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At least 883 records · Page 49

Numerical modeling of Joule heated ceramic melter

Computational fluid dynamics and heat transfer models of waste glass melters are being developed to support the vitrification campaign at the Waste Treatment and Immobilization Plant (WTP) as part of the United States nuclear waste stewardship and environmental protection programs. The WTP mission aims to achieve the stable and durable processing of vitrified waste in the safest, most efficient, and economical manner possible. Hanford’s tank waste is far more complex and varied than the waste treated by other vitrification facilities and both startup and long-term operational challenges are likely to be even greater than prior experience has shown. There are thousands of different waste compositions, which makes processing the waste a complex and challenging task. Models of test melters, pilot-scale, and full-scale melters have been developed to provide understanding and insight into the various physical and chemical phenomena occurring during vitrification. So the results of these modeling activities will be used to support the WTP operations to process legacy nuclear waste into a stable form for disposal.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Task 12 PV Sustainability - Human Health Risk Assessment Methods for PV, Part 3: Module Disposal Risks

End-of-life management is important for addressing large future photovoltaic (PV) waste volumes and conserving raw materials for use in new PV modules. In regions without regulatory mandates for PV recycling, end-of-life PV modules can be disposed in accordance with general waste laws. Given the use of various metals as raw materials in semiconductor compounds and electrical contacts in commercial PV modules, some stakeholders have raised concerns regarding potential environmental impacts if PV modules are subject to improper disposal instead of being recycled or disposed in sanitary landfills, as is required in most world regions. To evaluate these concerns, screening-level risk assessment methods are developed herein that evaluate potential human health risks from groundwater and surface (air, soil, surface water) exposure pathways. The methods estimate potential impacts from disposal of end-of-life (EOL) PV modules in non-sanitary landfills under the following worst-case conditions: no leachate collection or groundwater monitoring, no liner for preventing leachate migration, uncovered waste, and lack of stormwater management. Examining worst-case conditions allows the exploration of maximum potential risk to attempt to ensure disposal does not increase health risk above regulatory thresholds. Specifically, this report presents an analysis of potential human health risks associated with non-sanitary landfill disposal for three PV technologies, focusing on release of the highest-prioritized chemical element for each: lead (Pb) in crystalline-silicon (c-Si) PV modules, cadmium (Cd) in thin film cadmium telluride (CdTe) PV modules, and selenium (Se) in thin film copper indium selenide (CIS) PV modules. The prioritization of these chemical elements for analysis is based on stakeholder interest. Because the methodology is chemical-specific, the risk assessment results for these chemicals cannot be directly generalized to other chemicals, although the risk assessment methodology can be applied to other chemicals. If the chemicals chosen are indeed the ones presenting greatest risk, then the results herein should represent the upper bound of health risk from exposure to a single constituent.

14 SOLAR ENERGY↗

AmeriFlux FLUXNET-1F US-ADR Amargosa Desert Research Site (ADRS)

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-ADR Amargosa Desert Research Site (ADRS). This is the FLUXNET version of the carbon flux data for the site US-ADR Amargosa Desert Research Site (ADRS) produced by applying the standard ONEFlux (1F) software. Site Description - This tower is located at the Amargosa Desert Research Site (ADRS). The U.S. Geological Survey (USGS) began studies of unsaturated zone hydrology at ADRS in 1976. Over the years, USGS investigations at ADRS have provided long-term "benchmark" information about the hydraulic characteristics and soil-water movement for both natural-site conditions and simulated waste-site conditions in an arid environment. The ADRS is located in a creosote-bush community adjacent to disposal trenches for low-level radioactive waste.

Moreo, Michael [U.S. Geological Survey]↗

Potential Disposition Options for a Salt Fueled Molten Salt Reactor At the INL (A White Paper)

The molten salt reactor (MSR) design concept has been the focus of significant research and development efforts, both in the U.S. and around the world. There are generally two types of MSRs, salt fueled MSRs that have the fuel dissolved within the salt and solid fueled MSRs that only use the molten salt as a coolant. The range of conceptual designs and the flexibility of operations of MSRs results in a wide range of potential waste streams from salt fueled MSRs; all of which require safe and secure storage and eventual disposition. This white paper will 1) survey the range of salt fueled MSR designs, 2) recognize the implications of design, on the resulting waste streams, and 3) identify the definitions and regulations that apply to the safe and secure management, storage, and disposal of these streams. Research in MSR waste streams is young and the focus of intense research that requires more funding and time to become mature enough to fully support design decisions. Once a specific design is selected, a more detailed management and disposition effort must be performed.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

An Assessment of Applying Pyroprocessing Technology to Advanced Pebble-Type Fuels

With an expected increased demand for high-assay low enriched uranium (HALEU) to supply advanced reactors, the possibility of recovering actinides from various used nuclear fuels (UNF) is being reassessed. Pebble-type fuels such as tristructural isotropic (TRISO) fuel are intended to be directly disposed after use, but the HALEU remaining in each pebble is a resource with increasing value. An economically feasible recovery strategy would maximize the amount of HALEU recovered for reuse in new fuel without increasing the waste volume relative to the direct disposal of used TRISO fuel. We are evaluating the technical feasibility of recycling TRISO or pebble fuels to recover actinides for reuse as new fuel for advanced reactors by using pyrochemical methods.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

An Assessment of Applying Pyroprocessing Technology to Advanced Pebble-Type Fuels

With an expected increased demand for high-assay low enriched uranium (HALEU) to supply advanced reactors, the possibility of recovering actinides from various used nuclear fuels (UNF) is being re-assessed. Pebble-type fuels such as tristructural isotropic (TRISO) fuel are intended to be directly disposed after use, but the HALEU remaining in each pebble is a resource with increasing value. An economically feasible recovery strategy would maximize the amount of HALEU recovered for reuse in new fuel without increasing the waste volume relative to the direct disposal of used TRISO fuel. We are evaluating the technical feasibility of recycling TRISO or pebble fuels to recover actinides for reuse as new fuel for advanced reactors by using pyrochemical methods.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Consolidated Interim Storage Advantages and Disadvantages from Prior Reports and Studies

The question of whether centralized storage of civilian spent nuclear fuel (SNF) should be part of the federal waste management system as an intermediate step before permanent disposal has been debated for more than four decades. Since the Nuclear Waste Policy Act (NWPA) (U.S. House of Representatives 1982) was enacted, the need for interim storage facilities (ISFs) as part of the federal waste management system has been analyzed and documented in numerous reports and studies. This paper summarizes the advantages and disadvantages as described in those reports of incorporating an ISF into the waste management system.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Consolidated Interim Storage Advantages and Disadvantages from Prior Reports and Studies

The question of whether centralized storage of civilian spent nuclear fuel (SNF) should be part of the federal waste management system as an intermediate step before permanent disposal has been debated for more than four decades. Since the Nuclear Waste Policy Act (NWPA) [1] was enacted, the need for interim storage facilities (ISFs) as part of the federal waste management system has been analyzed and documented in numerous reports and studies. This presentation summarizes the advantages and disadvantages, as described in those reports, of incorporating an ISF into the waste management system.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Process Model Development and Experimental Investigation for Spent Fuel Disposal in Crystalline Rocks: FY20 Report.

The U.S. Department of Energy Office of Spent Fuel Waste Disposition (SFWD) established in fiscal year 2010 (FY10) the Spent Fuel Waste Science & Technology (SFWST) Program (formerly the Used Fuel Disposition Campaign - UFDC) program to conduct the research and development (R&D) activities related to storage, transportation and disposal of used nuclear fuel and high level nuclear waste. The Mission of the SFWST is: To identify alternatives and conduct scientific research and technology development to enable storage, transportation and disposal of used nuclear fuel and wastes generated by existing and future nuclear fuel cycles. Significant progress has been made in FY20 in both experimental and modeling arenas in evaluation of used fuel disposal in crystalline rocks, especially in model demonstration using field data. The work covers a wide range of research topics identified in the R&D plan.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Wind turbine blade material in the United States: Quantities, costs, and end-of-life options

Wind energy has experienced enormous growth in the past few decades; as a result, there are thousands of wind turbines around the world that will reach the end of their design lifetimes in the coming years. Much of the material in those turbines can be recycled using conventional processes, but the composite material that is the main component of the blades is more challenging to recycle. In the United States, turbine blades may be disposed of in landfills, adding a new solid waste stream to the material already being landfilled. This paper presents a spatially resolved estimate of the mass and volume of wind turbine blade waste in each state by 2050 and compares these amounts to estimates of the remaining landfill capacity by state. In this work, we estimate costs for each stage of the disposal process to indicate cost levels for alternatives. Assuming a 20-year turbine lifetime, the cumulative blade waste in 2050 is approximately 2.2 million tons. This value represents approximately 1% of remaining landfill capacity by volume, or 0.2% by mass. We also find that the current cost of disposing of blades in large segments or through grinding is relatively low in comparison to the overall life-cycle cost of energy. Based on these findings, landfill space constraints and disposal costs appear unlikely to motivate a change in waste handling strategies under current policy conditions. Instead, more profound shifts in recycling technologies, blade materials, or policy may be needed to move towards a circular economy for wind turbine blades.

17 WIND ENERGY↗

Whose Gas is it anyway? Differentiating the Source of a Large Soil Vapor Plume beneath Two Adjacent Waste Sites - 20487

DOE contractor CH2M Hill Plateau Remediation Company is currently responsible for conducting groundwater contamination monitoring at several RCRA treatment, storage, and disposal units located on the Hanford Site in Richland, Washington State. The Nonradioactive Dangerous Waste Landfill treatment, storage, and disposal unit presents a distinct groundwater monitoring problem because of a large multi-contaminant soil vapor plume beneath it that is a likely source of low-level volatile organic compound groundwater contamination. Adjacent to Nonradioactive Dangerous Waste Landfill is the Solid Waste Landfill. Volatile organic compounds are inventory components of both the Nonradioactive Dangerous Waste Landfill and the Solid Waste Landfill. Therefore, it is possible that both sites could be contributing to the soil vapor plume. For regulatory purposes, it is important to differentiate which site is the primary contributor of volatile organic compounds to the plume. An approach was developed to identify the primary volatile organic compound source of the soil vapor plume beneath Nonradioactive Dangerous Waste Landfill and Solid Waste Landfill. The site conceptual model hypothesis of vapor-phase volatile organic compound transport to the dissolved phase in groundwater was tested by a simple mathematical model of vapor/liquid equilibrium concentrations at the groundwater/air interface. Once it was shown that vapor-phase volatile organic compound transport to groundwater was a valid conceptual model for Nonradioactive Dangerous Waste Landfill and Solid Waste Landfill, spatial and statistical methods were used to determine the primary site contributing to the majority of volatile organic compounds to the soil vapor plume. Average groundwater chloroform, tetrachloroethene, and trichloroethene concentrations from Nonradioactive Dangerous Waste Landfill and Solid Waste Landfill monitoring network wells were plotted on maps of the facilities and immediate vicinities and compared to soil vapor sampling probe locations. Principal component analysis and mixing ratios were used to identify source contributions of each treatment, storage, and disposal unit to the plume. Results of the vapor/liquid equilibrium concentrations mathematical model showed that transport phenomena outweigh steady-state equilibria. Estimated vapor/liquid equilibrium concentrations were considerably lower than soil vapor measurements. The results indicate that dynamic vadose zone and groundwater factors such as decreased vapor concentrations with depth, vapor dilution from dispersion in the vadose zone, and advective and diffusional volatile organic compound dilution in groundwater result in groundwater volatile organic compound concentrations much less than would be measured under steady-state equilibrium conditions. Site source contribution differentiation by principal component analysis and mixing ratios was inconclusive using actual soil gas data because of the similarity in concentration values in both datasets for Nonradioactive Dangerous Waste Landfill and Solid Waste Landfill. Similar data populations suggest mixing of the vapor contributions from both sites by dispersion through the soil matrix pore spaces. However, when groundwater volatile organic compound data were compared between the Nonradioactive Dangerous Waste Landfill and Solid Waste Landfill monitoring networks, Solid Waste Landfill mean concentrations were higher, suggesting more vapor-phase volatile organic compound transport to groundwater at those locations. Simulated volatile organic compound soil vapor and groundwater datasets created to test the methods developed for this study show that the method can be successful in source differentiation when significantly different datasets are compared. This paper will describe a method of testing a conceptual model for vapor-phase contaminant transport to groundwater and for differentiating site sources of contaminants comprising a mixed-constituent soil vapor plume. (authors)

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Postclosure Criticality Analysis Results

The United States Department of Energy’s (DOE) Office of Nuclear Energy’s Spent Fuel and Waste Science and Technology Campaign seeks to better understand the technical basis, risks, and uncertainty associated with the safe and secure disposition of spent nuclear fuel (SNF) and high-level radioactive waste. Commercial nuclear power generation in the United States has resulted in thousands of metric tons of SNF, the disposal of which is the responsibility of DOE (Nuclear Waste Policy Act of 1982, as amended). Any repository licensed to dispose of SNF must meet requirements regarding the long-term performance of that repository. The evaluation of long-term performance of the repository may need to consider the SNF achieving a critical configuration during the postclosure period. Of particular interest is the potential for this situation to occur in dual-purpose canisters (DPCs), which are currently licensed and being used to store and transport SNF but were not designed for permanent geologic disposal. DOE has been considering disposing of SNF in DPCs to avoid the costs and worker dose associated with repackaging the SNF currently stored in DPCs into repository-specific canisters. This report examines the consequences of postclosure criticality to provide technical support to DOE in developing a disposal plan.

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Verification and Validation of the Stakeholder Tool for Assessing Radioactive Transportation (START) – 22323

The U.S. Department of Energy (DOE) Office of Integrated Waste Management is planning for the eventual transportation, storage, and disposal of spent nuclear fuel (SNF) and high-level radioactive waste (HLW) from nuclear power plant and DOE sites. The Stakeholder Tool for Assessing Radioactive Transportation (START) is a web-based, geospatial decision-support tool developed for evaluating routing options and other aspects of transporting SNF and HLW, covering rail, truck, barge, and intermodal infrastructure and operations in the continental United States. The verification and validation (V&V) process is intended to independently assess START to provide confidence in the ability of START to accurately provide intended results. The V&V process checks the START tool using a variety of methods, ranging from independent hand calculations to comparison of START performance and results to those of other codes. The V&V activity was conducted independently from the START development team with opportunities to provide feedback and collaborate throughout the process. The V&V analyzed attributes of transportation routes produced by START, including route distance and both population and population density captured within buffer zones around routes. Population in the buffer zone, population density in the buffer zone, and route distance were all identified as crucial outputs of the START code and were subject to V&V tasks. Some of the improvements identified through the V&V process were standardizing the underlying population data in START, changing the projection of the population raster data, and changes to the methodology used for population density to improve its applicability for expected users. This collaboration also led to suggested improvements to some of the underlying shape file segments within START. A formal series of test routes went through the V&V process from START version 3.2.1 following the implementation of the recommended improvements to START. The V&V of the buffer zone population and distance reported in START were achieved by utilizing a custom workflow developed in QGIS. This platform was chosen because it is fully independent of START. The buffer zone population and route distances in START showed excellent agreement to independent V&V test results. Over 200 route test cases were run; in all cases, the percent difference in the population within the buffer zone was less than +/- 5%, and the majority of cases were below +/- 1%. These cases were also duplicated in ArcMap, which is Environmental Systems Research Institute’s (ESRI) GIS desktop application. The ArcMap results also show good agreement; however, they cannot be considered independent of START because START also uses ESRI software. The V&V tasks are currently addressing population density and estimated radiation dose in START as well as implementing further automation of the V&V process to allow larger suites of test routes to be run more easily and quickly by less experienced GIS users. These improvements to the V&V process will make it a valuable tool for the development team and the stakeholders so that each new iteration of START can easily be checked for quality and consistency. This paper and presentation will describe the V&V process, findings and implications, and ongoing V&V activities.

START, DOE, Transporation, dose, GIS↗

Municipal Solid Waste Incineration Ash-Incorporated Concrete: One Step towards Environmental Justice

Municipal solid waste and cement manufacture are two sources of environmental justice issues in urban and suburban areas. Waste utilization is an attractive alternative to disposal for eliminating environmental injustice, reducing potential hazards, and improving urban sustainability. The re-use and recycling of municipal solid waste incineration (MSWI) ash in the construction industry has drawn significant attention. Incorporating MSWI ash in cement and concrete production is a potential path that mitigates the environmental justice issues in waste management and the construction industry. This paper presents a critical overview of the pretreatment methods that optimize MSWI ash utilization in cement/concrete and the influences of MSWI ash on the performance of cement/concrete. This review aims to elucidate the potential advantages and limitations associated with the use of MSWI ash for producing cement clinker, alternative binder (e.g., alkali-activated material), cement substitutes, and aggregates. A brief overview of the generation and characteristics of MSWI ash is reported, accompanied by identifying opportunities for the use of MSWI ash-incorporated products in industrial-scale applications and recognizing associated environmental justice implications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗