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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 883 records · Page 49
All sourcesNASA NTRSDOE OSTI
DOE OSTI2017

Neutron and Ion Irradiation Studies on Advanced Steels Using the Nuclear Science User Facilities

For nuclear reactor structural materials, irradiation is capable of inducing a series of microstructural modifications, such as dislocation loops/network, selective elemental segregation and precipitation, voids and helium bubbles, leading to the degradation in structural materials' performance through irradiation hardening and embrittlement, swelling, irradiation creep, etc. Since radiation poses challenges for structural applications in nuclear reactors in multiple aspects and the underlying mechanisms are often interconnected, radiation effect studies need well-designed test matrix and proper characterization techniques. The Nuclear Science User Facilities (NSUF) offer extensive capabilities for studying radiation effects in nuclear fuels and structural materials. This research covers both neutron and ion irradiation studies carried out using a variety of instruments through the NSUF. The neutron irradiation ferritic ODS steel MA957 was accomplished utilizing the neutron irradiation capability of the Advanced Test Reactor (ATR) and the post-irradiation examination (PIE) capabilities of the Center for Advanced Energy Studies (CAES). The neutron-irradiated specimens were characterized using transmission electron microscopy (TEM) and atom probe tomography (APT). The in situ TEM ion irradiation study on austenitic stainless steel (SS) 316H was completed using the IVEM-Tandem facility at Argonne National Laboratory.

36 MATERIALS SCIENCE↗
DOE OSTI2015

Investigating the Influence of the Initial Biomass Distribution and Injection Strategies on Biofilm-Mediated Calcite Precipitation in Porous Media

Attachment of bacteria in porous media is a complex mixture of processes resulting in the transfer and immobilization of suspended cells onto a solid surface within the porous medium. However, quantifying the rate of attachment is difficult due to the many simultaneous processes possibly involved in attachment, including straining, sorption, and sedimentation, and the difficulties in measuring metabolically active cells attached to porous media. Preliminary experiments confirmed the difficulty associated with measuring active Sporosarcina pasteurii cells attached to porous media. However, attachment is a key process in applications of biofilm-mediated reactions in the subsurface such as microbially induced calcite precipitation. Independent of the exact processes involved, attachment determines both the distribution and the initial amount of attached biomass and as such the initial reaction rate. As direct experimental investigations are difficult, this study is limited to a numerical investigation of the effect of various initial biomass distributions and initial amounts of attached biomass. This is performed for various injection strategies, changing the injection rate as well as alternating between continuous and pulsed injections. The results of this study indicate that, for the selected scenarios, both the initial amount and the distribution of attached biomass have minor influence on the Ca 2+ precipitation efficiency as well as the distribution of the precipitates compared to the influence of the injection strategy. The influence of the initial biomass distribution on the resulting final distribution of the precipitated calcite is limited, except for the continuous injection at intermediate injection rate. But even for this injection strategy, the Ca 2+ precipitation efficiency shows no significant dependence on the initial biomass distribution.

58 GEOSCIENCES↗
DOE OSTI2019

Interfacial Reaction Between High-Al Steel and CaO-Al{sub 2}O{sub 3}-Based Mold Fluxes with Different CaO/Al{sub 2}O{sub 3} Ratios at 1773 K (1500 °C)

The reaction between high-Al steel and CaO-Al{sub 2}O{sub 3}-based mold fluxes with different CaO/Al{sub 2}O{sub 3} ratios was investigated at 1773 K (1500 °C). The increase of CaO/Al{sub 2}O{sub 3} ratio from 1 to 3 accelerated the accumulation of Al{sub 2}O{sub 3} in the flux and reduction of Na{sub 2}O, but had no significant effect on the reduction of SiO{sub 2} and B{sub 2}O{sub 3}. The microstructure of flux-steel interfaces showed that emulsification occurred in the reaction between steel and mold flux. The emulsification was affected by the precipitation of crystals in the flux after the change of flux composition due to the interfacial reaction.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Significance of Finish Cooling Temperature to Microstructure and Property Relationship of Low-Carbon V-N-Cr Microalloyed High-Strength Steel

Herein, three final cooling temperatures were employed to achieve high strength and toughness communication in the V-N-Cr microalloyed steels. This study shows that V-N-Cr microalloyed steel primarily consisted of ferrite, granular bainite, acicular ferrite, and a small quantity of M/A phase at the final cooling temperature of 600 °C, while the polygonal ferrite, lamellar bainite, granular bainite, and a small fraction of acicular ferrite were obtained at 450 °C. The width of lamellar bainite was ~ 200-400 nm, and acicular ferrite was composed of fine non-parallel ferrite platelet structures with high dislocations densities. As the final cooling temperature decreased further, the microstructure included granular bainite and lath bainite at 350 °C. The nanoscale precipitates of V-N-Cr microalloyed steel were divided into two types, large-scale precipitates near the grain boundary that precipitated at high temperatures and small precipitates of diameter 5-10 nm at low temperatures, which significantly contributed toward strength. The hot rolled low-carbon V-N-Cr microalloy steel exhibited optimal mechanical properties at the final rolling temperature of 830 °C, as well the final cooling temperature was 450 °C. The highest yield strength and tensile strength of V-N-Cr microalloyed steel were 835 MPa and 989 MPa, respectively. The outstanding impact toughness of 161 J tested at − 60 °C was received. The transformation strengthening and precipitation hardening played a crucial role in affecting the thermo-mechanical properties.

36 MATERIALS SCIENCE↗
DOE OSTI2018

How Well Can We Represent the Spectrum of Convective Clouds in a Climate Model? Comparisons between Internal Parameterization Variables and Radar Observations

Current climate models cannot resolve individual convective clouds, and hence parameterizations are needed. The primary goal of convective parameterization is to represent the bulk impact of convection on the gridbox-scale variables. Spectral convective parameterizations also aim to represent the key features of the subgrid-scale convective cloud field such as cloud-top-height distribution and in-cloud vertical velocities in addition to precipitation rates. Ground-based radar retrievals of these quantities have been made available at Darwin, Australia, permitting direct comparisons of internal parameterization variables and providing new observational references for further model development. A spectral convective parameterization [the convective cloud field model (CCFM)] is discussed, and its internal equation of motion is improved. Results from the ECHAM–HAM model in single-column mode using the CCFM and the bulk mass flux Tiedtke–Nordeng scheme are compared with the radar retrievals at Darwin. The CCFM is found to outperform the Tiedtke–Nordeng scheme for cloud-top-height and precipitation-rate distributions. Radar observations are further used to propose a modified CCFM configuration with an aerodynamic drag and reduced entrainment parameter, further improving both the convective cloud-top-height distribution (important for large-scale impact of convection) and the in-cloud vertical velocities (important for aerosol activation). This study provides a new development in the CCFM, improving the representation of convective cloud spectrum characteristics observed in Darwin. This is a step toward an improved representation of convection and ultimately of aerosol effects on convection. It also shows how long-term radar observations of convective cloud properties can help constrain parameters of convective parameterization schemes.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Contribution of Tibetan Plateau ecosystems to local and remote precipitation through moisture recycling

The ecosystems of the Tibetan Plateau (TP) provide multiple important ecosystem services that benefit both local populations and those beyond, such as through climate regulation services on precipitation for East Asia and China. However, the precipitation regulation service of the TP ecosystems for supplying moisture and maintaining precipitation is yet to be evaluated. In this study, we used the moisture recycling framework and a moisture tracking model to quantify the precipitation regulation services of TP ecosystems for their contribution to precipitation. We found TP ecosystems contributed substantially to local and downwind precipitation, with a declined contribution from 221 mm/year for the TP and neighboring areas, to <10 mm/year for eastern China and other surrounding countries. Among ecosystem types, grassland contributed most to precipitation, followed by barren and snow lands, forests, and shrublands. In terms of seasonality, precipitation contribution from TP ecosystems was greater in summer months than in non-summer months for western China, while the opposite was true for eastern China – though the magnitude was much smaller. Over the past two decades, the significant evapotranspiration increases in TP translated to a widespread increase in precipitation contribution for TP and downwind beneficiary regions from 2000 to 2020. Our study provides a quantitative way to understand the precipitation regulation services of TP ecosystems through moisture recycling, substantiating their key role to safeguard precipitation and the water cycle for downwind regions– effectively acting as an ecological security shelter that could be perceived by the public.

Li, Yan↗
NASA NTRS1979

Some aspects of hydrology in the GLAS GCM

The response of hydrology in the Laboratory for Atmospheric Sciences General Circulation Model is evaluated. The results show that the distribution of precipitation agrees fairly well with observations of precipitation and that the model and that the model tends to maintain the hydrological balance.

Godbole, R.↗
NASA NTRS2008

Global Precipitation Measurement

This chapter begins with a brief history and background of microwave precipitation sensors, with a discussion of the sensitivity of both passive and active instruments, to trace the evolution of satellite-based rainfall techniques from an era of inference to an era of physical measurement. Next, the highly successful Tropical Rainfall Measuring Mission will be described, followed by the goals and plans for the Global Precipitation Measurement (GPM) Mission and the status of precipitation retrieval algorithm development. The chapter concludes with a summary of the need for space-based precipitation measurement, current technological capabilities, near-term algorithm advancements and anticipated new sciences and societal benefits in the GPM era.

Hou, Arthur Y.↗
NASA NTRS2008

Total Lightning Observations of Extreme Weather Events over the Contiguous United States

The overall objective is to investigate total lightning characteristics of extreme weather events over the contiguous United States (CONUS) using TRMM (Tropical Rainfall Measuring Mission) LIS (Lightning Image Sensor) and OTD (Optical Transient Detector) satellite observations. A large LIS (10+ years) and OTD (5 years) data base is available to study the instantaneous total or cloud-to-ground (CG) plus intracloud (IC) lightning characteristics of extreme weather events. More specifically, the LIS and OTD data are combined with National Lightning Detection Network (NLDN) observations to examine the total and CG lightning flash rate and density, the IC:CG ratio, and positive CG percentage. These instantaneous lightning characteristics can be used for basic science studies to better understand the physical and dynamical linkages between lightning and precipitation and their environmental controls. They can also provide a first-look of extreme weather events leading up to future satellite observations (e.g., NOAA GOES-R Geostationary Lightning Mapper [GLM]) for use in climate studies and the short-term prediction and warning process. Extreme weather events are defined by the NOAA Storm Data reports of tornadoes, large hail (at least 0.75 inch) and strong straight-line winds (at least 50 kts). Over CONUS, there are over 70,000 severe storm reports in the TRMM spatial domain (< 35 N) from 1998-2007 and over 100,000 storm reports in the OTD spatial domain (5/1995-4/2000). Temporal co-location is on the order of 1% (i.e., 1000 s of coincident overpasses), providing a statistically significant sample of instantaneous total lightning properties. This instantaneous behavior of lightning in extreme weather is then compared to that of typical thunderstorm events, or randomly sampled LIS/OTD events in which the extreme events have been eliminated from the population. Results describing the instantaneous behavior of total lightning within a large sample of extreme and typical thunderstorms over CONUS will be presented. When possible, coincident VHF lightning observations from the ground-based Northern Alabama Lightning Mapping Array (LMA) are compared to the LIS/OTD optical lightning signatures, providing a validation source for instantaneous space-based optical lightning properties and a means to extend lightning inferences over the life-cycle of extreme weather.

Carey, Lawrence D.↗
NASA NTRS2021

Trend Detection of Atmospheric Time Series: Incorporating Appropriate Uncertainty Estimates and Handling Extreme Events

This paper is aimed at atmospheric scientists without formal training in statistical theory. Its goal is to, 1) provide a critical review of the rationale for trend analysis of the time series typically encountered in the field of atmospheric chemistry; 2) describe a range of trend-detection methods; and 3) demonstrate effective means of conveying the results to a general audience. Trend detections in atmospheric chemical composition data are often challenged by a variety of sources of uncertainty, which often behave differently to other environmental phenomena such as temperature, precipitation rate, or stream flow, and may require specific methods depending on the science questions to be addressed. Some sources of uncertainty can be explicitly included in the model specification, such as autocorrelation and seasonality, but some inherent uncertainties are difficult to quantify, such as data heterogeneity and measurement uncertainty due to the combined effect of short- and long-term natural variability, instrumental stability, and aggregation of data from sparse sampling frequency. Failure to account for these uncertainties might result in an inappropriate inference of the trends and their estimation errors. On the other hand, the variation in extreme events might be interesting for different scientific questions, for example, the frequency of extremely high surface ozone events and their relevance to human health. In this study we aim to, 1) review trend detection methods for addressing different levels of data complexity in different chemical species; 2) demonstrate that the incorporation of scientifically interpretable covariates can outperform pure numerical curve fitting techniques in terms of uncertainty reduction and improved predictability; 3) illustrate the study of trends based on extreme quantiles that can provide insight beyond standard mean or median based trend estimates; and 4) present an advanced method of quantifying regional trends based on the inter-site correlations of multi-site data. All demonstrations are based on time series of observed trace gases relevant to atmospheric chemistry, but the methods can be applied to other environmental data sets.

Trace gas↗
DOE OSTI2019

SPRUCE Tritium in Porewater of SPRUCE Experimental Plots and Neighboring Peatlands, and in Groundwater, Stream Water, and Precipitation of the S1 Bog, 2014-2016

This data set reports the tritium concentrations in (1) porewater from selected SPRUCE experimental plots located in the S1 bog and in (2) groundwater, streamwater, and precipitation in the S1 bog watershed, and (3) in porewater from the S2 bog, S3 fen, and Bog Lake fen. All sites are located at the USDA Forest Service, Marcell Experimental Forest (MEF) near Grand Rapids, MN. Samples were collected between June of 2014 and August of 2016. These data include samples collected pre- and post-belowground warming treatments associated with the SPRUCE Experiment. There are 10 experimental plots in SPRUCE: 5 temperature treatments (+0, +2.25, +4.5, +6.75, +9°C) at ambient CO2, and the same 5 temperature treatments at elevated CO2 (+500 ppm). Porewater samples in this dataset were collected from three of the warming treatment plots (+0, +4.5, +9°C) at ambient CO2.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2015

Fine precipitation scenarios of AlZnMg(Cu) alloys revealed by advanced atomic-resolution electron microscopy study Part I: Structure determination of the precipitates in AlZnMg(Cu) alloys

Although they are among the most important precipitation-hardened materials for industry applications, the high-strength AlZnMg(Cu) alloys have thus far not yet been understood adequately about their underlying precipitation scenarios in relation with the properties. This is partly due to the fact that the structures of a number of different precipitates involved in electron microscopy in association with quantitative image simulations have to be employed; a systematic study of these hardening precipitates in different alloys is also necessary. In Part I of the present study, it is shown that there are five types of structurally different precipitates including the equilibrium η-phase precipitate. Using two state-of-the-art atomic-resolution imaging techniques in electron microscopy in association with quantitative image simulations, we have determined and clarified all the unknown precipitate structures. It is demonstrated that atomic-resolution imaging can directly suggest approximate structure models, whereas quantitative image analysis can refine the structure details that are much smaller than the resolution of the microscope. This combination is crucially important for solving the difficult structure problems of the strengthening precipitates in AlZnMg(Cu) alloys. - Highlights: Part I: • We determine and verify all the key precipitate structures in AlMgZn(Cu) alloys. • We employ aberration-corrected scanning transmission electron microscopy (STEM). • We use aberration-corrected high-resolution TEM (HRTEM) for the investigations. • We obtain atomic-resolution images of the precipitates and model their structures. • We refine all precipitate structures with quantitative image simulation analysis. Part II: • The hardening precipitates in AlZnMg alloys shall be classified into two groups. • Two precipitation scenarios coexist in the alloys. • The precipitation behavior of such an alloy depends on the alloy's composition. • Very detailed phase/structure transformations among the precipitates are revealed.

36 MATERIALS SCIENCE↗
DOE OSTI2019

The Second ARM Training and Science Application Event: Training the Next Generation of Atmospheric Scientists

The Atmospheric Radiation Measurement (ARM) user facility (Turner and Ellingson 2016) collects valuable observations of atmospheric variables affecting the Earth’s radiation budget. These include properties of aerosol, cloud, precipitation, dynamic, and thermodynamic fields. The ARM user facility also supports routine high-resolution modeling efforts at its Southern Great Plains (SGP) site, and over the years it has had significant impacts on cloud-resolving and Earth system model development (Krueger et al. 2016; Randall et al. 2016). In an effort to promote use of the ARM data by the next generation of atmospheric scientists, the second ARM Summer Training and Science Applications Event on observations and modeling of clouds and precipitation took place from 14 to 21 July 2018. The event was sponsored by the ARM User Facility and was catered toward graduate students and early career scientists interested in observations and modeling of aerosol, cloud, and precipitation processes. Theoretical and practical instructions on the application of ground- and aircraft-based observations from a wide array of active and passive sensors, and finescale-resolution model simulations were provided during the training. This informed the participants about innovative methods for using the ARM data and numerical models to address complex scientific questions. The event was locally organized by the Cooperative Institute for Mesoscale Meteorological Studies (CIMMS) and was held at the National Weather Center in Norman, Oklahoma. The training was attended by 12 instructors and 24 participants.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2019

Grain boundary segregation and intermetallic precipitation in coarsening resistant nanocrystalline aluminum alloys

In-spite of all of the unique properties of nanocrystalline materials, they are notorious when it comes to their susceptibility to thermally induced grain coarsening, thus imposing an upper limit to their application temperature. In this study, we demonstrate a coupled Monte Carlo-molecular dynamics simulation-guided experimental approach of improving the resistance to thermally induced grain coarsening in light-weight nanocrystalline Al-Mg alloys. The structure, grain boundary segregation of Mg, and extent of grain coarsening of the Al-Mg alloys were characterized using plan view and cross-sectional transmission electron microscopy and atom probe tomography. Coarsening resistance is attributed to a combination of thermodynamic stabilization of grain boundaries by controlled Mg segregation, and kinetic stabilization through pinning of the boundaries with nanoscale intermetallic precipitates. Thus, we highlight the opportunities in extending the upper limit of application temperature for nanocrystalline alloys by using a complementary thermodynamic and kinetic stabilization approach.

Nanostructured materials, Al Alloys, Thermal stabi↗
DOE OSTI2017

Mechanism of Texture and Precipitates Evolution in CGO Silicon Steel During High-Temperature Annealing Process

Grain-oriented silicon steel is an important soft magnetic material for electrical applications. A conventional grain-oriented silicon steel with final thicknesses of 0.27, 0.23 and 0.20 mm was prepared separately by a two-stage cold rolling process. Texture evolution, precipitates distribution and Goss textures formed during secondary recrystallization were analyzed by electron backscattered diffraction and field emission scanning electron microscopy. The results show that plate thickness influences the distribution density of secondary phase particles and the content of favorable texture components such as {111} <112>, {111} <110> and {112} <110> texture. Decreasing plate thickness increases the areal density of secondary phase particles, the temperature of secondary recrystallization, which also increases the content of favorable texture component, and the strength of Goss texture in secondary recrystallization. Goss grains have higher particle density than the grains with other orientations, which facilitates their abnormal growth by swallowing surrounding grains with lower particle density.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Extensive nanoprecipitate morphology transformation in a nanostructured ferritic alloy due to extreme thermomechanical processing

Nano-oxide precipitates in a modern nanostructured ferritic alloy were investigated after extreme thermomechanical processing into a thin-walled tube geometry. It was found that the morphology of the precipitates changed from spherical to rod-shaped, with some increasing to aspect ratios of up to 9, despite the precipitate volume fraction (0.3%) and number density (> 10 23 m -3 ) of precipitates remaining unchanged. High-resolution electron microscopy showed that the precipitates likely remained coherent with the Fe-matrix, while atom probe tomography confirmed that the precipitate compositions remained unaffected by the transformation. The morphological change was attributed to the shearable nature of the (Y,Ti,O)-rich precipitates, indicating they should be considered as “soft” obstacles to dislocation motion. The elongation was most pronounced in larger (>5 nm) precipitates, which may be caused by preferential dissolution of the smallest (1–3 nm) precipitates followed by the competition between re-precipitation and solute diffusion to larger precipitates during recovery heat treatments.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Precipitation in Mg-Gd-Y-Zr Alloy: Atomic-scale insights into structures and transformations

This paper reports on a comprehensive investigation, using atomic-scaled C{sub s} corrected high angle annular dark field-scanning transmission electron microscopy (HAADF-STEM), of the precipitation in Mg-9.28Gd-2.93Y-0.35Zr, including structures of the precipitates and several structural transformation processes. The precipitation sequence is identified as: Super saturated solid solution → clusters → nucleation β{sup '} (major)/ β{sub H} (minor)→ precipitate β{sup '} (major)/ β{sub M} , β{sub T}{sup '} (minor)→β{sub 1} → β(Equilibrium). Under peak-age condition, the strengthening structure is independent defect-free β{sup '} with little interaction among each other. Under over-age condition, the β{sup '} precipitates start to interact with each other, during which coarsening and orientation transformation of β{sup '} precipitates take place. The coarsening and orientation transformation, in which some RE atoms in the precipitates need to change their positions, are achieved by β{sub M} and β{sub T}{sup '} as transitional structures. - Highlights: • The precipitation in Mg-Gd-Y-Zr is comprehensively investigated by advanced atomic-scale Cs-corrected HAADF-STEM. • Various novel precipitate structures are unraveled. • Four types of interfaces between the precipitates are fully characterized. • The structural transformation processes of the precipitates are revealed.

36 MATERIALS SCIENCE↗