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At least 865 records · Page 48

Melting of magnesium oxide up to two terapascals using double-shock compression

Constraining the melting behavior of magnesium oxide, a major constituent of gaseous and rocky planets, is key to benchmarking their evolutionary models. Using a double-shock technique, we extended the MgO melt curve measurements to 2 TPa; this is twice the pressure achieved by previous melting experiments on any material. A temperature plateau is observed between 1218 and 1950 GPa in the second shock states, which is attributed to latent heat of melting. At 1950 GPa, the measured melting temperature is 17,600 K, 17% lower than recent theoretical predictions. Furthermore, the melting curve is steeper than that of MgSiO 3 , indicating that MgO is likely solid in the interior of Saturn-sized gas giants and extra-solar super-Earth planets.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Synthesis of mesoporous silica using a mineral silica source

Abstract Mesoporous silica has been applied in catalysis, separations, and drug delivery. It has generally been made using organosilicon precursors such as tetraethyl orthosilicate. For sustainability, it is necessary to find readily accessible mineral sources for making mesoporous silica. In this work, we demonstrate the successful synthesis of mesoporous silica with 10 nm average pore size using the mineral forsterite (Mg 2 SiO 4 ) as a silica source, providing a potentially cheaper and more Earth‐friendly route to making technologically important porous silica materials. Pure forsterite was synthesized by a solid‐state chemistry route at 1000°C and underwent dissolution–reprecipitation in aqueous hydrochloric acid containing the soft template surfactant, Pluronic P123. Variations of initial reaction pH (−0.2 to 0.6), reaction time (12–24 h), reaction temperature (50 to 90°C), and silica precursor (forsterite and fumed silica) were performed. The mesoporous silica aged at 70°C for 24 h had the highest porosity, with a surface area of 735 m 2 /g and a pore volume of 1.4 ml/g, comparable to mesoporous silica made using conventional starting materials. This novel geomimetic synthesis route supports the possibility of analogous formation of structured (mesoporous or zeolitic) silica in nature under abiotic or prebiotic conditions.

Materials Science↗

Mission analysis for the interplanetary monitoring platforms IMP-H and -J

IMP-H and -J were launched in September 1972 and October 1973, respectively, and placed into orbits of low eccentricity halfway distant to the moon. IMP-H was required to remain between 30 and 40 earth radii for three years, and IMP-J was to maintain a similar orbit while staying on the opposite side of the earth. In both cases no orbit-adjust capability was provided after firing of a solid-propellant apogee kick motor; so strategy during mission operations depended on advance studies of orbit evolution and sensitivity to pertinent error sources. This is presented in detail along with the launch window study, and comparisons are made between the target and achieved orbits.

Muhonen, D. P.↗

Tidal disruption and the origin of the Moon

The dynamic problem of the tidal disruption of a rocky planetismal was solved by a direct integration of the fully three-dimensional, nonlinear equations of motion. The hypothesis that any object that passes within the Roche limit is disrupted was disproven. A time dependent solution was performed numerically, treating the planetismal as a fluid with a Murnaghan equation of state in the solid regions and zero pressure otherwise. Calculations show that a rocky body which passes by the Earth on a parabolic orbit with a perigee within the Roche limit is not tidally disrupted. Objects on hyperbolic orbits would experience even less tidal disruption. The results herein do not apply to bodies with very low viscosity. It is shown, however, that tidal disruption can be ruled out as a mechanism for reducing planetismal masses. Mechanisms for forming the Moon which rely upon tidal disruption are unlikely to be correct.

Mizuno, H.↗

Intelsat VI (F-3) reboost mission

As the result of a launch vehicle malfunction, the Intelsat VI(F-3) communications satellite failed to achieve geostationary orbit. The satellite is presently safe in a low-earth orbit pending a NASA Space Shuttle Program (SSP) mission to retrieve it and attach a solid rocket. This paper describes the recovery hardware design and the overall mission efforts undertaken to recover and reboost the satellite.

Virdee, L.↗

The Geoscience Laser Altimeter System (GLAS) Laser Transmitter

The Geoscience Laser Altimeter System (GLAS), launched in January 2003, is a laser altimeter and lidar for the Earth Observing System's (EOS) ICESat mission. GLAS accommodates three, sequentially operated, diode-pumped, solid-state, Nd:YAG laser transmitters. The laser transmitter requirements, design and qualification test results for this space-based remote sensing instrument is summarized and presented

Afzal, Robert S.↗

In Situ Instrumentation for Sub-Surface Planetary Geochemistry

Novel instrumentation is under development at NASA's Goddard Space Flight Center, building upon earth-based techniques for hostile environments, to infer geochemical processes important to formation and evolution of solid bodies in our Solar System. A prototype instrument, the Pulsed Neutron Generator Gamma Ray and Neutron Detectors (PNG-GRAND), has a 14 MeV pulsed neutron generator coupled with gamma ray and neutron detectors to measure quantitative elemental concentrations and bulk densities of a number of major, minor and trace elements at or below the surfaces with approximately a meter-sized spatial resolution down to depths of about 50 cm without the need to drill. PNG-GRAND's in situ a meter-scale measurements and adaptability to a variety of extreme space environments will complement orbital kilometer-scale and in-situ millimeter scale elemental and mineralogical measurements to provide a more complete picture of the geochemistry of planets, moons, asteroids and comets.

Bodnarik, J.↗

Ionically conductive powders and films, and methods of preparation

A solid ionically conductive composition (e.g., nanoparticles of less than 1 micron or a continuous film) comprising at least one element selected from alkali metal, alkaline earth metal, aluminum, zinc, copper, and silver in combination with at least two elements selected from oxygen, sulfur, silicon, phosphorus, nitrogen, boron, gallium, indium, tin, germanium, arsenic, antimony, bismuth, transition metals, and lanthanides. Also described is a battery comprising an anode, a cathode, and a solid electrolyte (corresponding to the above ionically conductive composition) in contact with or as part of the anode and/or cathode. Further described is a thermal (e.g., plasma-based) method of producing the ionically conductive composition. Further described is a method for using an additive manufacturing (AM) process to produce an object constructed of the ionically conductive composition by use of particles of the ionically conductive composition as a feed material in the AM process.

Kercher, Andrew K.↗

Finding Near-Earth Asteroid (NEA) Destinations for Human Exploration: Implications for Astrobiology

The current number of known potential NEA targets for HSF is limited to those objects whose orbital characteristics are similar to that of the Earth. This is due to the projected capabilities of the exploration systems currently under consideration and development at NASA. However, NEAs with such orbital characteristics often have viewing geometries that place them at low solar elongations and thus are difficult to detect from the vicinity of Earth. While ongoing ground-based surveys and data archives maintained by the NEO Program Observation Program Office and the Minor Planet Center (MPC) have provided a solid basis upon which to build, a more complete catalog of the NEO population is required to inform a robust and sustainable HSF exploration program. Since all the present NEO observing assets are currently confined to the vicinity of the Earth, additional effort must be made to provide capabilities for detection of additional HSF targets via assets beyond Earth orbit. A space-based NEO survey telescope located beyond the vicinity of the Earth, has considerable implications for planetary science and astrobiology. Such a telescope will provide foundational knowledge of our Solar System small body population and detect targets of interest for both the HSF and scientific communities. Data from this asset will yield basic characterization data on the NEOs observed (i.e., albedo, size determination, potential for volatiles and organics, etc.) and help down select targets for future HSF missions. Ideally, the most attractive targets from both HSF and astrobiology perspectives are those NEAs that may contain organic and volatile materials, and which could be effectively sampled at a variety of locations and depths. Presented here is an overview of four space-based survey concepts; any one of which after just a few years of operation will discover many highly accessible NEO targets suitable for robotic and human exploration. Such a space-based survey mission will reveal incredible returns for several disciplines including: exploration, in situ resource utilization, planetary defense, and science. Of particular, interest to the scientific

Landis, Rob↗

Introducing Multisensor Satellite Radiance-Based Evaluation for Regional Earth System Modeling

Earth System modeling has become more complex, and its evaluation using satellite data has also become more difficult due to model and data diversity. Therefore, the fundamental methodology of using satellite direct measurements with instrumental simulators should be addressed especially for modeling community members lacking a solid background of radiative transfer and scattering theory. This manuscript introduces principles of multisatellite, multisensor radiance-based evaluation methods for a fully coupled regional Earth System model: NASA-Unified Weather Research and Forecasting (NU-WRF) model. We use a NU-WRF case study simulation over West Africa as an example of evaluating aerosol-cloud-precipitation-land processes with various satellite observations. NU-WRF-simulated geophysical parameters are converted to the satellite-observable raw radiance and backscatter under nearly consistent physics assumptions via the multisensor satellite simulator, the Goddard Satellite Data Simulator Unit. We present varied examples of simple yet robust methods that characterize forecast errors and model physics biases through the spatial and statistical interpretation of various satellite raw signals: infrared brightness temperature (Tb) for surface skin temperature and cloud top temperature, microwave Tb for precipitation ice and surface flooding, and radar and lidar backscatter for aerosol-cloud profiling simultaneously. Because raw satellite signals integrate many sources of geophysical information, we demonstrate user-defined thresholds and a simple statistical process to facilitate evaluations, including the infrared-microwave-based cloud types and lidar/radar-based profile classifications.

Planetary Boundary Layer↗

Magellan Prelaunch Mission Operations Report

The Magellan spacecraft will be launched from Kennedy Space Center (KSC) within a 31-day overall launch period extending from April 28 to May 28, 1989. The launch will use the Shuttle Orbiter Atlantis to lift an Inertial Upper Stage (IUS) and the Magellan Spacecraft into low Earth orbit. After the Shuttle achieves its parking orbit, the IUS and attached Magellan spacecraft are deployed from the payload bay. After a short coast time, the two-stage IUS is fired to inject the Magellan spacecraft into an Earth-Venus transfer trajectory. The Magellan spacecraft is powered by single degree of freedom, sun-tracking, solar panels charging a set of nickel-cadmium batteries. The spacecraft is three-axis stabilized by reaction wheels using gyros and a star sensor for attitude reference. The spacecraft carries a solid rocket motor for Venus Orbit Insertion (VOI). A hydrazine propulsion system allows trajectory correction and prevents saturation of the reaction wheels. Communication with Earth through the Deep Space Network (DSN) is provided by S- and X-band telemetry channels, through alternatively a low, medium, or 3.7 m high-gain parabolic antenna rigidly attached to the spacecraft. The high-gain antenna also serves as the radar and radiometer antenna during orbit around Venus.

Source record↗

Erbium-Implanted WS 2 Flakes with Room-Temperature Photon Emission at Telecom Wavelengths

Optically addressable spin impurities in crystals along with device engineering provide an attractive route to realizing quantum technologies in the solid state, but reconciling disparate emitter and host material constraints for a given target application is often challenging. Rare-earth ions in two-dimensional (2D) materials could mitigate this problem given the atomic-like transitions of the emitters and the versatile nature of van der Waals systems. Here we combine ion implantation, confocal microscopy, and ab initio calculations to examine the photon emission of Er-doped WS 2 flakes. Optical spectroscopy reveals narrow, long-lived photoluminescence lines in the telecom band, which we activate after low-temperature thermal annealing. Spectroscopic and polarization-selective measurements show a uniform response across the ensemble, while the fluorescence brightness remains mostly unchanged with temperature, suggesting nonradiative relaxation channels are inefficient. Our results create opportunities for novel solid state devices coupling 2D-hosted, telecom-band emitters to photonic heterostructures separately optimized for photon manipulation.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Constraints on the origin of viscoelastic bodies

While the oceans undoubtly contribute to energy dissipation, it seems implausible that such a small amount (0.02%) of the Earth's mass could play such a dominant role in lunar orbital evolution. An alternate hypothesis assumes that most of the dissipation is associated with solid-body tides. This mechanism is also capable of varying significantly over time for viscoelastic bodies. In such an analysis of orbital evolution, the bodies are modeled as incompressible, Kelvin-Voight solids. While this material is simplistic, it does provide an analytical characterization of solid-body dissipation and the resulting tidal moment. The orbital history of a two body system is traced back in time to develop constraints on the satellite's origin. These constraints suggest the Moon appeared in a significantly inclined orbit at a distance greater than ten Earth radii. This distance is outside of the Roche limit and would appear to alleviate some difficulties associated with capture hypotheses. Small eccentricity at close approach suggests an origin by accretion.

Vanarsdale, W. E.↗

Results of Large-Scale Spacecraft Flammability Tests

For the first time, a large-scale fire was intentionally set inside a spacecraft while in orbit. Testing in low gravity aboard spacecraft had been limited to samples of modest size: for thin fuels the longest samples burned were around 15 cm in length and thick fuel samples have been even smaller. This is despite the fact that fire is a catastrophic hazard for spaceflight and the spread and growth of a fire, combined with its interactions with the vehicle cannot be expected to scale linearly. While every type of occupied structure on earth has been the subject of full scale fire testing, this had never been attempted in space owing to the complexity, cost, risk and absence of a safe location. Thus, there is a gap in knowledge of fire behavior in spacecraft. The recent utilization of large, unmanned, resupply craft has provided the needed capability: a habitable but unoccupied spacecraft in low earth orbit. One such vehicle was used to study the flame spread over a 94 x 40.6 cm thin charring solid (fiberglasscotton fabric). The sample was an order of magnitude larger than anything studied to date in microgravity and was of sufficient scale that it consumed 1.5 of the available oxygen. The experiment which is called Saffire consisted of two tests, forward or concurrent flame spread (with the direction of flow) and opposed flame spread (against the direction of flow). The average forced air speed was 20 cms. For the concurrent flame spread test, the flame size remained constrained after the ignition transient, which is not the case in 1-g. These results were qualitatively different from those on earth where an upward-spreading flame on a sample of this size accelerates and grows. In addition, a curious effect of the chamber size is noted. Compared to previous microgravity work in smaller tunnels, the flame in the larger tunnel spread more slowly, even for a wider sample. This is attributed to the effect of flow acceleration in the smaller tunnels as a result of hot gas expansion. These results clearly demonstrate the unique features of purely forced flow in microgravity on flame spread, the dependence of flame behavior on the scale of the experiment, and the importance of full-scale testing for spacecraft fire safety.

microgravity↗

Temperature Dependent Local Atomic Structure and Vibrational Dynamics of Barium Hydride and Calcium Hydride

Solid-state ionic conductors that exhibit pure ionic transport of hydride anions are rare. Here, we investigate two alkaline earth metal hydrides, barium hydride and calcium hydride, using neutron scattering techniques to understand how the local atomic environment plays a role in the diffusion of hydride ions. At high temperatures, barium hydride exhibits exceptional transport properties with ionic conductivities that are higher than those of many of the typical proton and oxide ion conductors in use today. Total neutron scattering and pair distribution function analysis reveal how a structural phase transition converts barium hydride from a modest ionic conductor into a fast ionic conductor through the introduction of disorder, deuterium site splitting, and dynamic structural fluctuations. Furthermore, neutron vibrational spectroscopy is employed to probe changes in the temperature evolution of the lattice dynamics and local energy landscape. These results improve our fundamental knowledge of the interplay between structure and dynamics governing a rare conduction process of hydride ions in solid-state materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Why Isn't the Earth Completely Covered in Water?

If protoplanets formed from 10 to 20 kilometer diameter planetesimals in a runaway accretion process prior to their oligarchic growth into the terrestrial planets, it is only logical to ask where these planetesimals may have formed in order to assess the initial composition of the Earth. We have used Weidenschilling's model for the formation of comets (1997) to calculate an efficiency factor for the formation of planetesimals from the solar nebula, then used this factor to calculate the feeding zones that contribute to material contained within 10, 15 and 20 kilometer diameter planetesimals at 1 A.U. as a function of nebular mass. We find that for all reasonable nebular masses, these planetesimals contain a minimum of 3% water as ice by mass. The fraction of ice increases as the planetesimals increase in size and as the nebular mass decreases, since both factors increase the feeding zones from which solids in the final planetesimals are drawn. Is there really a problem with the current accretion scenario that makes the Earth too dry, or is it possible that the nascent Earth lost significant quantities of water in the final stages of accretion?

Nuth, Joseph A., III↗

Analysis of Antarctic Ice-Sheet Mass Balance from ICESat Measurements

If protoplanets formed from 10 to 20 kilometer diameter planetesimals in a runaway accretion process prior to their oligarchic growth into the terrestrial planets, it is only logical to ask where these planetesimals may have formed in order to assess the initial composition of the Earth. We have used Weidenschilling's model for the formation of comets (1997) to calculate an efficiency factor for the formation of planetesimals from the solar nebula, then used this factor to calculate the feeding zones that contribute to material contained within 10, 15 and 20 kilometer diameter planetesimals at 1 A.V. as a function of nebular mass. We find that for all reasonable nebular masses, these planetesimals contain a minimum of 3% water as ice by mass. The fraction of ice increases as the planetesimals increase in size and as the nebular mass decreases, since both factors increase the feeding zones from which solids in the final planetesimals are drawn. Is there really a problem with the current accretion scenario that makes the Earth too dry, or is it possible that the nascent Earth lost significant quantities of water in the final stages of accretion?

Zwally, H. Jay↗