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Marshall Space Flight Center Faculty Fellowship Program

The 2018 Marshall Faculty Fellowship Program involved 16 faculty in the laboratories and departments at Marshall Space Flight Center. These faculty engineers and scientists worked with NASA collaborators on NASA projects, bringing new perspectives and solutions to bear. This Technical Memorandum is a compilation of the research reports of the 2018 Marshall Faculty Fellowship program, along with the Program Announcement (Appendix A) and the Program Description (Appendix B). The research affected the following five areas: (1) Materials (2) Propulsion (3) Spacecraft systems (4) Vehicle systems (5) Space science The materials investigations includes Lunar Regolith for habitats, friction stir welding, and composite joints. Propulsion studies included cryogenic tank pressurization, transmitted torque in a cryogenic environment, and condensation in presence of noncondensables, Europa Lander Deorbit Stage, and catalyst development for a hybrid rocket. Spacecraft systems include wireless sensor networks and printed electronic inks. Vehicle systems studies were performed on Mars ascent vehicle analysis, architecture models, and Space Launch System manual steering. Space science studies included planetary lava flow. Our goal is to continue the Marshall Faculty Fellowship Program funded by Center internal project offices. Faculty Fellows in this 2018 program represented the following minority-serving institutions: Alabama A&M University, Southern University, Delgado Community College, and Dillard University.

Six, N. F.↗

Methods Reduce Cost, Enhance Quality of Nanotubes

For all the challenges posed by the microgravity conditions of space, weight is actually one of the more significant problems NASA faces in the development of the next generation of U.S. space vehicles. For the Agency s Constellation Program, engineers at NASA centers are designing and testing new vessels as safe, practical, and cost-effective means of space travel following the eventual retirement of the space shuttle. Program components like the Orion Crew Exploration Vehicle, intended to carry astronauts to the International Space Station and the Moon, must be designed to specific weight requirements to manage fuel consumption and match launch rocket capabilities; Orion s gross liftoff weight target is about 63,789 pounds. Future space vehicles will require even greater attention to lightweight construction to help conserve fuel for long-range missions to Mars and beyond. In order to reduce spacecraft weight without sacrificing structural integrity, NASA is pursuing the development of materials that promise to revolutionize not only spacecraft construction, but also a host of potential applications on Earth. Single-walled carbon nanotubes are one material of particular interest. These tubular, single-layer carbon molecules - 100,000 of them braided together would be no thicker than a human hair - display a range of remarkable characteristics. Possessing greater tensile strength than steel at a fraction of the weight, the nanotubes are efficient heat conductors with metallic or semiconductor electrical properties depending on their diameter and chirality (the pattern of each nanotube s hexagonal lattice structure). All of these properties make the nanotubes an appealing material for spacecraft construction, with the potential for nanotube composites to reduce spacecraft weight by 50 percent or more. The nanotubes may also feature in a number of other space exploration applications, including life support, energy storage, and sensor technologies. NASA s various efforts with carbon nanotubes have made it a global leader in this field. Among the many examples are Johnson Space Center s Carbon Nanotube Project, which focuses on bulk nanotube production, purification, and application, and Goddard Space Flight Center s improved arc discharge method of nanotube production, developed under the direction of Jeannette Benavides (featured in Spinoff 2007 and 2008). While the Agency continues its own research, it partners with private companies to advance this unique technology for use on Earth as well as among the stars.

Source record↗

Investigating Material Behavior in Atmospheric Entry Conditions: Arc-Jet Testing Insights from Meteorite Ablation to High-Temperature Coatings.

Arc-jet testing is an indispensable tool in elucidating the complex interactions materials undergo when subjected to the extreme thermal and mechanical stresses of atmospheric entry. By replicating these harsh conditions, arc-jets enable researchers to explore critical phenomena such as ablation, melting, and spallation, generating invaluable data that informs the development of sophisticated, physics-based models. These models are pivotal not only in predicting material performance for spacecraft re-entry systems but also in assessing the threat posed by celestial bodies as they encounter Earth’s atmosphere. One of the leading facilities for such investigations is the Hypersonic Materials Environmental Test System (HyMETS) at NASA’s Langley Research Center. A pioneering test campaign conducted at HyMETS focused on unraveling the ablation mechanisms of an ordinary chondrite meteorite (Tamdakht H5) and a terrestrial analog (basalt). These studies unveiled distinct material behaviors: Tamdakht demonstrated a remarkably stable melt flow, with mass loss primarily driven by the volatilization of elements such as iron and sodium, whereas basalt exhibited more aggressive surface degradation due to the rapid decomposition of hydrated minerals, culminating in significant spallation and surface material ejection. Beyond meteorite analysis, HyMETS has also been integral in the exploration of advanced Thermal Protection Systems (TPS) such as Phenolic Impregnated Carbon Ablator (PICA), a material with extensive flight heritage in missions like Stardust, Mars Science Laboratory, Mars 2020, and Osiris-REx. PICA, when coated with NuSil CV-1144-0—a polysiloxane resin designed to prevent particle shedding—undergoes a remarkable transformation upon heating. The resin pyrolyzes to form a thin, oxidation-resistant silicon oxycarbide layer that profoundly influences the material’s thermal response through a sophisticated four-stage process. Initially, the silicon oxycarbide acts as a formidable barrier, impeding reactive interactions with the PICA char and effectively suppressing surface temperature rise and material recession. However, as the heating persists, the protective layer decomposes via carbothermal reduction, exposing the underlying char, which in turn leads to a dramatic spike in surface temperature and accelerated material erosion. In the final stage, equilibrium is reached, with recession rates aligning with those of the virgin material. This intricate understanding of PICA-NuSil behavior under extreme conditions offers valuable insights, enhancing material response models and advancing the development of next-generation TPS for space exploration.

Chemistry↗

Report on active and planned spacecraft and experiments

Information is presented, concerning active and planned spacecraft and experiments known to the National Space Science Data Center. The information included a wide range of disciplines: astronomy, earth sciences, meteorology, planetary sciences, aeronomy, particles and fields, solar physics, life sciences, and material sciences. These spacecraft projects represented the efforts and funding of individual countries as well as cooperative arrangements among different countries.

Vette, J. I.↗

Report on active and planned spacecraft and experiments

Information on current and planned spacecraft activity for a broad range of scientific disciplines is presented. The information covers a wide range of disciplines: astronomy, Earth sciences, meteorology, planetary sciences, aeronomy, particles and fields, solar physics, life sciences, and material sciences. These spacecraft projects represent the efforts and funding of individual countries as well as cooperative arrangements among different countries.

Horowitz, R.↗

Ground-based simulation of LEO environment: Investigations of a select LDEF material: FEP Teflon (trademark)

The Long Duration Exposure Facility (LDEF) has produced a wealth of data on materials degradation in the low earth orbit (LEO) space environment and has conclusively shown that surface chemistry (as opposed to surface physics-sputtering) is the key to understanding and predicting the degradation of materials in the LEO environment. It is also clear that materials degradation and spacecraft contamination are closely linked and that the fundamental mechanisms responsible for this linking are in general not well understood especially in the area of synergistic effects. The study of the fundamental mechanisms underlying materials degradation in LEO is hampered by the fact that the degradation process itself is not observed during the actual exposure to the environment. Rather the aftermath of the degradation process is studied, i.e., the material that remains after exposure is observed and mechanisms are proposed to explain the observed results. The EOIM-3 flight experiment is an attempt to bring sophisticated diagnostic equipment into the space environment and monitor the degradation process in real time through the use of mass spectrometry. More experiments of this nature which would include surface sensitive diagnostics (Auger and photoelectron spectroscopes) are needed to truly unravel the basic chemical mechanisms involved in the materials degradation process. Since these in-space capabilities will most likely not be available in the near future, ground-based LEO simulation facilities employing sophisticated diagnostics are needed to further advance the basic understanding of the materials degradation mechanisms. The LEO simulation facility developed at Los Alamos National Laboratory has been used to investigate the atomic oxygen/vacuum ultraviolet (AO/VUV) enhanced degradation of FEP Teflon. The results show that photo-ejection of polymer fragments occur at elevated temperature (200 C), that VUV synergistic rare gas sputtering of polymer fragments occur even at 25 C, and that combined OA/VUV interaction produces a wide variety of gas phase reaction products.

Cross, Jon B.↗

The Radiation Environment in Free Space and Inside Low-Earth Spacecraft's

There are three main sources of radiation in free space. These are the trapped protons and electrons, solar energetic particles, and the galactic cosmic rays. For human mission to Mars or moon, the trapped protons and electrons are of a minor concern. The flux of trapped particles at a fixed spacecraft altitude, and of galactic cosmic rays, decreases as the solar activity increases; however, the probability of a solar particle event increases as the solar activity increases. As these particles interact with the shielding material of the spacecraft and human body, they produce secondary particles, such as lighter fragments, target fragments, and neutrons. These particles can have far more damaging effect on cells than the primary particles. Thus, the radiation environment is very complex and varies with time. In this paper, we review the sources of charged-particles that contribute significantly to radiation risk to the astronauts, and estimates of exposure for some typical missions, such as Space Shuttle, International Space Station, and a human mission to Mars.

Badhwar, Gautam D.↗

Thermal Desorption/GCMS Analysis of Astrobiologically Relevant Organic Materials

Several macromolecular organic materials, both biologically-derived (type II kerogen and humic acid) and abiotic in origin (Murchison insoluble organic material, cyanide polymer, and Titan tholin) were subjected to thermal desorption using a Chromatoprobe attachment on a Varian Saturn 2000 GCMS system. Each sample was heated sequentially at 100, 200, and 300 C to release volatile components. The evolved compounds were then separated on a Supelco EC-1 dimethylsilica GC column and detected by the Saturn 2000 ion trap mass spectrometer. The various types of macromolecular organic material subjected to thermal desorption produced distinctly different GCMS chromatograms at each temperature, containing fractions of both low and high chromatographic mobility. The relative amounts of detectable volatiles released at each temperature also differed, with type II kerogen and cyanide polymer containing the highest percentage of low-temperature components. In all the samples, the highest yield of released compounds occurred at 300 C. Only cyanide polymer evolved a homologous hydrocarbon series, suggesting that it is the only material among those examined that contains a truly polymeric structure. Pyrolysis/gas chromatography/mass spectrometry has been used extensively for analysis of terrestrial organic macromolecular materials, and was also part of the instrument package on the Viking landers. Thorough analysis by pyrolysis usually employs temperatures of 500 C or higher, which for in situ analyses can be problematic given spacecraft power and materials constraints. This study demonstrates that heating of organic materials of astrobiological relevance to temperatures as low as 200-300 C for short periods releases volatile components that can be analyzed by gas chromatography and mass spectrometry. Even in the absence of full pyrolysis, useful chemical information on samples can be obtained, and materials from different biological and abiological sources can be distinguished. The research described in this paper was carried out at the Jet Propulsion Laboratory, California Institute of Technology, under a contract with the National Aeronautics and Space Administration.

McDonald, Gene D.↗

Comparative Soot Diagnostics Experiment Looks at the Smoky World of Microgravity Combustion

From an economic standpoint, soot is one of the most important combustion intermediates and products. It is a major industrial product and is the dominant medium for radiant heat transport in most flames used to generate heat and power. The nonbuoyant structure of most flames of practical interest (turbulent flames) makes the understanding of soot processes in microgravity flames important to our ability to predict fire behavior on Earth. In addition, fires in spacecraft are considered a credible possibility. To respond to this risk, NASA has flown fire (or smoke) detectors on Skylab and the space shuttles and included them in the International Space Station design. The design of these detectors, however, was based entirely on normal gravity (1g) data. The detector used in the shuttle fleet is an ionization detector, whereas the system planned for the space station uses forward scattering of near-infrared light. The ionization detector, which is similar to smoke detectors used in homes, has a comparative advantage for submicron particulates. In fact, the space shuttle model uses a separation system that makes it blind to particles larger than a micron (believed to be dust). In the larger size range, the lightscattering detector is most sensitive. Without microgravity smoke data, the difference in the particle size sensitivities of the two detectors cannot be evaluated. As part of the Comparative Soot Diagnostics (CSD) experiment, these systems were tested to determine their response to particulates generated during long periods of low gravity. This experiment provided the first such measurements toward understanding soot processes on Earth and for designing and implementing improved spacecraft smoke detection systems. The objectives of CSD were to examine how particulates form from a variety of sources and to quantify the performance of several diagnostic techniques. The sources tested included four overheated materials (paper, silicone rubber, Teflon-coated (DuPont) wire, and Kapton-coated (DuPont) wires), each tested at three heating rates, and a candle tested at three air velocities. Paper, silicone rubber, and wire insulation, materials found in spacecraft crew cabins, were selected because of their different smoke properties. The candle yielded hydrocarbon soot typical of many 1g flames. Four diagnostic techniques were employed: thermophoretic sampling collected particulates for size analysis; laser light extinction measurements near the source tallied total particulate production; and laser light scattering and ionization detector measurements far from the particulate source provided data for evaluating the performance of smoke detection systems for these particulate sources.

Urban, David L.↗

A New Test Methodology for Evaluating Fire Risk Due to Electrical Faults in Oxygen-Enriched Environments

This paper discusses a new test methodology for assessing the safe use of materials found in spacecraft that may be exposed to electrical faults, as performed at the NASA White Sands Test Facility. “Wire-break” testing, modeled after the Cleveland Open Cup method, identifies the conditions under which pyrolyzed material transitions from a brief flash to a propagating flame. The approach focuses on fuel mass liberated through pyrolysis, mixed with oxygen, and ignited by a piloted ignition (spark due to fusion of wire) to achieve flame propagation with the least energy. The test approach attempts to find energy density thresholds derived using I²t values from current-induced heating of various test materials and wire characteristics. The application of the data provides a useful approach to mitigating fire risks in space systems by correlating threshold data to real-world designs and scaling factors, including oxygen pressure, wire diameter, heat sinking, and contained smoke volume. Several case studies, including Apollo missions and hypothetical scenarios, illustrate practical applications of these thresholds to enhance fire safety design considerations in space environments.

methodology↗

Report on Active and Planned Spacecraft and Experiments

Information concerning concerning active and planned spacecraft and experiments known to the National Space Science Data Center are included. The information contains a wide range of disciplines: astronomy, earth sciences, meteorology, planetary sciences, aeronomy, particles and fields, solar physics, life sciences, and material sciences. These spacecraft projects represent the efforts and funding of individual countries as well as cooperative arrangements among different countries. Approximately 850 articles are included.

Vostreys, R. W.↗

Proceedings of the Magnetics Workshop

Conference on measurement and reduction of spacecraft magnetic fields - materials and design criteria - magnetic decontamination of components - testing facilities and human tests

CONFERENCE↗

A method of isolating treadmill shock and vibration on spacecraft

A major problem is currently felt to exist in the implementation of materials processing on a spacecraft. Crystal growers place requirements of one micro-g or less on the vehicle. Simple math produces startling figures for such a restriction e.g., for each ton of vehicle mass with 10(-6) g acceleration limit; Perturbing Force limit, F = .002 lb. For each 10(5) lbs F = 0.1 lb. For each 10(6) lbs F = 1.0 lb. Forces generated by normal human movement on spacecraft of 5x10(5) pounds weight are on an order-of-magnitude greater than allowed by this specification and forces generated by locomotion on a treadmill are more than two orders-of-magnitude greater. Other exercises and normal onboard functions generate forces in between. To accommodate many essential functions it is obvious that even on a vehicle as large as Space Station, a reduction of more than two orders of magnitude in force is required. Commonly used passive shock and vibration isolation devices are complex, heavy, and also would have difficulty meeting the requirements. However, by a new arrangement, adequate isolation can be obtained. Isolation of the treadmill will be treated since it is considered the most significant disturbance at this time.

Thornton, William E.↗

Report on active and planned spacecraft and experiments

Information dealing with active and planned spacecraft and experiments known to the National Space Science Data Center (NSSDC) is presented. Included is information concerning a wide range of disciplines: astronomy, earth sciences, meteorology, planetary sciences, aeronomy, particles and fields, solar physics, life sciences, and material sciences. These spacecraft represent the efforts and funding of individual countries, as well as cooperative arrangements among different countries.

Brecht, J. J.↗

Development of a Thin-Film Solar Cell Interconnect for the Powersphere Concept

Dual junction amorphous silicon (a-Si) solar cells produced on polyimide substrate have been selected as the best candidate to produce a lightweight solar array for the PowerSphere program. The PowerSphere concept features a space-inflatable, geodetic solar array approximately 0.6 meters in diameter and capable of generating about 20W of electrical power. Trade studies of various wiring concepts and connection methods led to an interconnect design with a copper contact that wraps around the edge, to the back of the solar cell. Applying Plasma Vapor Deposited (PVD) copper film to both sides and the edge of the solar cell produces the wrap around contact. This procedure results in a contact pad on the back of the solar cell, which is then laser welded to a flex circuit material. The flex circuit is constructed of copper in a custom designed routing pattern, and then sandwiched in a Kapton insulation layer. The flex circuit then serves as the primary power distribution system between the solar cells and the spacecraft. Flex circuit material is the best candidate for the wiring harness because it allows for low force deployment of the solar cells by the inflatable hinges on the PowerSphere. An additional frame structure, fabricated and assembled by ILC Dover, will reinforce the wrap around contact-flex blanket connection, thus providing a mechanically robust solar cell interconnect for the PowerSphere multifunctional program. The PowerSphere team will use the wraparound contact design approach as the primary solution for solar cell integration and the flex blanket for power distribution.

Simburger, Edward J.↗

Europa Propulsion Valve Seat Material Testing

The Europa mission and spacecraft design presented unique challenges for selection of valve seat materials that met the fluid compatibility requirements, and combined fluid compatibility and high radiation exposure level requirements. The Europa spacecraft pressurization system valves will be exposed to fully saturated propellant vapor for the duration of the mission. The effects of Nitrogen Tetroxide (NTO) and Monomethylhydrazine (MMH) propellant vapors on heritage valve seat materials, such as Vespel SP-1 and Polychlorotrifluoroethylene (PCTFE), were evaluated to determine if an alternate material is required. In liquid system applications, Teflon is the only available compatible valve seat material. Radiation exposure data for Teflon in an air or vacuum environment has been previously documented. Radiation exposure data for Teflon in an oxidizer environment such as NTO, was not available, and it was unknown whether the effects would be similar to those on air-exposed samples. Material testing was conducted by Marshall Space Flight Center (MSFC) and White Sands Test Facility (WSTF) to determine the effects of propellant vapor on heritage seat materials for pressurization valve applications, and the effects of combined radiation and NTO propellant exposure on Teflon. The results indicated that changes in heritage pressurization valve seat materials' properties rendered them unsuitable for the Europa application. The combined radiation and NTO exposure testing of Teflon produced results equivalent to combined radiation and air exposure results.

Addona, Brad M.↗