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NASA NTRS1989

Multipolarization P-, L-, and C-band radar for coastal zone mapping - The Louisiana example

Multipolarization P-, L-, and C-band airborne SAR data sets were acquired over a coastal zone and a forested wetland of southern Louisiana. The data sets were used with field-collected surface-parameter data in order to determine the value of SAR systems in assessing and mapping coastal-zone surface features. The coastal-zone surface features in this study are sediments, sediment distribution, and the formation of new isles and banks. Results of the data analysis indicate that the P-band radar with 68-cm wavelength is capable of detecting the submerged sediment if the area is very shallow (i.e., a water depth of less than one meter). The penetration capability of P-band radar is also demonstrated in the forested wetland area. The composition and condition of the ground surface can be detected, as well as the standing water beneath dense tree leaves.

Wu, Shih-Tseng↗

NASA NTRS2016

Inland and Near-Shore Water Profiles Derived from the High-Altitude Multiple Altimeter Beam Experimental Lidar (MABEL)

The Advanced Topographic Laser Altimeter System (ATLAS) on the Ice, Cloud, and Land Elevation Satellite (ICESat-2) mission is a six beam, low energy, high repetition rate, 532-nanometer laser transmitter with photon counting detectors. Although designed primarily for detecting height changes in ice caps, sea ice, and vegetation, the polar-orbiting satellite will observe global surface water during its designed three-year life span, including inland waterbodies, coasts, and open oceans. In preparation for the mission, an ICESat-2 prototype, the Multiple Altimeter Beam Experimental Lidar (MABEL), was built and flown on high-altitude aircraft experiments over a range of inland and near-shore targets. The purpose was to test the ATLAS concept and to provide a database for developing an algorithm that detects along track surface water height and light penetration under a range of atmospheric and water conditions. The current analysis examines the data sets of three MABEL transects observed from 20 kilometers above ground of coastal and inland waters conducted in 2012 and 2013. Transects ranged from about 2 to 12 kilometers in length and included the middle Chesapeake Bay, the near-shore Atlantic coast at Virginia Beach, and Lake Mead. Results indicate MABEL's high capability for retrieving surface water height statistics with a mean height precision ofapproximately 5-7 centimeters per 100-meter segment length. Profiles of attenuated subsurface backscatter, characterized using a Signal to Background Ratio written in Log10 base, or LSBR (sub 0), were observed over a range of 1.3 to 9.3 meters, depending on water clarity and atmospheric background. Results indicate that observable penetration depth, although primarily dependent on water properties, was greatest when the solar background rate was low. Near-shore bottom reflectance was detected only at the Lake Mead site down to a maximum of 10 meters under a clear night sky and low turbidity of approximately 1.6 Nephelometric Turbidity Units (NTU). The overall results suggest that the feasibility of retrieving operational surface water height statistics from space-based photon counting systems such as ATLAS is very high for resolutions down to about 100 meters, even in partly cloudy conditions. The capability to observe subsurface backscatterprofiles is achievable but requires much longer transects of several hundreds of meters.

inland↗

DOE OSTI2025

Investigating intermolecular interactions among CO 2 , water and PEEK-ionene membrane using cryo ToF-SIMS and isotopic labeling

Cryogenic time-of-flight secondary ion mass spectrometry (cryo ToF-SIMS) has emerged as a powerful tool for investigating molecular interactions, speciation, and dynamics in materials for CO 2 capture. In this study, we apply cryo ToF-SIMS to probe interactions between CO 2 , water, and PEEK-ionene membranes—a promising material for direct CO 2 capture due to its selectivity, durability, and efficiency. Despite this potential, the mechanisms governing CO 2 diffusion and the influence of water vapor on CO 2 behavior remain unclear. To address this, we loaded PEEK-ionene membranes with 13 CO 2 and D 2 O and employed cryo ToF-SIMS to visualize the 3D distribution of CO 2 and water within the membrane. While prior studies suggest that 13 CO 2 is absorbed under ambient conditions, our cryo ToF-SIMS analysis revealed no enhancement of the 13 C/ 12 C ratio, suggesting weak CO 2 -membrane interactions. As a result, CO 2 vaporizes even at low temperatures (−140°C) under vacuum conditions. In contrast, D 2 O displayed a relatively homogeneous distribution in the membrane, suggesting stronger water-membrane interactions via hydrogen bonding (18–20 kJ/mol). Interestingly, CO 2 was not detected in D 2 O-loaded membranes, indicating minimal interference from water vapor on CO 2 diffusion. As a comparison, the cryo ToF-SIMS data show that 13 CO 2 can readily react with a basic Na 2 CO 3 aqueous solution to form NaH 13 CO 3 . These findings demonstrate cryo ToF-SIMS as a critical technique for understanding gas-water-membrane interactions, offering insights for membrane functionalization to improve CO 2 capture efficiency.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS2010

Earth Glint Observations Conducted During the Deep Impact Spacecraft Flyby

We describe observations of Earth conducted using the High Resolution Instrument (HRI) - a 0.3 m f/35 telescope - on the Deep Impact (DI) spacecraft during its recent flybys. Earth was observed on five occasions: 2008-Mar-18 18:18 UT, 2008-May-28 20:05 UT, 2008-Jun-4 16:57 UT, 2009-Mar-27 16:19 and 2009-Oct-4 09:37 UT. Each set of observations was conducted over a full 24-hour rotation of Earth and a total of thirteen NIR spectra were taken on two-hour intervals during each observing period. Photometry in the 450, SSO, 650 and 8S0 nm filters was taken every fifteen minutes and every hour for the 350, 750 and 950 nm filters. The spacecraft was located over the equator for the three sets of observations in 2008, while the 2009- Mar and 2009-Oct were taken over the north and south Polar Regions, respectively. Observations of calibrator stars Canopus and Achernar were conducted on multiple occasions through all filters. The observations detected a strong specular glint not necessarily associated with a body of water. We describe spectroscopic characterization of the glint and evidence for the possibility of detection of reflection from high cirrus clouds. We describe implications for observations of extrasolar planets.

Barry, R. K.↗

NASA NTRS2017

Electrochemical Detection of Biological Catalysts as Signatures of Extant Life

Liquid water is the quintessential ingredient for life. Biochemistry as we know it is not possible without it. There are two places in the Solar System, other than the Earth, where liquid water is known to exist: Europa and Enceladus. Cassini’s recent discovery of Enceladus’ ocean plumes has excited the scientific community about the possibility for liquid sampling and search for life. Characteristics of life are self-sustainability, its ability to evolve, and self-enclosure. To enable these, chemical energy must be utilized, information must be stored, and enclosing membranes must be built. Many of these processes are accomplished with the use of biological catalysts. To search for life in the ocean worlds, detection of biological catalysts serves as a strong marker of biological activity and thus life.

Koehne, J. E.↗

NASA NTRS2021

Synthesis and Characterization of Fe(III)-Fe(II)- Mg- Al Smectite Solid Solutions and Implications for Planetary Science

This study demonstrates the synergies and limits of multiple measurement types for the detection of smectite chemistry and oxidation state on planetary surfaces to infer past geochemical conditions. Smectite clay minerals are common products of water-rock interactions throughout the solar system, and their detection and characterization provides important clues about geochemical conditions and past environments if sufficient information about their composition can be discerned. Here, we synthesize and report on the spectroscopic properties of a suite of smectite samples that span the intermediate compositional range between Fe(II), Fe(III), Mg, and Al end-member species using bulk chemical analyses, X-ray diffraction, Vis/IR reflectance spectroscopy, UV and green-laser Raman spectroscopy, and Mössbauer spectroscopy. Our data show that smectite composition and the oxidation state of octahedral Fe can be reliably identified in the near infrared on the basis of combination and fundamental metal-OH stretching modes between 2.1–2.9 μm, which vary systematically with chemistry. Smectites dominated by Mg or Fe(III) have spectrally distinct fundamental and combination stretches, whereas Al-rich and Fe(II)-rich smectites have similar fundamental minima near 2.76 μm, but have distinct combination M-OH features between 2.24 and 2.36 μm. We show that with expanded spectral libraries that include intermediate composition smectites and both Fe(III) and Fe(II) oxidation states, more refined characterization of smectites from MIR data is now possible, as the position of the 450 cm–1 absorption shifts systematically with octahedral Fe content, although detailed analysis is best accomplished in concert with other characterization methods. Our data also provide the first Raman spectral libraries of smectite clays as a function of chemistry, and we demonstrate that Raman spectroscopy at multiple excitation wavelengths can qualitatively distinguish smectite clays of different structures and can enhance interpretation by other types of analyses. Our sample set demonstrates how X-ray diffraction can distinguish between dioctahedral and trioctahedral smectites using either the (02,11) or (06,33) peaks, but auxiliary information about chemistry and oxidation state aids in specific identifications. Finally, the temperature-dependent isomer shift and quadrupole splitting in Mössbauer data are insensitive to changes in Fe content but reliability differentiates Fe within the smectite mineral structure.

Valerie K Fox↗

NASA NTRS2023

Formation of Amino Acids and Carboxylic Acids in Weakly Reducing Planetary Atmospheres by Solar Energetic Particles from the Young Sun

Life most likely started during the Hadean Eon; however, the environmental conditions which contributed to the complexity of its chemistry are poorly known. A better understanding of various environmental conditions, including global (heliospheric) and local (atmospheric, surface, and oceanic), along with the internal dynamic conditions of the early Earth, are required to understand the onset of abiogenesis. Herein, we examine the contributions of galactic cosmic rays (GCRs) and solar energetic particles (SEPs) associated with superflares from the young Sun to the formation of amino acids and carboxylic acids in weakly reduced gas mixtures representing the early Earth’s atmosphere. We also compare the products with those introduced by lightning events and solar ultraviolet light (UV). In a series of laboratory experiments, we detected and characterized the formation of amino acids and carboxylic acids via proton irradiation of a mixture of carbon dioxide, methane, nitrogen, and water in various mixing ratios. These experiments show the detection of amino acids after acid hydrolysis when 0.5% (v/v) of initial methane was introduced to the gas mixture. In the set of experiments with spark discharges (simulation of lightning flashes) performed for the same gas mixture, we found that at least 15% methane was required to detect the formation of amino acids, and no amino acids were detected in experiments via UV irradiation, even when 50% methane was used. Carboxylic acids were formed in non-reducing gas mixtures (0% methane) by proton irradiation and spark discharges. Hence, we suggest that GCRs and SEP events from the young Sun represent the most effective energy sources for the prebiotic formation of biologically important organic compounds from weakly reducing atmospheres. Since the energy flux of space weather, which generated frequent SEPs from the young Sun in the first 600 million years after the birth of the solar system, was expected to be much greater than that of GCRs, we conclude that SEP-driven energetic protons are the most promising energy sources for the prebiotic production of bioorganic compounds in the atmosphere of the Hadean Earth.

Kensei Kobayashi↗

NASA NTRS2001

Detecting Plant Stress

Through an exclusive patent license from NASA Stennis Space Center, Spectrum Technologies, Inc., has developed a hand-held tool that helps farmers, foresters and other growers detect unhealthy crops before the human eye can see the damage. Developed by two NASA researchers, the Observer,TM shows the viewer which plants are under stress through multispectral imaging, a process that uses specific wavelengths of the light spectrum to obtain information about objects-in this case, plants. With this device, several wavelengths of light collect information about the plant and results are immediately processed and displayed. NASA research found that previsible signs of stress, such as such as a lack of nutrients, insufficient water, disease, or insect damage, can be detected by measuring the chlorophyll content based on light energy reflected from the plant. The Observer detects stress up to 16 days before deterioration is visible to the eye. Early detection provides an opportunity to reverse stress and save the plant. The hand-held, easily operated unit works in both natural and artificial light, making it suitable for outdoor or indoor planting.

Source record↗

NASA NTRS2005

Global monitoring of Sea Surface Salinity with Aquarius

Aquarius is a microwave remote sensing system designed to obtain global maps of the surface salinity field of the oceans from space. It will be flown on the Aquarius/SAC-D mission, a partnership between the USA (NASA) and Argentina (CONAE) with launch scheduled for late in 2008. The objective of Aquarius is to monitor the seasonal and interannual variation of the large scale features of the surface salinity field in the open ocean. This will provide data to address scientific questions associated with ocean circulation and its impact on climate. For example, salinity is needed to understand the large scale thermohaline circulation, driven by buoyancy, which moves large masses of water and heat around the globe. Of the two variables that determine buoyancy (salinity and temperature), temperature is already being monitored. Salinity is the missing variable needed to understand this circulation. Salinity also has an important role in energy exchange between the ocean and atmosphere, for example in the development of fresh water lenses (buoyant water that forms stable layers and insulates water below from the atmosphere) which alter the air-sea coupling. Aquarius is a combination radiometer and scatterometer (radar) operating at L-band (1.413 GHz for the radiometer and 1.26 GHz for the scatterometer). The primary instrument,for measuring salinity is the radiometer which is able to detect salinity because of the modulation salinity produces on the thermal emission from sea water. This change is detectable at the long wavelength end of the microwave spectrum. The scatterometer will provide a correction for surface roughness (waves) which is one of the greatest unknowns in the retrieval. The sensor will be in a sun-synchronous orbit at about 650 km with equatorial crossings of 6am/6pm. The antenna for these two instruments is a 3 meter offset fed reflector with three feeds arranged in pushbroom fashion looking away from the sun toward the shadow side of the orbit to minimize sunglint. The mission goal is to produce maps of the salinity field globally once each month with an accuracy of 0.2 psu and a spatial resolution of 100 km. This will be adequate to address l&ge scale features of the salinity field of the open ocean. The temporal resolution is sufficient to address seasonal changes and a three year mission is planned to-collect sufficient data to look for interannual variation. Aquarius is being developed by NASA as part of the Earth System Science Pathfinder (ESSP) program. The SAC-D mission is being developed by CONAE and will include the space craft and several additional instruments, including visible and infrared cameras and a microwave radiometer to monitor rain and wind velocity over the oceans, and sea ice.

Lagerloef, G. S. E.↗

DOE OSTI2022

Estimating biofuel contaminant concentration from 4D ERT with mixing models

Here, we present the results of a lab-scaled feasibility study to assess the performance of electrical resistivity tomography for detection, characterization, and monitoring of fuel grade ethanol releases to the subsurface. Further, we attempt to determine the concentration distribution of the ethanol from the electrical resistivity tomography data using mixing-models. Ethanol is a renewable fuel source as well as an oxygenate fuel additive currently used to replace the known carcinogen methyl tert-butyl ether; however, ethanol is preferentially biodegraded and a cosolvent. When introduced to areas previously impacted by nonethanol-based fuels, it will facilitate the persistence of carcinogenic fuel compounds like benzene and ethylbenzene, as well as remobilize them to the ground water. These compounds would otherwise be retained in the soil column undergoing active or passive remediation processes such as soil vapor extraction or natural attenuation. Here, we introduce ethanol to a saturated Ottawa sand in a tank instrumented for four-dimensional geoelectrical measurements. Forward model results suggest pure phase ethanol released into a water saturated silica sand should present a detectable target for electrical resistivity tomography relative to a saturated silica sand only. We observe the introduction of ethanol to the closed hydraulic system and subsequent migration over the duration of the experiment. One-dimensional and three–dimensional temporal data are assessed for the detection, characterization, and monitoring of the ethanol release. Results suggest one-dimensional geoelectrical measurements may be useful for monitoring a release, while three-dimensional geoelectrical field imaging would be useful to characterize, monitor, and design effective remediation approaches for an ethanol release, assuming field conditions do not preclude the application of geoelectrical methods. We then attempt to use predictive mixing models to calculate the distribution of ethanol concentration within the measurement domain. For this study we examine four different models: a nested parallel mixing model, a nested cubic mixing model, the complex refractive index model (CRIM), and the Lichtenecker-Rother (L-R) model. The L-R model, modified to include an electrical formation factor geometry term, provided the best agreement with expected EtOH concentrations.

09 BIOMASS FUELS↗

NASA NTRS1999

Amino acids in the Martian meteorite Nakhla

A suite of protein and nonprotein amino acids were detected with high-performance liquid chromatography in the water- and acid-soluble components of an interior fragment of the Martian meteorite Nakhla, which fell in Egypt in 1911. Aspartic and glutamic acids, glycine, alanine, beta-alanine, and gamma-amino-n-butyric acid (gamma-ABA) were the most abundant amino acids detected and were found primarily in the 6 M HCl-hydrolyzed, hot water extract. The concentrations ranged from 20 to 330 parts per billion of bulk meteorite. The amino acid distribution in Nakhla, including the D/L ratios (values range from <0.1 to 0.5), is similar to what is found in bacterially degraded organic matter. The amino acids in Nakhla appear to be derived from terrestrial organic matter that infiltrated the meteorite soon after its fall to Earth, although it is possible that some of the amino acids are endogenous to the meteorite. The rapid amino acid contamination of Martian meteorites after direct exposure to the terrestrial environment has important implications for Mars sample-return missions and the curation of the samples from the time of their delivery to Earth.

NASA Discipline Exobiology↗

NASA NTRS2016

A Fly-Through Mission Strategy Targeting Peptide as a Signature of Chemical Evolution and Possible Life in Enceladus Plumes

In situ detection of organic molecules in the extraterrestrial environment provides a key step towards better understanding the variety and the distribution of building blocks of life and it may ultimately lead to finding extraterrestrial life within the Solar System. Here we present combined results of two separate experiments that enable us to realize such in situ life signature detection from the deep habitats of the "Ocean World": a hydrothermal reactor experiment simulating complex organic synthesis and a simulated fly-through capture experiment of organic-bearing microparticles using silica aerogels, followed by subsequent analysis. Both experiments employ peptide as a plausible organics existing in Encleadus plume particles produced in its subsurface ocean. Recent laboratory hydrothermal experiments and a theoretical model on silica saturation indicated an on going hydrothermal reactions in subsurface Enceladus ocean. Given the porous chondritic origin of the core, it is likely that organic compounds originated by radiation chemistry such as amino acid precursors could have been provided, leached, and altered through widespread water-rock interactions. By using the same laboratory experimental setup from the latest water-rock interaction study, we performed amino acid polymerization experiments for 144 days and monitored the organic complexity changing over time. So far over 3,000 peaks up to the size of greater than 600 MW were observed through the analysis of capillary electrophoresis time-of-flight mass spectrometry (CE-TOF-MS) with an indication of amino acid derivatives and short peptides. Generally abiotic polymerization of enantiomeric amino acids results in forming stereoisomeric peptides with identical molecular weight and formula as opposed to homochiral biopolymers. Assuming Enceladus plume particles may contain a mixture of stereoisomeric peptides, we were able to distinguish 16 of the 17 stereoisomeric tripeptides as a test sample using capillary electrophoresis (CE) under optimized conditions. We further conducted Enceladus plume fly-through capture experiment by accelerating peptides soaked in rock particles up to a speed of 5.7 km/s and capturing with originally developed hydrophobic silica aerogels. Direct peptide extraction with acetonitrile-water followed by CE analysis led to detection of only but two stereoisomeric acidic peptide peaks, presenting the first run-through hypervelocuty impact sample analysis targeting peptides as key molecule to to understand the ongoing astrobiology on Enceladus.

organic molecules↗

NASA NTRS1981

Concentration of hydrocarbons associated with particles in the shelf waters adjacent to the entrance of Chesapeake Bay

Particulate hydrocarbon concentrations were measured in 94 water samples. The concentrations ranged from below the detection limit ( 0.7 micro-G/L) to 32 micro-g/l. The mean for all samples was 5.6 micro-g/l. Particulate hydrocarbon concentrations are higher in the Bay mouth and lower in the shelf waters adjacent to the entrance of Chesapeake Bay. No coherent particulate hydrocarbon distribution is seen with depth in the water column. The Bay is postulated as one of the possible chronic sources of particulate hydrocarbons for the adjacent shelf waters.

Wade, T. L.↗

DOE OSTI2023

Strengthening Cybersecurity for Industrial Control Systems: Innovations in Protecting PLC-Based Infrastructure

In this paper, we propose two new approaches aimed at enhancing the security of industrial control systems (ICS) that utilize programmable logic controllers (PLCs) for the control of critical processes. The first approach involves the addition of a unique digital watermark to the PWM control that adjusts the motor speed to control the critical process. This enables efficient detection and identification of any unauthorized modifications to the sensor signals responsible for controlling the plant. The second approach focuses on monitoring the input current (i.e power) drawn by the PLC during the execution of critical process control tasks. Malicious intrusions to change the PLC parameters and/or unauthorized firmware updates can be rapidly detected. Both approaches demonstrate a substantial improvement in the security of ICS, effectively safeguarding against potential cyber-attacks. Experimental results from a laboratory scale water tank level controlled via PLC showcases rapid intrusion detection capabilities.

Huang, Peng-Hao↗

NASA NTRS2011

Fluorescence Excitation Models of Ammonia and Amidogen Radical (NH2) in Comets: Application to Comet C/2004 Q2 (Machholz)

Ammonia is a major reservoir of nitrogen atoms in cometary materials. However, detections of ammonia in comets are rare, with several achieved at radio wavelengths. A few more detections were obtained through near-infrared observations (around the 3 m wavelength region), but moderate relative velocity shifts are required to separate emission lines of cometary ammonia from telluric absorption lines in the 3 micron wavelength region. On the other hand, the amidogen radical (NH2 -- a photodissociation product of ammonia in the coma) also shows rovibrational emission lines in the 3 micron wavelength region. Thus, gas production rates for ammonia can be determined from the rovibrational emission lines of ammonia (directly) and amidogen radical (indirectly) simultaneously in the near-infrared. In this article, we present new fluorescence excitation models for cometary ammonia and amidogen radical in the near-infrared, and we apply these models to the near-infrared high-dispersion spectra of comet C/2004 Q2 (Machholz) to determine the mixing ratio of ammonia to water in the comet. Based on direct detection of NH3 lines, the mixing ratio of NH3/H2O is 0.46% +/- 0.03% in C/2004 Q2 (Machholz), in agreement with other results. The mixing ratio of ammonia determined from the NH2 observations (0.31% -- 0.79%) is consistent but has relatively larger error, owing to uncertainty in the photodissociation rates of ammonia. At the present level of accuracy, we confirm that NH3 could be the sole parent of NH2 in this comet.

Kawakita, Hideyo↗

DOE OSTI2021

Diol isomer revealed as a source of methyl ketene from propionic acid unimolecular decomposition

Carboxylic acids are important combustion intermediates, especially regarding the combustion of oxygenates such as ethyl esters. The purpose of this study is to discern the unimolecular decomposition pathways of one such carboxylic acid, propionic acid, using microreactor flow experiments with line-tunable photoionization mass spectrometry and infrared spectroscopy, along with high-level electronic structure calculations (CCSD(T)/cc-pV∞Z//M06-2X/cc-pVTZ level of theory) and master equation theory. Here, microreactor experiments were performed at 300–1500 K, pressures decreasing from roughly 300 Torr to vacuum pressure, and around 100 μs residence times. Primary products are methyl ketene, ketene, ethylene, and methyl radical. Theory suggests the two lowest energy bond fissions are active at these conditions and responsible for the production of ketene, methyl radical, and some ethylene. Importantly, theory revealed the significance of the isomerization of propionic acid to propene-1,1-diol, and the subsequent dehydrogenation reaction of the diol as an alternative explanation for the unimolecular formation of methyl ketene. This is predicted to be the dominant thermal decomposition pathway at lower temperatures (up to ~850 K). Line-tunable VUV photons allowed for isomer resolution of the products and showed no evidence of the diol of propionic acid surviving until detection, suggesting propene-1,1-diol decomposes either to methyl ketene and water rapidly, fragments upon ionization to a distonic ion inseparable from methyl ketene through our detection methods, or never stabilizes as propionic acid well-skips directly to methyl ketene. Infrared spectroscopy showed no evidence of the decarboxylation of propionic acid at these conditions. Updated rate constants and branching ratios for propionic acid decomposition are calculated and provided for future modeling studies.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS2012

Design for the Structure and the Mechanics of Moballs

The moball is envisioned to be a round, self-powered, and wind-driven multifunctioning sensor used in the Gone with the Wind ON-Mars (GOWON) [http://www.lpi.usra.edu/meetings/ marsconcepts2012/pdf/4238.pdf]: A Wind-Driven Networked System of Mobile sensors on Mars. The moballs would have sensing, processing, and communication capabilities. The moballs would perform in situ detection of key environmental elements such as vaporized water, trace gases, wind, dust, clouds, light and UV exposure, temperature, as well as minerals of interest, possible biosignatures, surface magnetic and electric fields, etc. The embedded various low-power micro instruments could include a Multispectral Microscopic Imager (to detect various minerals), a compact curved focal plane array camera (UV/Vis/NIR) with a large field of view, a compact UV/Visible spectrometer, a micro-weather station, etc. The moballs could communicate with each other and an orbiter. Their wind- or gravity-driven rolling movement could be used to harvest and store electric energy. They could also generate and store energy using the sunlight, when available, and the diurnal temperature variations on Mars. The moballs would be self-aware of their (and their neighbors ) positions, energy storage, and memory availability; they would have processing power and could intelligently cooperate with neighboring moballs by distributing tasks, sharing data, and fusing information. The major advantages of using the wind-driven and spherical moball network over rovers or other fixed sensor webs to explore Mars would be: (1) moballs could explore a much larger expanse of Mars in a much faster fashion, (2) they could explore the difficult terrains such as steep slopes and sand dunes, and (3) they would be self-energy- generating and could work together and move around autonomously. The challenge in designing the structure and the mechanics of the moball would be that it should be sturdy enough to withstand the impact of its initial fall, as well as other impacts from obstacles in its way. A mechanism would be needed that could enable hundreds of moballs to be carried while they would be deflated and compact, then would inflate them just after deploying them to their drop site. Furthermore, the moballs should also be light enough to allow them to move easily over obstacles by force of the wind. They also should have some kind of maneuvering mechanism in place to help them avoid very hazardous sharp objects or events, and to enable them to get closer to the objects of interest. The structure of the moballs was designed so that they would have different layers. The outer layer should comprise a sturdy, yet light, polymer that could withstand both the impact of the initial drop, as well as the impact of the different obstacles it would encounter while traversing the surface of Mars. This polymer should not deteriorate with the 100 K daily temperature swings on Mars. The inner layer should consist of a very light gas such as nitrogen or helium. In terms of maneuvering, six very light weights placed at strategic locations would give moballs the ability to turn, or even hop, over hazardous (e.g., sharp) obstacles, or even initiate a movement (before getting more help from the wind to be carried around) when stuck. Maneuvering would be necessary in order to get closer to objects of interest. If the weights would be allowed to move freely, they could also be used to generate energy.

Davoodi, Faranak↗

NASA NTRS1972

An interdisciplinary study of the estuarine and coastal oceanography of Block Island Sound and adjacent New York coastal waters

The author has identified the following significant results. The synoptic repetitive coverage of the multispectral imagery from the ERTS-1 satellite, when photographically reprocessed using the state-of-the-art techniques, has given indication of spectral differences in Block Island and adjacent New England waters which were heretofore unknown. Of particular interest was the possible detection of relatively small amounts of phytoplankton prior to the occurrence of the red tide in Massachusetts waters. Preparation of spatial and temporal hydrographic charts using ERTS-1 imagery and ground truth analysis will hopefully determine the environmental impact on New York coastal waters.

Yost, E.↗