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At least 883 records · Page 49

Thermal-Epithermal eXperiments – Hafnium Experiment Performed at the DOE’s National Criticality Experiments Research Center (NCERC)

The Thermal-Epithermal eXperiments (TEX) – Hafnium (TEX-Hf) experiments were completed in October 2022 at the DOE National Criticality Experiments Research Center (NCERC) at the Nevada National Security Site (NNSS). This measurement campaign provides seven unique configurations that can be used to validate the neutron absorption and scattering cross sections of hafnium in a highly enriched uranium (HEU) system. Hafnium is a strong neutron absorber important for marine propulsion systems. Mike Zerkle of the Naval Nuclear Laboratory (NNL) states, “The experiments were requested by Naval Reactors to provide a suite of unclassified, clean, and well-characterized benchmarks to drive improvements to hafnium nuclear data.” The experiments were a collaboration between Los Alamos National Laboratory (LANL), Lawrence Livermore National Laboratory (LLNL), and NNL, funded by the Nuclear Criticality Safety Program (NCSP). The Hf was procured directly by NNL and provided for the experiment.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Zeus: Fast-Spectrum Critical Assemblies with a Pb-HEU Core Surrounded by a Copper Reflector

The Zeus experiments with lead (Pb) were a series of measurements performed at the National Criticality Experiments Research Center (NCERC) in collaboration with the Japan Atomic Energy Agency (JAEA). Personnel from the JAEA who assisted with the experiment were Masahiro Fukushima and Akito Oizumi. The measurements were performed by Joetta Goda, Geordie McKenzie, John Bounds, Jessie Walker, Travis Grove, Theresa Cutler, Rene Sanchez, and Jesson Hutchinson from Los Alamos National Laboratory (LANL). The purpose of these experiments was to validate Pb nuclear cross sections and Pb void reactivity worth using the Comet critical assembly machine. Plates of highly enriched uranium (HEU) and Pb were arranged in a cylindrical configuration with full copper (Cu) reflection. To study the Pb void reactivity worth, a varying number of cylindrical aluminum (Al) spacers with voids replaced Pb plates in different configurations. Four configurations, which used zero to eight Al spacers, were evaluated as benchmarks.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Criticality Safety and Fuel Performance Considerations for Enrichment Above 5 Weight Percent in the Uranium Dioxide Fuel Cycle

The U.S. Nuclear Regulatory Commission (NRC) is preparing for anticipated licensing applications requesting fuel enrichments of UO 2 ceramic fuels enriched in excess of 5 weight percent (w/o) 235 U for commercial light-water reactors (LWRs). PNNL has been tasked with providing technical assistance to the NRC related to the review and approval of requests for enrichment increases above the current 5 w/o 235 U enrichment limit. This report will provide the agency with technical assistance to enhance the staff’s knowledge base and to identify developmental needs required to support the licensing of greater than 5 w/o UO 2 ceramic fuels. This report provides a background on increasing enrichment of UO 2 LWR fuel beyond 5 w/o 235 U. The primary concern of increasing enrichment is the impacts to criticality safety. This report will focus on criticality safety as it relates to enrichment, conversion of uranium hexafluoride to UO 2 , fuel assembly fabrication, transportation of fresh/spent fuel assemblies, reactor operations, and storage of fresh/spent fuel assemblies. The report provides a general summary of each of the steps in the UO 2 fuel cycle starting from transportation of enriched UF 6 through dry cask storage of spent fuel assemblies. This report also discusses other impacts of increased enrichment during reactor operation and the surrounding fuel cycle activities. Current needs regarding both data and analytical codes to support the increase above 5 w/o 235 U are identified and discussed.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Hydrothermal Liquid Recovery of Rare Earth Elements and Critical Materials

This project demonstrated the technical viability of using tunable hydrothermal liquid (HTL) solutions to recover valuable minerals from a range of source materials. The effort focused upon rare earth elements (REE) and other minerals critical to the industrial security of the United States. This effort demonstrated, for the first time, that s, supercritical water (SCW) in particular, can: Extract critical and valuable minerals from a range of matrices ranging from rock ore to biomass; The process can be used to recover a wide range of minerals; This novel extraction chemistry can be cheap, simple, and nontoxic/”green”: The chemical extraction uses water, the cheapest industrial acid (sulfuric), and simple salts (i.e. sodium sulfate). However, other acids, salts, and additives could be used as appropriate. This Laboratory Directed Research and Development (LDRD) project identified that the process is complex with many interacting factors, but the benefits are significant if the complexities can be resolved. Challenges remain in the development of this technology and are described in this report. However, the results are positive, and commercial partners have already expressed interest. In summary, a novel, green, inexpensive mineral extraction process has been developed and demonstrated in a small batch reactor system. The effort provided information for an invention disclosure, proposal to DOE, and will support future business development efforts.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

SOLAr Critical Infrastructure Energization (SOLACE): Leveraging Distributed Energy Resources to Provide Local Power

This document is a technical report based on a large-scale DOE-funded project conducted between 2019 and 2022. The project, called SOLAr Critical infrastructure Energization (SOLACE), is aimed at leveraging distributed energy resources (DERs) to provide local power to communities, feeders, or other regions. The project included a particular focus on high-value critical loads such as municipal water supply, telecommunication hubs, and disaster shelters. The key developments of the project were: (1) A comprehensive pre-event power system analysis methodology that identifies and characterizes the viable local power options. (2) A DMS-based example control system for activating and operating the local power solution during a time of crisis. (3) Grid-forming inverter technology to enable isolated local power operation and black-starting. (4) Cyber-security considerations for isolated systems when wider-area communication may be offline. This report describes the overall process that identifies and assesses the viable DER-based local power solutions for a given facility, region, or community. The report documents the process, including the key analysis steps, tools required, data requirements, and recommended pass/fail criteria for each step. It also provides a sample implementation of this process through a test case. Finally, it provides details of how a viable pre-event plan can be selected and activated at go-time when an event has occurred.

14 SOLAR ENERGY↗

Status of Multiphysics Modeling of Critical DPCs in a Geological Repository

A summary of previous work focused on the first two scenarios is presented as an established workflow. These canisters could reach an equilibrium at a low quasi–steady-state power level that could be sustained for thousands of years. The majority of this report describes an effort to expand the initial methodology to include the scenario in which a DPC has enough excess reactivity to boil the water inside the canister. This scenario involves a variety of tools and modeling approaches to capture the two-phase behavior, including RELAP5-3D, STAR-CCM+, and TRACE. Efforts using the high-fidelity computational fluid dynamics results to verify the accuracy of RELAP5-3D and TRACE for boiling DPCs are also presented. A new modeling strategy using TRACE appears to be the most promising approach for expanding the analysis of critical DPCs beyond the subcooled scenarios. Finally, this report describes ongoing work investigating the fourth scenario, in which a critical DPC is sealed in saturated bentonite. The primary goal in this research is to understand the power output and associated pressure increase to inform geomechanics simulations that could predict the impact on a geological repository.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Quantum criticality and topology in non-equilibrium systems

A key goal of condensed matter physics research is to identify new phases of matter, and to understand the universal features of the phase transitions between them. In the past decade, physicists have uncovered a wealth of new phases with interesting surface properties, exemplified by the theoretical prediction and subsequent experimental discovery of topological insulators and superconductors. Traditional condensed matter systems are usually in a thermal equilibrium state and typically at very low temperature. Very recently, experimental advances have sparked interest in the non-equilibrium setting. Non-equilibrium systems can host new phases and phenomena with no equilibrium counterpart, and could also enable robust ways to build quantum memory devices to store and manipulate quantum information in a coherent manner. These phases and phenomena are inherently “dynamical”: they are described not by changes in the arrangement or structure of the constituent particles, but instead marked by sharp distinctions in how the particles move and exchange energy or quantum information. The discovery of robust non-equilibrium phases raises many fundamental questions: Can we develop a systematic theory of states of matter and of dynamical transitions between such states? How can such states be realized and probed experimentally? The main goal of this project was to explore the emergence of topological phases and quantum criticality (two cornerstones of modern condensed matter physics in equilibrium) in such non-equilibrium quantum systems. Specific goals included (1) using tensor networks to efficiently represent non-equilibrium states of matter and their phase transitions; (2) studying and designing new probes for periodically driven systems; and (3) developing analytic and numerical tools to analyze non-equilibrium topological phase transitions. Advances in these directions were achieved using novel techniques appropriate to study the non-equilibrium dynamics in many-body quantum systems combining strong interactions and randomness. Taken together, these results provide a new conceptual framework for understanding the emergence of quantum critical and topological properties in quantum systems far from thermal equilibrium.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

The Value of Sharing and Consolidating Critical Community, Electricity, and Natural Hazard Information

The California Public Utilities Commission (CPUC) sought support for the development of database schema specifications for a bi-directional data portal that would foster cross-jurisdictional collaboration necessary to improve resilient energy infrastructure planning processes. This technical assistance activity involved Berkeley Lab researchers reviewing 34 local/tribal government hazard mitigation plans to assess (1) the natural hazards that communities are most concerned about; (2) the variety of–and terminology used to describe–critical community infrastructure; and (3) the availability of GIS information that could be incorporated into CPUC-mandated "Microgrid Planning Portals". In addition, we develop a common, but generic data taxonomy showing what fields to collect to encourage consolidating and sharing of this information in the future. Finally, we partnered with the Bishop Paiute tribal government to demonstrate the value of combining electricity infrastructure, natural hazard layers, and critical community infrastructure into a series of maps. The project demonstrated that a single system containing both electric utility and community infrastructure data—as well as information about natural hazards—will help the state of California, the IOUs, first responders, and long-term planners better prepare for—and thus lower their exposure to these ongoing and emerging hazards. The project also identified a number of challenges that will need to be overcome before it is possible to stand up a single system to display this information.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Sub-Critical “Hands On” Demonstration [Slides]

Objectives: understand how the factors that affect criticality safety relate to working “hands on” with plutonium metal systems, including density, isotopic composition, moderating reflectors, absorbing reflectors. Understand the criticality safety implications for threshold fissioners.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Flattop Critical Assembly [Slides]

Objectives: Gain a working knowledge of the design of the Flattop critical assembly; Gain a working knowledge of how changes in reflector location can affect the criticality of a system; and, Understand the concept of temperature-dependent reactivity feedback.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Overview of SRNS NNSA Projects in the Eyes of Criticality Safet

Overview of NNSA Projects (Criticality Safety) – Savannah River Plutonium Processing Facility – Surplus Plutonium Disposition Project – Tritium Finishing Facility – Progress of Criticality Safety Analysis – Processes requiring CAAS

Stephens, Una D.↗

Addressing Critical Problems in Materials Science Through Multiscale and Multimode Characterization (Project 1); Characterization and Optimization of Novel Triple-Conducting Oxide Materials for Energy Applications (Project 2) (CRADA Final Report)

PROJECT 1: Address critical problems in materials science and simultaneously advance the state-of-the-art in multiscale and multimode characterization using the combined advanced analytical capabilities and expertise of Colorado School of Mines (CSM) and the National Renewable Energy Laboratory (NREL). The primary effort of the Phase I of this CRADA is to establish the International Center for Multiscale Characterization using shared resources at both NREL and CSM. Phase II will focus on capability development and marketing, choosing candidate materials science issues in the areas of structure imaging, chemical composition mapping, and correlating properties and performance of materials for impact in energy-related, environmental and critical materials areas. The CRADA will be modified to include specific topics of concern in materials science to industry member partners. Advanced analytical capabilities and expertise at CSM and NREL will be used to advance materials understanding and performance through characterization of multiscale phenomena including structural imaging, chemical composition mapping, and other techniques correlating properties and performance of materials. PROJECT 2: As part of the International Center for Materials Characterization, work under Modification #1 will be led by Colorado School of Mines (CSM), working in collaboration with NREL staff to mentor and advise CSM postdoctoral researchers on set up of diffusion annealing experiments. The purpose of the modification is to provide for NREL staff to mentor and advise CSM postdoctoral researchers on set up of diffusion annealing experiments, including mentoring and advising the CSM-NREL team on proper Secondary Ion Mass Spectrometry (SIMS) data analysis as needed. SIMS measurements of 10-20 samples will be performed at NREL during the project duration.

08 HYDROGEN↗

Godiva-IV Critical Assembly [Slides]

The objectives of this presentation are to: (1) gain awareness of the Godiva-IV assembly, including its design and intent; (2) create familiarization of the differences between subcritical, delayed-critical, and prompt-critical; and (3) observe the effects of temperature-dependent reactivity feedback.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

H-Canyon Flowsheet for the Neutralization of Dissolved Fast Critical Assembly (FCA) Fuel

The H-Canyon facility will be dissolving unirradiated stainless-steel clad Fast Critical Assembly (FCA) fuel in HNO3 and neutralizing the resulting solution with 50 wt% NaOH with no recovery operations prior to transfer to the Concentration, Storage, and Transfer Facility (CSTF). There are two types of FCA fuel, including a Pu-Al metal alloy and a mixed U and Pu oxide. H-Canyon anticipates dissolving 16 batches of the metal fuel and two batches of the oxide fuel. Potassium fluoride will be added to the dissolver solution at 0.05 M to promote dissolution. Gadolinium will be added after the dissolution as a thermal neutron poison for criticality control. H-Canyon requested that SRNL evaluate Gd:239Pu equivalent (239PuEq) ratios of 1:1 and 10:1. The neutralization process precipitates metals including actinides, Gd, and cladding components resulting in a slurry. Caustic neutralization is a routine H-Canyon operation, but the FCA dissolver solution will be unique relative to solutions that are typically processed due to the stainless-steel components, high HNO3 concentration of ~8.5 M, and an initial Pu concentration of up to 4 g/L. Previous neutralization studies have been performed for Pu containing solutions but at less than half the initial Pu concentration and much lower initial HNO3 concentrations. Experimental neutralizations targeted a final free hydroxide (OH-) concentration of 0.6 M as this was anticipated to be the final endpoint, but H-Canyon now expects the endpoint to be 1.2 M OH-. The purpose of this study was to characterize the distribution of the actinide, Gd, and cladding components between the precipitate and supernate, determine if the slurry will back up in the header during the transfer to the CSTF, and determine if solids will settle in the pipeline during the transfer.

Mills, Matthew S.↗

Critical current and stability tests of Nb 3 Sn for LBNL CCT magnet project

The Nb 3 Sn wires received from LBNL include the original round wires as well as the extracted wires from Rutherford cables. Total of 12 samples were prepared and heat treated. Five of them were tested for electric field versus current (E-I), among them 4 samples were further tested for electric field versus magnetic field (E-H). E-I traces were measured in magnetic field between 5 T and 8 T at 4.2 K. The critical currents of these sample are between 924 A and 993 A at 5 T. E-H measurements were performed at currents between 900 and 1500 A at 4.2 K. The stability currents, which is defined as the maximum current without quench during the E-H test, are determined to be between 1100 A and 1400 A. A separate Excel file presenting all the critical current and E-H curves is attached.

36 MATERIALS SCIENCE↗

National Criticality Experiments Research Center (NCERC) [Slides]

The National Criticality Experiments Research Center (NCERC) is a general-purpose critical assembly facility located within the Device Assembly Facility at the Nevada National Security Site. The NCERC is operated by Los Alamos National Laboratory.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗