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At least 883 records · Page 49
All sourcesNASA NTRSDOE OSTI
NASA NTRS1982

Solar irradiance variations and solar activity

A mean value for the 1 AU total solar irradiance of 1368.2 W/sq m and a downward trend of 0.05% per year were derived from measurements by the Active Cavity Radiometer Irradiance Monitor (ACRIM) experiment on the Solar Maximum Mission during 1980. Distinct temporary solar irradiance decreases associated with solar activity maxima were observed with a series of nine dips from April to October recurring at fairly regular intervals averaging 24 days. The decreases correlate inversely with sunspot area, 2800-MHz flux, and Zurich sunspot number. Dominant periods common to the irradiance and sunspot area power spectra link the irradiance decreases to sunspot flux deficit in solar active regions. Evidence of significant total irradiance modulation by facular flux excess is cited. A persistent radiative cycle of active regions consistent with the ACRIM irradiance results and the morphology of solar active regions was found. The pattern of regularly recurrent active region maxima between April and October suggests an asymmetry in solar activity generation during this period.

Willson, R. C.↗
NASA NTRS1987

The calculated influence of atmospheric conditions on solar cell ISC under direct and global solar irradiances

Calculations of the influence of atmospheric conditions on solar cell short-circuit current (Isc) are made using a recently developed computer model for solar spectral irradiance distribution. The results isolate the dependence of Isc on changes in the spectral irradiance distribution without the direct influence of the total irradiance level. The calculated direct normal irradiance and percent diffuse irradiance are given as a reference to indicate the expected irradiance levels. This method can be applied to the calibration of photovoltaic reference cells. Graphic examples are provided for amorphous silicon and monocrystalline silicon solar cells under direct normal and global normal solar irradiances.

Mueller, Robert L.↗
NASA NTRS1992

Variations in solar Lyman alpha irradiance on short time scales

Variations in solar UV irradiance at Lyman alpha are studied on short time scales (from days to months) after removing the long-term changes over the solar cycle. The SME/Lyman alpha irradiance is estimated from various solar indices using linear regression analysis. In order to study the nonlinear effects, Lyman alpha irradiance is modeled with a 5th-degree polynomial as well. It is shown that the full-disk equivalent width of the He line at 1083 nm, which is used as a proxy for the plages and active network, can best reproduce the changes observed in Lyman alpha. Approximately 72 percent of the solar-activity-related changes in Lyman alpha irradiance arise from plages and the network. The network contribution is estimated by the correlation analysis to be about 19 percent. It is shown that significant variability remains in Lyman alpha irradiance, with periods around 300, 27, and 13.5d, which is not explained by the solar activity indices. It is shown that the nonlinear effects cannot account for a significant part of the unexplained variation in Lyman alpha irradiance. Therefore, additional events (e.g., large-scale motions and/or a systematic difference in the area and intensity of the plages and network observed in the lines of Ca-K, He 1083, and Lyman alpha) may explain the discrepancies found between the observed and estimated irradiance values.

Pap, J. M.↗
NASA NTRS1994

Observed solar UV irradiance variations of importance to middle atmosphere energetics and photochemistry

Absorption of solar UV irradiance in the spectral interval 120-420 nm is chiefly responsible for radiative heating and photodissociation of important atmospheric constituents (e.g., O2, O3, H2O, NO2, etc.) in the stratosphere, mesosphere, and lower thermosphere. Thus, the absolute value and time perturbations of the UV irradiance could significantly affect the energetics, photochemistry, and subsequent dynamics of these regions. Analysis of preliminary data from the SOLSTICE (UARS) observations for a period of 244 days (3 Oct 1991-2 Jun 1992) is discussed in this paper. The data provide mean daily values of the spectral distribution of the observed irradiances at 1-nm resolution and their solar rotation and semirotation variations. The average amplitudes of the 27-day irradiance oscillations for the 244-day data period were 5.7% at Lyman-alpha (121 nm), 1% at 200 nm, 0.5% at 210 nm, and generally less than 0.2% at wavelengths longer than 280 nm. The average amplitudes of 13.5-day oscillations were, by and large, about half of these values. Solar irradiance variations at 10.7 cm are highly correlated with those at Ly-alpha and other chromospheric emission lines (r = 0.7 to 0.8) and only moderately correlated with irradiances at wavelengths of 180-208 nm (r = 0.5). The correlation decreases as the source region of the irradiance gets closer to the base of the photosphere. At the 2-nm interval 279-281 nm, however, which contains the cores of the Mg II h and k lines, the correlation is again approximately 0.8.

London, Julius↗
NASA NTRS1995

Response of the upper atmosphere to variations in the solar soft x-ray irradiance

Terrestrial far ultraviolet (FUV) airglow emissions have been suggested as a means for remote sensing the structure of the upper atmosphere. The energy which leads to the excitation of FUV airglow emissions is solar irradiance at extreme ultraviolet (EUV) and soft x-ray wavelengths. Solar irradiance at these wavelengths is known to be highly variable; studies of nitric oxide (NO) in the lower thermosphere have suggested a variability of more than an order of magnitude in the solar soft x-ray irradiance. To properly interpret the FUV airflow, the magnitude of the solar energy deposition must be known. Previous analyses have used the electron impact excited Lyman-Birge-Hopfield (LBH) bands of N2 to infer the flux of photoelectrons in the atmosphere and thus to infer the magnitude of the solar irradiance. This dissertation presents the first simultaneous measurements of the FUV airglow, the major atmospheric constituent densities, and the solar EUV and soft x-ray irradiances. The measurements were made on three flights of an identical sounding rocket payload at different levels of solar activity. The linear response in brightness of the LBH bands to variations in solar irradiance is demonstrated. In addition to the N2 LBH bands, atomic oxygen lines at 135.6 and 130.4 nm are also studied. Unlike the LBH bands, these emissions undergo radiative transfer effects in the atmosphere. The OI emission at 135.6 nm is found to be well modeled using a radiative transfer calculation and the known excitation processes. Unfortunately, the assumed processes leading to OI 130.4 nm excitation are found to be insufficient to reproduce the observed variability of this emission. Production of NO in the atmosphere is examined; it is shown that a lower than previously reported variability in the solar soft x-ray irradiance is required to explain the variability of NO.

Bailey, Scott Martin↗
NASA NTRS1999

Global Mapping of Underwater UV Irradiances and DNA-Weighted Exposures using TOMS and SeaWiFS Data Products

The global stratospheric ozone-layer depletion results In an increase in biologically harmful ultraviolet (UV) radiation reaching the surface and penetrating to ecologically significant depths in natural waters. Such an increase can be estimated on a global scale by combining satellite estimates of UV irradiance at the ocean surface from the Total Ozone Mapping Spectrometer (TOMS) satellite instrument with the SeaWIFS satellite ocean-color measurements in the visible spectral region. In this paper we propose a model of seawater optical properties in the UV spectral region based on the Case I water model in the visible range. The inputs to the model are standard monthly SeaWiFS products: chlorophyll concentration and the diffuse attenuation coefficient at 490nm. Penetration of solar UV radiation to different depths in open ocean waters is calculated using the RT (radiative transfer) quasi-single scattering approximation (QSSA). The accuracy of the QSSA approximation in the water is tested using more accurate codes. The sensitivity study of the underwater UV irradiance to atmospheric and oceanic optical properties have shown that the main environmental parameters controlling the absolute levels of the UVB (280-320nm) and DNA-weighted irradiance underwater are: solar-zenith angle, cloud transmittance, water optical properties, and total ozone. Weekly maps of underwater UV irradiance and DNA-weighted exposure are calculated using monthly-mean SeaWiFS chlorophyll and diffuse attenuation coefficient products, daily SeaWiFS cloud fraction data, and the TOMS-derived surface UV irradiance daily maps. The final products include global maps of weekly-average UVB irradiance and DNA-weighted daily exposures at 3m and 10m, and depths where the UVB irradiance and DNA-weighted dose rate at local noon are equal to 10% of their surface values.

Vasilkov, Alexander↗
NASA NTRS2003

Future Satellite Observations of Solar Irradiance

Required solar irradiance measurements for climate studies include those now being made by the Total Irradiance Monitor (TIM) and the Spectral Irradiance Monitor (SIM) onboard the SORCE satellite, part of the Earth Observing System fleet of NASA satellites. Equivalent or better measures of Total Solar Irradiance (TSI) and Spectral Solar Irradiance (SSI, 200 to 2000 nm) are planned for the post-2010 satellites of the National Polar-orbiting Operational Environmental Satellite System ("OESS). The design life of SORCE is 5 years, so a "Solar Irradiance Gap Filler" EOS mission is being planned for launch in the 2007 time frame, to include the same TSI and SSI measurements. Besides avoiding any gap, overlap of the data sources is also necessary for determination of possible multi-decadal trends in solar irradiance. We discuss these requirements and the impacts of data gaps, and data overlaps, that may occur in the monitoring of the critical solar radiative forcing.

Cahalan, R. F.↗
NASA NTRS2012

Late Effects of Heavy Ion Irradiation on Ex Vivo Osteoblastogenesis and Cancellous Bone Microarchitecture

Prolonged spaceflight causes degeneration of skeletal tissue with incomplete recovery even after return to Earth. We hypothesize that heavy ion irradiation, a component of Galactic Cosmic Radiation, damages osteoblast progenitors and may contribute to bone loss during long duration space travel beyond the protection of the Earth's magnetosphere. Male, 16 week old C57BL6/J mice were exposed to high LET (56 Fe, 600MeV) radiation using either low (5 or 10cGy) or high (50 or 200cGy) doses at the NASA Space Radiation Lab and were euthanized 3 - 4, 7, or 35 days later. Bone structure was quantified by microcomputed tomography (6.8 micron pixel size) and marrow cell redox assessed using membrane permeable, free radical sensitive fluorogenic dyes. To assess osteoblastogenesis, adherent marrow cells were cultured ex vivo, then mineralized nodule formation quantified by imaging and gene expression analyzed by RT PCR. Interestingly, 3 - 4 days post exposure, fluorogenic dyes that reflect cytoplasmic generation of reactive nitrogen/oxygen species (DAF FM Diacetate or CM H2DCFDA) revealed irradiation (50cGy) reduced free radical generation (20-45%) compared to sham irradiated controls. Alternatively, use of a dye showing relative specificity for mitochondrial superoxide generation (MitoSOX) revealed an 88% increase compared to controls. One week after exposure, reactive oxygen/nitrogen levels remained lower(24%) relative to sham irradiated controls. After one month, high dose irradiation (200 cGy) caused an 86% decrement in ex vivo nodule formation and a 16-31% decrement in bone volume to total volume and trabecular number (50, 200cGy) compared to controls. High dose irradiation (200cGy) up regulated expression of a late osteoblast marker (BGLAP) and select genes related to oxidative metabolism (Catalase) and DNA damage repair (Gadd45). In contrast, lower doses (5, 10cGy) did not affect bone structure or ex vivo nodule formation, but did down regulate iNOS by 0.54 - 0.58 fold. Thus, both low and high doses of heavy ion irradiation cause time dependent, adaptive changes in redox state within marrow cells but only high doses (50, 200cGy) inhibit osteoblastogenesis and cause cancellous bone loss. We conclude space radiation has the potential to cause persistent damage to bone marrow derived stem and progenitor cells for osteoblasts despite adaptive changes in cellular redox state.

Tran, Luan Hoang↗
NASA NTRS2019

Estimating Residual Uncertainties for Lunar Irradiance Measurements Due to Imaging Acquisition Parameters

Lunar calibration is a commonly used method to track a climate satellite sensor's long-term radiometric stability. We present a modeling approach to examine the satellite sensor lunar observation uncertainties due to several important aspects related to the lunar image acquisition by the satellite sensor: lunar pixel shift, point spread function (PSF), lunar orientation, pitch, and oversampling rates. Our analyses can be summarized as follows: (1) The sensor observed lunar irradiance can vary due to small lunar pixel shift if the PSF is less than ideal; (2) During lunar calibration, an unstable oversampling rate due to spacecraft control will result in errors in observed lunar irradiance. A drift in oversampling rate would result in a bias in observed lunar irradiance and a random variation in oversampling rate would cause random error in lunar irradiance. Increasing the overall oversampling rates can reduce random error in observed lunar irradiance but would not change the biases in the observation; (3) Furthermore, the biases can vary when the Moon is observed at different orientations. Our results show impacts on observed lunar irradiance are on the order of 0.1 percent, which is a significant part of the overall uncertainty for a lunar irradiance measurement of a climate satellite sensor.

Oversampling↗
NASA NTRS2020

Examining Biases in Diurnally-Integrated Shortwave Irradiances due to Two- and Four-Stream Approximations in Cloudy Atmosphere

Shortwave irradiance biases due to two- and four-stream approximations have been studied for the last couple of decades, but biases in estimating Earth’s radiation budget have not been examined in earlier studies. In order to quantify biases in diurnally-averaged irradiances, we integrate the two- and four-stream biases using realistic diurnal variations of cloud properties from Clouds and the Earth’s Radiant Energy System (CERES) synoptic (SYN) hourly product. Three approximations are examined in this study, delta-two-stream-Eddington (D2strEdd), delta- two-stream-quadrature (D2strQuad), and delta-four-stream-quadrature (D4strQuad). Irradiances computed by the Discrete Ordinates Radiative Transfer (DISORT) and Monte Carlo (MC) methods are used as references. The MC noises are further examined by comparing with DISORT results. When the biases are integrated with a one-day of solar zenith angle variation, regional biases of D2strEdd and D2strQuad reach up to 8 W/sq.m, while biases of D4strQuad reach up to 2 W/sq.m. When the biases are further averaged monthly or annually, regional biases of D2strEdd and D2strQuad can reach –1.5 W/sq.m in SW top-of-atmosphere (TOA) upward irradiances and +3 W/sq.m in surface downward irradiances. In contrast, regional biases of D4strQuad are within +0.9 for TOA irradiances and –1.2 W/sq.m for surface irradiances. Except for polar regions, monthly and annual global mean biases are similar, suggesting that the biases are nearly independent to season. Biases in SW heating rate profiles are up to –0.008 K/d for D2strEdd and –0.016 K/d for D2strQuad, while the biases of the D4strQuad method are negligible.

Ham, Seung-Hee↗
NASA NTRSDate not supplied

Comparison of Observed Longwave, Shortwave Irradiance and Surface Temperature from “MOSAiC” to CERES Radiative Transfer Calculations and Inputs

As atmospheric temperatures rise due to increased anthropogenic forcing, the effect is expected to be larger over the arctic than midlatitude and tropics, known as polar amplification. A multi-national program, the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) was ran between Sept 2019 and Oct 2020. The project deployed scientific instruments on board the German research vessel Polarstern with the ship remaining across a year to observe all aspects of polar climate. The US DOE deployed the ARM AMF2 aboard the ship along with several off-ship sites for extended spatial observations. Of particular importance was the measurement of the energetics of the ice/ocean/atmosphere interactions through observations of surface irradiance and surface temperatures. NASA’s Clouds and the Earth’s Radiant Energy System (CERES) project produces the SYN1deg Edition 4 data product. This product provides high quality, hourly, globally gridded and temporally complete maps of top of atmosphere (TOA), in atmosphere, and surface irradiances. TOA fluxes are derived from CERES instruments and geostationary satellites. In addition, TOA, in atmosphere, and surface irradiances are computed using the Langley Fu and Liou radiative transfer model. The radiative transfer model is run hourly at 1 degree ~equal area spatial resolution. Meteorological profiles are provided by Global Modeling and Assimilation Office’s GEOS-541 reanalysis product. Cloud properties are derived solely from Terra and Aqua MODIS imagers northward of 60°. Here we compare SYN1deg hourly calculations of surface irradiance to observations from the AMF2 to validate the products estimates of surface irradiance in this challenging area. Along with the irradiance comparisons we take a close look at the surface temperature record in the GEOS-541 product and compare it over both time and space to several surface observations provided by MOSAiC. Along with the comparison to the re-analysis record we will compare these observed surface temperatures to those derived from the AIRS product, which is known to have some difficulty in extreme high latitude areas. The goals of this study are 1) understand computed surface downward irradiance and temperature error separated by surface type (e.g. sea ice or open water) and by season, and 2) error covariance in spatial and temporal space. We seek to use this information to extrapolate the error from the MOSAiC domain to a larger arctic region.

David A Rutan↗
DOE OSTI2016

Blood Irradiator Interactive Tool Beta Version

The “Blood Irradiator Interactive Tool” compares a typical Cs-137 Blood Irradiator with that of the capabilities of an average X-ray Irradiator. It is designed to inform the user about the potential capabilities that an average X-ray Irradiator could offer them. Specifically the tool compares the amount of blood bags that can be irradiated by the users’ machine with that of the average X-ray capability. It also forcasts the amount of blood that can be irradiated on yearly basis for both the users’ machine and an average X-ray Device. The Average X-ray capabilities are taken from the three X-ray devices currently on the market: The RS 3400 Rad Source X-ray Blood Irradiator and both the 2.0L and 3.5 L versions of the Best Theratronis Raycell MK2

Howington, John↗
DOE OSTI2019

Using Microscopy and Magnetization Measurements to Characterize Electron Irradiation of Nb and Nb3Sn

Recently, high-energy irradiation experiments on industrial multilamentary Nb3Sn wires have been performed; previous work showed an enhancement in Jc with 24 GeV proton irradiation with uences up to t 1:381021p/m2 [Spina, 2015] and an enhancement in Jc with 1 MeV neutron irradiation with uences up to t 1 1022n/m2 [Baumgartner et al., 2013]. This enhancement is explained by an enhancement of the pinning force due to radiationinduced point pinning defects, in addition to the grain boundary pinning. However, this created a large amount of radioactivity, with 1{2 on the order of magnitude of years. Thus, electron irradiation is a promising technique for creating articial pinning centers, while minimizing the amount of radioactivity present. We present preliminary results for electron irradiation on Nb3Sn wires and give upper bounds on eective uences for Jc enhancement. Furthermore, creating vacancies via electron irradiation is useful in the realm of SRF cavities, as vacancies can trap Hydrogen, preventing the formation of degradatory Nb-H compounds during cryogenic cooling. We present computer-aided microscopy analysis comparing hydride formation on Nb platelets before and after irradiation.

43 PARTICLE ACCELERATORS↗
DOE OSTI2014

Measurements of Ionizing Radiation Doses Induced by High Irradiance Laser on Targets in LCLS MEC Instrument - Paper 75

High-power laser interaction with targets in vacuum at high laser irradiance levels can generate plasma and, consequently, create ionizing radiation hazards. The theory for ionizing radiation generation from laser-plasma interaction is complicated. The basics of theory and phenomenology are available qualitatively. However, the ionizing radiation yields associated with laser-plasma interaction have not been well quantified. Based on the theoretical analysis and review of the published reports and measurement data, SLAC National Accelerator Laboratory (SLAC) developed an analytic model to estimate conservatively the electron temperature and photon radiation yield (Sv/J) of a laser pulse hitting a solid target at 1 m as a function of laser irradiance between 10{sup 15} and 10{sup 21} W/cm{sup 2}. Ionizing radiation measurements from high-intensity laser-induced plasma interactions on solid targets inside the Al-walled vacuum chamber of the LCLS MEC instrument at SLAC were conducted using passive and active detectors at irradiance between 3x10{sup 16} and 6x10{sup 17} W/cm{sup 2}. Each run of the more than 20 runs had a unique set of laser, optic and target conditions with laser pulses rastering over the target surface mainly perpendicularly at a fixed irradiance. Significant effort was made in characterizing the laser irradiance values for each configuration of laser, focusing mirror, and target; four irradiances with targets of Au foils and copper plate were found to produce good measurement results. Electron doses inside the target chamber were highly anisotropic and peaked at backward direction by several orders of magnitude. Photon doses outside the target chamber were nearly isotropic (a factor of ∼2 higher in backward direction). When considering the large uncertainties of the irradiance (a factor of 2-3) and the potential shielding effects from detectors and target chamber, the measured photon dose rates at 1 m (150 mJ and 10 Hz) outside the target chamber (when averaged over different types of detectors) were in good agreement (a factor of ∼3) with the calculated values of the SLAC model, except at 3.0x10{sup 16} W/cm{sup 2}, which has an electron temperature of only 14 keV. At 6x10{sup 17} W/cm{sup 2}, a low level of ∼0.1 mrem/h from fast neutrons was measured (at 1 m, 150 mJ and 10 Hz) with a neutron-to-photon dose ratio of 0.2%. This is equivalent to a neutron dose yield of 2.8x10{sup -8} mSv/J (to be compared to the LULI measurements of 1x10{sup -4} mSv/J at 3x10{sup 19} W/cm{sup 2}). Both active and passive types of detectors performed well and the dose results were consistent, which is the same as the dose measurements in the Titan laser facility. Active detectors were not affected by the electromagnetic pulses associated with the MEC laser system; this was different from the Titan radiation measurements, in which all active detectors failed to respond, likely due to the high EMP in the Titan's high laser intensity fields. (authors)

43 PARTICLE ACCELERATORS↗
DOE OSTI2021

DOE-GENIORS Dynamic Irradiation Testing

As part of the homogeneous actinides recycling strategy, the EURO-GANEX process is one of the most promising options to achieve the goal of minor actinides recovery. Improvements made to EURO-GANEX system have resulted in the emergence of the so-called New EURO-GANEX process, where the composition of the solvent has been modified by replacing TODGA and DMDOHEMA with cis-mTDDGA in the organic phase and SO3-Ph-BTP with PyTri-Diol in the aqueous phase in order to resolve important issues. The objective of this work is twofold: evaluate the gamma radiolytic resistance of the new EURO-GANEX process by dynamic irradiation conditions simulating the three main steps of the process, and validate the design of CIEMAT Náyade, CEA Marcel and INL irradiation loop devices since each of them mimics different aspects of the real process. Náyade and the INL loops could irradiate the organic and aqueous phases together, whereas in the CEA loop, the irradiated solvent is recycled continuously inside a platform with several stages of mixer-settlers containing aqueous flows simulating the three main steps of the process. The extraction performances and changes in the composition of the solvent have been analyzed during the irradiation experiment by different techniques: gamma spectrometry and ICP-MS/OES for cations or radioactive tracer extraction, and HPLC-MS to identify and quantify the degradation compounds. Despite some differences between the three-irradiation facilities, this inter-institutional study shows that these three comparative tools provide similar trends in the radiolytic stability of a liquid-liquid extraction system. Favourable extraction results for the different steps are obtained according to the static irradiation studies found in literature. However, the degradation of cis-mTDDGA is appreciable leading to degradation compounds, some of which form precipitates and produce important changes in viscosity, important aspects that must be addressed prior to the successful industrial application of the new EURO-GANEX process.

38 - RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCL↗
DOE OSTI2025

Local chemical ordering of a neutron-irradiated CrFeMnNi compositionally complex alloy

While ion-irradiation studies are a critical first step in studying compositionally complex alloys (CCAs) for nuclear applications, they do not capture all the microstructural changes occurring under the low irradiation dose rates and different particles’ scattering patterns experienced in a nuclear reactor setting. To explore these phenomena in reactor-relevant conditions for the first time in CCA, the single-phase solid-solution Cr 10 Fe 30 Mn 30 Ni 30 was neutron irradiated up to 6.61 displacements per atom at 395 and 579 °C. Irradiation-enhanced local chemical ordering (LCO) well beyond the range of short range ordering was observed, and is predicted to be the precursor to the precipitation of a coherent Ni-Mn L1 0 phase and a Cr-rich α’ phase, though TEM analysis did not indicate the presence of either in any irradiation condition. The line density of faulted dislocation loops decreased from 6.47 to 1.69 ∙ 10 15 m -2 from 3.43 to 6.61 dpa at 579 °C despite no appreciable faulted loop content in the unirradiated material. LCO is expected to increase the complexity of the energy landscape within this alloy, restricting interstitial point defect mobility and creating local regions of greater stacking fault energy. These contribute to the negative correlation between irradiation dose and faulted dislocation loop density in this study, as well as the lack of void swelling observed.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Temperature and dose effects on dislocation loops in self-ion irradiated high-purity iron

Body-centered cubic (BCC) Fe-based alloys are promising candidate materials for advanced nuclear reactors. However, a detailed understanding of irradiation induced dislocation loop microstructure development remains unresolved. It is a widespread belief that 〈001〉 loops become increasingly favorable over ½〈111〉 loops as irradiation temperature rises above ∼300 C. Unfortunately, the temperature effects on 〈001〉 loop have been primarily examined in in-situ irradiation on TEM thin foils but poorly explored on bulk Fe due to exceedingly limited experimental studies on bulk specimens, raising concerns about the potential influence of TEM thin foil artifacts on observed results. Here, in this study, we conducted experiments on ultra-high purity BCC Fe specimens irradiated with 6.7–8 MeV Fe ions over a wide temperature range on bulk samples. We investigated the effects of temperature (T irr = 250–500 °C), dose rate (10⁻⁵ to 10⁻³ dpa/s), and dose (0.35 to 3.5 dpa) on the formation and evolution of 〈001〉 and ½〈111〉 loops as well as cavity (void) formation. Post-irradiation Burgers vector analysis via g•b method on dislocation segments and loops revealed that 〈001〉 loop fraction does not show a monotonic positive correlation with irradiation temperature. Combined with previous and current theoretical as well as experimental findings, we explore the temperature effects on all existing models of 〈001〉 loop formation. We conclude that the prevailing reports regarding the dominance of 〈001〉 loops in Fe at elevated temperatures are mainly attributable to the loss of glissile ½〈111〉 clusters in TEM thin foil experiments.

36 MATERIALS SCIENCE↗
DOE OSTI2019

A machine learning approach to thermal conductivity modeling: A case study on irradiated uranium-molybdenum nuclear fuels

A deep neural network was developed for the purpose of predicting thermal conductivity with a case study performed on irradiated nuclear fuel. Traditional thermal conductivity modeling approaches rely on existing theoretical frameworks that describe known, relevant phenomena that govern the microstructural evolution processes during neutron irradiation (such as recrystallization, and pore size, distribution and morphology). Current empirical modeling approaches, however, do not represent all irradiation test data well. We develop a machine learning approach to thermal conductivity modeling that does not require a priori knowledge of a specific material microstructure and system of interest. Our approach allows re-searchers to probe dependency of thermal conductivity on a variety of reactor operating and material conditions. The purpose of building such a model is to allow for improved predictive capabilities linking structure-property-processing-performance relationships in the system of interest (here, irradiated nuclear fuel), which could lead to improved experimental test planning and characterization. The uranium-molybdenum system is the fuel system studied in this work, and historic irradiation test data is leveraged for model development. Our model achieved a mean absolute percent error of approximately 10%. Results indicate our model generalizes well to never before seen data, and thus use of deep learning methods for material property predictions from limited, historic irradiation data is a viable approach. This work challenges the current paradigm in materials science, where material property models are based on limited experimental data fitted to low-dimensionality phenomenological models, or by simulations in which fundamental equations are explicitly solved. The work presented here aims to demonstrate the potential and limitations of machine learning in the field of materials science and material property modeling.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗