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At least 883 records · Page 49
All sourcesNASA NTRSDOE OSTI
NASA NTRS1973

Photochemistry of interstellar molecules

The role of photochemistry in determining the lifetime of interstellar molecules is considered. The probability of photodecomposition depends on three factors, including the absorption cross section, the quantum yield or probability of dissociation following photon absorption, and the interstellar radiation field. A more detailed discussion of the photochemistry of five molecules is presented, giving attention to carbonyl sulfide, methyl acetylene, nitric oxide, acetylene, and benzene. Lifetimes of interstellar molecules in unobscured regions are in the range from 5 to 100 years. It is concluded that polyatomic molecules can exist only in dense clouds which protect them from the full interstellar radiation field.

Stief, L. J.↗
NASA NTRS1974

The atmospheres of Titan and the Galilean satellites

The stability of various atmospheres on Titan and the Galilean satellites is examined relative to escape. One method consists of the comparison of exospheric temperature and a blow-off temperature defined for the various constituents. Another method consists of the evaluation of outflow based on a polytropic model. Hydrogen, methane, nitrogen, and neon atmospheres are examined. It is found that the Jovian satellites require heavier gases if they are to have any but very tenuous atmospheres, since all constituents examined are unstable. Nitrogen is stable on Titan, but methane and neon are marginally stable. Hydrogen is extremely unstable as a major constituent. As a minor constituent it is rapidly lost from Titan's thermosphere and must be replenished by outgassing or dissociation of a hydrogen compound, if the presently observed hydrogen content on Titan is not a transient occurrence. The rate of loss may be limited by diffusion, but could be augmented by vertical convection.

Gross, S. H.↗
NASA NTRS1974

Nonequilibrium boundary layer at a stagnation point for a hydrogen-helium stream over ablating graphite

The nonequilibrium axisymmetric stagnation point boundary layer over an ablating graphite surface is considered. The external stream is a high temperature mixture of hydrogen and helium. Variable thermodynamic and transport properties are assumed. Lennard-Jones potential model is used to calculate the transport coefficients of each species. Although the mixture rules for viscosity of the gas mixture are used, the weighting functions are more sophisticated than those commonly employed. For the conductivity of the mixture, generalized Wassiljewa coefficients are used. Seven species with 28 dissociation/recombination reactions are considered. Hansen's model for the dissociation rate constants is employed. The recombination rate constants are obtained by invoking detailed balance principles assisted by the JANAF thermodynamic data and the Hansen-Pearson thermodynamic data for C3.

Liu, T.-M.↗
NASA NTRS1974

An experimental and analytical study of slip and catalytic boundary conditions applied to spheres in low Reynolds number arc jet flows

Measurements of low-density dissociated arc-heated flows around low and high surface catalycity spheres are compared with numerical solutions to the full Navier-Stokes equations for reacting gas flow fields, taking into account slip and finite surface catalytic boundary conditions. A time-dependent finite difference solution technique developed by Li (1973, 1974) is used in the investigation and a simple transport model is employed for the flows considered. The correctness of the solution approach is demonstrated by the very good agreement obtained between experimental and computational data.

Scott, C. D.↗
NASA NTRS1974

Measurements of ion-molecule reactions of He/+/, H/+/, and HeH/+/ with H2 and D2

Drift tube-mass spectrometer measurements of several ion-molecule reactions believed to be prominent in the hydrogen-helium upper atmosphere of Jupiter are described. The total rate constant at 300 K of the reaction of He(+) with H2 is about 1.1 x 10 to the neg 13 cu cm/sec. The reaction proceeds mainly by dissociative charge transfer to produce H(+), with a small portion going by charge transfer to H2(+) and by atom rearrangement to HeH(+). The rate coefficient increases slowly with ion mean energy to a value of 2.8 x 10 to the neg 13 at 0.18 eV. The rate of the corresponding reaction with deuterium, He(+) + D2, has the rate coefficient of about 5 x 10 to the neg 14 at 300 K. Measurements of the three-body reaction of H' and the two-body reaction of HeH' with H2 to form H3(+) ions are described.

Johnsen, R.↗
NASA NTRS1974

CH and CH/+/ in interstellar clouds

Recycling and loss rates for a typical interstellar cloud are considered, giving attention to disagreements concerning some of the production rates. It is pointed out that the formation rate of CH(+) via vibrationally excited hydrogen molecules exceeds in many situations rates of other processes. In low density clouds comparable amounts of CH and CH(+) are produced when the fast dissociative recombination rate is used.

Stecher, T. P.↗
NASA NTRS1974

Manufacture and deflagration of an atomic hydrogen propellant

It is observed that the use of very low temperatures (in the range from 0.1 to 1.5 K) produced by advanced cryogenic apparatus and the use of very strong magnetic fields (in the range from 50 to 100 kG) produced by superconducting magnets can yield a significant improvement in the atomic hydrogen trapping effectiveness of an H2 matrix. The use of a radioactive beta-ray emiter isotope may yield H-H2 propellants (with a specific impulse of about 740 sec) by secondary electron impact dissociations of H2 in an impregnated matrix maintained below 1 K in a strong magnetic field. Another method for manufacturing an H-H2 propellant involves bombardment of supercooled solid H2 with a cyclotron-produced beam of 10-MeV hydrogen atoms. The matrix-isolated atomic hydrogen must be used directly without prior melting as a solid propellant, and an analysis of the steady deflagration is presented.

Rosen, G.↗
NASA NTRS1975

Laser using lead chloride vapor

By applying electric discharge, lead chloride vapor in tube is dissociated into lead and chlorine atoms. Population inversion of lead atoms is attained subsequently by second discharge, before chemical recombination of lead and chlorine has occurred. Optimum time interval between two discharges is required for maximum laser output.

Chen, C. J.↗
NASA NTRS1975

High-power CW laser using hydrogen-fluorine reaction

Continuous-wave laser has been proposed based on reaction of hydrogen and fluorine. Hydrogen is produced by dissociation of hydrazine, which can be stored as liquid in light containers at room temperature.

Moynihan, P. I.↗
NASA NTRS1973

Evaluation of Electrochemical Nitrogen/hydrogen Gas Separator

An electrochemical nitrogen-hydrogen separator subsystem was investigated for use following catalytic dissociation of ammonia or hydrazine in a storage system being considered for long-duration manned space flight. An experimental cell with concentric tubular Pd-25Ag alloy hydrogen diffusion electrodes and hermetically sealed aqueous caustic electrolyte was developed.It was found that this cell operated satisfactorily at 210 C to 245 C and produced dry nitrogen and dry hydrogen with either or both gases at pressures up to 6.8 atmospheres (100 psia) or higher for storage. The final cell developed was operated satisfactorily for 176 days (4200 hours) with no evidence of deterioration of current-voltage performance. The best experimental performance was obtained at 245 C at currents up to 4 amperes (180 ma/sq cm and 360 ma/sq cm anode and cathode current densities, respectively) with a maximum steady-state cell voltage of 0.125 volt for an anode feed of pure hydrogen.

Clifford, J. E.↗
NASA NTRS1975

Reaction of sulfur dioxide with modified 440C, studied by Auger electron spectroscopy and depth profiling

Auger electron spectroscopy and sputtering were used to study the interaction of SO2 with modified 440C, which is a nominally 77-wt%-Fe, 14-wt%-Cr, and 4-wt%-Mo bearing steel with C, S, Si, Ni, V, P, and Mn making up the balance. The sample was polycrystalline. Three temperatures were used: room temperature, 500 C, and 600 C. The reaction time was varied from 30 minutes to 2 hours. A surface cleaned of oxides was the starting point for each reaction. For reactions at 500 C, the major constituents Cr, O, Fe, and S were present in the surface film. At 600 C, the principal constituents of the film were Cr, O, and S with no Fe present. Therefore, a transition in film composition occurred between 500 and 600 C. Oxides were the primary constituents of the films at both temperatures. Room-temperature reactions indicated that SO2 adsorbed dissociatively, with approximately equal quantities of S and O on the surface. For the same reaction time (1 hr) and pressure, a strong temperature dependence of film thickness was observed. The film formed at 600 C was approximately seven times thicker than that formed at 500 C.

Ferrante, J.↗
NASA NTRS1975

Angular distribution, kinetic energy distributions, and excitation functions of fast metastable oxygen fragments following electron impact of CO2

Dissociative excitation of CO2 by electron impact was studied using the methods of translational spectroscopy and angular distribution analysis. Earlier time of flight studies revealed two overlapping spectra, the slower of which was attributed to metastable CO(a3 pi) fragments. The fast peak is the focus of this study. Threshold energy, angular distribution, and improve time of flight measurements indicate that the fast peak actually consists of five overlapping features. The slowest of the five features is found to consist of metastable 0(5S) produced by predissociation of a sigma u + state of CO2 into 0(5S) + CO(a3 pi). Oxygen Rydberg fragments originating directly from a different sigma u + state are believed to make up the next fastest feature. Mechanisms for producing the three remaining features are discussed.

Misakian, M.↗
NASA NTRS1975

High temperature chemical kinetic study of the H2-CO-CO2-NO reaction system

An experimental study of the kinetics of the H2-CO-CO2-NO reaction system was made behind incident shock waves at temperatures of 2460 and 2950 K. The overall rate of the reaction was measured by monitoring radiation from the CO + O yields CO2 + h upoilon reaction. Correlation of these data with a detailed reaction mechanism showed that the high-temperature rate of the reaction N + OH yields NO + H can be described by the low-temperature (320 K) rate coefficient. Catalytic dissociation of molecular hydrogen was an important reaction under the tests conditions.

Jachimowski, C. J.↗
NASA NTRS1975

Study of the reaction of atomic oxygen with aerosols

The rate of disappearance of atomic oxygen was measured at several pressures in a fast flow pyrex reactor system with its walls treated with (NH4)2SO4 (s), H2SO4 (l), and NH4CL (s). Atomic oxygen, P-3 was generated by dissociation of pure, low pressure oxygen in a microwave discharge. Concentrations of atomic oxygen were measured at several stations in the reactor system using chemiluminescent titration with NO2. Recombination efficiencies calculated from experimentally determined wall recombination rate constants are in good agreement with reported values for clean Pyrex and an H2SO4 coated wall. The recombination efficiency for (NH4)2SO4, results in a slightly lower value than for H2S04. A rapid exothermic reaction between atomic oxygen and the NH4Cl wall coating prevented recombination efficiency determination for this coating. The results show that the technique is highly useful for wall recombination measurements and as a means of extrapolating to the case of free stream aerosol-gas interactions.

Akers, F. I.↗
NASA NTRS1975

Emission spectrometric arcing procedure with minimal effect of chemical form of sample

Matrix effects related to the chemical form of analyzed materials were studied. An arc in argon was used which was buffered with silver chloride. The effect of chemical form was minimal for a variety of metals, oxides, and carbides representing the most refractory compounds and thermally stable metal-containing molecules. Only four of the most refractory materials known showed significant emission depressions due to incomplete volatilization in the arc system. These results are discussed in terms of vapor pressures of the solid materials placed on the anodes and dissociation reactions of the molecules in the gaseous environment.

Gordon, W. A.↗
NASA NTRS1975

Free radical OH, a molecule of astrophysical and aeronomic interest

The chemistry and physics of the gaseous OH free radical as it applies to interstellar space, planetary atmospheres, and the sun is presented. Topics considered are: (1) rotational-vibrational transitions; (2) dissociation and ionization processes; (3) spectral characteristics.

Mohan, H.↗
NASA NTRS1974

NO/+/ and O/+/ in the high latitude F-region

From an analysis of ionic reactions, it is deduced that NO(+) should be an important constituent of the high-latitude F-region. Owing to the rapid increase of the reaction O(+) + N2 yields NO(+) + N with ion velocity and temperature, high latitude electric fields and consequent E x B drifts act to deplete O(+) in favor of NO(+). As a consequence of this and the reduced rate of NO(+) dissociative recombination arising from high electron temperatures, it seems that NO(+) can, at times, replace O(+) as the major F2-region ion in the vicinity of the auroral ovals. The same processes should also be effective in creating nighttime electron density troughs composed primarily of NO(+) in regions equatorward of the auroral ovals where large electric fields are often present.

Banks, P. M.↗