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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 883 records · Page 49

Adsorption, Orientation, and Speciation of Amino Acids at Air–Aqueous Interfaces for the Direct Air Capture of CO 2

Amino acids make up a promising family of molecules capable of direct air capture (DAC) of CO 2 from the atmosphere. Under alkaline conditions, CO 2 reacts with the anionic form of an amino acid to produce carbamates and deactivated zwitterionic amino acids. The presence of the various species of amino acids and reactive intermediates can have a significant effect on DAC chemistry, the role of which is poorly understood. In this study, all-atom molecular dynamics (MD) based computational simulations and vibrational sum frequency generation (vSFG) spectroscopy studies were conducted to understand the role of competitive interactions at the air–aqueous interface in the context of DAC. We find that the presence of potassium bicarbonate ions, in combination with the anionic and zwitterionic forms of amino acids, induces concentration and charge gradients at the interface, generating a layered molecular arrangement that changes under pre- and post-DAC conditions. In parallel, an enhancement in the surface activity of both anionic and zwitterionic forms of amino acids is observed, which is attributed to enhanced interfacial stability and favorable intermolecular interactions between the adsorbed amino acids in their anionic and zwitterionic forms. The collective influence of these competitive interactions, along with the resulting interfacial heterogeneity, may in turn affect subsequent capture reactions and associated rates. Finally, these effects underscore the need to consider dynamic changes in interfacial chemical makeup to enhance DAC efficiency and to develop successful negative emission and storage technologies.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Soil carbon formation is promoted by saturation deficit and existing mineral-associated carbon, not by microbial carbon-use efficiency

Mineral-associated organic carbon (MAOC) is the largest terrestrial pool of organic carbon, yet controls on its formation remain unresolved. Existing MAOC is thought to preclude additional C storage on minerals, but this perspective is difficult to reconcile with observations that MAOC stacks in multilayers, suggesting that existing MAOC could promote greater C retention. Here, in a manipulative experiment using 118 soils from 15 agricultural sites across the United States, we show that MAOC formation is promoted by both existing MAOC and its counterpart—MAOC saturation deficit. The positive effect of existing MAOC on the formation of new MAOC persists after accounting for soil physicochemical properties that covary with MAOC. In contrast with current theory, we found that MAOC formation was not clearly influenced by microbial carbon-use efficiency (CUE). Our findings demonstrate that existing MAOC and saturation deficit, not microbial CUE, are key to determining new MAOC formation in agricultural soils.

King, Alison E. [Colorado State Univ., Fort Collin↗

Flare build-up study; Proceedings of the Workshop, Falmouth, Mass., September 8-11, 1975

The papers deal with problems which might be common to solar flares and earth's magnetosphere, problems associated with the initial phases of the flare phenomenon, the acceleration processes that seem to occur in flares and the magnetosphere, as well as the buildup and storage of flare energy in magnetic-field structures. Topics include the active role of magnetic fields in providing flare energy, current-sheet models of solar flares, the role of plasma turbulence in flare development, similarities and differences between magnetospheric substorms and solar flares, observations of magnetic merging in earth's magnetotail during magnetospheric substorms, evidence for magnetic-energy storage in coronal active regions, the possible role of transition-zone instabilities in preflare energy buildup, and flare energy storage and deposition. Other papers discuss energy release through the interaction of coronal magnetic fields, photospheric electric currents as a source of flare energy, magnetic-energy buildup in the solar atmosphere, magnetic and velocity fields in an active region, flare onset at meter wavelengths, laboratory experiments on field-line reconnection, key problems in auroral flare processes, and the solar-physics Shuttle/Spacelab program. Individual items are announced in this issue.

Svestka, Z.↗

The calculation of light element impurity (α, n) yield curves in a PuO 2 matrix and associated specific yield coefficients: Influence of the reaction cross sections

Most of the Pu separated from irradiated commercial nuclear fuel is stored as PuO 2 . The primary quantitative nondestructive measurement technique used to verify the amount of Pu in storage containers is passive neutron correlation counting. An important physical property of the oxide material is the ratio, α, of the rate of (α, n) neutrons produced inside the item to the rate of neutrons produced by spontaneous fission. This ratio influences the precision of the correlated counting method and affects the interpretation of the data because of how it changes both the primary total neutron production rate and the rate of induced fission events taking place inside the item. In addition to the main O(α, n) contribution, additional contributions come from α-particle interactions with light element impurities that are inevitably present. In this work, we calculate specific (α, n) yield coefficients, expressed in units of neutrons per second per gram of α-emitting nuclide per part per million by mass of the specified impurity element distributed in a pure PuO 2 matrix, for some key α-emitting actinides commonly present in reprocessed Pu ( 238–242 Pu+ 241 Am). These coefficients are directly applicable to nuclear safeguards verification work in which the α ratio is often calculated from the Pu-isotopic composition and chemical information obtained by other means. Further, they also provide a convenient up-to-date reference set against which values generated by other methods can be compared. Results are presented for impurities with atomic number from 3 to 17 inclusive, plus K and Fe. In most cases, these coefficients are not expected to change by more than 5%–10% at any time in the future. However, as new data become available, changes as large as 20% may be needed for some targets (e.g., F). The present yield calculations are limited by the general shortage of quality experimental total (α, n) reaction cross section data, which, together with unexplained variation between determinations, means that an objective and coherent evaluation is not possible. The situation is even less satisfactory for the partial differential cross section needed to calculate neutron spectra.

(𝛼, n) reactions↗

A high reliability battery management system

Over a period of some 5 years Canadian Astronautics Limited (CAL) has developed a system to autonomously manage, and thus prolong the life of, secondary storage batteries. During the development, the system was aimed at the space vehicle application using nickel cadmium batteries, but is expected to be able to enhance the life and performance of any rechargeable electrochemical couple. The system handles the cells of a battery individually and thus avoids the problems of over, and under, drive that inevitably occur in a battery of cells managed by an averaging system. This individual handling also allow cells to be totally bypassed in the event of failure, thus avoiding the losses associated with low capacity, partial short circuit, and the catastrophe of open circuit. The system has an optional capability of managing redundant batteries simultaneously, adding the advantage of on line reconditioning of one battery, while the other maintains the energy storage capability of the overall system. As developed, the system contains a dedicated, redundant, microprocessor, but the capability exists to have this computing capability time shared, or remote, and operating through a data link. As adjuncts to the basic management system CAL has developed high efficiency, polyphase, power regulators for charge and discharge power conditioning.

Moody, M. H.↗

Phasor-Measurement-Unit-Based Data Analytics Using Digital Twin and PhasorAnalytics Software

A major objective of this project was to apply GE’s commercial machine learning and data analytics toolsets to large-scale, real-world, anonymized Phasor Measurement Unit (PMU) datasets in order to extract signatures, correlated and/or causal factors, and precursor patterns associated with significant power system phenomena. The project had a particular emphasis on extraction of insights relevant to asset health monitoring, real-time load modeling and cybersecurity monitoring. Additionally, the team was directed to undertake a comprehensive data quality analysis for the provided datasets and encouraged to estimate the ‘machine-learning readiness’ of the datasets by documenting any major obstacles to the application of commercial machine learning algorithms. To accomplish the aforementioned objectives, the project team’s work centered around the identification of key event signatures and application of the identified event signatures for event detection and event classification. The industry-validated, semi-supervised machine learning strategy employed for event signature identification involved several major tasks, including data-preprocessing, generation of an overabundance of features, normal data identification, normality modeling, and event signature identification through a methodical, quantitative ranking of features in order of relevance to each studied event type. Throughout the project, data quality issues and mitigation techniques were investigated. In this report, insights are provided regarding the readiness of the provided synchrophasor datasets for application of machine learning and data analytics. The methodologies employed for this technical strategy are summarized in this report. With regards to data preprocessing and feature generation, the provided Training and Test Datasets were ingested into GE’s big data environment. Subsequently, the team applied bad data cleansing and data imputation scripts, event detection scripts, and application programming interfaces (APIs) to the datasets for convenient data access. The project team completed development and validation of dozens of physics-based, statistics-based and transformation-based feature functions used for the extraction of over 60 synchrophasor features. Using a new parallel feature generation technology developed on this project, over 60 features have been rapidly generated for the full two years’ worth of Training and Test Dataset data associated with both the Eastern and Western interconnects. Even accommodating for temporal down-sampling inherent to the feature extraction procedure, this parallel feature generation activity resulted in a massive feature set with a storage requirement approximately equal to that of the raw training dataset itself. With regards to normal data identification and normality modeling, a normality model was built using the feature data extracted from the Training Dataset and iteratively refined subsequent to incremental adjustments and expansions of the Training Dataset feature data. With respect to event characterization and signature identification, an event signature identification pipeline was developed and used in conjunction with the normality model to identify over 15 event signatures for key event categories within the Training Dataset. The identified event signatures were used to characterize hundreds of key events in terms of relative severity, duration, and location of the event. An investigation was undertaken to identify correlated and causal factors involved in transformer events. A separate investigation into temporal trends in ring-down analysis results was undertaken to determine possible associations between system dynamics and various other factors such as loading, season or year. To validate the identified event signatures, additional work was undertaken to develop signature-based anomaly detection and classification tools suitable for convenient application to the synchrophasor datasets. The anomaly detection and classification tools, suitable for online application, were then applied to the entirety of the Eastern Interconnect Training and Test Datasets. Performance of the event detection and classification tools was evaluated upon receipt of the Test Dataset event logs (i.e., the labels for events contained in the Test Dataset), and promising results were obtained despite several challenges (documented herein) associated with application of supervised or semi-supervised machine learning methods to large-scale, anonymized datasets. Finally, the detection and classification tools were used to detect, classify, and characterize thousands of new events not included in the original event logs provided by the DOE within both the Training and Test Datasets.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Assessing Nonlinear Polarization in Electrochemical Cells using AC Impedance Spectroscopy

AC impedance spectroscopy is widely used to evaluate performance limitations in energy storage and conversion devices (e.g., batteries, supercapacitors, and fuel cells). This work shows that integrating the resistive elements in an equivalent circuit as functions of steady-state current enables one to recover overpotentials associated with different processes (e.g., ion migration, charge transfer, and diffusion) in nonlinear electrochemical power supplies. Closed form expressions for diffusion overpotentials are derived using this method for transmissive and reflective boundary conditions and three electrode symmetries (planar, cylindrical, and spherical). Discussion is also extended to macroscopically homogenous porous electrodes which are relevant for most real-world devices. Overall, the approach described herein is a powerful tool to identify rate-limiting steps and guide material/component design.

25 ENERGY STORAGE↗

Considerations for Fire Service Response to Residential Battery Energy Storage System Incidents

Renewable energy sources (e.g., rooftop photovoltaics, wind turbines) are capable of addressing our grid-level energy challenges by reducing environmental impacts, increasing resiliency, and increasing the supply of input energy. However, renewable energy sources alone are not a complete solution. The generation of power from major renewable energy sources fluctuates with the weather, creating significant challenges in matching electrical power generation to electrical power consumption. The value of renewable power generation sources is multiplied when paired with battery energy storage systems (ESS), which can store excess power generated from renewable energy sources when it is not consumed and deliver that power later when demand exceeds base power generation. Residential ESS units are frequently installed to support renewable energy initiatives by storing energy from intermittent sources such as photovoltaic panels. Residential ESS units also offer an alternative to gas-powered generators or other backup power means. Lithium-ion batteries are the most common residential ESS technology due to their affordability and energy density. Though lithium-ion systems come with benefits, there is also a risk of thermal runaway within this technology which can result in flammable gas release, fire, and explosion. As the installations of these products increase, the frequency of response to fire incidents involving these products will increase. In response to this new and evolving hazard, UL Solutions (ULS) and UL Fire Safety Research Institute (FSRI) have partnered with the International Association of Fire Fighters (IAFF) to conduct a series of large-scale tests sponsored by the US Department of Energy to characterize the challenges for fire fighters responding to fires involving residential energy storage systems. The project focuses on developing size-up and tactical considerations to support the fire service in navigating the evolving modern fireground.

25 ENERGY STORAGE↗

Hybrid power plants: An effective way of decreasing loss-of-load expectation

Diversifying variable renewable resources by combining wind, solar photovoltaic, and battery assets in a hybrid power plant can increase renewable energy usage efficiency and improve system flexibility, particularly in distributed energy systems. However, the resilience impact of these systems, particularly outage mitigation, can be difficult to quantify due to uncertainty in resource, energy demand, and outage occurrence. Here, this study outlines a framework to quantify the incremental benefit of hybrid power plant assets for reducing loss-of-load expectation during random outage events. Hybrid power plant performance during outages (considering varying duration and severity) is simulated using a Monte Carlo methodology to reflect uncertainty associated with renewable resource, load demand, and outage timing. Results demonstrate the additional incremental value from increasingly hybrid designs, in which relative capacities of wind, solar photovoltaic, and storage assets contribute to lower loss-of-load expectation than the constituent technologies would alone. The value of added wind or solar capacity increases as the plant composition approaches an equal split. The value of added battery capacity depends on the outage duration and severity, but the first 50 MWh of added storage capacity is the most valuable for reducing the loss-of-load expectation for all plant designs.

14 SOLAR ENERGY↗

The Role of Atmospheric Rivers on Groundwater: Lessons Learned From an Extreme Wet Year

Abstract In the coastal regions of the western United States, atmospheric rivers (ARs) are associated with the largest precipitation generating storms and contribute up to half of annual precipitation, but the impact of ARs on the integrated hydrologic cycle, specifically on groundwater storage and hydrodynamics, is largely unknown. To better explore the hydrologic behavior of AR versus non‐AR event precipitation, we present a novel combination of two water tracking methods (one in the atmosphere and one in the subsurface) to explicitly track the full lifecycle of water parcels generated by ARs. Simulations of northern California's Cosumnes River watershed during the record wet 2017 water year are performed via the coupling of a high‐resolution regional climate model and a land surface‐groundwater model accounting for lateral groundwater flow. Despite ARs contributing more precipitation than non‐AR storms, we find less AR water is preferentially stored in aquifers by year end. Fractionally, ARs result in 300% less snow derived groundwater‐recharged compared to non‐AR precipitation. Rain‐on‐snow (RoS) plays an important role in AR‐driven discharge, where over 50% of total discharge from ARs snow is from RoS events. Finally, despite record‐breaking annual precipitation, simulated groundwater depletion occurs by year end due to estimates of groundwater pumping activities. The results from these simulations serve as a partial analogue of future hydrologic conditions where ARs are expected to intensify and provide a greater fraction of annual precipitation due to climate change.

54 ENVIRONMENTAL SCIENCES↗

Machine learning for automated experimentation in scanning transmission electron microscopy

Abstract Machine learning (ML) has become critical for post-acquisition data analysis in (scanning) transmission electron microscopy, (S)TEM, imaging and spectroscopy. An emerging trend is the transition to real-time analysis and closed-loop microscope operation. The effective use of ML in electron microscopy now requires the development of strategies for microscopy-centric experiment workflow design and optimization. Here, we discuss the associated challenges with the transition to active ML, including sequential data analysis and out-of-distribution drift effects, the requirements for edge operation, local and cloud data storage, and theory in the loop operations. Specifically, we discuss the relative contributions of human scientists and ML agents in the ideation, orchestration, and execution of experimental workflows, as well as the need to develop universal hyper languages that can apply across multiple platforms. These considerations will collectively inform the operationalization of ML in next-generation experimentation.

36 MATERIALS SCIENCE↗

Optimizing Grid-interactive Efficient Building Designs with Stacked Value Streams

Grid-interactive efficient buildings (GEBs) are those characterized by the combination of energy efficiency and demand flexibility with smart technologies and communications to not only deliver greater affordability and comfort to buildings, but also help utilities manage grid operations and lower system costs. This paper presents an innovative techno-economic assessment framework to effectively examine different GEB design options, explore various use cases, define technically achievable benefits, and thereby assist in informed decision-making. In particular, building load flexibility, thermal storage, and battery energy storage are considered. Advanced optimal dispatch problem is formulated to maximize the stacked value streams from multiple, competing use cases, subject to the physical capabilities and operational flexibility associated with different designs and configurations. Comprehensive case studies were performed for a real-world building to evaluate the cost-effectiveness of different GEB designs and offer in-depth insights. It was found that the proposed assessment method could effectively capture the costs and benefits linked to each GEB design option. Furthermore, the study revealed that outage mitigation and demand response are the two most significant sources of benefits for GEBs.

Ma, Xu↗

An Assessment of Non-Powered Dam Hydropower Development Opportunities in the United States

Retrofitting non-powered dams (NPDs) to add hydropower offers multiple benefits over traditional, new hydropower development. Since much of the civil works infrastructure already exists, many retrofits require minimal new construction and can leverage existing water conveyances and discharge for generation. Although NPDs vary considerably in terms of their defining characteristics, identifying similarities helps support targeted investment and find opportunities to develop solutions for common challenges. With the publication of NPD-related data in 2022 (Hansen et al. 2022b), the US Department of Energy and relevant stakeholders are equipped with key information across roughly 89,000 US NPDs. These data represent the best-available information to date and extend beyond previous assessments of potential power capacity by describing design, operational, socioeconomic, environmental aspects of NPDs (Hadjerioua et al. 2012). To capitalize on these efforts to improve breadth and depth of NPD data access, this study uses a data-driven approach to assess NPD hydropower development opportunities in the United States. To help describe project feasibility drivers for NPDs, recent NPD retrofits were reviewed to examine variability with respect to a variety of characteristics. Based on the assessment of recent retrofits and data availability, several attributes were selected to characterize the remaining NPD population: (1) owner type, (2) 30% exceedance flow (a common design flow that describes the flow that is exceeded by 30% of the flow in the record), (3) hydraulic head, and (4) maximum reservoir storage. These four characteristics were used as inputs to a statistical clustering analysis (a common technique for grouping individuals of a population based on similarities or how closely associated individuals are to one another) of a set of 2,709 NPDs with at least 100 kW potential capacity and recently retrofit dams with available data. With the large dataset of NPDs, the clusters help describe how the population breaks down into different types (i.e., how many types of dams there are and what portion of the population belongs to each cluster).

13 HYDRO ENERGY↗

Long-term risk analysis associated with nuclear waste disposal in space

An assessment and verification of previous analytic results on the long term risk of earth reentry for hazardous payloads is presented. The two areas were studied: (1) stability of nominal, near-circular storage orbits in the regions between Venus and earth and between earth and Mars, and (2) probability of earth reentry for off-nominal planet-crossing orbits resulting from deployment system failures. In the first area, numerical integrations of the equations of motion are compared with stability predications based on secular perturbation theory. The agreement is good in terms of the heliocentric distances covered and the general behavior of the orbital history, although certain near-resonance situations can lead to difficulty. In the second area, a Monte Carlo simulation of orbital evolution is used and the results compared with Opik's analytic theory of planetary encounters and collision statistics, with data verified to within a close order-of-magnitude.

Friedlander, A. L.↗

Solar heating and domestic hot water system installed at Kansas City, Fire Stations, Kansas City, Missouri

The solar system was designed to provide 47 percent of the space heating, 8,800 square feet area and 75 percent of the domestic hot water (DHW) load. The solar system consists of 2,808 square feet of Solaron, model 2001, air, flat plate collector subsystem, a concrete box storage subsystem which contains 1,428 cubic feet of 0.5 inch diameter pebbles weighing 71.5 tons, a DHW preheat tank, blowers, pumps, heat exchangers, air ducting, controls and associated plumbing. Two 120 gallon electric DHW heaters supply domestic hot water which is preheated by the solar system. Auxiliary space heating is provided by three electric heat pumps with electric resistance heaters and four 30 kilowatt electric unit heaters. There are six modes of system operation.

Source record↗

Frequency and time standards based on stored ions

The method of ion storage provides a basis for excellent time and frequency standards. This is due to the ability to confine ions for long periods of time without the usual perturbations associated with confinement (e.g., wall shifts). In addition, Doppler effects can be greatly suppressed. The use of stored ions for microwave frequency standards and the future possibilities for an optical frequency standard based on stored ions are addressed.

Bollinger, J. J.↗

Energy storage and thermal control system design status

The Space Station Freedom electric power system (EPS) will initially rely on photovoltaics for power generation and Ni/H2 batteries for electrical energy storage. The current design for the development status of two major subsystems in the PV Power Module is discussed. The energy storage subsystem comprised of high capacity Ni/H2 batteries and the single-phase thermal control system that rejects the excess heat generated by the batteries and other components associated with power generation andstorage is described.

Simons, Stephen N.↗

Assessing 'Dangerous Climate Change': Required Reduction of Carbon Emissions to Protect Young People, Future Generations and Nature

We assess climate impacts of global warming using ongoing observations and paleoclimate data. We use Earth's measured energy imbalance, paleoclimate data, and simple representations of the global carbon cycle and temperature to define emission reductions needed to stabilize climate and avoid potentially disastrous impacts on today's young people, future generations, and nature. A cumulative industrial-era limit of approx.500 GtC fossil fuel emissions and 100 GtC storage in the biosphere and soil would keep climate close to the Holocene range to which humanity and other species are adapted. Cumulative emissions of approx.1000 GtC, sometimes associated with 2 C global warming, would spur "slow" feedbacks and eventual warming of 3-4 C with disastrous consequences. Rapid emissions reduction is required to restore Earth's energy balance and avoid ocean heat uptake that would practically guarantee irreversible effects. Continuation of high fossil fuel emissions, given current knowledge of the consequences, would be an act of extraordinary witting intergenerational injustice. Responsible policymaking requires a rising price on carbon emissions that would preclude emissions from most remaining coal and unconventional fossil fuels and phase down emissions from conventional fossil fuels.

climate↗