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At least 865 records · Page 48
All sourcesNASA NTRSDOE OSTI
NASA NTRS1987

Collisional excitation of interstellar sulfur dioxide

State-to-state rotational excitation rates for the asymmetric top molecule SO2 in collisions with low-energy He atoms have been computed. The intermolecular forces were obtained from an electron gas model, and collision dynamics were treated with the finite-order sudden approximation. The total excitation rate is probably accurate to better than 50 percent; however, individual state-to-state rates may be in error by factors of 2 or 3, and some smaller rates may be accurate only to an order of magnitude. Present results are expected to reflect within the same level of accuracy rates for excitation by collisions with H2 molecules.

Palma, Amedeo↗
NASA NTRS1987

Detection of neutral oxygen and sulfur emissions near Io using IUE

IUE spectra have shown several O I and S I emissions near Io. The optical thickness of the S I 1814 A multiplet indicates that the S column density is greater than about 2 x 10 to the 12th/sq cm. The presence of an S I 1479 A feature suggests that electron collisions with SO2 could be a major source of the emissions. It is likely that particle excitation in the denser collision-dominated part of the atmosphere is also responsible for a substantial part of the observed emissions.

Ballester, G. E.↗
NASA NTRS1987

Atmospheric science

The following types of experiments for a proposed Space Station Microgravity Particle Research Facility are described: (1) growth of liquid water drop populations; (2) coalescence; (3) drop breakup; (4) breakup of freezing drops; (5) ice nucleation for large aerosols or bacteria; (6) scavenging of gases, for example, SO2 oxidation; (7) phoretic forces, i.e., thermophoresis versus diffusiophoresis; (8) Rayleigh bursting of drops; (9) charge separation due to collisions of rimed and unrimed ice; (10) charged drop dynamics; (11) growth of particles in other planetary atmospheres; and (12) freezing and liquid-liquid evaporation. The required capabilities and desired hardware for the facility are detailed.

Hamill, Patrick↗
NASA NTRS1987

Evaluation of high temperature structural adhesives for extended service, phase 5

The evaluation of 3 experimental polymers from NASA-Langley and a commercially produced polymer from Mitsui Toatsu Chemicals as high temperature structural adhesives is presented. A polyphenylquinoxaline (PPQ), polyimide (STPI/LaRC-2), and a polyarylene ether (PAE-SO2) were evaluated as metal-to-metal adhesives. Lap shear, crack extension, and climbing drum peel specimens were fabricated from all three polymers and tested after thermal, combined thermal/humidity, and stressed hydraulic fluid (Skydrol) exposure. The fourth polymer, LARC-TPI was evaluated as an adhesive for titanium honeycomb sandwich structure. All three experimental polymers performed well as metal-to-metal adhesives from 219 K (-65 F) to 505 K (450 F), including humidity exposure. Structural adhesive strength was also maintained at 505 K for a minimum of 3000 hours. LaRC-TPI was evaluated as a high temperature (505 K) adhesive for titanium honeycomb sandwich structure. The LaRC-TPI bonding process development concentrated on improving the honeycomb core-to-skin bond. The most promising approach of those evaluated combined a LaRC-TPI polymer solution with a semi-crystalline LaRC-TPI powder for adhesive film fabrication and fillet formation.

Hendricks, C. L.↗
NASA NTRS1987

Role of molybdenum in the Na2SO4 induced corrosion of superalloys at high temperature

Sodium sulfate induced corrosion of a molybdenum containing nickel-base superalloy, Udimet 700, was studied in laboratory furnace test and in a high velocity (Mach 0.3) burner rig. Tlhe effect of SO2 content in the atmosphere on the corrosion behavior in the laboratory furnace tests was determined. catastrophic corrosion occursonly when the melt contains MoO3 in addition to Na2SO4 and Na2MoO4. The conditions under which catastrophic corrosion occurs are identified and a mechanism is described to explain the catastrophic corrosion.

Misra, A. K.↗
NASA NTRS1987

Determination of O2(a1Delta g) and O2(b1Sigma + g) yields in the reaction O + ClO yields Cl + O2 - Implications for photochemistry in the atmosphere of Venus

A discharge flow apparatus with a chemiluminescence detector was used to investigate the reaction O + ClO yields Cl + O2(asterisk), where O2(asterisk) = O2(a1Delta g) or O2(b1Sigma + g). It is found that the observed O2(a1Delta g) airglow of Venus cannot be explained in the framework of standard photochemistry using the experimental results obtained here and those reported in the recent literature. The possibility of an alternative source of O atoms derived from SO2 photolysis in the Venus mesosphere is suggested.

Leu, Ming-Taun↗
NASA NTRS1987

Mechanisms and observations for isotope fractionation of molecular species in planetary atmospheres

Chemcial and physical processes which may give rise to isotope fractionation of molecular species in the atmospheres of both earth and other planets are reviewed, along with observations of isotopically substituted molecules in planetary atmospheres. Mechanisms for production of isotope fractionation considered include atmospheric escape and the effect of isotope substitution on equilibrium constants (including those of phase changes), photolysis rates, and chemical reaction rates. The isotopes considered for compounds in the terrestrial atmosphere include D, T, C-13, C-14, N-15, O-18, and S-34. Compounds for which data about isotopic composition in the terrestrial atmosphere are summarized include CO, CO2, O3, N2O, NH3, SO2, H2S, H2O, H, H2, and CH4. Planetary atmospheres discussed include those of Venus, Mars, Jupiter, Saturn, Uranus, and Titan; isotopes reviewed are D, C-13, N-15, and O-18. Suggestions for additional research in the area of isotopically substituted molecules in atmospheres are offered.

Kaye, Jack A.↗
NASA NTRS1988

The cycle of biogenic sulfur compounds over the Amazon Basin. I - Dry season

The concentrations of SO2, methylmercaptan, dimethylsulfide, H2S, aerosol sulfate, and methanesulfonate over the Amazon Basin during the July/August dry season were determined from samples collected by the NASA research aircraft. The results indicate that biogenic emissions represent an important, if not the dominant, source of sulfur to the atmosphere over Amazonia. Per unit area, the wet continental tropics appear to have about the same reduced sulfur emission flux as the oceanic area average (about 6 nmol/sq m per min), consistent with the fact that the aerosol sulfate concentration over the Amazon Basin is similar to the excess sulfate levels over the remote oceans. However, since the wet tropical continents represent only about 3 percent of the earth's surface, their global contribution is modest; it is also small relative to the anthropogenic emissions from fossil fuel burning.

Andreae, M. O.↗
NASA NTRS1988

A general model for Io's neutral gas clouds. I - Mathematical description

A general mathematical formalism for calculating the physical properties of any of Io's neutral gas clouds (Na, K, O, S, SO2) is presented. The dynamical effects of both the gravitational fields of Io and Jupiter and solar radiation pressure are included, in addition to the many complex space- and time-dependent interactions that occur between the neutral clouds and the plasma torus. The importance of this new model in studying both the plasma conditions prevalent in the inner planetary magnetosphere and the nature of Io's local atmosphere is discussed. A numerical method for evaluating the physical properties of the neutral clouds using the new model is described.

Smyth, W. H.↗
NASA NTRS1988

Deccan volcanism at the Cretaceous-Tertiary boundary

The accuracy with which one can claim that Deccan trap volcanism occurred at the Cretaceous-Tertiary boundary (KTB) over a very short time interval is of key importance in deciding whether a volcanic origin of the KTB events should be taken seriously. In the two years since paleomagnetic, paleontological and geodynamic evidence was published, further data have become available and the case now appears to be well constrained. The Ar-40/Ar-39 results from six labs have yielded some 24 reliable plateau ages that narrow the age range to 65 to 69 Ma. Moreover, it appears that a significant part of this range results from inter-lab spread and possible minor alteration. Paleontology demonstrates that volcanism started in the Maestrichtian, more precisely in the A. mayaroensis zone. Paleomagnetism shows that volcanism spanned only 3 chrons and only one correlation remains possible, that of the main central reversed chron with 29R. Therefore, whereas Ar-40/Ar-39 is able only to restrict the duration of volcanism to some 4 Ma, paleomagnetism restricts it to 0.5 Ma. Using some geochemical indicators such as C-13 as proxy, it is suggested that volcanism actually consists of a few shorter events of unequal magnitude. Extrusion rates may be as high as 100 cu km/yr and fissure lengths as long as several 100 km. Such a scenario appears to be at least as successful as others in accounting for most anomalies observed at the KTB. Particularly important are Iridium and other platinum group elements (PGE) profiles, Sr-87/Sr-86, C-13, 0-18, other exotic geochemical signatures, spherules, soot, shocked minerals, selective and stepwise extinctions. The environmental impact of CO2 possibly released during explosive phases of volcanism, and SO2 released during effusive phases, and the ability of volcanism to ensure worldwide distribution of KTB products are now all addressed. In conclusion, the case for a causal link between internal hotspot activity, birth of the Reunion hotspot itself as the Deccan and KTB events appears to rest on an increasingly stronger basis.

Courtillot, V.↗
NASA NTRS1989

Radiation-resistant, amorphous, all-aromatic poly(arylene ether sulfones) - Synthesis, physical behavior, and degradation characteristics

The effects of Co-60 gamma radiation on a series of poly(arylene ether sulfones) prepared by nucleophilic activated aromatic substitution are investigated experimentally. The preparation of the test compounds is described, and the test results are presented in extensive tables and graphs. Radiation-induced degradation, as measured by SO2 production, was found to be lowest in compounds based on biphenol rather than bisphenol A; these findings were also well correlated with ultimate-tensile-strain measurements.

Lewis, D. A.↗
NASA NTRS1989

Spectral properties of condensed phases of disulfur monoxide, polysulfur oxide, and irradiated sulfur

The spectral reflectances of S2O, as well as the polysulfur oxide (PSO) condensate dissociation products of SO2 and condensates of elemental sulfur irradiated with UV light and X-rays, have been ascertained in the 200-1700 nm range with a view to the relevance of these compounds to the interpretation of planetary data. While S2O is a dark red solid, PSO is a pale yellow one that absorbs strongly in the UV but exhibits no bands in either the visible or near IR. Elemental S produces strong bands in the UV, and while it is normally white at room temperature, UV irradiation causes it to turn yellow. X-ray irradiation of S turns it orange.

Hapke, Bruce↗
NASA NTRS1989

Surface acoustic-wave piezoelectric crystal aerosol mass microbalance

The development of a particulate mass-sensing instrument based on a quartz-crystal microbalance and enhanced with the new surface acoustic-wave (SAW) technology is reported. Mass sensitivity comparisons of a 158-MHz SAW piezoelectric microbalance and a conventional 10-MHz quartz-crystal microbalance show that the SAW crystal is 266 times more sensitive, in good agreement with the theoretical value of 250. The frequency stability of a single SAW resonator is 6 parts in 10 to the 8th over 1 min. The response to temperature changes is found to be very linear over the range +30 to -30 C. A strong response to 15 ppm SO2 has been demonstrated on a chemically coated SAW crystal.

Bowers, W. D.↗
NASA NTRS1989

Self-limiting physical and chemical effects in volcanic eruption clouds

One-dimensional aerosol microphysical and photochemical models are used to study the chemistry of stratospheric volcanic clouds. The results indicate that the aerosol microphysical processes of condensation and coagulation produce larger particles as the SO2 injection rate is increased. Larger particles have a smaller optical depth per unit mass and settle out of the stratosphere at a faster rate than smaller ones, restricting the total number of particles in the stratosphere. The microphysical processes moderate the impact of volcanic clouds on the earth's radiation budget and climate, suggesting that volcanic effects may be self limiting. It is noted that the injection of HCl into the stratosphere, which could lead to large ozone changes, is limited by a cold trap effect in which HCl and water vapor condense on ash particles in the rising volcanic plume and fall out as ice.

Pinto, Joseph P.↗
NASA NTRS1989

Sulfur compounds in comets

Cometary atmospheres exhibit abundant sulfur and sulfur compounds, which are absent in planetary atmospheres. Sulfur compounds were also detected in interstellar media, including SO, SO2, CS, etc., but excluding S2 which was identified only in IRAS-Araki-Alcock 1983d. Fluorescence calculations are used to analyze the B-X system of S2 which appeared in IUE and ground-based spectra of IRAS-Araki-Alcock 1983d. Single- and multiple-cycle fluorescence calculations indicate that fluorescent equilibrium accounts for the observed spectra despite the fact that the S2 lifetime against solar ultraviolet radiation is relatively short. This analysis confirms unambiguously that emission peaks in the 3000 to 4000 A spectral range of the ground-based data are due to the B-X bands of S2. New evidence is presented of at least one S2 outburst before it was detected by A'Hearn, Feldman, and Schleicher. The time variation of S2 outgassing rates and discussion on the correlation between solar wind flux and the S2 outbursts will be presented.

Kim, S.↗
NASA NTRS1990

Laboratory investigations: Low Earth orbit environment chemistry with spacecraft surfaces

Long-term space operations that require exposure of material to the low earth orbit (LEO) environment must take into account the effects of this highly oxidative atmosphere on material properties and the possible contamination of the spacecraft surroundings. Ground-based laboratory experiments at Los Alamos using a newly developed hyperthermal atomic oxygen (AO) source have shown that not only are hydrocarbon based materials effected but that inorganic materials such as MoS2 are also oxidized and that thin protective coatings such as Al2O3 can be breached, producing oxidation of the underlying substrate material. Gas-phase reaction products, such as SO2 from oxidation of MoS2 and CO and CO2 from hydrocarbon materials, have been detected and have consequences in terms of spacecraft contamination. Energy loss through gas-surface collisions causing spacecraft drag has been measured for a few select surfaces and has been found to be highly dependent on the surface reactivity.

Cross, Jon B.↗
NASA NTRS1990

Submillimeter and millimeter observations of solar system objects

Microwave spectroscopy of solar system objects was supported. It necessarily involves millimeter and submillimeter wavelengths where rotational transitions reside. The existing national facilities are at OVRO, the 12-meter at Kitt Peak, UC array at Hat Creek, the Caltech CSO on Mauna Kea, and the 14-meter at the Univ. of Massachusetts, near Amherst. The group used all of these instruments in the last year except the Univ. of Massachusetts 14-meter. This wavelength range (0.3 to 3 mm) is about to enjoy an explosion of interest as submillimeter receivers become better and easier to use. This region of the spectrum is rich in transitions of molecules that exist in the planetary atmospheres which can be studied for temperature-pressure profiles, wind tracers, and atmospheric chemistry. The list of solar system objects that have been recently addressed with these techniques include: (1) Venus: CO studies of T-P profiles, winds, and photochemistry; SO2 detections; Continuum mapping remains to be done at 1 mm; (2) Earth H2O, CO, NO, NO2, O(18)O, etc. as a test bed for other atmospheres; (3) Mars: H2O, CO, O(18)O studies of T-P profiles, winds (fall of 1990), and photochemistry; (4) Saturn: Same as Jupiter plus submillimeter and millimeter mapping of the ring system; (5) Uranus and Neptune: Continuum thermal mapping; and (6) Titan: CO, HCN, and HC3NT-P information and photochemistry. Recent results are given.

Muhleman, Duane O.↗
NASA NTRS1990

Microwave spectra of van der Waals complexes of importance in planetary atmospheres

The Fourier-transform Fabry-Perot pulsed-molecular-beam microwave spectrometer at NIST was used to study the microwave spectra of a number of molecular dimers and trimers that may be present in planetary atmospheres. The weak van der Waals bonds associated with these species usually give rise to rotational-tunneling splittings in the microwave spectra. The microwave spectrum of the water dimer species was used to illustrate the complications that can arise in the study of the rotational spectra of these loosely bound species. In addition to the water dimer species, the microwave spectra of the following hydrogen-bonded and van der Waals complexes were studied: (CO2)2-H2O, CO2-(H2O)2, CO2-H2S, N2-H2O, CO-H2O, SO2-H2O, and O3-H2O.

Suenram, R. D.↗