI) to be flown on the Upper Atmosphere Research Satellite (UARS). These instruments measure the Doppler line profiles of the emission and absorption of certain atmospheric species (such as atomic oxygen) in the visible spectral region. The successful space flight of DE-FPI and the test and delivery of UARS-HRDI demonstrated the extremely high spectral resolution and ruggedness of the etalon system for the remote sensing of earth and planetary atmospheres. Recently, an innovative FPI focal plane detection technique called the Circle-to-Line Interferometer Optical (CLIO) system was invented at the Space Physics Research Laboratory (SPRL). The CLIO simplifies the FPI focal plane detection process by converting the circular rings or fringes into a linear pattern similar to that produced by a conventional spectrometer, while retaining the throughput advantage of the etalon interferometer. CLIO makes the use of linear array detectors more practical and efficient with FPI, the combination of FPI and CLIO represents a very promising new technique for the remote sensing of the lower atmospheres of Earth, Mars, Venus, Neptune, and other planets. The Multiorder Etalon Spectrometer (MOES), as a combination of the rugged etalon and the CLIO, compares very favorably to other spaceborne optical instruments in terms of performance versus complexity. The feasibility of an advanced etalon spectrometer for the remote sensing of tropospheric trace species, particularly carbon monoxide (CO), nitrous oxide (N2O), and methane (CH4) was discussed. The etalon atmospheric spectroscopy techniques are described, instrument design and related technical issues are discussed. The primary objective is to establish the concept of atmospheric spectroscopy with the CLIO and etalon system and its applications for the measurements of tropospheric trace species analyze system requirements and performance, determine the feasibility of components and subsystem implementation with available technology, and develop inversion algorithm for retrieval simulation and data analysis.

Drayson, S. Roland↗

Abundances, planetary nebulae, and stellar evolution

Among Henry Norris Russell's many achievements were his contributions to solar and stellar spectroscopy, in particular, to an analysis of the chemical composition of the solar atmosphere. The question of composition differences between stars was hotly debated; some distinguished astronomers argued that all stars had the solar composition. Some early challenges to this doctrine are described. Determinations of chemical compositions of gaseous nebulae were much more difficult. If we observe the lines of a given chemical element in one ionization stage in a stellar spectrum, we can deduce readily the abundance of that element. No such luxury is available for a planetary or diffuse gaseous nebula. We must measure lines of as many ionization stages as we can. Furthermore, a nebula is an extended object. Often detailed spectroscopy is at hand only for narrow pencil columns taken through the image. Different observers use a variety of apertures. Fortunately it is possible to calculate theoretical spectra for any arbitrary cross section taken through a symmetrical model, so UV, optical, and IR observations all can be compared properly with a prediction. The value of high-resolution spectra obtained with instruments such as the Hamilton Echelle Spectrograph at Lick Observatory is emphasized. Improved fluxes for weak but important transitions are found. Close blends of lines of different ions can be resolved, and checks can be made on predictions of atomic parameters such as Einstein A-values and collision strengths. High spectral resolution data have been obtained and reduced for 22 planetary nebulae of varying size, structure, stellar population membership, dustiness, level of excitation, evolutionary status, and chemical compositions. The promise seems justified that with such extensive, high quality data, additional insights on nebular genesis and late states of stellar evolution can be found. The present survey is confined to nebulae of high surface brightness, but among these are found some engaging objects such as NGC 7027, IC 4997, and NGC 6572.

Aller, Lawrence H.↗

Degradation of FEP thermal control materials returned from the Hubble Space Telescope

After an initial 3.6 years of space flight, the Hubble Space Telescope was serviced through a joint effort with the NASA and the European Space Agency. Multi-layer insulation (MLI) was retrieved from the electronics boxes of the two magnetic sensing systems (MSS), also called the magnetometers, and from the returned solar array (SA-I) drive arm assembly. The top layer of each MLI assembly is fluorinated ethylene propylene (FEP, a type of Teflon). Dramatic changes in material properties were observed when comparing areas of high solar fluence to areas of low solar fluence. Cross sectional analysis shows atomic oxygen (AO) erosion values up to 25.4 mu m (1 mil). Greater occurrences of through-thickness cracking and surface microcracking were observed in areas of high solar exposure. Atomic force microscopy (AFM) showed increases in surface microhardness measurements with increasing solar exposure. Decreases in FEP tensile strength and elongation were measured when compared to non-flight material. Erosion yield and tensile results are compared with FEP data from the Long Duration Exposure Facility. AO erosion yield data, solar fluence values, contamination, micrometeoroid or debris impact sites, and optical properties are presented.

Zuby, Thomas M.↗

A High Energy 2-microns Laser for Multiple Lidar Applications

Solid-state 2-microns laser has been receiving considerable interest because of its eye-safe property and efficient diode pump operation, It has potential for multiple lidar applications to detect water vapor. carbon dioxide and winds. In this paper, we describe a 2-microns double pulsed Ho:Tm:YLF laser and end-pumped amplifier system. A comprehensive theoretical model has been developed to aid the design and optimization of the laser performance. In a single Q-switched pulse operation the residual energy stored in the Tm atoms will be wasted. However, in a double pulses operation mode, the residual energy stored in the Tm atoms will repopulate the Ho atoms that were depleted by the extraction of the first Q-switched pulse. Thus. the Tin sensitized Ho:YLF laser provides a unique advantage in applications that require double pulse operation, such as Differential Absorption Lidar (DIAL). A total output energy of 146 mJ per pulse pair under Q-switch operation is achieved with as high as 4.8% optical to optical efficiency. Compared to a single pulse laser, 70% higher laser efficiency is realized. To obtain high energy while maintaining the high beam quality, a master-oscillator-power-amplifier 2-microns system is designed. We developed an end-pumped Ho:Tm:YLF disk amplifier. This amplifier uses two diode arrays as pump source. A non-imaging lens duct is used to couple the radiation from the laser diode arrays to the laser disk. Preliminary result shows that the efficiency of this laser can be as high as 3%, a factor of three increases over side-pump configuration. This high energy, highly efficient and high beam quality laser is a promising candidate for use in an efficient, multiple lidar applications.

Yu, Jirong↗

Nonvolatile Rad-Hard Holographic Memory

We are investigating a nonvolatile radiation-hardened (rad-hard) holographic memory technology. Recently, a compact holographic data storage (CHDS) breadboard utilizing an innovative electro-optic scanner has been built and demonstrated for high-speed holographic data storage and retrieval. The successful integration of this holographic memory breadboard has paved the way for follow-on radiation resistance test of the photorefractive (PR) crystal, Fe:LiNbO3. We have also started the investigation of using two-photon PR crystals that are doubly doped with atoms of iron group (Ti, Cr, Mn, Cu) and of rare-earth group (Nd, Tb) for nonvolatile holographic recordings.

Chao, Tien-Hsin↗

Slow Light in Coupled Resonator Optical Waveguides

Recently, we discovered that a splitting of the whispering gallery modes (WGMs) occurs in coupled resonator optical waveguides (CROWs), and that these split modes are of a higher Q than the single-resonator modes, leading to enormous circulating intensity magnification factors that dramatically reduce thresholds for nonlinear optical (NLO) processes. As a result of the enhancements in Q, pulses propagating at a split resonance can propagate much slower (faster) for over (under)-coupled structures, due to the modified dispersion near the split resonance. Moreover, when loss is considered, the mode-splitting may be thought of as analogous to the Autler-Townes splitting that occurs in atomic three-level lambda systems, i.e., it gives rise to induced transparency as a result of destructive interference. In under- or over-coupled CROWs, this coupled resonator induced transparency (CRIT) allows slow light to be achieved at the single-ring resonance with no absorption, while maintaining intensities such that NLO effects are maximized. The intensity magnification of the circulating fields and phase transfer characteristics are examined in detail.

Chang, Hongrok↗

Lunar-surface UV Photometric Investigation of Exospheres (LUPINE): Thermal Modeling of Payload in a Relevant Daylit Environment

Direct upward remote sensing of the moon’s exosphere from a surface vantage can address production of water-related lunar volatiles as well as their exospheric loss, ballistic transport, and ultimate adsorption in permanently shadowed regions (PSRs). Far UV (FUV) dayside measurements of atomic oxygen, liberated from regolith by energetic solar protons and micrometeorite impact, can provide critical insight into the endogenic lunar water cycle by constraining total column density [O] at site of production. A notional Lunar-surface UV Photometric Investigation of Exospheres (LUPINE) instrument is designed to exploit solar-pumped atomic oxygen fluorescence at 130.4-nm, in a manner similar to the Apollo 17 UV Spectrometer (UVS) experiment [Fastie 1973; Feldman and Morrison, 1991] and the LRO Lyman-alpha Mapping Project (LAMP) spectrograph [Cook et al., 2013], by implementing a zenith-directed FUV photometer from the lunar surface at low (± 10°) selenographic latitude during the lunar day. Atomic oxygen production from solar energetic particle impact sources is thought to maximize in near solar noon [Sarantos et al., 2012], and the lander-embedded zenith-directed LUPINE photometer, in contrast to UVS and LAMP twilight measurements from orbit, can potentially capture the full column abundance of lunar regolith liberated oxygen. Herein we describe adaptation of FUV reflective optics, pulse-counting electronics, and scattered-light-suppression technologies developed for LEO FUV photometry for the challenging thermal environment of the daylit lunar surface. Preliminary thermal modeling and TVAC measurements of heritage FUV photometer components suggests that, if allowed to shed ~8W of waste heat into the bus of a reference Commercial Lunar Payload Services (CLPS) lander, the LUPINE photometer will be kept sufficiently cool to limit dark current to less than 20 counts/s. This level of dark signal enables an OI 130.4-nm 3-sigma detection threshold of ~1 mR for assumed 2-hour integrations.

Lunar UV Photometer↗

Spectroscopic Determination of the Physical Conditions in Hot, Optically Thin Sources

This annual report covers the period from Oct 1, 2000 to Sep 30, 2001. The Astrophysics Plasma Emission Code and Database (APEC/APED), developed in part under this grant, have been upgraded to Version 1.1 and are now beginning to be used outside our research group in applications to X-ray spectral data from Chandra and XMM-Newton. These models represent the best theoretical data currently available and are reasonably complete below about 30 angstroms. Stellar coronae are being used to benchmark the atomic data in APED as part of the Emission Line Project. Initial results suggest that the models for most of the strongest lines are in good agreement with the observations, including the H-like and He-like emission from dominant elements and the Fe L shell emission, both near 1 keV and in the extreme ultraviolet near 100 eV. At this point in time, we define 'good agreement' at the level of accuracy expected from the atomic physics, approximately 20-30%. In order to benchmark the spectral models beyond the canonical theoretical accuracy, we are working closely with the Chandra gratings calibration group to ensure that we are using the optimal calibration, primarily effective areas and line response functions.

Brickhouse, N.↗