ENERGIES OF TWO INTERSTITIAL CONFIGURATIONS IN A FACE-CENTERED CUBIC CRYSTAL
Energies of formation in face-centered cubic crystal
FACE CENTERED CUBIC /FCC/ CRYSTAL↗
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Twisted multifilament superconductor
Masking selected portions of a ribbon and forming an intermetallic compound on the unmasked portions by a controlled diffusion reaction produces a twisted filamentary structure. The masking material prohibits the formation of superconductive material on predetermined areas of the substrate.
Coles, W. D.↗
Guidebook of nondestructive evaluation techniques for materials and structures
Seventy nondestructive techniques for evaluating material and structures are described in guidebook. Standardized format facilitates comparison of their merits and limitations for solving various problems. Guide includes index of flaw types and tabulated guide to use of nondestructive evaluation techniques. Alternative technique names are cross-referenced.
Vary, A.↗
Biological activity of ionene polymers
Ionene polymers are polyammonium salts with positive nitrogens in the backbone, resulting from the polycondensation of diamines with dihalides or from the polycondensation of halo amines. The mechanism of formation of ionene polymers of different structures and their biological activity is reviewed. The antimicrobial and antifungal properties are compared with low molecular weight ammonium salts. Ionenes were found to combine with DNA by means of ionic bonds to yield similar complexes to those obtained with polyamines (spermine and spermidine). They also combine with nerve cell receptors and exercise a more powerful and longer duration ganglionic blocking action than their monomeric analogs. The antiheparin activity of ionenes and the thromboresistance of elastomeric ionene heparin coatings is described. The enhanced biological activity of ionenes as compared with low molecular weight compounds is attributed to a cooperative effect of a large number of positive charges on the polymeric chains.
Rembaum, A.↗
The surface structure of titanium and its interaction with bromine and chlorine
The surface structure and composition of titanium have been studied by electron diffraction and Auger electron spectroscopy in the temperature range 25 to 850 C. Atomically clean, well-defined Ti surfaces were obtained by a combination of argon ion sputtering and thermal treatment at 700 to 800 C. A series of surface superstructures was observed as the crystal temperature was gradually decreased. The development of the superstructures is best explained as due to surface reconstruction as a result of surface relaxation. The interaction of bromine and chlorine vapors with clean Ti surfaces was investigated in the temperature range 25 to 500 C. Bromine exposure at room temperature gave rise to an amorphous surface layer, which on annealing transformed into an epitaxial TiBr2 structure. Chlorine interaction resulted in the formation of an epitaxial TiCl3 on both cold and hot Ti surfaces. Surface impurities inhibited the chemical interaction process on the Ti surface.
Khan, I. H.↗
Mass spectrometry of aerospace materials
Mass spectrometry is used for chemical analysis of aerospace materials and contaminants. Years of analytical aerospace experience have resulted in the development of specialized techniques of sampling and analysis which are required in order to optimize results. This work has resulted in the evolution of a hybrid method of indexing mass spectra which include both the largest peaks and the structurally significant peaks in a concise format. With this system, a library of mass spectra of aerospace materials was assembled, including the materials responsible for 80 to 90 percent of the contamination problems at Goddard Space Flight Center during the past several years.
Colony, J. A.↗
Preparation of tantalum-based alloys by a unique CVD process
The paper describes a sequential pulsing technique for deposition of refractory alloys and evaluates the technique for the deposition of the tantalum-base alloys Ta-10W (Ta-10 st% W) and T-111 (Ta-8 wt% W-2 wt% Hf). The deposition cycle for Ta-10W was chosen as alternate injections of TaCl5 plus hydrogen and WCl6 plus hydrogen. The cycle for T-111 was chosen as injections of TaCl5 plus hydrogen interspersed with injections of WCl6 plus hydrogen. A temperature range of 900-1300 C was chosen for both alloys. The ability of the pulse process to blanket a uniformly heated section of substrate with a mixture of gases, whose composition varies not with position on the substrate but instead with time of residence in the reactor, allows metal of uniform thickness to be deposited. It is shown that Ta and W can be deposited at high temperature with the formation of a dense columnar grain structure, so that the feasibility of preparing uniformly thick deposits of these elements by a 'pulsing' modification of CVD is demonstrated. A similar attempt to deposit T-111 was unsuccessful due to the difficulty in reducing HfCl4.
Bryant, W. A.↗
LISP: Data is program. A tutorial in LISP
A novel approach at teaching LISP to a novice was developed. The abstract data format is presented, emphasizing its real structure and its machine implantation. Then the technique of writing programs in the data language, and of interpreting them, is presented. Illustrative features are drawn from various extant LISP implementations.
White, J. L.↗
CAVE: A computer code for two-dimensional transient heating analysis of conceptual thermal protection systems for hypersonic vehicles
A digital computer code CAVE (Conduction Analysis Via Eigenvalues), which finds application in the analysis of two dimensional transient heating of hypersonic vehicles is described. The CAVE is written in FORTRAN 4 and is operational on both IBM 360-67 and CDC 6600 computers. The method of solution is a hybrid analytical numerical technique that is inherently stable permitting large time steps even with the best of conductors having the finest of mesh size. The aerodynamic heating boundary conditions are calculated by the code based on the input flight trajectory or can optionally be calculated external to the code and then entered as input data. The code computes the network conduction and convection links, as well as capacitance values, given basic geometrical and mesh sizes, for four generations (leading edges, cooled panels, X-24C structure and slabs). Input and output formats are presented and explained. Sample problems are included. A brief summary of the hybrid analytical-numerical technique, which utilizes eigenvalues (thermal frequencies) and eigenvectors (thermal mode vectors) is given along with aerodynamic heating equations that have been incorporated in the code and flow charts.
Rathjen, K. A.↗
New languages for numerical software
Existing languages for numerical software are not altogether satisfactory. FORTRAN, even preprocessed, has troublesome limitations. Unfortunately, proposed replacements are discouragingly large, or omit essential features like variably dimensioned arrays and FORTRAN capability. A new language was designed to include such crucial features, but otherwise be as small as possible. This language, called T, includes: indention to indicate block structure, novel loop syntax, and engineering format for real constants. By preprocessing into PL/1, implementation cost was kept low.
Grosse, E.↗
Changes in bone tissue under conditions of hypokinesia and in connection with age
X-ray micrography was used to study the optical density of the blackening of X-ray photographs made of five bones in 9 young people (ages 24 to 29) before and after strict bed rest for 16 to 37 days. Photometric studies of the X-ray film determined the relative concentration of bone structure before and after hypokinesia. In addition, the bone tissues of 25 cadavers of practically healthy individuals (aged 18 to 70) who died from injuries were investigated using X-ray structural analysis. Results show that the reaction to the state of hypokinesia is not uniform in different individuals and is quite often directly reversed. It was established that pronounced osteoporosis can be found in a relatively short time after conditions of hypokinesia in healthy young individuals. Results show that the stabilization of the crystalline structure of hydroxyapatite, especially its crystal formation, is finished by the age of 20 to 25. From 25 to 60, the crystal lattice remains in stable condition but X-ray analysis shows a reduction in the hydroxyapatite density.
Podrushnyak, E. P.↗
The structure of chromospheres around late-type giants and supergiants
Observations alpha Tau (K5III) and beta Gru (M2II) made at high resolution are used to confirm line identifications of features blended at low resolution. The high resolution spectra allow selected pairs of lines to be used to find the electron density and the opacity. Methods for determining these factors and the usual emission measure are presented. The electron density and opacity can be used together with the emission measure to place constraints on the structure of the atmosphere. The line formation processes are briefly discussed. Photo-excitation by strong lines appears to be important in these late type atmospheres.
Brown, A.↗
Mach number dependence of the coherent structure in high speed subsonic jets
The coherent structure in high Reynolds number, Mach 0.6 to 0.8 axisymmetric cold air jets exhausting at atmospheric pressure has been studied. The mean flow and the statistical time averaged turbulence properties have been measured. The coherent structure in the jets was measured using two hot-wire probes and cross correlations. The coherent structure was represented in a wave format. The axial wavelength was measured for several frequencies and was compared to results obtained by other investigators for various Mach and Reynolds numbers. The results indicated that the axial wavelength-frequency relationship was the same for a wide range of Mach and Reynolds numbers.
Morrison, G. L.↗
Modeling Interface Motion Of Combustion (MINOC). A computer code for two-dimensional, unsteady turbulent combustion
A computer code for calculating the flow field and flame propagation in a turbulent combustion tunnel is described. The model used in the analysis is the random vortex model, which allows the turbulent field to evolve as a fundamental solution to the Navier-Stokes equations without averaging or closure modeling. The program was used to study the flow field in a model combustor, formed by a rearward-facing step in a channel, in terms of the vorticity field, the turbulent shear stresses, the flame contours, and the concentration field. Results for the vorticity field reveal the formation of large-scale eddy structures in the turbulent flow downstream from the step. The concentration field contours indicate that most burning occurred around the outer edges of the large eddies of the shear layer.
Ghoneim, A. F.↗
Communications satellites - The experimental years
Only eight years after the launc of Sputnik-1 by the Soviet Union, the first commercial satellite, 'Early Bird', entered service. In just twelve years commercial satellite service extended around the earth and became profitable. The reasons for the successful development of the communications satellite services in a comparatively short time are considered. These reasons are related to the presence of three ingredients, taking into account technology to create the system, communications requirements to form a market, and a management structure to implement the system. The formation of the concept of using earth orbiting satellites for telecommunications is discussed. It is pointed out that the years from 1958 to 1964 were the true 'experimental years' for satellite communications. The rapid development of technology during this crucial period is described, giving attention to passive satellites, active systems, and development satellites.
Edelson, B. I.↗
Backstreaming ions from oblique earth bow shocks
One-dimensional, hybrid (particle ions, fluid electrons) numerical simulations of oblique shock structure are used to analyze the mechanism by which solar wind ions can be reflected off the earth's bow shock front and escape upstream. It is shown that no backstreaming ions are produced in the simulation over 50-90 degrees of theta(nB), the angle between the interplanetary magnetic field and the shock normal. Backstreaming ions are emitted for theta(nB) of 45 degrees or less, with characteristics in reasonable agreement with those of observed reflected ion streams. The simulated shock structure becomes rather turbulent as theta(nB) decreases from 45 to 30 degrees. Analysis of the backstreaming ion trajectories shows that all backstreaming ions are originally specularly reflected. The oblique shock structure and effects such as whistler formation and ion heating are discussed.
Leroy, M. M.↗
The flow of plasma in the solar terrestrial environment
The development of electric fields in an expanding plasma was studied. With regard to the polar wind, it was found that hot magnetospheric electrons have a pronounced effect on the polar wind. In addition, there is no O(+) charge exchange barrier and substantial fluxes of O(+) ions can escape with the polar wind. In the auroral plasma physics area, the excitation of electrostatic waves by field aligned auroral electron beams was examined. It was demonstrated that the auroral field aligned current density can be large enough to excite Buneman double layers. For situations that lead to strong double layers, it was shown that the temporal evolution of the potential profile is controlled by current fluctuations. Two dimensional particle in cell simulations were conducted, and the high frequency wave turbulence excited by an auroral electron beam of finite width perpendicular to an ambient magnetic field was investigated. The formation of V shaped auroral potential structures was studied, and numerical simulations of double layers and auroral electric fields were reviewed.
Schunk, R. W.↗
Crystal growth of GaAs in space
It is shown that stoichiometry variations in the GaAs melt during growth constitute the most critical parameter regarding defect formations and their interactions; this defect structure determines all relevant characteristics of GaAs. Convection in the melt leads to stoichiometric variations. Growth in axial magnetic fields reduces convection and permits the study of defect structure. In order to control stoichiometry in space and to accommodate expansion during solidification, a partially confined configuration was developed. A triangular prism is employed to contain the growth melt. This configuration permits the presence of the desired vapor phase in contact with the melt for controlling the melt stoichiometry.
Gatos, H. C.↗