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At least 865 records · Page 48
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Exploring the Interaction of Amphiphilic Mycobacterial Lipoarabinomannan with Lipoproteins: Implications for Blood Based Diagnosis

Currently, over one-third of the global population is infected with tuberculosis (TB), one of the world’s most deadly infectious diseases. The current gold standard for TB diagnosis is microbiological culture, which can take up to 6-8 weeks, which is not conducive to timely treatment. There are no reliable diagnostics for TB. Disease manifestation and outcome of diagnostic tests for TB is influenced by co-morbidities such as HIV co-infection, further complicating diagnostics development. Thus, there is a need for reliable diagnostics for TB. This is especially true in pediatric populations where the differential disease presentation further complicates outcomes. This dissertation describes the development and evaluation of new tailored methods-lipoprotein capture and membrane insertion- for the discriminative detection of an amphiphilic mycobacterial biomarker, lipoarabinomannan (LAM), for diagnosis of TB in adult and pediatric populations. LAM is released by Mycobacterium tuberculosis during active infection and associates with serum lipoproteins such as high and low density lipoproteins (HDL/LDL) in the human host. The guiding hypothesis of this work is that the vi sequestration of LAM in immune complexes and by lipoprotein carriers in the host contributes to difficulty in detection of the amphiphilic antigen in blood. To this end, we have evaluated the use of tailored amphiphile detection assays to process and measure sequestered LAM in host blood, and examined the application of this methodology in adults and children with TB disease. In addition, we have developed and studied an in vitro cell model to further extrapolate the impact of association of LAM with host carriers on its ability to induce innate immune processes, in order to better refine and design strategies for its direct detection. Overall, our conclusions indicate that the amphiphilic biochemistry of LAM and its interaction with lipoproteins is a feature which should be taken into account for the effective development of diagnostics.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2021

Nano-Engineered Catalyst Supported on Ceramic Hollow Fibers for the Utilization of CO 2 in Dry Reforming to Produce Syngas

The objective of this project was to develop a novel catalytic reactor containing nano-engineered catalysts for the utilization of CO 2 (captured from coal-fired power plants and other CO 2 emitting sources) in dry methane reforming (DMR) (CO 2 + CH 4 → 2 H 2 + 2 CO) to produce synthesis gas (syngas). The technology aims to reduce CO2 emissions by developing beneficial uses for CO 2 from coal-fired power plants. It also offers an alternative to mitigate CO 2 emissions in areas where geologic storage may not be an optimal solution and/or utilization could significantly offset the costs of carbon capture and sequestration. The nano-engineered Ni-based catalyst was prepared by atomic layer deposition (ALD). The Ni particles were as small as ~2-4 nm. The nano-engineered catalyst showed CH 4 conversion >95%, H 2 /CO ratio in the range of 0.7-1.0, and CH 4 reforming rate as high as 2,500 L/h/gNi at 850 ºC and pressure of 15-25 psia. The Ni-based ALD catalyst also showed good stability in DMR reaction during a 200-h continuous operation at 850 °C. This is due to strong bonding between the nanoparticles and substrates since the Ni nanoparticles were chemically bonded to the substrate during the ALD process. The high thermal stability maintains the high dispersion of Ni nanoparticles, which can inhibit coke formation because their step edges are small enough to limit carbon nucleation and growth. Technoeconomic analysis (TEA) indicates the levelized cost of syngas (LCOS) is $172/ton with our technology, which is lower than the equivalent (molar) cost of hydrogen produced by steam methane reforming (SMR) or autothermal reforming (ATR). The major operating cost is natural gas feed and fuel, and the levelized cost is highly sensitive to the price of natural gas and relatively insensitive to the CAPEX. Revenues from syngas could have a significant impact on the net cost of electricity (COE), depending on the cost of natural gas and the selling price of syngas, estimated at $36 per MWh if the syngas were sold at $195 per ton. Following DOE NETL’s guidance, a lifecycle analysis (LCA) was conducted to compare with SMR. The functional unit for the basis of comparison was defined as 1kg carbon monoxide in the product stream. The global warming potential (GWP) of our process was found to be 40% lower than the state-of-the-art SMR process. The sensitivity analysis confirms the emissions are most sensitive to the natural gas fuel requirements to deliver heat to the process.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2021

Fractured Earth Laboratory

Researchers at Los Alamos apply extensive knowledge and expertise through the Los Alamos Fractured Earth Laboratory to measure elusive rock fracture, chemical, cementing, and flow properties with purposebuilt systems that apply new and emerging measurement approaches. Unlike traditional rock mechanics laboratories, this unique laboratory capability allows researchers to accurately measure and observe fracture growth and transient flow in rock samples with microtomography at subsurface conditions. This provides critical information to solve complex and challenging subsurface fracture and flow process problems. Los Alamos is seeking to offer the Fractured Earth Laboratory’s measurement capabilities and expertise to researchers and developers in the oil and gas; geothermal; and the carbon capture, sequestration, and utilization industries. By utilizing the Fractured Earth Laboratory’s capabilities, researchers in these industries will have access to tools diagnose problems and develop solutions to subsurface issues.

58 GEOSCIENCES↗
DOE OSTI2021

Understanding Discrete Fracture Networks Through Spectral Graph Theory

Discrete Fracture Network models (DFNs) are used to simulate fluid flow and particle transport through fracture networks in low permeability rock. Understanding these processes are essential in many subsurface applications, such as environmental restoration of contaminated fractured media, CO 2 sequestration, detection of low-level nuclear tests, and hydrocarbon extraction. Compared with other models, DFNs allow for incorporation of a wider range of network characteristics but have substantially greater computation cost. These networks can be represented with graphs, allowing the use of graph theory tools to study the networks. I used Python to simulate flow and transport on a range of DFNs and analyzed these networks using methods from network analysis and spectral graph theory. My purpose was to find ways to gain insight about flow and transport on DFNs using these graph representations, bypassing the computationally intensive meshing typically required. My work is still in progress, but I have discovered several interesting trends and patterns that I believe could be useful towards my goal. If I am able to bring these results to fruition, they will aid subsurface geologists in extracting flow and transport information about fracture networks more efficiently.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Report Q3FY21 - High-Resolution 3D Acoustic Borehole Integrity Monitoring

Real-time, in-situ, high spatial resolution (sub-cm) imaging of the near-borehole environment would revolutionize wellbore diagnostics and integrity assessment by direct observation of defects. It is becoming increasingly apparent, that better understanding of the near-wellbore environment is required to meet the safety and operational needs in challenging environments such as those present in subsurface energy extraction (geothermal) and storage (CO 2 sequestration) applications. Therefore, it is important to have a more robust ability to image the near-borehole and reliably detect defects. It was proposed to further develop and improve our advanced 3D imaging system to evaluate casing defects (e.g. corrosion) and cement quality in either open- or cased-borehole with the ultimate goal to develop a commercially deployable technology. The system consists of a unique acoustic source (LANL) and advanced inversion techniques for image processing (LANL, ORNL). This system will provide comprehensive borehole integrity monitoring with improved resolution over existing techniques. As an application of this imaging system, we will characterize the effectiveness of next-generation wellbore completion technology (NETL, SNL), and will demonstrate that, unlike current technology, the proposed approach can successfully characterize foamed cements.

42 ENGINEERING↗
DOE OSTI2021

CO2 Capture Strategies via Mineralization with Industrial Waste Brines

Large coal-fired power plants (>500 MW) account for 30% of global CO2 emissions, and long-term management of this CO2 to is urgently needed mitigate global temperature increases. Sequestration of CO2 within stable mineral carbonates (e.g., CaCO3) represents an attractive emission reduction strategy because it offers a leakage-free alternative to geological storage of CO2 in an environmentally friendly form. We have previously described a mineralization process in which divalent cations are sourced from various waste streams (e.g., produced water and brackish water) and alkalinity is induced via regenerable ion-exchange materials (Bustillos et. al. Frontiers in Energy Research. 2020, 8, 352). In our process, aqueous carbonate-bearing streams with pH > 8 are produced by contacting fresh water and carbon dioxide with various ion-exchange materials (e.g., Na form zeolites or ion exchange resins). These streams are mixed with produced water containing varying concentrations (~0.01 – 1.0 M) of Ca2+ leading to the precipitation of solid calcium carbonate (PCC). This process has the advantages of using regenerable solids in a simple and continuous process to increase the pH of water by ion exchange instead of relying on the consumption of costly and unsustainable sources of alkalinity (e.g., sodium hydroxide). While once-through column experiments showed the above benefits, the same were yet to established in a steady-state process with recycle streams. In this work, we set up a process simulation to quantify the energy requirements and CO2 emissions associated with the process and seek optimal produced water compositions and CO2 concentrations (5 – 20 vol%). The process simulation was set up in ASPEN Plus using eRNTL as the thermodynamic property method and sequential modular strategy. Ion exchange alkaline solution was simulated using sodium hydroxide and validated against the experimental data obtained from once-through kinetic experiments. Nanofiltration and reverse osmosis membrane steps were also implemented for the separation of divalent cations and production of fresh water and a regeneration stream following mineralization. Sensitivity analysis was carried out using a range of produced water compositions (0.01 – 1.0 M Ca2+, 0.001 – 0.15 M Mg2+, 0.5 – 3.5 M Na+ and 0.0004 – 0.002 M Fe2+) according to the United States Geological Survey (USGS) database. Calcium carbonate yields increased with increasing CO2 concentrations and were maximized using produced water compositions with larger Ca2+ concentrations. Maximum calcium carbonate yields produced at 5 vol%, 12 vol% and 20 vol% CO2 were 2.3 mmol/L, 5.5 mmol/L, and 9.3 mmol/L, respectively, with the formation of brucite (a magnesium hydroxide phase, Mg(OH)2) and goethite (an iron hydroxide phase, FeOOH) as the primary contaminant phases (99% calcite, 0.6% brucite, 0.4% goethite), which agree with phases detected by XRD experimentally. These results indicate high purity calcium carbonate can be precipitated using industrial waste streams. Consequentially, energy consumption and net CO2 emissions were minimized where precipitated calcium carbonate was maximized for all produced water compositions and CO2 concentrations. Minimum energy consumptions were 0.21 kWh/ton CO2 processed, with 98% of the energy input required coming from the membrane filtration steps. Produced water compositions with large Na+ concentrations (> 0.5 M) were effective at reducing energy consumptions due to faster regeneration time of ion exchange materials. Additionally, calculated net CO2 emissions were negative for the process and ranged from -0.02 kg/ton CO2 to -0.15 kg/ton CO2 processed, indicating a low emission process. We will also present techno-economic assessment showing the economic benefits of the current process as an alternative to the addition of stoichiometric bases to induce alkalinity for the precipitation of CaCO3.

Simonetti, Dante↗
DOE OSTI2021

Steel Corrosion Impacts on Radionuclide Immobilization

This progress report (Level 4 Milestone Number M4SF-21LL010302052) summarizes research conducted at Lawrence Livermore National Laboratory (LLNL) within the Crystalline Activity Number SF-21LL01030205. The research is focused on actinide and radionuclide sequestration in steel corrosion products. Fuel matrix degradation models suggest that the near field is likely to be reducing at the time of canister breaching, steel corrosion, and radionuclide release, but more oxidizing conditions may prevail in the far field. The incorporation of radionuclides into corrosion phases may limit the rate of radionuclide release by sequestering a portion of the radionuclide source term. For these reasons there is a need to evaluate the incorporation of Pu and other radionuclides into various Fe-oxide phases, and to understand the behavior of coprecipitated phases during mineral recrystallization processes and during re-oxidation events. Radionuclide coprecipitation with Fe minerals may impact long-term repository performance and is an ongoing research focus at Lawrence Livermore National Laboratory.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2021

SECARB Post Injection Assessment Report

The Southern States Energy Board (SSEB) managed the overall Southeast Regional Carbon Sequestration Partnership (SECARB) Phase III project and The Bureau of Economic Geology (BEG), at the University of Texas at Austin, managed all activities associated with the Early Test field site near Cranfield, Mississippi (the Early Test or Cranfield Project). The SECARB project at Cranfield was focused downdip of the oil rim and on demonstrating the stacked nature of the storage potential at this location: enhanced oil recovery (EOR) up-dip and saline downdip. Because the injection for EOR continued after the SECARB project ended, no actual post-injection period occurred. However, information collected during the SECARB-monitored injection period, including pressure and CO2 plume position, was utilized in an EOR carbon lifecycle assessment. The carbon lifecycle assessment provided insight on tracking injection fronts and production efficiencies across the field. To complete the post injection assessment, taking into account the continuing EOR period after closeout of SECARB field activities, this report provides data and analysis done under another DOE-funded project. The follow up project focused on the carbon lifecycle of EOR and included an assessment of EOR at as-operated and under possible future scenarios. This work was published by Hossieni et al. (2018) and Hosseininoosheri (2019).

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2020

SECARB Semi-Annual Field Review Reports - Early Test

The Southern States Energy Board (SSEB) managed the overall Southeast Regional Carbon Sequestration Partnership (SECARB) Phase III project and The Bureau of Economic Geology (BEG), at the University of Texas at Austin, managed all activities associated with the Early Test field site near Cranfield, Mississippi (the Early Test or Cranfield Project). BEG was assisted in the management of site activities by Sandia Technologies (Sandia). BEG and Sandia implemented reporting procedures that included monthly and quarterly technical progress reports, as well as periodic reporting on key field activities. Subsequent sections of this report catalog the field activities and are organized in a semiannual chronology. The Cranfield Project was located approximately 12 miles east of Natchez, Mississippi. Denbury Onshore, LLC, began operating a commercial CO 2 flood of the field (using the subsurface injection of CO 2 for EOR) in June 2008. Carbon dioxide from the Jackson Dome, a natural source near Jackson, Mississippi, was delivered to the Cranfield oilfield via pipeline. Beginning in October 2008, the SECARB Early Test team characterized the surface and subsurface of the Cranfield site. During the field test CO 2 was injected into the lower Tuscaloosa Formation, a regionally extensive saline formation with the potential to hold millions of tons of CO 2 emissions. By January 2015, the team injected more than 11 million metric tons of CO 2 and monitored a total stored CO 2 mass of 5,326,975 metric tons. SECARB’s study operations occurred in four integrated research program areas within Cranfield field: (1) the High Volume Injection Test area (HiVIT); (2) the Detailed Area of Study (DAS); (3) the Geomechanical area; and (4) the near-surface observatory, also called the “P-site.” Carbon dioxide injection activities were conducted at the HiVIT and the DAS. Figure 1.1-1 provides a depiction of the DAS.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2020

SECARB 2020 Semi-Annual Field Review Reports - Anthropogenic Test

The Southern States Energy Board (SSEB) managed the overall Southeast Regional Carbon Sequestration Partnership (SECARB) Phase III project and the Electric Power Research Institute (EPRI) managed all activities associated with the Anthropogenic Test site. Advanced Resources International, Inc. (ARI) assisted EPRI with the management of site activities. EPRI and ARI followed reporting procedures that included monthly and quarterly technical progress reports, as well as periodic reporting on key field activities. Subsequent sections of this report catalog the field activities and are organized in a semi-annual chronology. The SECARB Anthropogenic Test was the largest demonstration of a fully integrated, pulverized coal-fueled carbon capture and storage (CCS) project in the United States as of 2012 and supports a commercial prototype of CO 2 capture; transportation; subsurface storage; and monitoring, verification, and accounting (MVA); and assessment. The demonstration-scale, post-combustion CO 2 capture facility at Alabama Power Company’s Plant Barry diverted flue gas (25MW equivalent) from its Unit #5 coal burning facility and captured the CO 2 using Mitsubishi Heavy Industries (MHI) KM-CDRTM advanced amine technology. The captured CO2 was compressed at Plant Barry and transported by pipeline to the injection location southeast of Citronelle, Alabama. The Citronelle Project’s geologic storage and MVA sites were located on the flanks of the Citronelle Dome, approximately three miles southeast of the city of Citronelle. The injection zone, the Paluxy Formation, a saline formation that occurs at approximately 9,400 feet and overlies the oil production horizon of the Citronelle oilfield, presents a favorable injection reservoir in terms of areal extent and petrophysical characteristics. The confining zone, the basal shale of the overlying Washita-Fredericksburg Formation, is persistent throughout the Citronelle area and possesses the appropriate criteria to act as an effective CO 2 seal.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2021

Geologic Risk Assessment Activities at SECARB Cranfield, MS Site

Risk Assessment (RA) of RCSP Phase 3 sites is a DOE requirement and valuable to DOE’s program because this process encourage careful consideration of elements that could damage an individual project, or if severe ,damage credibility and public commercial acceptance of the sequestration process. Poor outcomes even from small projects can have negative consequences larger than the cost to the individual project. In addition, practice in risk assessment compared to project evolution is needed as part of the confidence-building toward future large scale, long term industrial activities.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2021

CO 2 Source Assessment, Wabash CarbonSAFE Subtask 10.1 (Technical Report)

This document describes the CO 2 source at Wabash Valley Resources, namely the gasification process and configuration of the facility, and separation of the hydrogen product from the CO 2 byproduct which will be captured for subsurface storage. This document then presents a summary of CO 2 storage considerations and estimated project expenses for adding CO 2 capture and sequestration to the existing gasification plant.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2021

Intelligent Monitoring System for Real-time Geologic Storage, Optimization, and Reservoir Management

The objective of the subtask was to develop a near-real-time monitoring system for seismic data at the Decatur, IL, geologic carbon sequestration (GCS) site and specifically include fiber-optic cable derived distributed acoustic signal (DAS) data in the process. Owing to the large volumes of data, we opted to utilize existing deep borehole conventional seismic sensors for detection and pull DAS and shallow borehole seismic data once a detection has been made. Unfortunately, the horizontal fiber-optic cables did not yield microseismic signals for use in locating events near the GCS site. Various stacking and filtering approaches were tested without any coherent detection becoming apparent. We attribute the insensitivity to local microseismic events to a lack of coupling in downhole, vertical cable and the non-ideal alignment of the horizontal fiber-optic cable to the vertically polarized seismic energy. Despite the inability to detect and utilize the DAS data from the fiber-optic cables, we developed a general processing framework that enables easy adaptation for future deployment of fiber-optic cables with better suited alignment at Decatur or elsewhere.

Kaven, J. Ole↗
DOE OSTI2021

CO 2 Storage Site Screening Platform Development and CO 2 Storage Resource Analysis in SECARB Offshore Reservoirs Using SAS Viya

A major goal of the SECARB Offshore Partnership (DE-FE0031557) is to screen deep saline aquifers and hydrocarbon reservoirs in the central Gulf of Mexico for CO 2 sequestration and CO 2 -enhanced oil and gas recovery (EOR/EGR) and estimate the corresponding CO 2 storage resources for select reservoirs. CO 2 storage potential associated with offshore CO 2 -EOR is considerable and likely represents “low hanging fruit” for near-term CO 2 storage given the in-place infrastructure in the region. It is for these reasons that this assessment focuses on oil and gas fields. To this end, three major objectives have been completed and include (1) managing geological data derived from different sources, (2) building a reservoir screening platform for CO 2 storage, and (3) ranking the reservoirs based on the estimated CO 2 storage resources. The SAS ® Viya platform was used for data management and analytics. The Viya platform is a cloud service platform that provides data integration, data management, quick analytics, data visualization, machine learning functions, and application programming interfaces (APIs) for multi-programming languages. Different sources of data containing geologic information, reservoir properties, and EOR/EGR information were collected, cleaned, formatted, and loaded into the SAS ® Viya platform for evaluation. The major geological characteristics of both shelf and deep-water areas of the central Gulf were examined and compared to define the appropriate reservoir screening criteria. Next, a CO 2 storage site screening system was built in the SAS ® Viya platform with the pre-defined criteria. Finally, the CO 2 storage resources of the screened reservoirs were calculated and reported at the BOEM field level to identify fields with the highest estimated CO 2 storage resource. The fields with the largest total estimated CO 2 storage resource are located in the Mississippi Canyon protraction area. Due to proximity to the Mississippi Delta (indicative of less infrastructure) and large estimated CO 2 storage resources, future development activities may wish to focus efforts in the Mississippi Canyon protraction area.

02 PETROLEUM↗
DOE OSTI2021

A Non-Invasive Approach for Elucidating the Spatial Distribution of In-Situ Stress in Deep Subsurface Geologic Formations Considered for CO 2 Storage (Final Report)

The primary objectives of this project were to: develop a new, non-invasive method to define the orientation and magnitude of in-situ stresses in deep geologic formations (depths that exceed 1500 meters) considered for carbon dioxide (CO 2 ) sequestration; to demonstrate the method at a real field site; and, to extend current technical capabilities and reduce costs of acquiring information about deep-stress fields. This investigation was segmented into five tasks, including Project Management (Task 1) and four technical tasks (Tasks 2 through 5). The results of the technical tasks are described in this document.

02 PETROLEUM↗
DOE OSTI2020

SECARB-USA: Initial Inventory of Non-Technical Challenges to CCUS Deployment

The "Southeast Regional CO 2 Utilization and Storage Acceleration Partnership" (SECARB-USA) project supports the U.S. Department of Energy (DOE) Office of Fossil Energy's (FE) mission to help the United States meet its need for secure, affordable, and environmentally sound fossil energy supplies by utilizing the advancements made by the current Regional Carbon Sequestration Partnerships (RCSP) Initiative to continue to identify and address knowledge gaps.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

High-Resolution 3D Acoustic Borehole Integrity Monitoring (Final Report)

Real-time, in-situ, high spatial resolution (sub-cm) imaging of the near-borehole environment would revolutionize wellbore diagnostics and integrity assessment by direct observation of defects. It is becoming increasingly apparent, that better understanding of the near-wellbore environment is required to meet the safety and operational needs in challenging environments such as those present in subsurface energy extraction (geothermal) and storage (CO2 sequestration) applications. Therefore, it is important to have a more robust ability to image the near-borehole and reliably detect defects. It was proposed to further develop and improve our advanced 3D imaging system to evaluate casing defects (e.g. corrosion) and cement quality in either open- or cased-borehole with the ultimate goal to develop a commercially deployable technology. The system consists of a unique acoustic source (LANL) and advanced inversion techniques for image processing (LANL, ORNL). This system will provide comprehensive borehole integrity monitoring with improved resolution over existing techniques. As an application of this imaging system, we will characterize the effectiveness of next-generation wellbore completion technology (NETL, SNL), and will demonstrate that, unlike current technology, the proposed approach can successfully characterize foamed cements.

42 ENGINEERING↗