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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 883 records · Page 49
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Criteria Air Pollutants and Greenhouse Gas Emissions from Hydrogen Production in U.S. Steam Methane Reforming Facilities

The global and U.S. domestic effort to develop a clean energy economy and curb environmental pollution incentivizes the use of hydrogen as a transportation fuel, owing to its zero tailpipe pollutant emissions and high fuel efficiency in fuel cell electric vehicles (FCEVs). However, the hydrogen production process is not emissions free. Conventional hydrogen production via steam methane reforming (SMR) is energy intensive, coproduces carbon dioxide, and emits air pollutants. Therefore, it is necessary to quantify the environmental impacts of SMR hydrogen production alongside the use-phase of FCEVs. This study fills the information gap, analyzing the greenhouse gas (GHG) and criteria air pollutant (CAP) emissions associated with hydrogen production in U.S. SMR facilities by compiling and matching the facility-reported GHG and CAP emissions data with facilities’ hydrogen production data. The actual amounts of hydrogen produced at U.S. SMR facilities are often confidential. Thus, we have developed four approaches to estimate the hydrogen production amounts. The resultant GHG and CAP emissions per MJ of hydrogen produced in individual facilities were aggregated to develop emission values for both a national median and a California state median. Lastly, this study also investigates the breakdown of facility emissions into combustion emissions and noncombustion emissions.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2015

Three-dimensional spectrum mapping of bright emission centers: Investigating the brightness-limiting process in Eu-doped GaN red light emitting diodes

A pulse-driven emission-spectroscopy mapping technique is used to investigate the bright emission centers in Eu-doped GaN (GaN:Eu) red light emitting diodes (LED). The LEDs are operated in pulse-driven mode, and the emission spectra are acquired for a range of pulse frequencies. This ensemble of emission spectral data yields a three-dimensional mapping that allows the origin of emission lines to be identified by visual inspection. The identification was achieved even for a weak {sup 5}D{sub 0} → {sup 7}F{sub 3} transition in conventional photoluminescence measurements. A peculiar split is observed in the {sup 5}D{sub 0} → {sup 7}F{sub 3} transition for the bright emission center referred to as OMVPE 8. Despite the unique transition at this emission center, the emission efficiencies for the {sup 5}D{sub 0} → {sup 7}F{sub 3} and {sup 5}D{sub 0} → {sup 7}F{sub 2} transitions were identical. This finding indicates that the excitation of the emission centers, rather than the radiative transitions, is the limiting process that determines the GaN:Eu red LED brightness.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2011

SPINNING DUST EMISSION: EFFECTS OF IRREGULAR GRAIN SHAPE, TRANSIENT HEATING, AND COMPARISON WITH WILKINSON MICROWAVE ANISOTROPY PROBE RESULTS

Planck is expected to answer crucial questions on the early universe, but it also provides further understanding on anomalous microwave emission. Electric dipole emission from spinning dust grains continues to be the favored interpretation of anomalous microwave emission. In this paper, we present a method to calculate the rotational emission from small grains of irregular shape with moments of inertia I{sub 1} {>=} I{sub 2} {>=} I{sub 3}. We show that a torque-free rotating irregular grain with a given angular momentum radiates at multiple frequency modes. The resulting spinning dust spectrum has peak frequency and emissivity increasing with the degree of grain shape irregularity, which is defined by I{sub 1}:I{sub 2}:I{sub 3}. We discuss how the orientation of the dipole moment {mu} in body coordinates affects the spinning dust spectrum for different regimes of internal thermal fluctuations. We show that the spinning dust emissivity for the case of strong thermal fluctuations is less sensitive to the orientation of {mu} than in the case of weak thermal fluctuations. We calculate spinning dust spectra for a range of gas density and dipole moment. The effect of compressible turbulence on spinning dust emission is investigated. We show that the emission in a turbulent medium increases by a factor from 1.2 to 1.4 relative to that in a uniform medium, as the sonic Mach number M{sub s} increases from 2 to 7. Finally, spinning dust parameters are constrained by fitting our improved model to five-year Wilkinson Microwave Anisotropy Probe cross-correlation foreground spectra, for both the H{alpha}-correlated and 100-{mu}m-correlated emission spectra.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2012

GALACTIC OUTFLOWS IN ABSORPTION AND EMISSION: NEAR-ULTRAVIOLET SPECTROSCOPY OF GALAXIES AT 1 < z < 2

We study large-scale outflows in a sample of 96 star-forming galaxies at 1 {approx}< z {approx}< 2, using near-UV spectroscopy of Fe II and Mg II absorption and emission. The average blueshift of the Fe II interstellar absorption lines with respect to the systemic velocity is -85 {+-} 10 km s{sup -1} at z {approx} 1.5, with standard deviation 87 km s{sup -1}; this is a decrease of a factor of two from the average blueshift measured for far-UV interstellar absorption lines in similarly selected galaxies at z {approx} 2. The profiles of the Mg II {lambda}{lambda}2796, 2803 lines show much more variety than the Fe II profiles, which are always seen in absorption; Mg II ranges from strong emission to pure absorption, with emission more common in galaxies with blue UV slopes and at lower stellar masses. Outflow velocities, as traced by the centroids and maximum extent of the absorption lines, increase with increasing stellar mass with 2{sigma}-3{sigma} significance, in agreement with previous results. We study fine structure emission from Fe II*, finding several lines of evidence in support of the model in which this emission is generated by the re-emission of continuum photons absorbed in the Fe II resonance transitions in outflowing gas. In contrast, photoionization models indicate that Mg II emission arises from the resonant scattering of photons produced in H II regions, accounting for the differing profiles of the Mg II and Fe II lines. A comparison of the strengths of the Fe II absorption and Fe II* emission lines indicates that massive galaxies have more extended outflows and/or greater extinction, while two-dimensional composite spectra indicate that emission from the outflow is stronger at a radius of {approx}10 kpc in high-mass galaxies than in low-mass galaxies.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2015

A tale of three galaxies: Deciphering THE infrared emission of the spectroscopically anomalous galaxies IRAS F10398+1455, IRAS F21013–0739, and SDSS J0808+3948

The Spitzer/Infrared Spectrograph spectra of three spectroscopically anomalous galaxies (IRAS F10398+1455, IRAS F21013–0739, and SDSS J0808+3948) are modeled in terms of a mixture of warm and cold silicate dust, and warm and cold carbon dust. Their unique infrared (IR) emission spectra are characterized by a steep ∼5–8 μm emission continuum, strong emission bands from polycyclic aromatic hydrocarbon (PAH) molecules, and prominent silicate emission. The steep ∼5–8 μm emission continuum and strong PAH emission features suggest the dominance of starbursts, while the silicate emission is indicative of significant heating from active galactic nuclei (AGNs). With warm and cold silicate dust of various compositions (“astronomical silicate,” amorphous olivine, or amorphous pyroxene) combined with warm and cold carbon dust (amorphous carbon, or graphite), we are able to closely reproduce the observed IR emission of these galaxies. We find that the dust temperature is the primary cause in regulating the steep ∼5–8 μm continuum and silicate emission, insensitive to the exact silicate or carbon dust mineralogy and grain size a as long as a≲1 μm. More specifically, the temperature of the ∼5–8 μm continuum emitter (which is essentially carbon dust) of these galaxies is ∼250–400 K, much lower than that of typical quasars, which is ∼640 K. Moreover, it appears that larger dust grains are preferred in quasars. The lower dust temperature and smaller grain sizes inferred for these three galaxies compared with that of quasars could be due to the fact that they may harbor a young/weak AGNs that is not maturely developed yet.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

The zero-emissions cost of energy: a policy concept

The energy sector generates over 70% of global greenhouse gas (GHG) emissions, but existing energy-climate policies do little to reduce GHG emissions to prevent climate change. We present a new carbon tax policy concept in which energy users would be taxed an amount equal to the cost of cleaning up the emissions that they create, wherein the tax revenues would be used to operate negative emissions technologies. The policy is based on applying the zero-emissions cost (ZEC) metric to energy prices, which includes the 'regular' cost of an energy source plus the cost of sequestering its emissions. Using the ZEC, (a) the energy sector would be emissions-neutral, (b) biofuels would be cheaper than petroleum fuels, and (c) renewable electricity would be cheaper than fossil-fuel electricity. We calculate the energy spending as a fraction of gross domestic product for 'regular' and ZEC cost scenarios. Implementing the ZEC carbon-tax policy would enable a monumental shift to a net-zero emissions energy sector, but carries a significant risk of causing an economic recession. The summary point of this commentary is to demonstrate a pathway to achieve net-zero GHG emissions from the US energy sector, and to contemplate the associated economic impacts on our society.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2018

Methane emissions from tree stems: a new frontier in the global carbon cycle

Tree stems from wetland, floodplain and upland forests can produce and emit methane (CH 4 ). Tree CH 4 stem emissions have high spatial and temporal variability, but there is no consensus on the biophysical mechanisms that drive stem CH 4 production and emissions. Here, we summarize up to 30 opportunities and challenges for stem CH 4 emissions research, which when addressed will improve estimates of magnitudes, patterns, drivers and trace the potential origin of CH 4 emissions. We identified the need (i) for both long–term high frequency measurements of stem CH 4 emissions to understand the fine scale processes, alongside rapid large–scale measurements designed to understand variability across individuals, species and ecosystems; (ii) to identify microorganisms and biogeochemical pathways associated with CH 4 production; and (iii) to develop a mechanistic model including passive and active transport of CH 4 from the soil–tree–atmosphere continuum. Addressing these challenges would help to constrain magnitudes and patterns of CH 4 emissions, and would allow for the integration of pathways and mechanisms of CH 4 production and emissions into process–based models. As a result, these advances will facilitate upscaling of stem CH 4 emissions to the ecosystem level and quantify the role of stem CH 4 emissions for the local–to–global CH 4 budget.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Greenhouse gas emissions reduction strategies that maximize portfolio-wide life cycle cost reduction, resilience, and environmental justice benefits

While strategies to achieve net-zero emissions at an individual site are well understood, new analysis methods are required for organizations seeking to achieve net-zero across multiple facilities, each with concurrent priority goals. At a portfolio level, distinct locations present varied challenges that cannot be addressed through singular solutions, and competing goals can take precedence with the assumption that net-zero emissions strategies deter from energy resilience and cost savings, therefore negatively impacting nearby communities. This study tests these assumptions by analyzing 16 diverse sites (varying in size, climate, and energy use) to identify strategies that reduce emissions and assess the impact these strategies have on life cycle costs, resilience, and communities with environmental justice concerns. Methods were developed to approximate missing information essential to net-zero evaluation. Established methods were augmented to evaluate life cycle costs, resilience, and environmental justice impacts across a set of strategies and accommodate the multi-criteria analyses. Potential benefits from identified strategies were quantified using site characteristics and a set of corresponding metrics. The net-zero analysis found that 11 sites could use on-site strategies to eliminate all but 2% of emissions generated. The remaining emissions can be offset, for instance through sequestration, executed at the portfolio scale. On-site carbon-free energy was found to reduce 51% of emissions across all sites; efficiency reduced 19% of emissions; sequestration 16%; procured carbon-free energy 15%; fuel switching 1.6%; and fleet electrification 1.3%. Building electrification, however, increased emissions by 4.4%. Different strategies also provide cost, resilience, and/or environmental justice benefits—the degree to which varies with individual site conditions. The findings indicate an advantage to considering the strategies as a comprehensive set, which leads to co-benefits, both in the ability to achieve net-zero goals and in advancing other goals. The results present the case for comprehensive advanced planning at the portfolio level to prioritize investments that will balance the minimization of emissions and life cycle cost with the maximization of resilience and environmental justice benefits. The novel methods for evaluation and integration, valuation of benefits, and consideration at the portfolio scale allow organizations to select investments that simultaneously address multiple key priorities.

Net-Zero Emissions↗
DOE OSTI2012

Estimates of the Global Indirect Energy-Use Emission Impacts of USA Biofuel Policy

This paper evaluates the indirect energy-use emission implications of increases in the use of biofuels in the USA between 2001 and 2010 as mandates within a dynamic global computable general equilibrium model. The study incorporates explicit markets for biofuels, petroleum and other fossil fuels, and accounts for interactions among all sectors of an 18-region global economy. It considers bilateral trade, as well as the dynamics of capital allocation and investment. Simulation results show that the biofuel mandates in the USA generate an overall reduction in global energy use and emissions over the simulation period from 2001 to 2030. Consequently, the indirect energy-use emission change or emission leakage under the mandate is negative. That is, global emission reductions are larger than the direct emission savings from replacing petroleum with biofuels under the USA RFS2 over the last decade. Under our principal scenario this enhanced the direct emission reduction from biofuels by about 66%. The global change in lifecycle energy-use emissions for this scenario was estimated to be about 93 million tons of CO2e in 2010, 45 million tons of CO2e in 2020, and an increase of 5 million tons of CO2e in 2030, relative to the baseline scenario. Sensitivity results of six alternative scenarios provided additional insights into the pattern of the regional and global effects of biofuel mandates on energy-use emissions.

02 PETROLEUM↗
DOE OSTI2019

Spatiotemporal dynamics of CO 2 emissions from central heating supply in the North China Plain over 2012–2016 due to natural gas usage

Energy consumption from central heating has rapidly increased in the cities of the North China Plain (NCP). The significant use of natural gas in the central heating supply system may have altered the spatial and temporal patterns of CO 2 emissions from central heating, yet the quantitative impacts are poorly understood. In this work, we detect the spatio-temporal dynamics of CO 2 emissions of central heating from 2012 to 2016 at the prefectural-city level in the NCP region, by using the satellite NPP-VIIRS nighttime light data and a panel regression model to estimate CO 2 emissions on a 5 x 5 km 2 grid. We find that despite a slight decrease (2%) in 2014 under the "Natural Gas Utilization Policy", CO 2 emissions continued to grow. Between 2012 and 2016, CO 2 emissions from central heating in the NCP increased from 106 to 121 Tg, although CO 2 emissions declined by 12% in Beijing due to the increasing contribution of natural gas boilers. The gridded CO 2 emissions map shows that over 2012-2016 coal burning is the main driving force of CO 2 emissions in both urban and non-urban regions, despite the increasing fraction of gas-based heating. Our results contribute to city-level policymaking on carbon reduction and climate change mitigation. The high-resolution gridded CO 2 emissions can also be applied in physical models to facilitate carbon cycle studies.

03 NATURAL GAS↗
DOE OSTI2019

Impact of ethanol blending into gasoline on aromatic compound evaporation and particle emissions from a gasoline direct injection engine

This study examined the interactions of ethanol with aromatic compounds on aromatic species evolution during gasoline evaporation and the consequent impacts on particle emissions from a single-cylinder, gasoline direct injection engine. From a chemical kinetic standpoint, the dilution of the aromatic species in gasoline by ethanol blending should reduce particle emissions because aromatics are the primary species that form particles during gasoline combustion. However, increased evaporative cooling from the ethanol and ethanol's effect on when aromatics in the fuel droplet (or surface film or pool) evaporate can drive an increase in particle emissions. The objective of this study was to quantify these competing effects. The results show that a combination of ethanol's increased evaporative cooling and impact on aromatic compound vapor-liquid equilibrium can extend droplet lifetime and cause aromatics to evaporate later in the droplet evaporation process than would be the case without ethanol. When fuels were burned in a direct-injection single-cylinder engine at high speed (2500 rpm) and relatively high load, ethanol blending caused an increase in particle emissions for fuels containing a low vapor pressure aromatic. At a lower speed (1500 rpm), no statistically significant increase in particle emissions was observed, likely because more time was available for evaporation and mixing to occur. In contrast, particle emissions from a fuel blended with a high vapor pressure aromatic were either insensitive to or reduced by ethanol blending, likewise to engine operating conditions. Current models for predicting particle emissions from gasoline engines, such as particulate matter index (PMI), generally lack variables for non-linear interactions between ethanol and gasoline hydrocarbons. To identify nonlinear interactions between predictor variables that might better explain the observed particle emissions, the least absolute shrinkage and selection operator (LASSO) regularized regression approach was employed. Among the predictor variables evaluated was the Yield Sooting Index (YSI) which is as an improved measure to quantify the aromatic's chemical tendency to generate particle emissions. Following this analysis, two variables were selected based on their frequent appearance. The first was ethanol mole percent multiplied by aromatic mole percent divided by aromatic vapor pressure [(EtOH * Aro%)/Aro VP@443 K]. The second was aromatic mole percent multiplied by aromatic YSI divided by aromatic molecular weight [(Aro% * Aro YSI)/Aro MW]. The results of linear regression including only these two combined explanatory variables achieved an r 2 = 0.959, substantially improved over the PMI model (r 2 = 0.688) and provides insight into how the PMI formalism might be modified to account for non-linear oxygenate-hydrocarbon coupling.

09 BIOMASS FUELS↗
DOE OSTI2013

Probe into Gaseous Pollution and Assessment of Air Quality Benefit under Sector Dependent Emission Control Strategies over Megacities in Yangtze River Delta, China

On February 29th 2012, China published its new National Ambient Air Quality Standard (CH-NAAQS) aiming at revising the standards and measurements for both gaseous pollutants including ozone (O3), nitrogen dioxide (NO2), and sulfur dioxide (SO2), and also particle pollutants including PM10 and PM2.5. In order to understand the air pollution status regarding this new standard, the integrated MM5/CMAQ modeling system was applied over Yangtze River Delta (YRD) within this study to examine the criteria gaseous pollutants listed in the new CH-NAAQS. Sensitivity simulations were also conducted to assess the responses of gaseous pollutants under 8 different sector-dependent emission reduction scenarios in order to evaluate the potential control strategies. 2006 was selected as the simulation year in order to review the air quality condition at the beginning of China’s 11th Five-Year-Plan (FYP, from 2006 to 2010), and also compared with air quality status in 2010 as the end of 11th FYP to probe into the effectiveness of the national emission control efforts. Base case simulation showed distinct seasonal variation for gaseous pollutants: SO2, and NO2 were found to have higher surface concentrations in winter while O3 was found to have higher concentrations in spring and summer than other seasons. According to the analyses focused on 3 megacities within YRD, Shanghai, Nanjing, and Hangzhou, we found different air quality conditions among the cities: NO2 was the primary pollutant that having the largest number of days exceeding the CH-NAAQS daily standard (80 μg/m3) in Shanghai (59 days) and Nanjing (27 days); SO2 was the primary pollutant with maximum number of days exceeding daily air quality standard (150 μg/m3) in Hangzhou (28 days), while O3 exceeding the daily maximum 8-hour standard (160 μg/m3) for relatively fewer days in all the three cities (9 days in Shanghai, 14 days in Nanjing, and 11 days in Hangzhou). Simulation results from predefined potential applicable emission control scenarios suggested significant air quality improvements from emission reduction: 90% of SO2 emission removed from power plant in YRD would be able to reduce more than 85% of SO2 pollution, 85% NOx emission reduction from power plant would reduce more than 60% of NO2 pollution, in terms of reducing the number of days exceeding daily air quality standard. NOx emission reduction from transportation and industry were also found to effectively reduce NO2 pollution but less efficient than emission control from power plants. We also found that multi-pollutants emission control including both NOx and VOC would be a better strategy than independent NOx control over YRD which is China’s 12th Five-Year-Plan (from 2011 to 2015), because O3 pollution would be increased as a side effect of NOx control and counteract NO2 pollution reduction benefit.

Chinese National Air Quality Standard↗
DOE OSTI2015

CH{sub 4} and N{sub 2}O emissions from China’s beef feedlots with ad libitum and restricted feeding in fall and spring seasons

Accurately quantifying methane (CH{sub 4}) and nitrous oxide (N{sub 2}O) emissions from beef operations in China is necessary to evaluate the contribution of beef cattle to greenhouse gas budgets at the national and global level. Methane and N{sub 2}O emissions from two intensive beef feedlots in the North China Plain, one with a restricted feeding strategy and high manure collection frequency and the other with an ad libitum feeding strategy and low manure collection frequency, were quantified in the fall and spring seasons using an inverse dispersion technique. The diel pattern of CH{sub 4} from the beef feedlot with an ad libitum feed strategy (single peak during a day) differed from that under a restricted feeding condition (multiple peaks during a day), but little difference in the diel pattern of N{sub 2}O emissions between two feeding strategies was observed. The two-season average CH{sub 4} emission rates of the two intensive feedlots were 230 and 198 g CH{sub 4} animal{sup −1} d{sup −1} and accounted for 6.7% and 6.8% of the gross energy intake, respectively, indicating little impact of the feeding strategy and manure collection frequency on the CH{sub 4} conversion factor at the feedlot level. However, the average N{sub 2}O emission rates (21.2 g N{sub 2}O animal{sup −1} d{sup −1}) and conversion factor (8.5%) of the feedlot with low manure collection frequency were approximately 131% and 174% greater, respectively, than the feedlot under high frequency conditions, which had a N{sub 2}O emission rate and conversion factor of 9.2 g N{sub 2}O animal{sup −1} d{sup −1} and 3.1%, respectively, indicating that increasing manure collection frequency played an important role in reducing N{sub 2}O emissions from beef feedlots. In addition, comparison indicated that China’s beef and dairy cattle in feedlots appeared to have similar CH{sub 4} conversion factors. - Highlights: • CH{sub 4} and N{sub 2}O emissions from China’s beef feedlots were provided in the first time. • Feeding strategies determined the diurnal pattern of feedlot CH{sub 4} emission. • Frequency of manure collection played an important role in N{sub 2}O from feedlots.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Integrated system to reduce emissions from natural gas-fired reciprocating engines

Natural gas-fired reciprocating engines (NGFRE), which are naturally aspirated are used in the oil and gas industry for the production, storage, processing, and transmission of natural gas extracted from wells. These stationary, lean-burn engines exhibit increased combustion instability and higher emissions of methane (CH 4 ) and Volatile Organic Compounds (VOCs) at lower loads, resulting in restrictions on the operational envelope of such engines. Here, in this paper, some of the emission reduction technologies for NGFREs are reviewed. Also, an experimental investigation of an integrated system to reduce emissions and improve the combustion performance of an NGFRE is presented. The integrated system consists of an air management package and integrated sensors including an amperometric NOx/O 2 sensor, exhaust temperature thermocouple, pressure transducers and vibration sensors. Experiments were carried out using natural gas and natural gas/propane blends at different load steps, and combustion performance, as well as emissions, were analyzed. For natural gas fuel, the results show that the standard deviation of peak pressure and indicated thermal efficiency (ITE) improved by 67.4 psi and 4.2% respectively, at 40% load. Similarly, CH 4 and Nitrogen Oxides (NOx) emissions reduced considerably by 84% and 63% respectively. However, CO emissions increased from 8 ppm to 152 ppm. At 60% load, the ITE improved by 3.8% and the CH 4 emissions were reduced by 68%. The reduction in VOCs emissions was 63% at 40% load and 69% at 60% load. The findings of this research provide evidence of the effectiveness of the integrated air management system in improving the sustainability of NGFREs. In general, this technology can be implemented on air-assisted combustion applications to improve combustion performance and, consequently, reduce emissions.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2013

Structural consideration on the emission properties of Eu²⁺-doped Ba(Sr, Ca)₂MgSi₂O₈

Emission properties of Eu²⁺-doped Ba(Sr, Ca)₂MgSi₂O₈ are discussed in terms of the crystal structure refined by Rietveld method. Ba(Sr, Ca)₂MgSi₂O₈ has glaserite-type layered structure. In response to Sr/(Sr+Ca) ratio, the layer-framework build up by corner-sharing of MgO₆ octahedra and SiO₄ tetrahedra twists around C₃ axes to match the size of B-site cation (Sr²⁺/Ca²⁺). This twist significantly affects the unit cell size and the coordination environment around B-site. Eu²⁺-doped Ba(Sr, Ca)₂MgSi₂O₈ exhibited blue emission under ultraviolet irradiation. The emission spectra have been characterized by two emission components derived from Eu²⁺ ions occupying A- and B-site. Both components showed similar wavelength shift for different Sr/(Sr+Ca), in response to Si–O₁ polarization and to the structural change. - Graphical abstract: Emission properties of Eu²⁺-doped Ba(Sr, Ca)₂MgSi₂O₈ are discussed in terms of the crystal structure refined by Rietveld method. Highlights: • Glaserite-type Ba(Sr, Ca)₂MgS₂O₈ has been prepared by a solid state reaction. • Ba(Sr, Ca)₂MgSi₂O₈ changes the crystal structure, depending on Sr/(Sr+Ca) ratio. • Eu²⁺-doped Ba(Sr, Ca)₂MgSi₂O₈ exhibits blue emission under ultraviolet irradiation. • Emission from Ba(Sr, Ca)₂MgSi₂O₈ is characterized by two Eu²⁺ emission components. • The two emissions show wavelength shift in a similar manner against Sr/(Sr+Ca)

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2011

Gas production, composition and emission at a modern disposal site receiving waste with a low-organic content

AV Miljo is a modern waste disposal site receiving non-combustible waste with a low-organic content. The objective of the current project was to determine the gas generation, composition, emission, and oxidation in top covers on selected waste cells as well as the total methane (CH{sub 4}) emission from the disposal site. The investigations focused particularly on three waste disposal cells containing shredder waste (cell 1.5.1), mixed industrial waste (cell 2.2.2), and mixed combustible waste (cell 1.3). Laboratory waste incubation experiments as well as gas modeling showed that significant gas generation was occurring in all three cells. Field analysis showed that the gas generated in the cell with mixed combustible waste consisted of mainly CH{sub 4} (70%) and carbon dioxide (CO{sub 2}) (29%) whereas the gas generated within the shredder waste, primarily consisted of CH{sub 4} (27%) and nitrogen (N{sub 2}) (71%), containing no CO{sub 2}. The results indicated that the gas composition in the shredder waste was governed by chemical reactions as well as microbial reactions. CH{sub 4} mass balances from three individual waste cells showed that a significant part (between 15% and 67%) of the CH{sub 4} generated in cell 1.3 and 2.2.2 was emitted through leachate collection wells, as a result of the relatively impermeable covers in place at these two cells preventing vertical migration of the gas. At cell 1.5.1, which is un-covered, the CH{sub 4} emission through the leachate system was low due to the high gas permeability of the shredder waste. Instead the gas was emitted through the waste resulting in some hotspot observations on the shredder surface with higher emission rates. The remaining gas that was not emitted through surfaces or the leachate collection system could potentially be oxidized as the measured oxidation capacity exceeded the potential emission rate. The whole CH{sub 4} emission from the disposal site was found to be 820 {+-} 202 kg CH{sub 4} d{sup -1}. The total emission rate through the leachate collection system at AV Miljo was found to be 211 kg CH{sub 4} d{sup -1}. This showed that approximately 1/4 of the emitted gas was emitted through the leachate collections system making the leachate collection system an important source controlling the overall gas migration from the site. The emission pathway for the remaining part of the gas was more uncertain, but emission from open cells where waste is being disposed of or being excavated for incineration, or from horizontal leachate drainage pipes placed in permeable gravel layers in the bottom of empty cells was likely.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2020

Methane Emissions from Gathering Compressor Stations in the U.S.

Using results from a nationally representative measurement campaign at 180 gathering compressor stations conducted with nine industry partners, this study estimated emissions for the U.S. gathering sector, where sector-specific emission factors have not been previously available. The study drew from a partner station population of 1705 stations—a significantly larger pool than was available for prior studies. Data indicated that whole gas emission rates from components on gathering stations were comparable to or higher than emission factors utilized by the EPA’s greenhouse gas reporting program (GHGRP) but less than emission factors used for similar components on transmission compressor stations. Field data also indicated that the national population of stations likely has a higher fraction of smaller stations, operating at lower throughput per station, than the data used to develop the per-station emission factor used in EPA’s greenhouse gas inventory (GHGI). This was the first national study to incorporate extensive activity data reported to the GHGRP, including 319 basin-level reports, covering 15,895 reported compressors. Further, combining study emission data with 2017 GHGRP activity data, the study indicated statistically lower national emissions of 1290 [1246–1342] Gg methane per year or 66% [64–69%] of current GHGI estimates, despite estimating 17% [12–22%] more stations than the 2017 GHGI (95% confidence interval). Finally, we propose a replicable method that uses GHGRP activity data to annually update GHGI gathering and boost sector emissions.

03 NATURAL GAS↗
DOE OSTI2024

Thermal-Strain-Enabled Enhanced Emission from UV Laser-Induced Defect Levels near the Surface of Multilayer MoS 2

Monolayer two-dimensional (2D) materials have been intensively studied while research on multilayers is still in its infancy. Here, we induce defects inside bulk MoS 2 through thermal annealing and near the surface of multilayer MoS 2 using 375 nm laser irradiation, and investigate their photoluminescence (PL) and fluorescence lifetime imaging (FLIM). Enhanced emission is limited within a certain MoS 2 thickness. The observed enhanced emission is evidenced by a threshold behavior in super-linear PL intensity increase, strong polarization effects, and increased lifetime of defect peak. The laser power threshold for enhanced emission is much smaller in defects near the surface than that inside the bulk of multilayer MoS 2 . The mechanical strain from a wrinkle of the sample further lowers the laser power threshold for enhanced emission. By exciting with a 639 nm laser that is close to the fundamental gap between the conduction band minimum and the valence band maximum, the lifetime of defect enhanced emission increased by 5 times. Furthermore, one of the competing indirect bandgap emissions disappears, and the defect emission peak dominates the PL spectrum in the wrinkle area with a strain. Furthermore, the discovered principle can be applied to future studies on the integration of enhanced emission and single photon emission involving selectively depopulating the conduction band of the host crystal to defect levels for quantum emitters.

2D materials↗