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At least 883 records · Page 49

Properties of the Hermean Regolith: New Optical Reflectance Spectra, Comparison with Lunar Anorthosites and Mineralogical Modelling - 5

We present new optical (0.4-0.65 micron) spectra of Mercury and lunar pure anorthosite locations, obtained quasi-simultaneously with the Nordic Optical Telescope (NOT) in 2002. A comparative study is performed with the model of Lucey et al. between iron-poor, mature, pure anorthosite (less than 90% plagioclase feldspar) Clementine spectra from the lunar farside and a combined 0.4-1.0 micron mercurian spectrum, obtained with the NOT, calculated for standard photometric geometry. Mercury is located at more extreme locations in the Lucey ratio-reflectance diagrams than any known lunar soil, specifically with respect to the extremely iron-poor mature anorthosites. Though quantitative prediction of FeO and TiO2 abundances cannot be made without a more generally applicable model, we find qualitatively that the abundances of both these oxides must be near zero for Mercury. We utilize the theory of Hapke, with realistic photometric parameters, to model laboratory spectra of matured mineral powders and lunar soils, and remotely sensed spectra of lunar anorthosites and Mercury. An important difference between fabricated and natural powders is the high value for the internal scattering parameter necessary to interpret the spectra for the former, and the requirement of rough and non-isotropically scattering surfaces in the modelling of the latter. The mature lunar anorthosite spectra were well modelled with binary mixtures of calcic feldspars and olivines, grain sizes of 25-30 micron and a concentration of submicroscopic metallic iron (SMFe) of 0.12-0.15% in grain coatings. The mercurian spectrum is not possible to interpret from terrestrial mineral powder spectra without introducing an average particle scattering function for the bulk soil that increases in backscattering efficiency with wavelength. The observed spectrum is somewhat better predicted with binary mixture models of feldspars and pyroxenes, that single-component regoliths consisting of either albite or diopside. Correct spectral reflectance values were predicted with a concentration of 0.1 wt% SMFe in coatings of 15-30 micron sized grains. Since reasonable cosmogonical formation scenarios for Mercury, or meteoritic infall, predict iron concentrations at least this high, we draw the conclusion that the average grain size of Mercury is about a factor of two smaller than for average returned lunar soil samples. The 0.6-2.5 micron spectrum of McCord and Clark is used to further limit the possible range of mineralogical composition of Mercury. It is found that an intimately mixed and matured 3 : 1 labradorite-to-enstatite regolith composition best matches both the optical and near-infrared spectra, yielding an abundance of approx. 1.2 wt% FeO and -approx. 0 wt% TiO2.

Warell, J.↗

The Optical Signatures of Stochastic Processes in Many-Body Exciton Scattering

We review our recent quantum stochastic model for spectroscopic lineshapes in the presence of a coevolving and nonstationary background population of excitations. Starting from a field theory description for interacting bosonic excitons, we derive a reduced model whereby optical excitons are coupled to an incoherent background via scattering as mediated by their screened Coulomb coupling. The Heisenberg equations of motion for the optical excitons are then driven by an auxiliary stochastic population variable, which we take to be the solution of an Ornstein–Uhlenbeck process. Here, we present an overview of the theoretical techniques we have developed as applied to predicting coherent nonlinear spectroscopic signals. We show how direct (Coulomb) and exchange coupling to the bath give rise to distinct spectral signatures and discuss mathematical limits on inverting spectral signatures to extract the background density of states.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Biomass burning emission analysis based on MODIS aerosol optical depth and AeroCom multi-model simulations: implications for model constraints and emission inventories

We assessed the biomass burning (BB) smoke aerosol optical depth (AOD) simulations of 11 global models that participated in the AeroCom phase III BB emission experiment. By comparing multi-model simulations and satellite observations in the vicinity of fires over 13 regions globally, we (1) assess model-simulated BB AOD performance as an indication of smoke source–strength, (2) identify regions where the common emission dataset used by the models might underestimate or overestimate smoke sources, and (3) assess model diversity and identify underlying causes as much as possible. Using satellite-derived AOD snapshots to constrain source strength works best where BB smoke from active sources dominates background non-BB aerosol, such as in boreal forest regions and over South America and southern hemispheric Africa. The comparison is inconclusive where the total AOD is low, as in many agricultural burning areas, and where the background is high, such as parts of India and China. Many inter-model BB AOD differences can be traced to differences in values for the mass ratio of organic aerosol to organic carbon, the BB aerosol mass extinction efficiency, and the aerosol loss rate from each model. The results point to a need for increased numbers of available BB cases for study in some regions and especially to a need for more extensive regional-to-global-scale measurements of aerosol loss rates and of detailed particle microphysical and optical properties; this would both better constrain models and help distinguish BB from other aerosol types in satellite retrievals. More generally, there is the need for additional efforts at constraining aerosol source strength and other model attributes with multi-platform observations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Spatially Resolved Mapping of Three-Dimensional Molecular Orientations with ~2 nm Spatial Resolution through Tip-Enhanced Raman Scattering

We record local optical field images of silver nanocubes (75 nm) using tip-enhanced Raman (TER) spectral imaging. The images that we observe are consistent with several recent reports from our group, but here, we demonstrate sub-2 nm spatial resolution in local optical field nanoimaging under ambient laboratory conditions. This is achieved by scanning the substrate (nanocube on Si) relative to a 4-thiobenzonitrile (TBN)-functionalized Ag-coated TER probe. The spatial resolution that we obtain necessitates that only a few molecules govern the recorded optical response; molecular orientation becomes an important consideration in such measurements. We model the orientation through geometry optimization of a TBN molecule chemisorbed onto an Ag79 cluster (sphere with a ~1 nm diameter). Using the computed orientation of the cluster-bound molecule, we then model the optical response using formalism that accounts for the orientation of the molecule relative to vector components of the local optical fields. We find optimal agreement between experiment and theory. In effect, this work reveals the parallels between single-molecule Raman scattering and high-spatial-resolution TER spectroscopy, even when the images themselves cannot be used to visualize a single molecule in real space.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Executive summary

The Astrotech 21 Optical Systems Technology Workshop was held in Pasadena, California on March 6-8, 1991. The purpose of the workshop was to examine the state of Optical Systems Technology at the National Aeronautics Space Administration (NASA), and in industry and academia, in view of the potential Astrophysics mission set currently being considered for the late 1990's through the first quarter of the 21st century. The principal result of the workshop is this publication, which contains an assessment of the current state of the technology, and specific technology advances in six critical areas of optics, all necessary for the mission set. The workshop was divided into six panels, each of about a dozen experts in specific fields, representing NASA, industry, and academia. In addition, each panel contained expertise that spanned the spectrum from x-ray to submillimeter wavelengths. This executive summary contains the principal recommendations of each panel. The six technology panels and their chairs were: (1) Wavefront Sensing, Control, and Pointing, Thomas Pitts, Itek Optical Systems, A Division of Litton; (2) Fabrication, Roger Angel, Steward Observatory, University of Arizona; (3) Materials and Structures, Theodore Saito, Lawrence Livermore National Laboratory; (4) Optical Testing, James Wyant, WYKO Corporation; (5) Optical Systems Integrated Modeling, Robert R. Shannon, Optical Sciences Center, University of Arizona; and (6) Advanced Optical Instruments Technology, Michael Shao, Jet Propulsion Laboratory, California Institute of Technology. This Executive Summary contains the principal recommendations of each panel.

Ayon, Juan A.↗

Implanted Silicon Resistor Layers for Efficient Terahertz Absorption

Broadband absorption structures are an essential component of large format bolometer arrays for imaging GHz and THz radiation. We have measured electrical and optical properties of implanted silicon resistor layers designed to be suitable for these absorbers. Implanted resistors offer a low-film-stress, buried absorber that is robust to longterm aging, temperature, and subsequent metals processing. Such an absorber layer is readily integrated with superconducting integrated circuits and standard micromachining as demonstrated by the SCUBA II array built by ROE/NIST (1). We present a complete characterization of these layers, demonstrating frequency regimes in which different recipes will be suitable for absorbers. Single layer thin film coatings have been demonstrated as effective absorbers at certain wavelengths including semimetal (2,3), thin metal (4), and patterned metal films (5,6). Astronomical instrument examples include the SHARC II instrument is imaging the submillimeter band using passivated Bi semimetal films and the HAWC instrument for SOFIA, which employs ultrathin metal films to span 1-3 THz. Patterned metal films on spiderweb bolometers have also been proposed for broadband detection. In each case, the absorber structure matches the impedance of free space for optimal absorption in the detector configuration (typically 157 Ohms per square for high absorption with a single or 377 Ohms per square in a resonant cavity or quarter wave backshort). Resonant structures with -20% bandwidth coupled to bolometers are also under development; stacks of such structures may take advantage of instruments imaging over a wide band. Each technique may enable effective absorbers in imagers. However, thin films tend to age, degrade or change during further processing, can be difficult to reproduce, and often exhibit an intrinsic granularity that creates complicated frequency dependence at THz frequencies. Thick metal films are more robust but the requirement for patterning can limit their absorption at THz frequencies and their heat capacity can be high. patterned absorber structures that offer low heat capacity, absence of aging, and uniform, predictable behavior at THz frequencies. We have correlated DC electrical and THz optical measurements of a series of implanted layers and studied their frequency dependence of optical absorption from .3 to 10 THz at cryogenic temperatures. We have modeled the optical response to determine the suitability of the implanted silicon resistor as a function of resistance in the range 10 Ohms/sq to 300 Ohms/sq.

Chervenak, J. A.↗

Using Observations of Deep Convective Systems to Constrain Atmospheric Column Absorption of Solar Radiation in the Optically Thick Limit

Atmospheric column absorption of solar radiation A(sub col) is a fundamental part of the Earth's energy cycle but is an extremely difficult quantity to measure directly. To investigate A(sub col), we have collocated satellite-surface observations for the optically thick Deep Convective Systems (DCS) at the Department of Energy Atmosphere Radiation Measurement (ARM) Tropical Western Pacific (TWP) and Southern Great Plains (SGP) sites during the period of March 2000 December 2004. The surface data were averaged over a 2-h interval centered at the time of the satellite overpass, and the satellite data were averaged within a 1 deg X 1 deg area centered on the ARM sites. In the DCS, cloud particle size is important for top-of-atmosphere (TOA) albedo and A(sub col) although the surface absorption is independent of cloud particle size. In this study, we find that the A(sub col) in the tropics is approximately 0.011 more than that in the middle latitudes. This difference, however, disappears, i.e., the A(sub col) values at both regions converge to the same value (approximately 0.27 of the total incoming solar radiation) in the optically thick limit (tau greater than 80). Comparing the observations with the NASA Langley modified Fu_Liou 2-stream radiative transfer model for optically thick cases, the difference between observed and model-calculated surface absorption, on average, is less than 0.01, but the model-calculated TOA albedo and A(sub col) differ by 0.01 to 0.04, depending primarily on the cloud particle size observation used. The model versus observation discrepancies found are smaller than many previous studies and are just within the estimated error bounds. We did not find evidence for a large cloud absorption anomaly for the optically thick limit of extensive ice cloud layers. A more modest cloud absorption difference of 0.01 to 0.04 cannot yet be ruled out. The remaining uncertainty could be reduced with additional cases, and by reducing the current uncertainty in cloud particle size.

Dong, Xiquan↗

The central, compact source in the Cygnus A galaxy

Single, optically thin, component models as well as double, optically thick at low frequencies, component models have been examined in trying to explain the central source in the nucleus of Cygnus A. In the course of exploring those models, it is found that this compact radio source may be quite similar to other compact and variable sources in Seyfert galaxies and quasars. Double component models generally do better because they fit the X-rays, and there is a good chance that the X-rays arise in the central source; these models can naturally explain variability which may already have been detected in X-rays. The IR is most likely due to emission by cold dust in the nucleus of Cygnus A. Optical emission is, very likely, primarily thermal, except perhaps at UV wavelengths. A number of observations are suggested to check the predictions of this work.

Kafatos, M.↗

Remote Americium Detection Using an Optical Sensor: A D-Optimal Strategy for Efficient PLS-Based Modeling

A fiber-optic visible–near-infrared absorption spectroscopy system in a glove box was demonstrated for remote quantification of Am(III) (0–500 µM) and HNO 3 (0.1–9 M) using partial least squares regression (PLSR) models. The sensor platform, featuring a simple plug-and-play spectrophotometer, can enable noninvasive, real-time monitoring of actinide process solutions. To establish a flexible PLSR model calibration strategy, a D-optimal design developed using Nd(III) in previous studies was successfully extended to an actinide system with Am(III) to effectively minimize sample set size while maintaining robust prediction performance. The results suggest strong spectral similarities between Nd(III) and Am(III) and validate Nd(III) as an effective optical surrogate for trivalent actinide species. This work also supports the generalizability of a D-optimal training set selection approach for two-factor systems. The PLS1 models for Am(III) and HNO 3 outperformed a PLS2 model and maintained reasonable performance in the presence of interfering U(VI). The resulting sensor system and multivariate approach provides a flexible and scalable solution for process monitoring, control, and safety in diverse nuclear applications.

actinide↗

Some aspects of cosmic synchrotron sources

Synchrotron emission is considered from individual particles which have small pitch angles and the general properties of synchrotron sources which mainly contain such particles, as well as the emissivities and degrees of circular polarization for specific source distributions. The limitation of synchrotron source models for optical pulsars and compact extragalactic objects are discussed, and it is shown that several existing models for the pulsar NP 0532 are inconsistent with the measured time variations and polarizations of the optical emission. Discussion is made also of whether the low frequency falloffs in the extragalactic objects PKS 2134 + 004, OQ 208, and NGC 1068 is due to emission from particles with small pitch angles or absorption by a thermal plasma or synchrotron self-absorption. It is concluded that the absorption interpretations cannot account for the turnover in the spectrum of PKS 2134 + 004. Measurements of polarization, angular structure, and X-ray flux are also described.

Epstein, R. I.↗

Structural and thermal response of 30 cm diameter ion thruster optics

This paper presents tabular and graphical data intended for use in calibrating and validating structural and thermal models of ion thruster optics. A 30-cm-diameter, two electrode, mercury ion thruster was operated using two different electrode assembly designs. With no beam extraction, the transient and steady state temperature profiles and center electrode gaps were measured for three discharge powers. The data showed that the electrode mount design had little effect on the temperatures, but significantly impacted the motion of the electrode center. Equilibrium electrode gaps increased with one design and decreased with the other. Equilibrium displacements in excess of 0.5 mm and gap changes of 0.08 mm were measured at 450 W discharge power. Variations in equilibrium gaps were also found among assemblies of the same design. The presented data illustrate the necessity for high fidelity ion optics models and development of experimental techniques to allow their validation.

Macrae, G.↗

Optical emission from a small scale model electric arc furnace in 250-600 nm region

Optical emission spectroscopy has been for long proposed for monitoring and studying industrial steel making processes. Whereas the radiative decay of thermal excitations is always taking place in high temperatures needed in steel production, one of the most promising environment for such studies are electric arc furnaces, creating plasma in excited electronic states that relax with intense characteristic emission in the optical regime. Unfortunately, large industrial scale electric arc furnaces also present a challenging environment for optical emission studies and application of the method is not straightforward. To study the usability of optical emission spectroscopy in real electric arc furnaces, we have developed a laboratory scale DC electric arc furnace presented in this paper. With the setup, optical emission spectra of Fe, Cr, Cr{sub 2}O{sub 3}, Ni, SiO{sub 2}, Al{sub 2}O{sub 3}, CaO, and MgO were recorded in the wavelength range 250-600 nm and the results were analyzed with the help of reference data. The work demonstrates that using characteristic optical emission, obtaining in situ chemical information from oscillating plasma of electric arc furnaces is indeed possible. In spite of complications, the method could possibly be applied to industrial scale steel making process in order to improve its efficiency.

36 MATERIALS SCIENCE↗

Optical Instruments Synergy in Determination of Optical Depth of Thin Clouds

Optically thin clouds have a strong radiative effect and need to be represented accurately in climate models. Cloud optical depth of thin clouds was retrieved using high resolution digital photography, lidar, and a radiative transfer model. The Doppler Lidar was operated at 1.5 μm, minimizing return from Rayleigh scattering, emphasizing return from aerosols and clouds. This approach examined cloud structure on scales 3 to 5 orders of magnitude finer than satellite products, opening new avenues for examination of cloud structure and evolution.

54 ENVIRONMENTAL SCIENCES↗

Thermochromic undoped and Mg-doped VO{sub 2} thin films and nanoparticles: Optical properties and performance limits for energy efficient windows

Undoped and Mg-doped thermochromic VO{sub 2} films with atom ratios z ≡ Mg/(Mg + V) of 0 ≤ z < 0.21 were deposited by reactive DC magnetron sputtering onto heated glass and carbon substrates. Elemental compositions were found by Rutherford backscattering spectrometry. Optical constants were determined from transmittance and reflectance measurements and were used for modeling the optical properties of thin films and dilute nanoparticle composite layers below and above the critical temperature for thermochromic switching between a low-temperature infrared transparent state and a high-temperature infrared reflecting or absorbing state. Mg-doped films showed superior luminous transmittance T{sub lum} and solar transmittance modulation ΔT{sub sol} compared to undoped VO{sub 2} films, and both of these parameters could be further enhanced by anti-reflection. VO{sub 2}-containing nanocomposites had much larger values of T{sub lum} and ΔT{sub sol} than VO{sub 2}-based films. Mg-doping was found to erode the properties of the nanocomposites. Approximate performance limits are given on T{sub lum} and ΔT{sub sol} for thermochromic VO{sub 2} films, with and without Mg doping and antireflection coating, and also for VO{sub 2}-containing dilute nanocomposites.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

High-frequency techniques for RCS prediction of plate geometries and a physical optics/equivalent currents model for the RCS of trihedral corner reflectors

Part 1 of this report continues the investigation, initiated in previous reports, of scattering from rectangular plates coated with lossy dielectrics. The hard polarization coefficients given in the last report are incorporated into a model, which includes second- and third-order diffractions, for the coated plate. Computed results from this model are examined and compared to measured data. A breakdown of the contribution of each of the higher-order terms to the total radar cross section (RCS) is given. The effectiveness of the uniform theory of diffraction (UTD) model in accounting for the coating effect is investigated by examining a Physical Optics (PO) model which incorporates the equivalent surface impedance approximation used in the UTD model. The PO, UTD, and experimental results are compared. Part 2 of this report presents a RCS model, based on PO and the Method of Equivalent Currents (MEC), for a trihedral corner reflector. PO is used to account for the reflected fields, while MEC is used for the diffracted fields. Single, double, and triple reflections and first-order diffractions are included in the model. A detailed derivation of the E(sub theta)-polarization, monostatic RCS is included. Computed results are compared with finite-difference time-domain (FDTD) results for validation. The PO/MEC model of this report compares very well with the FDTD model, and it is a much faster model in terms of computational speed.

Balanis, Constantine A.↗

A Digital Twin Approach to Study Additive Manufacturing Processing Using Embedded Optical Fiber Sensors and Numerical Modeling

One of the major challenges for metal-powder-based additive manufacturing is measuring and mitigating residual strain induced during the manufacturing processes. This article reports distributed fiber optic sensors embedded in Inconel alloy components as experimental means to validate numerical models of additive manufacturing process. Electroplating was used to deposit a metal protective jacket onto standard telecom single-mode fibers for strain measurements, Fiber sensors were embedded in an Inconel alloy substrate using the laser engineered net shaping (LENS) process. Here by using a Rayleigh-scattering optical frequency domain reflectometer (OFDR), temperature changes, and residual strain in the metal substrate were monitored with 5 mm spatial resolution during the LENS process. Using finite element analysis, temperature and strain profiles induced by the LENS deposition processes were also numerically studied. Discrepancies between the simulated temperature and strain profiles and those measured directly were less than 10%. Results presented in this article demonstrates a digital twin approach to fuse modeling results with distributed fiber sensor measurement data to study additive manufacturing process toward design and fabrication process optimization.

36 MATERIALS SCIENCE↗

Econ's optimal decision model of wheat production and distribution-documentation

The report documents the computer programs written to implement the ECON optical decision model. The programs were written in APL, an extremely compact and powerful language particularly well suited to this model, which makes extensive use of matrix manipulations. The algorithms used are presented and listings of and descriptive information on the APL programs used are given. Possible changes in input data are also given.

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