Temperature effects on silicon solar-cell short-circuit currents
Temperature effects on Si solar cell short circuit currents, considering solar spectrum, photon absorption coefficient and diffusion length
Shumka, A.↗
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Results for “Diffusion coefficient”
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An example of the use of laboratory results in the optics of the sea
A relation between the average cosine in underwater conditions and the coefficient of diffuse reflection is used to determine the optical characteristics of the sea. The cosine is considered equal to the ratio of the radiation flux through a horizontal cross section to the flux irradiating a spherical surface surrounding the observation point.
Timofeyeva, V. A.↗
Gas phase hydrogen permeation in alpha titanium and carbon steels
Commercially pure titanium and heats of Armco ingot iron and steels containing from 0.008-1.23 w/oC were annealed or normalized and machined into hollow cylinders. Coefficients of diffusion for alpha-Ti and alpha-Fe were determined by the lag-time technique. Steady state permeation experiments yield first power pressure dependence for alpha-Ti and Sievert's law square root dependence for Armco iron and carbon steels. As in the case of diffusion, permeation data confirm that alpha-titanium is subject to at least partial phase boundary reaction control while the steels are purely diffusion controlled. The permeation rate in steels also decreases as the carbon content increases. As a consequence of Sievert's law, the computed hydrogen solubility decreases as the carbon content increases. This decreases in explained in terms of hydrogen trapping at carbide interfaces. Oxidizing and nitriding the surfaces of alpha-titanium membranes result in a decrease in the permeation rate for such treatment on the gas inlet surfaces but resulted in a slight increase in the rate for such treatment on the gas outlet surfaces. This is explained in terms of a discontinuous TiH2 layer.
Johnson, D. L.↗
Modification of the flow pass method as applied to problems of chemistry of planet atmospheres
It was shown that the modified flow pass method possesses considerable effectiveness, both in the case when the coefficient of diffusion changes severely in the examined region and in the case when diffusion is the prevalent process, as compared with chemical reactions. The case when a regular pass proves inapplicable, or applicable in a limited interval of the decisive parameters, was examined.
Parshev, V. A.↗
High power densities from high-temperature material interactions
Thermionic energy conversion (TEC) and metallic-fluid heat pipes (MFHPs), offering unique advantages in terrestrial and space energy processing by virtue of operating on working-fluid vaporization/condensation cycles that accept great thermal power densities at high temperatures, share complex materials problems. Simplified equations are presented that verify and solve such problems, suggesting the possibility of cost-effective applications in the near term for TEC and MFHP devices. Among the problems discussed are: the limitation of alkali-metal corrosion, protection against hot external gases, external and internal vaporization, interfacial reactions and diffusion, expansion coefficient matching, and creep deformation.
Morris, J. F.↗
End region and current consolidation effects upon the performance of an MHD channel for the ETF conceptual design
The effects of MHD channel end regions on the overall power generation were considered. The peak plant thermodynamic efficiency was found to be slightly lower than for the active region (41%). The channel operating point for the peak efficiency was shifted to the supersonic mode (Mach No., M sub c approx. 1.1) rather than the previous subsonic operation (M sub c approx. 0.9). The sensitivity of the channel performance to the B-field, diffuser recovery coefficient, channel load parameter, Mach number, and combustor pressure is also discussed. In addition, methods for operating the channel in a constant-current mode are investigated. This mode is highly desirable from the standpoint of simplifying the current and voltage consolidation for the inverter system. This simplification could result in significant savings in the cost of the equipment. The initial results indicate that this simplification is possible, even under a strict Hall field constraint, with resonable plant thermodynamic efficiency (40.5%).
Wang, S. Y.↗
Transient thermal stress problem for a circumferentially cracked hollow cylinder
The transient thermal stress problem for a hollow elasticity cylinder containing an internal circumferential edge crack is considered. It is assumed that the problem is axisymmetric with regard to the crack geometry and the loading, and that the inertia effects are negligible. The problem is solved for a cylinder which is suddenly cooled from inside. First the transient temperature and stress distributions in an uncracked cylinder are calculated. By using the equal and opposite of this thermal stress as the crack surface traction in the isothermal cylinder the crack problem is then solved and the stress intensity factor is calculated. The numerical results are obtained as a function of the Fourier number tD/b(2) representing the time for various inner-to-outer radius ratios and relative crack depths, where D and b are respectively the coefficient of diffusivity and the outer radius of the cylinder.
Nied, H. F.↗
End region and current consolidation effects upon the performance of an MHD channel for the ETF conceptual design
It is noted that operating conditions which yielded a peak thermodynamic efficiency (41%) for an EFT-size MHD/steam power plant were previously (Wang et al., 1981; Staiger, 1981) identified by considering only the active region (the primary portion for power production) of an MHD channel. These previous efforts are extended here to include an investigation of the effects of the channel end regions on overall power generation. Considering these effects, the peak plant thermodynamic efficiency is found to be slightly lowered (40.7%); the channel operating point for peak efficiency is shifted to the supersonic mode (Mach number of approximately 1.1) rather than the previous subsonic operation (Mach number of approximately 0.9). Also discussed is the sensitivity of the channel performance to the B-field, diffuser recovery coefficient, channel load parameter, Mach number, and combustor pressure.
Wang, S. Y.↗
Ocean color measurements
Ocean color observations by the Coastal Zone color scanner (CZCS) aboard the Nimbus-7 satellite are discussed, together with the factors contributing to the 'apparent' color of the ocean. The CZCS optical systems and the tecniques for extraction of the phytoplankton pigment concentration and the diffuse attenuation coefficient K from the 'apparent' water color are described in detail. Special consideration is given to the use of biooptical algorithms and the development of the K algorithm for the CZCS imagery. It is shown that under typical atmospheric conditions, the pigment concentration can be extracted from the satellite imagery to within + or - 30 percent over concentration ranges from 0 to 5 mg/cu m for the Morel case 1 water (Morel and Prieur, 1977), to which the oceanic waters belong as a rule.
Gordon, H. R.↗
Moorable spectroradiometers in the BIOWATT experiment
A new oceanographic instrument, the MER-2020, has been developed for the long term measurement of bio-optical properties. This instrument is a self-contained reflectance spectroradiometer with 40 megabytes of internal data storage and battery power permitting deployments for as long as 6 months. It can serve as the control and recording center for a variety of other sensors including fluorometers, transmissometers, temperature and conductivity probes. Instruments of this type were deployed at depths to 70 meters on a 5000 meter mooring during the BIOWATT experiment between February and November 1987. Measurements of the spectral diffuse attenuation coefficient and of the remote sensed reflectance from the ten month period in 1987 in the Northern Sargasso Sea are presented. In addition, the temperature, pressure, package orientation and sunlight stimulated natural fluorescence of phytoplankton are discussed. This instrument will be a key part of in situ optical calibration for future remote color sensors, and presently permits direct measurement of long term optical variability, important in visibility and communication problems.
Booth, C. R.↗
FTIR Spectroscopic Characterization Of II-VI Semiconductors
Combination of commercial Fourier-transform infrared (FTIR) spectrometer with computer and special-purpose software constitutes highly automated facility for acquisition and processing of infrared transmission or reflection spectral image data. Intended principally to acquire transmission spectra of some compounds of elements in groups II and VI of periodic table. System used to characterize specimens of II/VI alloy semiconductors grown by directional solidification and quenching. Transmission-edge maps helpful in studies of flows, gradients of temperature, and coefficients of diffusion in solidifying melts. Data acquired by system include optical characteristics, and they both verify and complement data obtained by such other techniques as measurements of density and x-ray-dispersion analysis.
Perry, G. L. E.↗
Optical variability and pigment biomass in the Sargasso Sea as determined using deep-sea optical mooring data
A 9-month time series of optical data, composed of three separate deployments, from the Biowatt 1987 deep-sea mooring located in the oligotrophic waters of the Sargasso Sea at 32 deg N, 70 deg W, is presented. These data were analyzed using several biooptical models for the purpose of providing a continuous estimate of the spectral diffuse attenuation coefficient and pigment biomass. Results of the first 70-day deployment demonstrate the utility of optical observations as proxy measures of biological parameters, and facilitate a preliminary analysis of the temporal variations and a comparison of the present biooptical observations with concurrent physical observations. Biooptical properties exhibit variation in response to physical forcings, such as diel variations of incident solar irradiance, episodic wind forcing, advective mesoscale eddy layer depth, and succession of phytoplankton. The mooring data are discussed in the context of contemporaneous shipboard observations as well as in terms of future ocean satellite observations.
Smith, R. C.↗
Follow up on the crystal growth experiments of the LDEF
The 4 solution growth experiments on the LDEF were presented thoroughly elsewhere. The CaCO3-experiment, and to a certain extent also the TTF-TCNQ-experiments yielded useful results. In Jan. 1992, the next series of solution growth experiments were sent to ESA for shipment to KSC. As on the LDEF, the SGF (solution growth facility) of the EURECA-1 contains 4 large experiments. From the beginning, the planning and developments were introduced. Still, the basic concept was maintained, and the CaCO3-experiment, that showed the best results on the LDEF, will now be repeated with improved technology and in larger scale on the EURECA-1. The contents of the 4 SGF experiments are as follows: (1) growth of calcium-carbonate crystals; (2) formation and transformation of tri-calcium-phosphate; (3) growth of zeolite crystals; and (4) soret coefficient measurements (diffusion). The scientific background for the choice of experiments and the major improvements of the SGF are reviewed. Furthermore, some ideas on basic microgravity solution growth experimentation from ESA's newly established EWG (Expert Working Group) on solution growth are reported.
Nielsen, K. F.↗
Testing the Li-Strahler four-component canopy reflectance model in the HAPEX-Sahel shrub savanna sites using ground reflectance data
The rate at which a light field decays in water is characterized by the diffuse attenuation coefficient k. The Li-Strahler discrete-object canopy reflectance model was tested in two sites, a shrub grass savanna and a degraded shrub savanna on bare soil, in the proposed HAPEX (Hydrologic Atmospheric Pilot Experiment) II/Sahel study area in Niger, West Africa. Average site reflectance was predicted for each site from the reflectances and cover proportions of four components: shrub canopy, background (soil or grass and soil), shaded canopy, and shaded background. Component reflectances were sampled in the SPOT wavebands using a hand-held radiometer. Predicted reflectance was compared to average site reflectance measured using the same radiometer mounted on a backpack with measurements recorded every 5 m along two 1-km transects, also in the SPOT (Systeme Probatoire d'Observation de la Terre) bands. Measurements and predictions were made for each of the three days during the summer growing season, approximately two weeks apart. Red, near infrared reflectance, and the NDVI (normalized difference vegetation index) were all predicted with a high degree of accuracy for the shrub/grass site and with reasonable accuracy for the degraded shrub site.
Franklin, J.↗
The Airborne Ocean Color Imager - System description and image processing
The Airborne Ocean Color Imager was developed as an aircraft instrument to simulate the spectral and radiometric characteristics of the next generation of satellite ocean color instrumentation. Data processing programs have been developed as extensions of the Coastal Zone Color Scanner algorithms for atmospheric correction and bio-optical output products. The latter include several bio-optical algorithms for estimating phytoplankton pigment concentration, as well as one for the diffuse attenuation coefficient of the water. Additional programs have been developed to geolocate these products and remap them into a georeferenced data base, using data from the aircraft's inertial navigation system. Examples illustrate the sequential data products generated by the processing system, using data from flightlines near the mouth of the Mississippi River: from raw data to atmospherically corrected data, to bio-optical data, to geolocated data, and, finally, to georeferenced data.
Wrigley, Robert C.↗
SeaWiFS technical report series. Volume 26: Results of the SeaWiFS Data Analysis Round-Robin, July 1994 (DARR-1994)
The accurate determination of upper ocean apparent optical properties (AOP's) is essential for the vicarious calibration of the sea-viewing wide field-of-view sensor (SeaWiFS) instrument and the validation of the derived data products. To evaluate the role that data analysis methods have upon values of derived AOP's, the first Data Analysis Round-Robin (DARR-94) workshop was sponsored by the SeaWiFS Project during 21-23 July, 1994. The focus of this intercomparison study was the estimation of the downwelling irradiance spectrum just beneath the sea surface, E(sub d)(0(sup -), lambda); the upwelling nadir radiance just beneath the sea surface, L(sub u)(0(sup -), lambda); and the vertical profile of the diffuse attenuation coefficient spectrum, K(sub d)(z, lambda). In the results reported here, different methodologies from four research groups were applied to an identical set of 10 spectroradiometry casts in order to evaluate the degree to which data analysis methods influence AOP estimation, and whether any general improvements can be made. The overall results of DARR-94 are presented in Chapter 1 and the individual methods of the four groups are presented in Chapters 2-5. The DARR-94 results do not show a clear winner among data analysis methods evaluated. It is apparent, however, that some degree of outlier rejection is required in order to accurately estimate L(sub u)(0(sup -), lambda) or E(sub d)(0(sup -), lambda). Furthermore, the calculation, evaluation and exploitation of confidence intervals for the AOP determinations needs to be explored. That is, the SeaWiFS calibration and validation problem should be recast in statistical terms where the in situ AOP values are statistical estimates with known confidence intervals.
Hooker, Stanford B.↗
Coastal zone color scanner 'system calibration': A retrospective examination
During its lifetime the Coastal Zone Color Scanner (CZCS) produced approximately 66,000 images. These have been placed in an archive of 'raw' radiance (sensor counts) in a subsampled format that is easily accessible. They have also been processed to form global fields, at reduced resolution, of normalized water-leaving radiance, phytoplankton pigments, and diffuse attenuation coefficient. Using this archive, we have tried to characterize some aspects of the 'system calibration' for the 8-year lifetime of CZCS. Specifically, we have assumed that the sensitivity of the red band decayed in a simple manner similar to the well-known long-term degradation of the shorter-wavelength bands, and we examined the sensitivity of the green and yellow bands by computing the globally averaged water-leaving radiance, over 10-day periods, for all of the imagery. The results provided evidence that in addition to the long-term degradation, short-term (2 weeks to 1 month) variations in the radiometric sensitivity of these bands started in early fall 1981 and continued for the rest of the mission. In contrast, the data suggested the absence of such variations prior to August 1981. It is reasonable to believe that the sensitivity of the blue (and probably the red) band underwent such variations as well; however our methodology cannot be used to study the other bands. Thus, after these fluctuations began, the actual values of CZCS - estimated pigment concentrations at a given location should be viewed with skepticism; however, the global patterns of derived pigment concentrations should be valid. Had an extensive set of surface measurements of water-leaving radiance, e.r., from moored buoyes or drifters, had been available during the CZCS mission, these fluctuations could have been removed from the data set, and this would have greatly increased its value. The lessons learned from CZCS that is, the requirement of good radiometric calibration and stability and the necessity of 'sea truth' stations to monitor the performance of the system (sensor plus algorithms), are being applied to the sea-viewing wide-field-of-view senso (Sea WiFS) scheduled for launch in August 1993.
Evans, Robert H.↗
Seasonal variability of light availability and utilization in the Sargasso Sea
A 2 year time series of optical, biogeochemical, and physical parameters, taken near the island of Bermuda, is used to evaluate the sources of temporal variability in light avaliability and utilization in the Sargasso Sea. Integrated assessments of light availability are made by examining the depth of constant percent incident photosynthetically available radiation (% PAR) isolumes. To first order, changes in the depth %PAR isolumes were caused by physical processes: deep convection mixing in the winter which led to the spring bloom and concurrent shallowing of %PAR depths and the occurrence of anomalous thermohaline water masses during the summer and fall seasons. Spectral light availability variations are assessed using determinations of diffuse attenuation coefficient spectra which illustrates a significant seasonal cycle in colored detrital particulate and/or dissolved materials that is unrelated to changes in chlorophyll pigment concentrations. Temporal variations in the photosynthetic light utilization index Psi are used to assess vertically intergrated light utilization variations. Values of Psi are highly variable and show no apparent seasonal pattern which indicates that Psi is not simply a 'biogeochemical constant.' Determinations of in situ primary production rates and daily mean PAR fluxes are used to diagnose the relative role of light limitation in determining vertically integrated rates of primary production integral PP. The mean depth of the light-saturated zone (the vertical region where the daily mean PAR flux was greater than or equal to the saturation irradiance) is only approximately 40 m, although more than one half of interal PP occurred within this zone. Production model results illustrate that accurate predictions of integral PP are dependent upon rates of light-saturated production rather than upon indices of light limitation. It seems unlikely that significant improvements in simple primary production models will come from the partitioning of the Earth's seas into biogeochemical provinces.
Siegel, David A.↗