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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 883 records · Page 49
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Comparison of breakdown-voltage of contemporary and veteran photovoltaic backsheets

The ability of designated electrically insulating materials in a module, including the backsheet, to act as insulators is a key safety requirement for photovoltaic technology. The recently developed test standards IEC TS 62788-2 (including a method for direct-current breakdown-voltage) and IEC TS 62788-7-2 (for ultraviolet [UV] weathering) are examined for the first time together in this study. Thirty-six contemporary backsheets were compared using the breakdown-voltage test, before and after UV weathering, according to the recent A3 test condition. Twenty-eight backsheets, extracted from a variety of veteran photovoltaic modules, were also examined using the breakdown test. Additional characterizations were performed to interpret the breakdown-voltage results, including: surface and cross-sectional optical microscopy failure analysis; cross-sectional scanning electron (SEM) microscopy with EDS energy-dispersive X-ray spectroscopy (EDX) failure analysis; Fourier-transform infrared spectroscopy (FTIR) to identify the base resin and its chemical integrity; and differential scanning calorimetry (DSC) to identify phase transitions that might adversely affect degradation during weathering. The electrical insulation for the backsheets is discussed relative to: the industry safety requirement; features observed to facilitate the degradation of insulation; the validity of the artificial UV weathering test; the validity of the sheet geometry used for specimens in this study; and the validity of subsequent mechanical testing.

14 SOLAR ENERGY↗
DOE OSTI2019

Voltage Control of a van der Waals Spin-Filter Magnetic Tunnel Junction

Atomically thin chromium triiodide (CrI 3 ) has recently been identified as a layered antiferromagnetic insulator, in which adjacent ferromagnetic monolayers are antiferromagnetically coupled. This unusual magnetic structure naturally comprises a series of antialigned spin filters, which can be utilized to make spin-filter magnetic tunnel junctions with very large tunneling magnetoresistance (TMR). Here we report voltage control of TMR formed by four-layer CrI 3 sandwiched by monolayer graphene contacts in a dual-gated structure. By varying the gate voltages at fixed magnetic field, the device can be switched reversibly between bistable magnetic states with the same net magnetization but drastically different resistance (by a factor of 10 or more). Also, without switching the state, the TMR can be continuously modulated between 17,000% and 57,000%, due to the combination of spin-dependent tunnel barrier with changing carrier distributions in the graphene contacts. Our work shows new kinds of magnetically moderated transistor action and opens up possibilities for voltage-controlled van der Waals spintronic devices.

2D magnets↗
DOE OSTI2021

Long-Term Cycling of a Mn-Rich High-Voltage Spinel Cathode by Stabilizing the Surface with a Small Dose of Iron

The high-voltage, cobalt-free spinel cathode LiNi 0.5 Mn 1.5 O 4 (LNMO) is receiving extensive attention for lithium-ion batteries due to its low cost, high operating voltage and energy density, superior power density, and good thermal stability. However, its high operating voltage hampers its stability with commercial electrolytes and makes its practical viability challenging. We present here a Mn-rich LNMO cathode to encourage the disordering of Mn and Ni in the lattice and the incorporation of a small dose of Fe into Mn-rich LNMO (Fe-LNMO) to improve the cycling stability. The introduction of Fe further increases the cation disorder between Mn and Ni, thus enabling a better rate capability. Electron energy loss spectroscopy analysis indicates that Fe is concentrated on the surface, and X-ray photoelectron spectroscopy analysis shows that Fe-LNMO alleviates the aggressive reaction between the cathode surface and the electrolyte, thus stabilizing the interface and cycle life. Furthermore, a full cell assembled with a graphite anode with an areal capacity of 3 mA h cm –2 displays a capacity retention of 90% over 300 cycles. Furthermore, the present work demonstrates an effective way to promote cation disordering and lower the surface reactivity of LNMO with the electrolyte, thereby enhancing the conductivity, stabilizing the cathode–electrolyte interphase, and making LNMO promising for practical applications.

25 ENERGY STORAGE↗
DOE OSTI2024

Nonsolvating Fluoroaromatic Cosolvent Enabled Long-Term Cycling of High-Voltage Lithium-Ion Batteries with Organosulfur Electrolytes

Here, the structure–activity relationships of nonsolvating cosolvents for organosulfur-based electrolyte systems were revealed. The performance of nonsolvating dilutant fluorobenzene (FB) was compared to various fluorinated ether dilutants in high-voltage electrolytes containing a concentration of 1.2 M LiPF 6 dissolved in fluoroethylene carbonate (FEC), ethyl methyl sulfone (EMS), and the dilutant. In a high-voltage and high-loading LiNi 0.8 Mn 0.1 Co 0.1 O 2 (NMC811) full cell configuration, the organosulfur-based electrolyte containing FB dilutant enabled superior electrochemical performance compared to the electrolytes using other nonsolvating fluorinated ether formulations. Moreover, the FB-containing electrolyte exhibited the highest ionic conductivity and lowest viscosity among all organosulfur-based electrolytes containing nonsolvating dilutant. These improvements are attributed to the enhanced physical properties of electrolyte and lithium-ion mobility. Furthermore, by employing first-principles simulations, the observed suppression of side reactions at high voltage is linked to FB’s lower reactivity toward singlet dioxygen, which is likely produced at the NMC interface. Overall, FB is considered an excellent diluent that does not impede cell operation by mass decomposition at the cathode.

25 ENERGY STORAGE↗
DOE OSTI2019

Evaluation of Gas Formation and Consumption Driven by Crossover Effect in High-Voltage Lithium-Ion Batteries with Ni-Rich NMC Cathodes

Gas formation during lithium-ion battery (LIB) cycling impacts the stability and safety of these batteries, especially for those containing Ni-rich NMC cathodes. In this paper, the cycling performance and gassing behavior of NMC811/graphite full cells with 4.2 and 4.4 V upper cutoff voltages were first compared. We report cells with a 4.2 V upper cutoff voltage had good cycling stability, exhibiting a capacity retention of 96.8% after 100 cycles and generated little gas. On the other hand, cells with a 4.4 V upper cutoff voltage lost over 25% of initial capacity after 100 cycles and generated large amounts of gas in the first 10 cycles. Electrochemical cycling of anode and cathode symmetric cells was implemented to isolate gases formed at the electrode. Gas chromatography–mass spectrometry, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and scanning transmission electron microscopy were used to characterize the gas formation and associated material surfaces and structural properties. It was found that CO2 and fluorinated alkanes were the dominant gases evolved on the cathode side during cycling to 4.4 V. Gas crossover to the anode led to the depletion of gaseous products, which stabilized the cell performance to some extent. However, the growing surface reconstruction layer at the cathode, the thickening of the solid electrolyte interphase layer at the anode, and the gradual depletion of lithium inventory collectively contributed to the continuous capacity loss of full cells cycled to 4.4 V.

25 ENERGY STORAGE↗
DOE OSTI2022

Halogen Redox Shuttle Explains Voltage-Induced Halide Redistribution in Mixed-Halide Perovskite Devices

Voltage-induced halide segregation greatly limits the optoelectronic applications of mixed-halide perovskite devices, but a mechanistic explanation behind this phenomenon remains unclear. In this work, we use electron microscopy and elemental mapping to directly measure the halide redistribution in mixed-halide perovskite solar cells with quasi-ion-impermeable contact layers under different bias polarities to find iodide and bromide accumulation at the cathode and anode, respectively. This is consistent with a mechanism based on preferential iodide oxidation at the anode, leading to unbalanced I$^{+}_{i}$, I$^{-}_{X}$, and Br$^{-}_{X}$ fluxes. Importantly, switching the anode from "inert" Au to "active" Ag prevents segregation because Ag oxidation precludes the oxidation of lattice iodide, which suggests employing redox-active additives as a general strategy to suppress halide segregation. Finally, these results show that halide perovskite devices operate as solid-state electrochemical cells when threshold voltages are exceeded, providing fresh insight to understand the impacts of voltage bias on halide perovskite devices.

14 SOLAR ENERGY↗
DOE OSTI2019

High-Concentration Ether Electrolytes for Stable High-Voltage Lithium Metal Batteries

High-voltage (>4.0 V) rechargeable lithium (Li) metal batteries face huge obstacles due to the high reactivity of Li metal with traditional organic carbonate electrolytes. It is generally accepted that ether-based electrolytes are unstable above 4.0 V and thus unsuitable for high voltage applications, despite of their good compatibility with Li metal. Here we report a concentrated ether electrolyte that could be used under high voltage up to 4.5 V with the formation of a unique cathode/electrolyte interphase enriched in LiF, which effectively preserves the cathode crystalline structural integrity. Employing this high concentration ether electrolyte, Li metal batteries with a moderately high cathode loading of 1.5 mAh cm-2 can have a capacity retention of 92% after 500 cycles at 4.3 V and demonstrate nearly 100% cycling efficiency even at 4.5 V.

Ether, electrolyte, high voltage, stability, lithi↗
DOE OSTI2026

Molecular Tuning of Ether Cosolvent Chemistry for High-Voltage Sodium-Ion Batteries

Ethers as electrolyte cosolvents in sodium-ion batteries (SIBs) provide favorable Na + solvation and interfacial properties, but their low oxidative stability limits their use in high-voltage SIBs. Herein, we address this limitation via molecular tuning of ether cosolvents for high-voltage (4.2 V) hard carbon || NaNi 0.33 Fe 0.33 Mn 0.33 O 2 full cells. Tetrahydropyran (THP) is functionalized with a nitrile group to form tetrahydropyran-4-carbonitrile (THPCN). To delineate the effect of nitrile functionalization and benchmark ether against a conventional carbonate, THP, THPCN, and diethyl carbonate (DEC) are evaluated as cosolvents with ethylene carbonate. Nitrile functionalization lowers the HOMO energy of the ether, extends the electrolyte stability window, and alters Na⁺ solvation. Spectroscopic techniques and molecular dynamics simulations reveal that THPCN exhibits predominantly aggregate-dominated solvation (95.1 %) with weakened Na + -solvent interactions, producing the most anion-rich environment relative to DEC and THP cosolvents. THPCN-modified solvation promotes the formation of highly conductive, fluorine-enriched interphases that suppress parasitic reactions. Pouch full cells with THPCN sustained ~ 600 cycles at 4.2 V, outperforming THP and DEC. Operando gas analysis reveals that THPCN reduces CO 2 generation by 45% and H 2 generation by 30% relative to THP. Furthermore, the findings demonstrate nitrile functionalization as a molecular design strategy to stabilize ethers and enable high-voltage SIBs.

25 ENERGY STORAGE↗
DOE OSTI2012

Cryogenic lifetime tests on a commercial epoxy resin high voltage bushing

High-temperature superconducting (HTS) power devices operating in liquid nitrogen frequently require high-voltage bushings to carry the current leads from the superconducting windings to the room temperature grid connections. Oak Ridge National Laboratory is collaborating with Waukesha Electric Systems, SuperPower, and Southern California Edison to develop and demonstrate an HTS utility power transformer. Previous dielectric high voltage tests in support of this program have been carried out in test cryostats with commercial epoxy resin bushings from Electro Composites Inc. (ECI). Though the bushings performed well in these short-term tests, their long-term operation at high voltage in liquid nitrogen needs to be verified for use on the utility grid. Long-term tests are being carried out on a sample 28-kV-class ECI bushing. The bushing has a monolithic cast, cycloaliphatic resin body and is fire- and shatter-resistant. The test cryostat is located in an interlocked cage and is energized at 25 kVac around the clock. Liquid nitrogen (LN) is automatically refilled every 9.5 hours. Partial discharge, capacitance, and leakage resistance tests are periodically performed to check for deviations from factory values. At present, over 2400 hours have been accumulated with no changes in these parameters. The tests are scheduled to run for four to six months.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2026

High-voltage and electrode system for a cryogenic experiment to search for the neutron electric dipole moment

The cryogenic approach to the search for the neutron electric dipole moment—performing the experiment in superfluid liquid helium—holds promise for a substantial increase in sensitivity, potentially enabling a sensitivity level of 10 −28 𝑒cm. A crucial component in realizing such an experiment is the high-voltage and electrode system capable of providing an electric field of 75 kV/cm. This, in turn, requires an electric potential of 635 kV to be applied to the high-voltage electrode, while simultaneously satisfying other experimental constraints, such as those on heat load and magnetic noise requirements. In this work, we describe the outcome of a comprehensive development program addressing these challenges. It outlines the system requirements, discusses new insights into relevant physical phenomena, and details selected technical solutions with their corresponding experimental demonstrations and expected performance. The results collectively demonstrate the successful development of the necessary technology for the high-voltage and electrode system for this approach.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2014

2.3-MW Medium-Voltage, Three-Level Wind Energy Inverter Applying a Unique Bus Structure and 4.5-kV Si/SiC Hybrid Isolated Power Modules: Preprint

A high-efficiency, 2.3-MW, medium-voltage, three-level inverter utilizing 4.5-kV Si/SiC (silicon carbide) hybrid modules for wind energy applications is discussed. The inverter addresses recent trends in siting the inverter within the base of multimegawatt turbine towers. A simplified split, three-layer laminated bus structure that maintains low parasitic inductances is introduced along with a low-voltage, high-current test method for determining these inductances. Feed-thru bushings, edge fill methods, and other design features of the laminated bus structure provide voltage isolation that is consistent with the 10.4-kV module isolation levels. Inverter efficiency improvement is a result of the (essential) elimination of the reverse recovery charge present in 4.5-kV Si PIN diodes, which can produce a significant reduction in diode turn-off losses as well as insulated-gate bipolar transistor (IGBT) turn-on losses. The hybrid modules are supplied in industry-standard 140 mm x 130 mm and 190 mm x 130 mm packages to demonstrate direct module substitution into existing inverter designs. A focus on laminated bus/capacitor-bank/module subassembly level switching performance is presented.

17 WIND ENERGY↗
DOE OSTI2023

Impedance Modeling and Stability Analysis for the PLL-less and Voltage Sensor-less Grid-tied Converters

The newly developed control methodology, which omits the phase-locked loop (PLL) and voltage sensor, has garnered considerable attention for its rapid dynamic response and reduced hardware expenses. Nonetheless, its stability concerns have not yet been thoroughly scrutinized. In this paper, the impedance modeling of the PLL-less and voltage sensorless control strategy has been established. The impedance model has been contrasted with the traditional PLL-based control scheme. Our findings demonstrate that the PLL-less and voltage sensorless control approach lacks the negative resistance behavior that is frequently observed in the traditional scheme, which results in unstable operations. Furthermore, the role of virtual resistance has been examined. To substantiate the aforementioned findings, simulation results are presented.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2023

Modified Virtual Oscillator Based Operation of Grid Forming Converters with Single Voltage Sensor

Virtual oscillator based control architecture for grid forming converter with inner current control loop for additional objective accomplishments is proposed in this paper. In general, virtual oscillator is based on Lienard type of oscillator equation with a cubic nonlinearity. Virtual oscillator alone cannot accommodate unbalanced or harmonic mitigation while operating converters in grid forming mode. Therefore, to accomplish better tracking performance, incorporating the provision for nonlinear and/or unbalanced loads, an inner current control loop is utilized which is based upon Lyapunov energy function type control architecture due to its advantages. To reduce the overall cost of implementation and ensure proper phase difference in the generated voltages, the implemented virtual oscillator operates with only one voltage feedback from the point of common coupling as presented in this paper. To verify the effectiveness of the proposed approach, the overall system has been modeled in MATTLAB/Simulink and PLECS domain and case studies showing the successful production of low harmonic load voltages under nonideal loading condition along with other important results are presented in this paper.

dual second order generalized integrator↗
DOE OSTI2012

Droop Compensation with soft Switching for High Voltage Converter Modulator (HVCM)

High Voltage Converter Modulators (HVCM) offer significant performance advantages over conventional modulator technologies for long pulse applications. One of the key advantages of HVCM technology is the ability to compensate for capacitor bank voltage droop. Achieving droop compensation without incurring significant additional switching loss has not been possible in existing designs. This paper presents an analysis of the 'Y-point' variant of the HVCM topology using the Combined Phase and Frequency Modulation (CPFM) technique. This, combined with the addition of a 'lossless' snubber circuit, enables droop compensation while achieving soft switching over the entire pulse duration. The rise time and overshoot of the output voltage pulse is optimized using an iterative extreme seeking algorithm. The optimization reduces the rise time from 100 {micro}s to 50 {micro}s with no overshoot. This will lead to an increase in overall accelerator efficiency.

42 ENGINEERING↗
DOE OSTI2017

Application of Autonomous Smart Inverter Volt-VAR Function for Voltage Reduction Energy Savings and Power Quality in Electric Distribution Systems: Preprint

This paper evaluated the impact of smart inverter Volt-VAR function on voltage reduction energy saving and power quality in electric power distribution systems. A methodology to implement the voltage reduction optimization was developed by controlling the substation LTC and capacitor banks, and having smart inverters participate through their autonomous Volt-VAR control. In addition, a power quality scoring methodology was proposed and utilized to quantify the effect on power distribution system power quality. All of these methodologies were applied to a utility distribution system model to evaluate the voltage reduction energy saving and power quality under various PV penetrations and smart inverter densities.

14 SOLAR ENERGY↗
DOE OSTI2021

Grid Value Investigation of Medium-Voltage Back-to-Back Converters

This paper presents the results of an investigation into the value that medium voltage back-to-back (MVB2B) converters can be realized through two potential applications: voltage regulation via the provision of reactive power supply or absorption, and distributed energy resource (DER) hosting capacity improvement via the controlled transfer of real power within the distribution system. Two groups of distribution systems have been prepared for the value investigation: the IEEE 123-bus system for the voltage regulation study and two utility-provided, realistic distribution systems for the DER hosting capacity improvement study. The results demonstrate that the MVB2B converter can realize significant value for the grid through these two applications. In particular, with the MVB2B converter transferring power between two feeders, DER-based power can be routed to nearby loads instead of feed through the distribution substation. Additionally, the size of energy storage elements used to enable higher levels of DERs can be significantly reduced.

28 EE - Advanced Manufacturing Office (EE-5A)↗
DOE OSTI2024

Mitigating Voltage Instability in the Saudi Grid for a Decarbonized, Fully Solar Power System

Lately, solar photovoltaic (PV) has received significant interest due to its economic and environmental benefits. As the integration of renewable energy sources (RES) increases into existing power grids, challenges such as the decrease in short circuit ratio (SCR) are introduced. Here, this paper investigates a case study of the Saudi power grid, examining the voltage stability as the grid transitions from traditional power generation to 100% penetration of solar PV gradually. Moreover, the paper explores the relationship between the increase in solar penetration and the potential effects on the short circuit MVA (SCMVA), which could significantly impact the overall SCR of the system. To meet the North American Electric Reliability Corporation (NERC) recommendation of maintaining SCR at a particular level, synchronous condensers (SC)s were integrated into the grid. The effectiveness of utilizing SCs to maintain the system voltage at optimal levels in a fully solar grid is also considered. In addition, this paper covers the weak grid analysis via utilizing the Newton-Raphson load flow method, along with PV and QV curve analyses. The purpose behind that is to determine weak bus locations in need of voltage improvements, and to meet the amount of reactive power to be injected. Finally, the amount of power being delivered by SCs will be added progressively in three scenarios to show the enhancements on SCR more precisely.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2021

Medium Voltage Converter Inductor Insulation Design Considering Grid Requirements

Medium voltage (MV) SiC devices facilitate direct (without 50-/60-Hz transformer) connection of the power electronics converter to the MV grid using simple topology. Compared to the insulation design of MV inductors that have been widely used in the power system, the insulation design of the MV converter filter inductors has new challenges. Particularly, the grid impact on insulation requirements on converter filter inductors is rarely discussed. This article introduces the insulation design of a grid-side filter inductor for a 13.8-kV power conditioning system converter. The grid insulation requirements, including the short-duration power frequency overvoltage and the lightning impulse voltage, are considered in the design. To meet the requirements, the layer-to-layer insulation, winding-to-core/ground insulation, the air gap discharge between the winding and the core, the local electric field, as well as the interturn transient voltage distribution are considered. Furthermore, the designed inductors are validated by the 46 kV (>1 min) dc hi-pot test, 12-kV ac partial discharge test, one-hour single-phase converter full rating test, as well as three-phase converter full rating test.

42 ENGINEERING↗