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NASA NTRS2015

Testing of an Arcjet Thruster with Capability of Direct-Drive Operation

Electric thrusters typically require a power processing unit (PPU) to convert the spacecraft provided power to the voltage-current that a thruster needs for operation. Testing has been initiated to study whether an arcjet thruster can be operated directly with the power produced by solar arrays without any additional conversion. Elimination of the PPU significantly reduces system-level complexity of the propulsion system, and lowers developmental cost and risk. The work aims to identify and address technical questions related to power conditioning and noise suppression in the system and heating of the thruster in long-duration operation. The apparatus under investigation has a target power level from 400-1,000 W. However, the proposed direct-drive arcjet is potentially a highly scalable concept, applicable to solar-electric spacecraft with up to 100's of kW and beyond. A direct-drive electric propulsion system would be comprised of a thruster that operates with the power supplied directly from the power source (typically solar arrays) with no further power conditioning needed between those two components. Arcjet thrusters are electric propulsion devices, with the power supplied as a high current at low voltage; of all the different types of electric thruster, they are best suited for direct drive from solar arrays. One advantage of an arcjet over Hall or gridded ion thrusters is that for comparable power the arcjet is a much smaller device and can provide more thrust and orders of magnitude higher thrust density (approximately 1-10 N/sq m), albeit at lower I(sub sp) (approximately 800-1000 s). In addition, arcjets are capable of operating on a wide range of propellant options, having been demonstrated on H2, ammonia, N2, Ar, Kr, Xe, while present SOA Hall and ion thrusters are primarily limited to Xe propellant. Direct-drive is often discussed in terms of Hall thrusters, but they require 250-300 V for operation, which is difficult even with high-voltage solar arrays. The arcjet requires under 100 V, which is more in-line with what is easily possible with a solar array. Direct-drive of an electric propulsion system confers the advantage of reducing or eliminating the power processing unit (PPU) that is typically needed to convert the spacecraft-provided power to the voltage and current needed for thruster operation. Since the PPU is typically the most expensive piece of an electric thruster system, from both a fabrication and qualification standpoint, its elimination offers the potential for major reductions in system cost and risk. The design of the arcjet built for this effort was based on previous low power (1 kW class) arcjets. It has a precision machined 99.95% pure tungsten anode which also serves as the nozzle. The anode constrictor region is 1 mm (0.040-in) diameter and 1 mm (0.040-in) long. The cathode is a tungsten welding electrode doped with LaO2; its tip was precision ground to a 30◦ angle ending in a blunt end. The two electrodes are separated by a boron-nitride insulator which also serves as the propellant injection manifold; it ends in six small holes which introduce the propellant gas in the diverging section of the nozzle, directly adjacent to the cathode. The electrodes and insulator are housed in a stainless-steel outer-body, with a Macor insulator at the mid-plane to provide thermal isolation between the front and back halves of the device. The gas seals were made using Grafoil gaskets. Figure 1A shows the assembled thruster in the vacuum chamber; figure 1B shows the thruster in operation on argon at a flow rate of 676 sccm (20 mg/s). Initial testing was conducted in a 3.5-ft diameter vacuum chamber; the ultimate pressure reached during quasi-steady operation of the thruster was about 330 millitorr. The thruster was powered with a high-current, 0-100A, 15 kW power supply. The discharge was initiated with a high-voltage (approximately 10 kV) spark initiator that was isolated from the supply by a stack of diodes. The testing indicated that an operating point exists within the I-V characteristics that is compatible with direct-drive solar-electric operation; for a flow rate of 20 mg/s (argon) the arc could be sustained at a voltage of about 20 V and a current of 25 A (500W).

Martin, Adam K.↗

NASA NTRSDate not supplied

Heliophysics Environmental & Radiation Measurement Experiment Suite (HERMES): A Small External Payload for the Lunar Gateway with Big Challenges

Currently scheduled for liftoff in 2024, Gateway will be an outpost orbiting the moon for astronauts headed to and from the lunar surface and serve as a staging point for deep space exploration. In January of 2020 NASA headquarters contacted Goddard Space Flight Center to request that they develop a Heliophysics instrumentation package for Gateway. This package would later become known as HERMES-Heliophysics Environmental & Radiation Measurement Experiment Suite. HERMES consists of a Miniaturized Electron pRoton Telescope (MERIT), an Electron Electrostatic Analyzer (EEA), Solar Probe Analyzers (SPAN)-A-ions, and Noise Eliminating Magnetometer Instrument in a Small Integrated System (NEMISIS), which consists of one fluxgate and two Magneto-Inductive Magnetometers. From the beginning the HERMES mission faced a number of Challenges. It was constrained to fit in a small, half meter, cube and it was required to weigh no more than 25kg. A new boom design for the magnetometer would be required and for safety reasons it must be able to retract autonomously with power removed. To complicate matters the location of the SORI-Small ORU- (Orbital Replacement Unit) Robotics Interface, the primary interface for the HERMES platform to the Gateway elements, was undetermined. Also, the mechanical, thermal and electrical interfaces are not fully defined. The Canadian Space Agency is still in process of designing the version of the SORI that will be flown on the Power and Propulsion Element (PPE) and Habitation and Logistics Outpost (HALO) elements, each of which are being developed by different contractors. At the time of initiating the HERMES project, neither of the Gateway module providers were under contract. Additionally, we would later learn the ISS heritage SORI modules were not originally designed for launching on the Gateway elements with a payload directly attached but rather were intended to be brought up on a separate carrier outfitted with launch locks and specialized launch structures from which the robotic arm on Gateway would then be used to detach the payload and install it on the SORI adapters while on orbit. Launching the integrated Payload/SORI on the PPE and HALO elements complicates the stiffness requirements and coupled loads analysis. Adding to this are serious constraints on Field-Of-View (FOV) for solar viewing and severe radiation exposure considerations brought on by slowly raising the orbit through the Van Allen Belts. Just to make things a little more challenging the budget for the entire project was intended to be a low-cost tailored Class-D mission approach. Plus, the effects of Corona VIrus Disease 2019 (COVID-19) were not factored in from the beginning. This paper will discuss what’s being done to overcome these challenges and put HERMES on track for a 2024 Launch Readiness Date (LRD).

Irving Joseph Burt↗

NASA NTRS2012

Spectroscopic Chemical Analysis Methods and Apparatus

This invention relates to non-contact spectroscopic methods and apparatus for performing chemical analysis and the ideal wavelengths and sources needed for this analysis. It employs deep ultraviolet (200- to 300-nm spectral range) electron-beam-pumped wide bandgap semiconductor lasers, incoherent wide bandgap semiconductor lightemitting devices, and hollow cathode metal ion lasers. Three achieved goals for this innovation are to reduce the size (under 20 L), reduce the weight [under 100 lb (.45 kg)], and reduce the power consumption (under 100 W). This method can be used in microscope or macroscope to provide measurement of Raman and/or native fluorescence emission spectra either by point-by-point measurement, or by global imaging of emissions within specific ultraviolet spectral bands. In other embodiments, the method can be used in analytical instruments such as capillary electrophoresis, capillary electro-chromatography, high-performance liquid chromatography, flow cytometry, and related instruments for detection and identification of unknown analytes using a combination of native fluorescence and/or Raman spectroscopic methods. This design provides an electron-beampumped semiconductor radiation-producing method, or source, that can emit at a wavelength (or wavelengths) below 300 nm, e.g. in the deep ultraviolet between about 200 and 300 nm, and more preferably less than 260 nm. In some variations, the method is to produce incoherent radiation, while in other implementations it produces laser radiation. In some variations, this object is achieved by using an AlGaN emission medium, while in other implementations a diamond emission medium may be used. This instrument irradiates a sample with deep UV radiation, and then uses an improved filter for separating wavelengths to be detected. This provides a multi-stage analysis of the sample. To avoid the difficulties related to producing deep UV semiconductor sources, a pumping approach has been developed that uses ballistic electron beam injection directly into the active region of a wide bandgap semiconductor material.

Hug, William F.↗

NASA NTRS2015

Combined Global Navigation Satellite Systems in the Space Service Volume

Besides providing position, navigation, and timing (PNT) services to traditional terrestrial and airborne users, GPS is also being increasingly used as a tool to enable precision orbit determination, precise time synchronization, real-time spacecraft navigation, and three-axis attitude control of Earth orbiting satellites. With additional Global Navigation Satellite System (GNSS) constellations being replenished and coming into service (GLONASS, Beidou, and Galileo), it will become possible to benefit from greater signal availability and robustness by using evolving multi-constellation receivers. The paper, "GPS in the Space Service Volume," presented at the ION GNSS 19th International Technical Meeting in 2006 (Ref. 1), defined the Space Service Volume, and analyzed the performance of GPS out to seventy thousand kilometers. This paper will report a similar analysis of the signal coverage of GPS in the space domain; however, the analyses will also consider signal coverage from each of the additional GNSS constellations noted earlier to specifically demonstrate the expected benefits to be derived from using GPS in conjunction with other foreign systems. The Space Service Volume is formally defined as the volume of space between three thousand kilometers altitude and geosynchronous altitude circa 36,000 km, as compared with the Terrestrial Service Volume between 3,000 km and the surface of the Earth. In the Terrestrial Service Volume, GNSS performance is the same as on or near the Earth's surface due to satellite vehicle availability and geometry similarities. The core GPS system has thereby established signal requirements for the Space Service Volume as part of technical Capability Development Documentation (CDD) that specifies system performance. Besides the technical discussion, we also present diplomatic efforts to extend the GPS Space Service Volume concept to other PNT service providers in an effort to assure that all space users will benefit from the enhanced interoperability of GNSS services in the space domain. A separate paper presented at the conference covers the individual GNSS performance parameters for respective Space Service Volumes.

navigation satellites↗

NASA NTRS2004

Simulations of Solar Wind Plasma Flow Around a Simple Solar Sail

In recent years, a number of solar sail missions of various designs and sizes have been proposed (e.g., Geostorm). Of importance to these missions is the interaction between the ambient solar wind plasma environment and the sail. Assuming a typical 1 AU solar wind environment of 400 km/s velocity, 3.5 cu cm density, ion temperature of approx.10 eV, electron temperature of 40 eV, and an ambient magnetic field strength of 10(exp -4) G, a first order estimate of the plasma interaction with square solar sails on the order of the sizes being considered for a Geostorm mission (50 m x 50 m and 75 m x 75 m corresponding to approx.2 and approx.3 times the Debye length in the plasma) is carried out. First, a crude current balance for the sail surface immersed in the plasma environment and in sunlight was used to estimate the surface potential of the model sails. This gave surface potentials of approx.10 V positive relative to the solar wind plasma. A 3-D, Electrostatic Particle-in-Cell (PIC) code was then used to simulate the solar wind flowing around the solar sail. It is assumed in the code that the solar wind protons can be treated as particles while the electrons follow a Boltzmann distribution. Next, the electric field and particle trajectories are solved self-consistently to give the proton flow field, the electrostatic field around the sail, and the plasma density in 3-D. The model sail was found to be surrounded by a plasma sheath within which the potential is positive compared to the ambient plasma and followed by a separate plasma wake which is negative relative to the plasma. This structure departs dramatically from a negatively charged plate such as might be found in the Earth s ionosphere on the night side where both the plate and its negative wake are contiguous. The implications of these findings are discussed as they apply to the proposed Geostorm solar sail mission.

Garrett, Henry B.↗

NASA NTRS2002

The Winds of B Supergiants

We present the most suitable data sets available in the International Ultraviolet Explorer (IUE) archive for the study of time-dependent stellar winds in early B supergiants. The UV line profile variability in 11 B0 to B3 stars is analyzed, compared and discussed, based on 16 separate data sets comprising over 600 homogeneously reduced high-resolution spectrograms. The targets include 'normal' stars with moderate rotation rates and examples of rapid rotators. A gallery of grey-scale images (dynamic spectra) is presented, which demonstrates the richness and range of wind variability and highlights different structures in the winds of these stars. This work emphasizes the suitability of B supergiants for wind studies, under-pinned by the fact that they exhibit unsaturated wind lines for a wide range of ionization. The wind activity of B supergiants is substantial and has highly varied characteristics. The variability evident in individual stars is classified and described in terms of discrete absorption components, spontaneous absorption, bowed structures, recurrence, and ionization variability and stratification. Similar structures can occur in stars of different fundamental parameters but also different structures may occur in the same star at a given epoch. We discuss the physical phenomena that may be associated with the spectral signatures, and highlight the challenges that these phenomena present to theoretical studies of time-dependent outflows in massive stars. In addition, SEI line-synthesis modelling of the UV wind lines is used to provide further information about the state of the winds in our program stars. Typically the range, implied by the line profile variability, in the product of mass-loss rate and ion fraction (M qi) is a factor of approximately 1.5, when integrated between 0.2 and 0.9 v infinity; it it can however be several times larger over localized velocity regions. At a given effective temperature the mean relative ion ratios can differ by a factor of 5. The general excess in predicted (forward-scattered) emission in the low velocity regime is discussed in turns of structured outflows. Mean ion fractions are estimated over the B0 to B1 spectral classes, and trends in the ionic ratios as a function of wind velocity are described. The low values obtained for the ion fractions of UV resonance lines may reflect the role of clumping in the wind.

Massa, Derck↗

NASA NTRS2002

The Winds of B Supergiants

We present the most suitable data sets available in the International Ultraviolet Explorer (IUE) archive for the study of time-dependent stellar winds in early B supergiants. The UV line profile variability in 11 B0 to B3 stars is analyzed, compared and discussed, based on 16 separate data sets comprising over 600 homogeneously reduced high-resolution spectrograms. The targets include 'normal' stars with moderate rotation rates and examples of rapid rotators. A gallery of grey-scale images (dynamic spectra) is presented, which demonstrates the richness and range of wind variability and highlights different structures in the winds of these stars. This work emphasises the suitability of B supergiants for wind studies, under-pinned by the fact that they exhibit unsaturated wind lines for a wide range of ionization. The wind activity of B supergiants is substantial and has highly varied characteristics. The variability evident in individual stars is classified and described in terms of discrete absorption components, spontaneous absorption, bowed structures, recurrence, and ionization variability and stratification. Similar structures can occur in stars of different fundamental parameters, but also different structures may occur in the same star at a given epoch. We discuss the physical phenomena that may be associated with the spectral signatures, and highlight the challenges that these phenomena present to theoretical studies of time-dependent outflows in massive stars. In addition, SEI line-synthesis modelling of the UV wind lines is used to provide further information about the state of the winds in our program stars. Typically the range, implied by the line profile variability, in the product of mass-loss rate and ion fraction (M (dot) q(sub i)) is a factor of approximately 1.5, when integrated between 0.2 and 0.9 v infinity; it can however be several times larger over localized velocity regions. At a given effective temperature the mean relative ion ratios can differ by a factor of 5. The general excess in predicted (forward-scattered) emission in the low velocity regime is discussed in terms of structured outflows. Mean ion fractions are estimated over the B0 to B1 spectral classes, and trends in the ionic ratios as a function of wind velocity are described. The low values obtained for the ion fractions of UV resonance lines may reflect the role of clumping in the wind.

Massa, D.↗

NASA NTRS2019

FUN3D and USM3D Analysis of the 4th AIAA Propulsion Aerodynamics Workshop Nozzle Test Case

This work presents the results of FUN3D and USM3D analyses that were performed for the 4th AIAA Propulsion Aerodynamics Workshop. The workshop was separated into three sections that focus on internal duct flows, nozzle flows, and a special topic of interest. This paper focuses on the nozzle section while an accompanying paper discusses the analyses performed for the internal duct flow section. For the nozzle flow section, the participants were provided with two configurations consisting of a rectangular convergent nozzle with and without an aft-deck. User-generated grids were developed under the guidelines of the workshop for the present analyses. The results show that both solvers compare favorably to the experimental results for the baseline nozzle with the largest differences observed at the lower NPR values. Additionally, both solvers showed favorable agreement with the experimental data for the pressures on the surface of the aft-deck. However, neither solver was able to match the jet flow further downstream for the nozzle with aft-deck configuration. A turbulence model study was conducted to compare the two-equation SST model, SA-QCR model, and two-equation k-kL model (FUN3D only). The results show that the SA-QCR turbulence model was unable to match the experimental results downstream of the nozzle. The k-kL model was shown to better match the experimental data compared to the SST model for most cases simulated using the FUN3D flow solver. Suggestions for future workshops include gridding guidelines similar ion Workshop series for the grid refinement study and a reduction in scope to allow for more detailed exploration of the individual problems. rticipation by reducing time requirements

Bozeman, Michael D.↗

NASA NTRS1989

Electrocatalysts for oxygen electrodes in fuel cells and water electrolyzers for space applications

In most instances separate electrocatalysts are needed to promote the reduction of O2 in the fuel cell mode and to generate O2 in the energy storage-water electrolysis mode in aqueous electrochemical systems operating at low and moderate temperatures (T greater than or equal to 200 C). Interesting exceptions are the lead and bismuth ruthenate pyrochlores in alkaline electrolytes. These catalysts on high area carbon supports have high catalytic activity for both O2 reduction and generation (1,2). Rotating ring-disk electrode measurements provide evidence that the O2 reduction proceeds by a parallel four-electron pathway. The ruthenates can also be used as self-supported catalysts to avoid the problems associated with carbon oxidation, but the electrode performance so far achieved in the research at Case Western Reserve University (CWRU) is considerably less. At the potentials involved in the anodic mode the ruthenate pyrochlores have substantial equilibrium solubility in concentrated alkaline electrolyte. This results in the loss of catalyst into the bulk solution and a decline in catalytic activity. Furthermore, the hydrogen generation counter electrode may become contaminated with reduction products from the pyrochlores (lead, ruthenium). A possible approach to this problem is to immobilize the pyrochlore catalyst within an ionic-conducting solid polymer, which would replace the fluid electrolyte within the porous gas diffusion O2 electrode. For bulk alkaline electrolyte, an anion-exchange polymer is needed with a transference number close to unity for the Oh(-) ion. Preliminary short-term measurements with lead ruthenates using a commercially available partially-fluorinated anion-exchange membrane as an overlayer on the porous gas-fed electrode indicate lower anodic polarization and virtually unchanged cathodic polarization.

Prakash, Jai↗

NASA NTRS2012

Analysis of Direct Samples of Early Solar System Aqueous Fluids

Over the past three decades we have become increasingly aware of the fundamental importance of water, and aqueous alteration, on primitive solar-system bodies. Some carbonaceous and ordinary chondrites have been altered by interactions with liquid water within the first 10 million years after formation of their parent asteroids. Millimeter to centimeter-sized aggregates of purple halite containing aqueous fluid inclusions were found in the matrix of two freshly-fallen brecciated H chondrite falls, Monahans (1998, hereafter simply "Monahans") (H5) and Zag (H3-6) (Zolensky et al., 1999; Whitby et al., 2000; Bogard et al., 2001) In order to understand origin and evolution of the aqueous fluids inside these inclusions we much measure the actual fluid composition, and also learn the O and H isotopic composition of the water. It has taken a decade for laboratory analytical techniques to catch up to these particular nanomole-sized aqueous samples. We have recently been successful in (1) measuring the isotopic composition of H and O in the water in a few fluid inclusions from the Zag and Monahans halite, (2) mineralogical characterization of the solid mineral phases associated with the aqueous fluids within the halite, and (3) the first minor element analyses of the fluid itself. A Cameca ims-1270 equipped with a cryo-sample-stage of Hokkaido University was specially prepared for the O and H isotopic measurements. The cryo-sample-stage (Techno. I. S. Corp.) was cooled down to c.a. -190 C using liquid nitrogen at which the aqueous fluid in inclusions was frozen. We excavated the salt crystal surfaces to expose the frozen fluids using a 15 keV Cs+ beam and measured negative secondary ions. The secondary ions from deep craters of approximately 10 m in depth emitted stably but the intensities changed gradually during measurement cycles because of shifting states of charge compensation, resulting in rather poor reproducibility of multiple measurements of standard fluid inclusions of +/- 90 0/00(2 sigma) for delta D, and +/- 29 0/00 (2 sigma) for delta O-18. On the other hand, the reproducibility of Delta O-17 is plus or minus 8 /00 (2 sigma ) because the observed variations of isotope ratios follow a mass dependent fractionation law. Variations of delta D of the aqueous fluids range over sog,a 330(90; 2 sigma ) to +1200(90) 0/00 for Monahans and delta 300(96) 0/00 to +90(98)0/00 for Zag. Delta O-17 of aqueous fluids range over delta 16(22) 0/00 to +18(10) 0/00 for Monahans and +3(10) 0/00 to +27(11) 0/00 for Zag. These variations are larger than the reproducibility of standard analyses and suggest that isotope equilibria were under way in the fluids before trapping into halite. The mean values of delta D and Delta O-17 are +290 0/00 and +9 0/00, respectively. The mean values and the variations of these fluids are different from the representative values of ordinary chondrites, verifying our working hypothesis that the fluid inclusion-bearing halites were not indigenous to the H chondrite parent-asteroid but rather represent exogenous material delivered onto the asteroid from a separate cryovolcanically-active body. This initial isotopic work has demonstrated the feasibility of the measurements, but also revealed sample processing and analytical shortcomings that are now being addressed. Examination of solid mineral inclusions within Monahans and Zag halite grains by confocal Raman spectroscopy at the Carnegie Geophysical Laboratory has revealed them to be metal, magnetite, forsteritic olivine (Fo.98), macromolecular carbon (MMC), pyroxenes, feldspar with Raman spectral affinity to anorthoclase and, probably, fine-grained lepidocrocite (FeO(OH)). In addition, one inclusion features aliphatic material with Raman spectral features consistent with a mixture of short-chain aliphatic compounds. We have initiated analyses of the bulk composition of the fluids within the inclusions in Zag and Monahans halites at Virginia Tech by LA ICPMS using angilent 7500ce quadrupole ICPMS and a Lambda Physik GeoLas 193 nm excimer laser ablation system. Preliminary results reveal that the inclusion aqueous fluids contain highly charged cations of Ca, Mg and Fe. The minerals and compounds discovered thus far within Monahans/Zag halites are indicative of an originating body at least partly composed of unequilibrated anhydrous materials (high Fo olivine, pyroxenes, feldspars, possibly the metal) which were subjected to aqueous alteration (the halite parent brine) and containing a light organic component (the short-chain aliphatic compounds). This material was ejected from the originating body with little or no disruption, as evidenced with the presence of fluid inclusions. An actively geysering body similar to modern Enceladus (Postberg et al., 2011) may be a reasonable analogue in this respect. Also, the originating body should have been within close proximity to the H chondrite parent in order to generate the number of halite grains seen in Monahans and Zag. Other candidates for Monahans/Zag halite parent bodie(s) may include a young Ceres with its possible liquid ocean, or Main Belt comets.

Zolensky, Michael E.↗

NASA NTRS1994

Effect of B(sub y) on neutral line ridges and dynamical source ordering

In this paper we study the effect of a uniform magnetic field B(sub y) in the cross-tail y direction on the dynamics and distribution of energetic ions in a current sheet model including a neutral line. Martin and Speiser (1988) have previously shown that a 'ridge' in the velocity space distribution function is a remote neutral line signature in a two-dimensional field without B(sub y). Our results show that as B(sub y) is increased, using nominal tail parameters, there is very little change in the ridge signature for small B(sub y) (up to about 4 times B(sub z)). For intermediate values (up to about 10 times times B(sub Y)) the ridge becomes observable further from the neutral line, while close to the X line the ridge is strongly modified. For large B(sub y) (of the order of B(sub x)) the ridge evolves into the new neutral line signatures which depend strongly on whether the observations point is above or below the current sheet. These results are used to estimate B(sub y) less than 2 nT in the Active Magentospheric Particle Traces Explorers/Ion Release Module (AMPTE/IRM) event modeled by Speiser and Martin (1994), which is consistent with onboard magnetometer measurements. We further show that the cause of the new structures appearing at large B(sub Y) is the same source seperation effect that produced the original ridge and that all these signatures are relatively insensitive to a small parallel electric field. Finally, we point our a dynamical ordering which occurs at large B(sub y): Using high-resolution simulations, we find a common boundary separating regions of positive and negative initial x, y, and z position, as well as initial pitch angle. This boundary is purely dynamical in nature and is independent of modeled source distributions.

Martin, R. F., Jr.↗

NASA NTRS2013

Method for Reduction of Silver Biocide Plating on Metal Surfaces

Silver ions in aqueous solutions (0.05 to 1 ppm) are used for microbial control in water systems. The silver ions remain in solution when stored in plastic containers, but the concentration rapidly decreases to non-biocidal levels when stored in metal containers. The silver deposits onto the surface and is reduced to non-biocidal silver metal when it contacts less noble metal surfaces, including stainless steel, titanium, and nickel-based alloys. Five methods of treatment of contact metal surfaces to deter silver deposition and reduction are proposed: (1) High-temperature oxidation of the metal surface; (2) High-concentration silver solution pre-treatment; (3) Silver plating; (4) Teflon coat by vapor deposition (titanium only); and (5) A combination of methods (1) and (2), which proved to be the best method for the nickel-based alloy application. The mechanism associated with surface treatments (1), (2), and (5) is thought to be the development of a less active oxide layer that deters ionic silver deposition. Mechanism (3) is an attempt to develop an equilibrium ionic silver concentration via dissolution of metallic silver. Mechanism (4) provides a non-reactive barrier to deter ionic silver plating. Development testing has shown that ionic silver in aqueous solution was maintained at essentially the same level of addition (0.4 ppm) for up to 15 months with method (5) (a combination of methods (1) and (2)), before the test was discontinued for nickel-based alloys. Method (1) resulted in the maintenance of a biocidal level (approximately 0.05 ppm) for up to 10 months before that test was discontinued for nickel-based alloys. Methods (1) and (2) used separately were able to maintain ionic silver in aqueous solution at essentially the same level of addition (0.4 ppm) for up to 10 months before the test was discontinued for stainless steel alloys. Method (3) was only utilized for titanium alloys, and was successful at maintaining ionic silver in aqueous solution at essentially the same level of addition (0.4 ppm) for up to 10 months before the test was discontinued for simple flat geometries, but not for geometries that are difficult to Teflon coat.

Steele, John↗

NASA NTRS1999

High-Resolution Mapping of Lunar Crustal Magnetic Fields: Correlations with Albedo Markings of the Reiner Gamma Class

During the last eight months of the Lunar Prospector mission (December 1999-July 1999), the spacecraft was placed in a relatively low-altitude (15-30-km perapsis), near-polar orbit that allowed high-resolution mapping of crustal magnetic fields. We report here initial studies of the correlation of locally strong magnetic anomalies with unusual, swirl-like albedo markings of the Reiner Gamma class. Based on this correlation, which is known from earlier studies of Apollo subsatellite magnetometer data, it has been proposed that the swirls represent regions whose higher albedos have been preserved via deflection of the solar-wind ion bombardment by strong crustal fields. This model in turn depends on the hypothesis that solar-wind implanted H is at least one component of the process that optically matures exposed silicate surfaces in the inner solar system . Specifically, it is hypothesized that implanted H acts as an effective reducing agent to enhance the rate of production of nanophase metallic Fe particles from preexisting silicates during micrometeoroid impacts. According to the model, the curvilinear shapes of these albedo markings are caused, at least in part, by the geometry of ion deflections in a magnetic field. The improved resolution and coverage of the Prospector data allow more detailed mapping of the fields, especially on the lunar farside. This permits a more quantitative test of whether all albedo markings of this class are associated with strong local magnetic fields.Only if the latter condition is met can the solar-wind deflection hypothesis he valid. The basic procedure for mapping crustal magnetic fields using Lunar Prospector magnetometer data follows that developed for analysis of Apollo subsatellite magnetometer data. The specific mapping steps are (1) selection of mission time intervals suitable for mapping crustal fields; these are limited essentially either to times when the Moon is in a lobe of the geomagnetic tail or to times when the Moon is in the solar wind but the spacecraft is in the lunar wake; the data are transformed to a radial, east, and north coordinate system with measurements given as a function of spacecraft latitude, longitude, and altitude; (2) visual editing of individual orbit segments selected for minimal external field disturbances; (3) minimization of remaining low-frequency external fields for individual orbit data segments by quadratic detrending; and (4) two-dimensional filtering of individual orbit segments to produce a vector field map along the slightly curved surface defined by the spacecraft altitude; maps of the three field components (radial, east, and north), the field magnitude, and the spacecraft altitude are constructed. For data obtained at low to middle latitudes, the horizontal resolution of the field maps is limited by the orbit-track separation (about 30 km at the equator). Maps of the field magnitude have been constructed within limited selenographic regions based mainly on data acquired in March, April, and May of 1999. This was a time period when the orbit plane was nearly aligned with the Sun-Moon line so that field mapping was possible at times when the Moon was in the solar wind as well as when the Moon was in the geomagnetic tail. Most of the coverage is across the lunar farside. However, a shows an example of a field map produced from solar-wind wake data for a region including Reiner Gamm on western Oceanus Procellarum (location: 58.5W, 7.5N). The contour interval is 3 nT and the mean spacecraft altitude is 18 km to within the accuracy allowed by the resolution of the map (30 km or about 1 deg.); strong magnetic anomalies correlate closely with swirl locations. Individual orbit profiles (whose resolution along the orbit track is comparable to the spacecraft altitude of 18 km) also demonstrate a good correlation of field magnitude with surface albedo. In order to investigate the correlation of magnetic fields with the location of swirl features, we have reexamined available lunar imagery (Lunar Orbiter, Apollo, and Clementine) to identify and map swirl locations within regions where swirls have previously been mapped. In these images, swirls were distinguished from other high-albedo features such as crater rays by their curvilinear shapes and increased visibility in forward-scattered light. Digital maps of swirls identified by all available imagery were then superposed on maps of the field magnitude at the spacecraft altitude. Based upon analysis of these composite magnetic/geologic maps, we draw the preliminary conclusion that swirl features are associated with magnetic anomalies revealed by Lunar Prospector. Detailed maps of these swirl features are currently being constructed for the magnetically strong regions antipodal to the Imbrium, Serenitatis, and Crisium Basins. Additional information contained in the original,

Hood, L. L.↗

NASA NTRS2008

Composite Cathodes for Dual-Rate Li-Ion Batteries

Composite-material cathodes that enable Li-ion electrochemical cells and batteries to function at both high energy densities and high discharge rates are undergoing development. Until now, using commercially available cathode materials, it has been possible to construct cells that have either capability for high-rate discharge or capability to store energy at average or high density, but not both capabilities. However, both capabilities are needed in robotic, standby-power, and other applications that involve duty cycles that include long-duration, low-power portions and short-duration, high-power portions. The electrochemically active ingredients of the present developmental composite cathode materials are: carbon-coated LiFePO4, which has a specific charge capacity of about 160 mA h/g and has been used as a high-discharge-rate cathode material and Li[Li(0.17)Mn(0.58)Ni(0.25)]O2, which has a specific charge capacity of about 240 mA h/g and has been used as a high-energy-density cathode material. In preparation for fabricating the composite material cathode described, these electrochemically active ingredients are incorporated into two sub-composites: a mixture comprising 10 weight percent of poly(vinylidine fluoride); 10 weight percent of carbon and 80 weight percent of carbon coated LiFePO4; and, a mixture comprising 10 weight percent of PVDF, and 80 weight percent of Li[Li(0.17)Mn(0.58)Ni(0.25)]O2. In the fabrication process, these mixtures are spray-deposited onto an aluminum current collector. Electrochemical tests performed thus far have shown that better charge/discharge performance is obtained when either 1) each mixture is sprayed on a separate area of the current collector or (2) the mixtures are deposited sequentially (in contradistinction to simultaneously) on the same current-collector area so that the resulting composite cathode material consists of two different sub-composite layers.

Whitacre, Jay↗

NASA NTRS2003

Dynamical and Physical Properties of a Post-Coronal Mass Ejection Current Sheet

In the eruptive process of the Kopp-Pneuman type, the closed magnetic field is stretched by the eruption so much that it is usually believed to be " open " to infinity. Formation of the current sheet in such a configuration makes it possible for the energy in the coronal magnetic field to quickly convert into thermal and kinetic energies and cause significant observational consequences, such as growing postflare/CME loop system in the corona, separating bright flare ribbons in the chromosphere, and fast ejections of the plasma and the magnetic flux. An eruption on 2002 January 8 provides us a good opportunity to look into these observational signatures of and place constraints on the theories of eruptions. The event started with the expansion of a magnetic arcade over an active region, developed into a coronal mass ejection (CME), and left some thin streamer-like structures with successively growing loop systems beneath them. The plasma outflow and the highly ionized states of the plasma inside these streamer-like structures, as well as the growing loops beneath them, lead us to conclude that these structures are associated with a magnetic reconnection site, namely, the current sheet, of this eruptive process. We combine the data from the Ultraviolet Coronagraph Spectrometer, Large Angle and Spectrometric Coronagraph Experiment, EUV Imaging Telescope, and Coronal Diagnostic Spectrometer on board the Solar and Heliospheric Observatory, as well is from the Mauna Loa Solar Observatory Mark IV K-coronameter, to investigate the morphological and dynamical properties of this event, as well as the physical properties of the current sheet. The velocity and acceleration of the CME reached up to 1800 km/s and 1 km/sq s, respectively. The acceleration is found to occur mainly at the lower corona (<2.76 Solar Radius). The post-CME loop systems showed behaviors of both postflare loops (upward motion with decreasing speed) and soft X-ray giant arches (upward motion with constant speed, or acceleration) according to the definition of Svestka. In the current sheet, the presence of highly ionized ions, such as Fe(+17) and Ca(+13), suggests temperature as high as (3-4) x 10(exp 6) K, and the plasma outflows have speeds ranging from 300 to 650 km/s. Absolute elemental abundances in the current sheet show a strong first ionization potential effect and have values similar to those found in the active region streamers. The magnetic field strength in the vicinity of the current sheet is found to be of the order of 1 G.

Ko, Yuan-Kuen↗

NASA NTRS2005

Removal of organic contaminants by RO and NF membranes

Rejection characteristics of organic and inorganic compounds were examined for six reverse osmosis (RO) membranes and two nanofiltration (NF) membranes that are commercially available. A batch stirred-cell was employed to determine the membrane flux and the solute rejection for solutions at various concentrations and different pH conditions. The results show that for ionic solutes the degree of separation is influenced mainly by electrostatic exclusion, while for organic solutes the removal depends mainly upon the solute radius and molecular structure. In order to provide a better understanding of rejection mechanisms for the RO and NF membranes, the ratio of solute radius (r(i,s)) to effective membrane pore radius (r(p)) was employed to compare rejections. An empirical relation for the dependence of the rejection of organic compounds on the ratio r(i,s)/r(p) is presented. The rejection for organic compounds is over 75% when r(i,s)/r(p) is greater than 0.8. In addition, the rejection of organic compounds is examined using the extended Nernst-Planck equation coupled with a steric hindrance model. The transport of organic solutes is controlled mainly by diffusion for the compounds that have a high r(i,s)/r(p) ratio, while convection is dominant for compounds that have a small r(i,s)/r(p) ratio. c2005 Elsevier B.V. All rights reserved.

NASA Discipline Life Sciences Technologies↗

NASA NTRS1988

Effect of salicylhydroxamic acid on endosperm strength and embryo growth of Lactuca sativa L. cv Waldmann's Green seeds

Salicylhydroxamic acid (SHAM) stimulated germination of photosensitive lettuce (Lactuca sativa L. cv Waldmann's Green) seeds in darkness. To determine whether SHAM acts on the embryo or the endosperm, we investigated separately effects of SHAM on growth potential of isolated embryos as well as on endosperm strength. Embryo growth potential was quantified by incubating decoated embryos in various concentrations of osmoticum and measuring subsequent radicle elongation. Growth potential of embryos isolated from seeds pretreated with 4 millimolar SHAM was equal to that of untreated controls. Rupture strength of endosperm tissue excised from seeds pretreated with SHAM was 33% less than that of controls in the micropylar region. To determine if the embryo must be in contact with the endosperm of SHAM to weaken the endosperm, some endosperms were incubated with SHAM only after dissection from seeds. Rupture strength of SHAM-treated, isolated endosperms in the micropylar region was 25% less than that of untreated controls. There was no difference in rupture strength in the cotyledonary region of endosperm isolated from seeds treated with SHAM in buffer or buffer alone. SHAM therefore stimulates germination not by enhancing embryo growth potential, but by weakening the micropylar region of the endosperm enclosing the embryo.

NASA Discipline Plant Biology↗

NASA NTRSDate not supplied

Oxygen Isotopic Composition of Refractory Inclusions from the Miller Range (MIL) 090019 Carbonaceous Chondrite

Introduction: Primitive meteorites contain Calcium-Aluminum-rich Inclusions (CAIs)that preserve the records of the earliest times in the Solar System. CAIs record O isotopic variations with time and/or location from solar (16O-rich) to planetary (16O-poor) compositions [e.g., 1, 2].However, CAIs were also affected by parent body processing to varying degrees. The goal of this work was to identify the processes that resulted in the fine-scale spatial variations in oxygen isotopic compositions within the most ancient Solar System solids. We report oxygen isotopic composition of CAIs from MIL 090019 CO3.1 carbonaceous chondrite. MIL 090019 contains a high abundance of CAIs showing mineralogical as well as textural variations [3]. Methods: We analyzed 10 CAIs with different mineralogical assemblages, classified as corundum-bearing, grossite-bearing, hibonite-bearing, melilite-bearing, anorthite-bearing inclusions and amoeboid olivine aggregates(AOA’s). The mineralogical and petrological characterization of CAIs was performed using the JOEL Hyperprobe 8530 electron microprobe at NASA JSC. Oxygen isotopic imaging of the CAIs was done using the Cameca NanoSIMS 50L ion microprobe at NASA JSC. We followed the analytical protocol described in [4]. O-isotopic maps of the CAI were acquired by rastering a ~3 pA primary Cs+beam at 16 keVover an area of 20 ×20μm2over a period of ~7 hours. Negative secondary ions of 16O−, 17O−, 18O−, 28Si−, 24Mg16O−, 27Al16O−, and 40Ca16O−were simultaneously acquired using electron multiplier detectors at a mass resolving power sufficient to resolve the 16OH−interference from the 17O−peak, where the contribution of 16OH−was <0.1%.An electron flood gun was used to mitigate sample charging during the analyses. We used San Carlos olivine and Madagascar hibonite as isotopic standards to correct for the instrumental mass fractionation. The O-isotopic ratios were corrected for the quasi simultaneous arrival (QSA) effect and the detector dead time. All reported errors are 1 sigma. Results: The MIL 090019 carbonaceous chondrite hosts refractory inclusions varying in their mineralogies and textures[2, 3]. We found the oxygen isotopic compositions of mineral phases in MIL 090019 CAIs show large variations with Δ17O values varying from -27 to 0‰. A corundum-bearing inclusion records isotopic variations with corundum, melilite, perovskite, and anorthite showing Δ17Ovalues of -20 ±2.5, -10.2 ± 6.5, -10.7 ± 1.3,and -1.2 ± 3.2‰ respectively. A grossite-hibonite-bearing inclusion also records O-isotopic heterogeneity, where grossite, hibonite, Mg-rich spinel, and melilite show -3.7 ± 2.7, -22.9 ± 2.5, -21.4 ± 2.6, and -17.3 ± 2.8‰ respectively, whereas perovskite grains record a heterogenous isotopic composition ranging from -22.6 to -13.9‰. A hibonite-bearing inclusion shows average Δ17Ο values of -17.6 ± 5.3 ‰ and -15.1 ± 4.8 ‰ for hibonite and spinel respectively. The two perovskite grains also show relatively 16O-poor composition (Δ17Ο = -11.8 ± 6.4 ‰ and -8.6 ± 5.2 ‰). Anorthite has ~0.1 wt% Na2O and ~0.52 wt% FeO and a Δ17Ο value of -7.2 ± 5.0 ‰, whereas diopside records a Δ17Ο value of -3.5 ± 5.0 ‰. A hibonite-spinel-rich inclusion contains spinel and hibonite that are16O-rich (Δ17Οvalues -21.3 ± 2.8‰ and -19.4 ± 3.0‰, respectively). Melilite shows heterogenous oxygen isotopic composition, with an inner 16O-rich region and an outer 16O-poor region separated by a sharp boundary, with a bulk Δ17Ο= -16.2 ± 2.1‰, whereas two perovskite grains are relatively 16O-poor (Δ17Ο= -13.2 ± 3.7‰ and -7.1 ± 3.4‰).A spinel-rich inclusion contains perovskite grains with Δ17Οranging from -27.0 to -22.8 ‰and spinel with average Δ17Οvalue of -21.4 ± 2.8 ‰. In a melilite and spinel-rich CAI, perovskite, spinel, diopside, melilite, and Al-Ti-rich pyroxene record Δ17Ο values of-26.9 ± 4.6‰, -22.4 ± 4.3‰,-23.4 ± 4.9, -19.3 ± 3.4, and -19.0 ± 4.3 ‰ respectively. Olivine and spinel components of 2 AOA’s record a 16O-rich composition with Δ17O~-23‰. Discussion: The coexistence of 16O-rich and 16O-poor minerals within CAIs has been attributed to differing degrees of O isotopic exchange, reflecting a wide range of O diffusion rates[5]. However, the O isotopic heterogeneity observed in these CAIs cannot be explained by oxygen diffusion in nebular or parent body settings alone. The isotopic imaging of CAIs from the MIL 090019 meteorite shows variations in the O isotopic composition recorded in their mineral components, suggesting that these CAIs record the oxygen isotopic heterogeneity in the nebular gas from which they condensed. The coexistence of 16O-rich and 16O-poor mineral components in the CAI-forming region suggests that the gas in this region was not well-mixed and consisted of distinct 16O-rich and 16O-poor gaseous reservoirs.

P Mane↗