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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 865 records · Page 48
All sourcesNASA NTRSDOE OSTI
DOE OSTI2016

Sustainable Remediation of Radionuclides By a Common Sense Approach to Enhanced Attenuation - 16441

Development of in situ and relatively passive remedies for treatment of groundwater contaminated by metals and radionuclides is becoming more important because of the difficulty and cost - both to the environment and financially -- of removing these types of contaminants from the subsurface by pump-and-treat or excavation. In situ technologies rely on reactions that tend to remove contaminants from groundwater by partitioning them to solid phases in the aquifer. Monitored natural attenuation (MNA) relies solely on natural reactions to achieve remedial goals. Enhanced attenuation (EA) uses engineered approaches to supplement remediation when MNA is not sufficient to meet remedial goals. Both approaches leave contaminants in the subsurface and require a high burden of proof that contaminants will not be mobilized and become a risk in the future. Proof of the sustained effectiveness of an EA remedy is made much easier by strategic design. In multi-contaminant plumes, it is important to prioritize contaminants according to the risk they pose, with the recognition that one remedy rarely treats all contaminants. The goal for the engineered portion of the remedy should be maximum risk reduction with minimal engineering. Natural attenuation or negotiated alternate concentration levels will often allow low risk contaminants to go untreated. Whenever possible, the remedy should be consistent with the geochemical evolution of the waste site, insuring that the treated immobilized contaminants are likely to remain relatively immobile for long time frames. Finally, use what nature provides geologically, hydrologically, geochemically, or microbiologically in the remedy design. One of the impediments faced by waste site managers in implementing EA remedies is paralysis by perceived complexity. There are things that must be known to design an effective EA remedy, but there is always the temptation to know everything to eliminate the possibility of failure. Furthermore, there are plenty of people warning of failure if all is not known and they are usually willing to help the design team know all, for a price. Yet, the price of trying to eliminate all risk is never implementing an innovative remedy. All parties involved -- scientists/engineers, waste site managers, regulators and stakeholders must assume some degree of risk to deploy an EA remedy. If all parties are to assume some risk, then trust built through close communication from the start is required. The U.S. Department of Energy Office of Environmental Management has funded an applied field research initiative for several years focused, in part, on developing EA remedies for metals and radionuclides using these guiding principles. This approach to EA remedies grew out of developing and deploying a remediation strategy to replace a pump-and-treat system at the F-Area Seepage Basins on the Savannah River Site. The pump-and-treat system was energy intensive, produced several thousand cubic feet of solid radioactive waste per year, and cost $ 1 million per month to operate. The EA remedy that replaced the pump-and-treat is energy efficient, produces no waste, and costs approximately $1 million per year to maintain. At the F-Area Seepage Basins approximately 7 billion liters of low level radioactive waste solutions were disposed in three unlined basins resulting in contaminated groundwater containing various radionuclides and other contaminants. The primary contaminants of concern are tritium, strontium-90, uranium, and iodine-129. Other key features of the contaminant plume are its acidic nature with pH values as low as 3.2, its vertical stratification in the water table aquifer, and the tendency of the most contaminated portions to follow troughs in the top of the clay separating the upper aquifer zone from the lower aquifer zone. The geology was exploited by installing a funnel-and-gate system into the clay with the barrier portion blocking contaminant flow paths in the troughs in the clay. This forces the most contaminated water to flow through the gates where it encounters an in situ treatment zone created by periodic injections of alkaline solution. The flux of tritium has been reduced significantly by the barrier walls. Strontium-90 and uranium are treated by enhanced sorption in the circum-neutral pH treatment zone, consistent with natural geochemical evolution of the waste site from acidic to more neutral pH. An additional in situ treatment zone was created up-gradient of the one of the gates to treat iodine-129. Sub-micrometer diameter silver chloride particles were injected into the aquifer by direct push methods to create the treatment zone. In the laboratory and in a field pilot test the poorly soluble silver chloride particles reacted with iodide to form much less soluble silver iodide. Evaluation of the effectiveness of the silver chloride is ongoing. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2015

Innovative Use of Cr(VI) Plume Depictions and Pump-and-Treat Capture Analysis to Estimate Risks of Contaminant Discharge to Surface Water at Hanford Reactor Areas

The Hanford Site nuclear reactor operations required large quantities of high-quality cooling water, which was treated with chemicals including sodium dichromate dihydrate for corrosion control. Cooling water leakage, as well as intentional discharge of cooling water to ground during upset conditions, produced extensive groundwater recharge mounds consisting largely of contaminated cooling water and resulted in wide distribution of hexavalent chromium (Cr[VI]) contamination in the unconfined aquifer. The 2013 Cr(VI) groundwater plumes in the 100 Areas cover approximately 6 km2 (1500 acres), primarily in the 100-HR-3 and 100-KR-4 groundwater operable units (OUs). The Columbia River is a groundwater discharge boundary; where the plumes are adjacent to the Columbia River there remains a potential to discharge Cr(VI) to the river at concentrations above water quality criteria. The pump-and-treat systems along the River Corridor are operating with two main goals: 1) protection of the Columbia River, and 2) recovery of contaminant mass. An evaluation of the effectiveness of the pump-and-treat systems was needed to determine if the Columbia River was protected from contamination, and also to determine where additional system modifications may be needed. In response to this need, a technique for assessing the river protection was developed which takes into consideration seasonal migration of the plume and hydraulic performance of the operating well fields. Groundwater contaminant plume maps are generated across the Hanford Site on an annual basis. The assessment technique overlays the annual plume and the capture efficiency maps for the various pump and treat systems. The river protection analysis technique was prepared for use at the Hanford site and is described in detail in M.J. Tonkin, 2013. Interpolated capture frequency maps, based on mapping dynamic water level observed in observation wells and derived water levels in the vicinity of extraction and injection wells, are developed initially. Second, simulated capture frequency maps are developed, based on transport modelling results. Both interpolated and simulated capture frequency maps are based on operation of the systems over a full year. These two capture maps are then overlaid on the plume distribution maps for inspection of the relative orientation of the contaminant plumes with the capture frequency. To quantify the relative degree of protection of the river from discharges of Cr(VI) (and conversely, the degree of threat) at any particular location, a systematic method of evaluating and mapping the plume/capture relationship was developed. By comparing the spatial relationship between contaminant plumes and hydraulic capture frequency, an index of relative protectiveness is developed and the results posted on the combined plume/capture plan view map. Areas exhibiting lesser degrees of river protection are identified for remedial process optimization actions to control plumes and prevent continuing discharge of Cr(VI) to the river.

Miller, Chuck W.↗
DOE OSTI2015

Innovative use of Cr(VI) plume depictions and pump-and-treat capture analysis to estimate risks of contaminant discharge to surface water at Hanford reactor areas - 15315

The Hanford Site nuclear reactor operations required large quantities of high-quality cooling water, which was treated with chemicals including sodium dichromate dihydrate for corrosion control. Cooling water leakage, as well as intentional discharge of cooling water to ground during upset conditions, produced extensive groundwater recharge mounds consisting largely of contaminated cooling water and resulted in wide distribution of hexavalent chromium (Cr[VI]) contamination in the unconfined aquifer. The 2013 Cr(VI) groundwater plumes in the 100 Areas cover approximately 6 km{sup 2} (1500 acres), primarily in the 100-HR-3 and 100-KR-4 groundwater operable units (OUs). The Columbia River is a groundwater discharge boundary; where the plumes are adjacent to the Columbia River there remains a potential to discharge Cr(VI) to the river at concentrations above water quality criteria. The pump-and-treat systems along the River Corridor are operating with two main goals: 1) protection of the Columbia River, and 2) recovery of contaminant mass. An evaluation of the effectiveness of the pump-and-treat systems was needed to determine if the Columbia River was protected from contamination, and also to determine where additional system modifications may be needed. In response to this need, a technique for assessing the river protection was developed which takes into consideration seasonal migration of the plume and hydraulic performance of the operating well fields. Groundwater contaminant plume maps are generated across the Hanford Site on an annual basis. The assessment technique overlays the annual plume and the capture efficiency maps for the various pump and treat systems. The river protection analysis technique was prepared for use at the Hanford site and is described in detail in M.J. Tonkin, 2013. Interpolated capture frequency maps, based on mapping dynamic water level observed in observation wells and derived water levels in the vicinity of extraction and injection wells, are developed initially. Second, simulated capture frequency maps are developed, based on transport modelling results. Both interpolated and simulated capture frequency maps are based on operation of the systems over a full year. These two capture maps are then overlaid on the plume distribution maps for inspection of the relative orientation of the contaminant plumes with the capture frequency. To quantify the relative degree of protection of the river from discharges of Cr(VI) (and conversely, the degree of threat) at any particular location, a systematic method of evaluating and mapping the plume/capture relationship was developed. By comparing the spatial relationship between contaminant plumes and hydraulic capture frequency, an index of relative protectiveness is developed and the results posted on the combined plume/capture plan view map. Areas exhibiting lesser degrees of river protection are identified for remedial process optimization actions to control plumes and prevent continuing discharge of Cr(VI) to the river. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
NASA NTRS2017

Technology Development and Design of an Electrically Driven Pump Fed (EDPF) Bi-Propellant Propulsion System for a Mars Ascent Vehicle (MAV)

A Mars Ascent Vehicle (MAV), as part of a potential Mars Sample Return (MSR) campaign, is a very unique challenge and has been the focus of technology development and design efforts at JPL (Jet Propulsion Lab.) for several decades. Recent trajectory studies, for the current range of notional MAV payloads (6-25 kilograms), evaluated performance using propulsion systems in the 2.5 kiloNewton to 4.5 kiloNewton (600-1000 pounds-force) thrust range. The study examined several propulsion system approaches - solid rocket, bi-propellant and hybrid propulsion systems - and developed a ranking based on several key figures of merit. This paper focuses on the evaluations conducted for the two bi-propellant propulsion system options considered for a potential MAV. Historically, bi-propellant propulsion systems have been considered for this application; this study took a fresh look at both a conventional State of the Art (SOA) pressure fed bi-propellant propulsion system and recent developments using small EDPF (Electrically-Driven Pump-Fed) bi-propellant propulsion systems.

Vaughan, David↗
NASA NTRS2012

885-nm Pumped Ceramic Nd:YAG Master Oscillator Power Amplifier Laser System

The performance of a traditional diode pumped solid-state laser that is typically pumped with 808-nm laser diode array (LDA) and crystalline Nd:YAG was improved by using 885-nm LDAs and ceramic Nd:YAG. The advantage is lower quantum defect, which will improve the thermal loading on laser gain medium, resulting in a higher-performance laser. The use of ceramic Nd:YAG allows a higher Nd dopant level that will make up the lower absorption at the 885-nm wavelength on Nd:YAG. When compared to traditional 808-nm pump, 885-nm diodes will have 30% less thermal load (or wasted heat) and will thus see a similar percentage improvement in the overall laser efficiency. In order to provide a more efficient laser system for future flight missions that require the use of low-repetition- rate ( 1% Nd. To make certain that the absorption at 885 nm is on the same par as the 808-nm diode, the Nd:YAG material needs to be doped with higher concentration of Nd. Ceramic Nd:YAG is the only material that can be tailored to specific needs.

Yu, Anthony↗
DOE OSTI2020

Results of a Soil Flushing Treatability Test for Hanford Site Hexavalent Chromium Removal - 20446

U.S. Department of Energy contractor CH2M Hill Plateau Remediation Company has made significant progress remediating hexavalent chromium in groundwater near the Columbia River through the operation of pump and treat facilities and source removal activities. To mitigate risks associated with hexavalent chromium contamination, which was identified in a CERCLA interim action record of decision as the primary groundwater contaminant of concern for the 100-KR-4 Operable Unit from discharging to the Columbia River, three ion-exchange pump and treat systems were installed between 1997 and 2009. Between 2010 and 2016, operation of the K West pump and treat system, located near the former 105K West plutonium production reactor, reduced concentrations below the groundwater remediation target for hexavalent chromium. In 2016, a rebound study was performed to evaluate the effectiveness of the pump and treat remedy and assess the potential for any residual hexavalent chromium sources continuing to contribute to groundwater contamination. As a result of the rebound study, a source of continued groundwater contamination was identified. To address this condition, a soil flushing treatability test was written and approved by the U.S. Department of Energy and the U.S. Environmental Protection Agency. The test included saturating about a 1-acre area of soil with treated water with the goal of forcing the residual hexavalent chromium to groundwater where existing extraction wells could remove it for treatment, accelerating the cleanup process. In spring and summer 2019, CH2M Hill Plateau Remediation Company installed and began operating a shallow underground leach system to support the treatability test. Preliminary sampling data show the test was effective in removing the residual contamination. Following further evaluation and analysis from the initial test, the process will be considered for implementation elsewhere on the Hanford Site, particularly at locations where there is a known or suspected continuing contamination source in the soil column. The paper will cover the goals of the study, as well as more details about the following: - Overview of pump and treat exit strategy (using U.S. Environmental Protection Agency guidance); - The design and installation of the soil flushing technology in the 100-K Area; - The testing process and results of sampling data; - Post-study evaluation and potential for implementation in other locations at the Hanford Site. Innovative solutions for cleanup, such as the soil flushing technology, have resulted in substantial progress in the removal of groundwater contaminants at the Hanford Site, potentially shortening the time frame required to meet cleanup goals and resulting in significant cost savings. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2017

Simulation of Taylor flow evaporation for bubble-pump applications

Single-pressure absorption systems incorporate bubble-pump generators (BPGs) for refrigerant separation and passive fluid circulation. In conventional spot-heated BPGs, heat is transferred over a small area, requiring high source temperatures. Distributed-heated BPGs receive thermal input over most of the component surface, enabling low temperature operation. In this investigation, a Volume-of-Fluid phase-change simulation formulation is developed and validated. Here this approach is applied to the evaporating Taylor flow pattern in distributed-heated BPGs. A 2-D axisymmetric simulation is performed, which yields detailed information about the developing heat transfer and two-phase flow phenomena. Results are used to assess predicted trends and sub-models from a 1-D segmented BPG model. Close agreement is obtained between segmented model and simulation results for bubble rise velocity (5–7% deviation), bubble and slug lengths, void fraction (3%), and hydrodynamic pressure drop (18%). Specifying average Taylor bubble lengths from the simulation as an input to the segmented model reduces hydrodynamic pressure drop deviation to 6%. Simulated flow-evaporation heat transfer coefficients are significantly higher than those predicted using analytic models from the literature. A new flow evaporation heat transfer correlation that accounts for developing slug flow effects is proposed, and yields close agreement with simulation results for heat transfer coefficient (AAD = 11%) and overall heat transfer rate (2%). Overall, this investigation provides validation for a distributed-heated BPG modeling approach, which can enable passive refrigeration for diverse applications.

42 ENGINEERING↗
DOE OSTI2015

Development of a Groundwater Transport Simulation Tool for Remedial Process Optimization

The groundwater remedy for hexavalent chromium at the Hanford Site includes operation of five large pump-and-treat systems along the Columbia River. The systems at the 100-HR-3 and 100-KR-4 groundwater operable units treat a total of about 9,840 liters per minute (2,600 gallons per minute) of groundwater to remove hexavalent chromium, and cover an area of nearly 26 square kilometers (10 square miles). The pump-and-treat systems result in large scale manipulation of groundwater flow direction, velocities, and most importantly, the contaminant plumes. Tracking of the plumes and predicting needed system modifications is part of the remedial process optimization, and is a continual process with the goal of reducing costs and shortening the timeframe to achieve the cleanup goals. While most of the initial system evaluations are conducted by assessing performance (e.g., reduction in contaminant concentration in groundwater and changes in inferred plume size), changes to the well field are often recommended. To determine the placement for new wells, well realignments, and modifications to pumping rates, it is important to be able to predict resultant plume changes. In smaller systems, it may be effective to make small scale changes periodically and adjust modifications based on groundwater monitoring results. Due to the expansive nature of the remediation systems at Hanford, however, additional tools were needed to predict the plume reactions to system changes. A computer simulation tool was developed to support pumping rate recommendations for optimization of large pump-and-treat groundwater remedy systems. This tool, called the Pumping Optimization Model, or POM, is based on a 1-layer derivation of a multi-layer contaminant transport model using MODFLOW and MT3D.

Ivarson, Kristine A.↗
DOE OSTI2020

Electrochemical devices and fuel cell systems

Electrochemical devices including electrochemical pumps (ECPs) and fuel cell systems comprising a fuel cell and an ECP are disclosed. In particular, this electrochemical device can be an ECP that comprises an anode, a cathode and an anion exchange polymer separating the anode from the cathode. The ECP can be coupled to a hydroxide exchange membrane fuel cell (HEMFC) that is disclosed herein as a fuel cell system. These devices can be used in methods for removing carbon dioxide from air and for generating electricity.

Yan, Yushan↗
DOE OSTI2023

Electrochemical devices and fuel cell systems

Electrochemical devices including electrochemical pumps (ECPs) and fuel cell systems comprising a fuel cell and an ECP are disclosed. In particular, this electrochemical device can be an ECP that comprises an anode, a cathode and an anion exchange polymer separating the anode from the cathode. The ECP can be coupled to a hydroxide exchange membrane fuel cell (HEMFC) that is disclosed herein as a fuel cell system. These devices can be used in methods for removing carbon dioxide from air and for generating electricity.

Yan, Yushan↗
DOE OSTI2023

A hybrid method to evaluate the life cycle climate performance of heat pumps

Heat pumps have a significant impact on the climate, and numerous studies exist discussing the environmental impact of heat pumps quantitatively. Life Cycle Climate Performance (LCCP) is a widely accepted metric and can evaluate the carbon footprint of heat pumps from cradle to grave. LCCP calculation typically requires inputs like annual energy consumption, the material used, refrigerant type, and charge level, which are usually the intermediate or final results from heat pump simulation tools. Thus, a platform linking the heat pump simulation software, local weather conditions, and LCCP evaluation tool can simplify the heat pump design process, especially for complicated systems. This paper presents an LCCP evaluation tool accessing the outputs from the DOE Heat Pump Design Model and the building loads and temperature bin data from AHRI standard 210/240. As for case studies, this paper investigates the LCCP values and life cycle electricity costs (LCEC) of a given cooling-based heat pump with R410A in five typical US cities. In conclusion, this cooling-based heat pump has the highest LCCP value at Chicago and lowest LCCP value at Seattle. In contrast, the heat pump has the highest LCEC at Seattle and the lowest LCEC at Miami. As a future work, a more comprehensive carbon emission and cost analysis of heat pump systems will be conducted through all major cities around the world.

Shen, Bo↗
DOE OSTI2023

Desiccants enabling energy-efficient buildings: A review

Buildings account for about 39% of the total energy consumption in the United States. Developing highly energy-efficient and environmentally friendly systems that are either actively or passively integrated into buildings plays a crucial role in decarbonizing the building sector. Among various technologies, desiccant-based energy systems have received particular attention in recent years due to their unique advantages, such as being thermally driven using low-grade waste or solar energies and being reliable over a wide range of operating ranges. Extensive research efforts have been exerted on desiccant-enabled technologies at both material and system levels aiming to increase their performance and achieve high technological readiness levels. The present review paper comprehensively discusses research works made at the system level. It overviews desiccant-based air conditioning systems, desiccant-based humidity pumps, desiccant-based thermal energy storage systems, and desiccant-based appliances. The study identifies challenges and opportunities to accelerate the commercialization of desiccant-enabled technologies. It is found that desiccant materials offer great promise to improve energy efficiency and functionality of future buildings through decoupling the latent and sensible cooling loads in air conditioning systems, humidity pumps integrated into building facades, and next-generation appliances. However, commercial viability and widespread acceptance of desiccant-based systems have been hampered by several major obstacles, including liquid and air flow mal-distribution and inferior thermo-physical properties of desiccant materials resulting in low ab/adsorption and regeneration rates and bulky/costly systems.

25 ENERGY STORAGE↗
NASA NTRS1995

An inflight refill unit for replenishing research animal drinking water

This paper presents the design process and development approach for a method of maintaining sufficient quantities of water for research animals during a Shuttle mission of long duration. An inflight refill unit (IRU) consisting of two major subsystems, a fluid pumping unit (FPU) and a collapsible water reservoir (CWR), were developed. The FPU provides the system measurement and controls, pump, water lines, and plumbing necessary to collect water coming into the unit from the potable water system and pump it out into the RAHF drinking water tanks. The CWR is a Kevlar (TM) reinforced storage bladder connected to the FPU, which has a capacity of 6 liters in its expanded volume and functions to store the water collected from the potable water system, allowing for transport of the water back to the Spacelab where it is pumped into each of two research animal holding facilities. Additional components of the IRU system include the inlet and outlet fluid hoses, a power cable for providing 29V direct current spacecraft electrical power to the pump within the FPU, a tether system for the unit when in use in Spacelab, and an adapter for mating the unit to the orbiter waste collection system in order to dump excess water after use in Spacelab.

Savage, P. D.↗
DOE OSTI2015

Development of a groundwater transport simulation tool for remedial process optimization - 15316

The groundwater remedy for hexavalent chromium at the Hanford Site includes operation of five large pump-and-treat systems along the Columbia River. The systems at the 100-HR-3 and 100-KR-4 groundwater operable units treat a total of about 9,840 liters per minute (2,600 gallons per minute) of groundwater to remove hexavalent chromium, and cover an area of nearly 26 square kilometers (10 square miles). The pump-and-treat systems result in large scale manipulation of groundwater flow direction, velocities, and most importantly, the contaminant plumes. Tracking of the plumes and predicting needed system modifications is part of the remedial process optimization, and is a continual process with the goal of reducing costs and shortening the time frame to achieve the cleanup goals. While most of the initial system evaluations are conducted by assessing performance (e.g., reduction in contaminant concentration in groundwater and changes in inferred plume size), changes to the well field are often recommended. To determine the placement for new wells, well realignments, and modifications to pumping rates, it is important to be able to predict resultant plume changes. In smaller systems, it may be effective to make small scale changes periodically and adjust modifications based on groundwater monitoring results. Due to the expansive nature of the remediation systems at Hanford, however, additional tools were needed to predict the plume reactions to system changes. A computer simulation tool (the Pumping Optimization Model, or POM) was developed to support pumping rate recommendations for optimization of large pump-and-treat groundwater remedy systems. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2014

Energy Savings and Peak Demand Reduction of a SEER 21 Heat Pump vs. a SEER 13 Heat Pump with Attic and Indoor Duct Systems

This report describes results of experiments that were conducted in an unoccupied 1600 square foot house--the Manufactured Housing (MH Lab) at the Florida Solar Energy Center (FSEC)--to evaluate the delivered performance as well as the relative performance of a SEER 21 variable capacity heat pump versus a SEER 13 heat pump. The performance was evaluated with two different duct systems: a standardattic duct system and an indoor duct system located in a dropped-ceiling space.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗