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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 883 records · Page 49
All sourcesNASA NTRSDOE OSTI
NASA NTRS1986

The development and test of multi-anode microchannel array detector systems. Part 2: Soft X-ray detectors

Multi-Anode Microchannel Array (MAMA) detector systems with formats of 256 x 1024 pixels and active areas of 6 x 26 square mm are now under evaluation at visible, ultraviolet and soft x-ray wavelengths. Very-large-format versions of the MAMA detectors with formats of 2048 x 2048 pixels and active areas of 52 x 52 square mm are under development for use in the NASA Goddard Space Flight Center's Space Telescope Imaging Spectrograph (STIS). Open-structure versions of these detectors with CsI photocathodes can provide a high-resolution imaging capability at extreme ultraviolet (EUV) and soft x-ray wavelengths and can deliver a maximum count rate from each array in excess of 1 million counts s-1. In addition, these detector systems have the unique capability to determine the arrival time of a detected photon to an accuracy of 100 ns or better. The construction, mode-of-operation and performance characteristics of the MAMA detectors are described and the program for the development of the very-large-format detectors is outlined.

Timothy, J. G.↗
NASA NTRS1986

Modeling for CO poisoning of a fuel cell anode

Poisoning losses in a half-cell in the 110-190 C temperature range have been measured in 100 wt pct H3PO4 for various mixtures of H2, CO, and CO2 gases in order to investigate the polarization loss due to poisoning by CO of a porous fuel cell Pt anode. At a fixed current density, the poisoning loss was found to vary linearly with ln of the CO/H2 concentration ratio, although deviations from linearity were noted at lower temperatures and higher current densities for high CO/H2 concentration ratios. The surface coverages of CO were also found to vary linearly with ln of the CO/H2 concentration ratio. A general adsorption relationship is derived. Standard free energies for CO adsorption were found to vary from -14.5 to -12.1 kcal/mol in the 130-190 C temperature range. The standard entropy for CO adsorption was found to be -39 cal/mol per deg K.

Dhar, H. P.↗
NASA NTRS1988

Anodization As A Repair Technique

Thin, hard oxide layer added to aluminum part. Surfaces on aluminum part worn out of tolerance by no more than 0.004 in. often repaired by anodizing to build up aluminum oxide layers. Oxide layers very hard and grounded to desired final dimensions.

Groff, Roy E.↗
NASA NTRS1989

Oxygen evolution on a SrFeO3 anode - Mechanistic considerations from molecular orbital theory

Various pathways proposed in the literature for the evolution of O2 in electrochemical oxidations are explored using the atom superposition and electron delocalization molecular orbital (ASED-MO) theory and the cluster models of the SrFeO3 surface as a prototype material. Calculations indicate that oxygen atoms can be easily formed on the (100) surface as well as on the edge cation sites of a SrFeO3 anode by the discharge of OH(-), followed by its deprotonation and electron transfer to the electrode. The O atoms can form O2 on the edge and corner sites, where the Fe(4+) is coordinated to four and three bulk oxygen anions, respectively. The calculations strongly disfavor mechanisms involving coupling of oxygen atoms adsorbed on different cations as well as a mechanism featuring an ozone intermediate.

Mehandru, S. P.↗
NASA NTRS1989

High resolution decoding techniques and single-chip decoders for multi-anode microchannel arrays

While the pixel size in a standard multianode microchannel array (MAMA) photon-counting detector is determined by the spacing of the anode array, the factor most fundamentally limiting pixel resolution is the spacing of the channels in the microchannel plate. Detector resolution can be improved by means of digitization followed by a centroiding procedure. The decoding hardware and the techniques for enhanced pixel resolution are presently discussed with a view to the factors of speed and complexity. A single-chip CMOS gate-array implementation of the decoder is devised and compared with existing multichip decoders' performance.

Kasle, David B.↗
NASA NTRS1991

Condition of chromic acid anodized aluminum clamps flown

A survey of the condition of the chromic acid anodized (CAA) coating on selected LDEF tray clamps was carried out. Measurements of solar absorptance and thermal emittance were carried out at multiple locations on both the space exposed and spacecraft facing sides of the clamps. Multiple clamps from each available angle relative to the ram direction were examined. The diffuse component of the reflectance spectrum was measured for a selected subset of the clamps. The thickness of the CAA was determined for a small set of clamps. Examples of variation in integrity of the coatings from leading to trailing edge will be shown.

Plagemann, W. L.↗
NASA NTRS1991

Characterization of the corrosion resistance of biologically active solutions: The effects of anodizing and welding

An understanding of fabrication processes, metallurgy, electrochemistry, and microbiology is crucial to the resolution of microbiologically influenced corrosion (MIC) problems. The object of this effort was to use AC impedance spectroscopy to characterize the corrosion resistance of Type II anodized aluminum alloy 2219-T87 in sterile and biologically active media and to examine the corrosion resistance of 316L, alloy 2219-T87, and titanium alloy 6-4 in the welded and unwelded conditions. The latter materials were immersed in sterile and biologically active media and corrosion currents were measured using the polarization resistance (DC) technique.

Walsh, Daniel W.↗
NASA NTRS1992

Space environmental effects on the integrity of chromic acid anodized coatings

The Long Duration Exposure Facility (LDEF) tray clamps used to hold the experiment trays in place on the LDEF were analyzed to determine the effects of long term space exposure on the performance of the chromic acid anodized coating. Spectroscopic anomalies observed appeared to be random and related to application techniques as opposed to exposure or position on LDEF. Thickness measurements indicated that the coating was less than 1u and was probably not degraded by space exposure. Metallurgical analysis revealed that leading edge exposure may have increased the porosity of the coating. Emittance values for the coating decreased uniformly by an average of 6.8 percent while solar absorptance values increased for trailing edge and decreased for leading edge specimens. The a/e ratio for the coating also increased as a result of long term space exposure.

Plagemann, Walter L.↗
NASA NTRS1992

Surface analysis of anodized aluminum clamps from NASA-LDEF satellite

Surface analysis results of selected anodized aluminum clamps containing black (Z306) and white (A276) paints which received nearly six years of Low Earth Orbit (LEO) exposure on the Long Duration Exposure Facility are reported. Surface analytical techniques, including x-ray photoelectron spectroscopy (XPS), Auger electron spectroscopy (AES), and scanning electron microscopy/energy dispersive analysis by x-ray (SEM/EDAX), showed significant differences in the surface composition of these materials depending upon the position on the LDEF. Differences in the surface composition are attributed to varying amounts of atomic oxygen and vacuum ultraviolet radiation (VUV). Silicon containing compounds were the primary contaminant detected on the materials.

Grammer, H. L.↗
NASA NTRS1992

Anodized aluminum coatings for thermal control. I - Coating process and stresses

Anodized aluminum is a candidate material for use as a thermal radiator surface on Space Station Freedom. Here, results of measurements of coating stress at room temperature are presented. The effects of coating process conditions and also subsequent exposure to different humidities, from above ambient to vacuum, are reported. The most important observation with regard to space applications is that the coating stress is very dependent on humidity, changing from compressive at ambient humidity to strongly tensile in 10 exp -6 torr vacuum. The increase in stress is accompanied by loss of water from the coating, and the process is reversible.

Alwitt, R. S.↗
NASA NTRS1992

Anodized aluminum coatings for thermal control. II - Environmental effects and cracking

The environmental effects of thermal cycling and humidity on coating cracking are examined. Experimental measurements of thermal deflection were used to calculate values for the thermal expansion coefficient and the in situ elastic modulus of an anodized aluminum. The thermal expansion coefficient is found to be approximately the same as for alumina in bulk form. The modulus in atmospheres with less than 100 ppm water is about 12,500 ksi. Two sets of experiments are used to study cracking directly during thermal excursions: one determines the minimum temperature (Tc) at which cracks first appear during a single heating cycle and the other involves rapid thermal cycling (RTC) between fixed T max and T min values. Fatigue models for describing initiation of the first crack and the development of multiple cracking are presented, which can be used as the basis for prediction of LEO cracking.

Mcclung, R. C.↗
NASA NTRS1992

The effect of a magnetic field gradient on anode double layers

In experiments on anode (ionization) double layers in nonuniform magnetic fields it has been noted that the magnetic field gradient seems to stabilize the double layer position. This effect is further investigated in a Q machine in which the magnetic field geometry could be varied. It is found that the position of the double layers, along the axis of the device, could be controlled by changing the magnetic geometry. This effect is accounted for in a physical model which takes into account the effect of ion reflection by the magnetic mirror force in the region of magnetic field nonuniformity. This model is also able to account for variation of the double layer position when the neutral gas pressure is varied.

Song, B.↗
NASA NTRS1992

Anodic etching of p-type cubic silicon carbide

p-Type cubic silicon carbide was anodically etched using an electrolyte of HF:HCl:H2O. The etching depth was determined versus time with a fixed current density of 96.4 mA/sq cm. It was found that the etching was very smooth and very uniform. An etch rate of 22.7 nm/s was obtained in a 1:1:50 HF:HCl:H2O electrolyte.

Harris, G. L.↗
NASA NTRS1991

An application specific integrated circuit based multi-anode microchannel array readout system

Size reduction of two new multi-anode microchannel array (MAMA) readout systems is described. The systems are based on two analog and one digital application specific integrated circuits (ASICs). The new readout systems reduce volume over previous discrete designs by 80 percent while improving electrical performance on virtually every significant parameter. Emphasis is made on the packaging used to achieve the volume reduction. Surface mount technology (SMT) is combined with modular construction for the analog portion of the readout. SMT reliability concerns and the board area impact of MIL SPEC SMT components is addressed. Package selection for the analog ASIC is discussed. Future sytems will require even denser packaging and the volume reduction progression is shown.

Smeins, Larry G.↗
NASA NTRS1993

Direct observation of porous SiC formed by anodization in HF

A process for forming porous SiC from single-crystal SiC wafers has been demonstrated. Porous SiC can be fabricated by anodizing n-type 6H-SiC in HF under UV illumination. TEM reveals pores of sizes 10-30 nm with interpore spacings ranging from roughly 5 to 150 nm. This is the first reported direct observation of porous SiC formation.

Shor, Joseph S.↗
NASA NTRS1994

Anode for rechargeable ambient temperature lithium cells

An ambient room temperature, high density, rechargeable lithium battery includes a Li(x)Mg2Si negative anode which intercalates lithium to form a single crystalline phase when x is up to 1.0 and an amorphous phase when x is from 1 to 2.0. The electrode has good reversibility and mechanical strength after cycling.

Huang, Chen-Kuo↗
NASA NTRS1995

Measuring Fluxes Of Heat To A Plasma-Arc Anode

Three probes constructed to provide measurements indicative of conductive, convective, and radiative transfer of heat from free-burning plasma arc to water-cooled copper anode used in generating arc. Each probe consists mainly of copper body with two thermocouples embedded at locations 4 mm apart along length. Thermocouples provide measure of rate of conduction of heat along probe and transfers of heat from plasma to sensing surface at tip of probe. Probes identical except sensing surface of one uncoated and other two coated with different materials to make them sensitive to different components of overall flux of heat.

Sankovic, John M.↗
NASA NTRS1998

High performance zinc anode for battery applications

An improved zinc anode for use in a high density rechargeable alkaline battery is disclosed. A process for making the zinc electrode comprises electrolytic loading of the zinc active material from a slightly acidic zinc nitrate solution into a substrate of nickel, copper or silver. The substrate comprises a sintered plaque having very fine pores, a high surface area, and 80-85 percent total initial porosity. The residual porosity after zinc loading is approximately 25-30%. The electrode of the present invention exhibits reduced zinc mobility, shape change and distortion, and demonstrates reduced dendrite buildup cycling of the battery. The disclosed battery is useful for applications requiring high energy density and multiple charge capability.

Casey, John E., Jr.↗