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At least 865 records · Page 48

Photoelectrolysis of water at high current density - Use of laser light excitation of semiconductor-based photoelectrochemical cells

In the present paper, some results are given for UV laser light irradiation of the photoanode (SnO2, SrTiO3, or TiO2) in a cell for the light-driven electrolysis of H2O, at radiation intensities of up to 380 W/sq cm. The properties of the anode material are found to be independent of light intensity. Conversion of UV light to stored chemical energy in the form of 2H2/O2 from H2O was driven at a rate of up to 30 W/sq cm. High O2 evolution rates at the irradiated anodes without changes in the current-voltage curves are attributed to the excess oxidizing power associated with photogenerated holes. A test for this sort of hypothesis for H2 evolution at p-type materials is proposed.

Wrighton, M. S.↗

Search for effect of longitudinally polarized protons on optically active amino acids

The influence of irradiation by longitudinally polarized protons on the differential decomposition of amino acid is investigated in a test of the Vester Ulbricht hypothesis that L-amino acids were produced in preference to the D isomers on the primitive earth due to the effects of parity violation in beta decay. Samples of DL-leucine were irradiated with protons of both positive and negative longitudinal polarization, then analyzed by gas chromatography. Despite advantages of higher polarization, lower velocity and higher ionization density of protons with respect to electrons, proton irradation is found to lead to no detectable asymmetries in DL-leucine degradation, even at 50% gross degradation.

Lemmon, R. M.↗

Globular cluster origin of X-ray bursters

X-ray bursters and galactic bulge X-ray sources, or the most luminous X-ray sources in the Galaxy, are reasonably well constrained in their basic nature but not in their origin. It is suggested they may all have been produced by tidal capture in high density cores of globular clusters, which have now largely been disrupted by tidal stripping and shocking in the galactic plane. General arguments are presented for cluster disruption by the possible ring of giant molecular clouds in the Galaxy. Tests of the cluster disruption hypothesis are in progress and preliminary results are summarized here. The G-K star 'companions' previously noted for at least four bursters have spectra (in the two cases observed) consistent with metal-rich cluster giants. Several possibilities are discussed, including the formation of hierarchical triples in the dissolving cluster or in the galactic plane.

Grindlay, J. E.↗

Mapping Structures Characteristic of the Highland Boundary Scarp on Mars

In an effort to shed some light on the processes which have produced the highlands/lowlands boundary scrap on Mars, the global distributions of knobby terrain, detached and separated blocks and mesas, and craters larger than 10 km diameter were mapped. These data were represented as fractional areal percentages of the sample box, which is 2.5 deg high (latitude) along north-south profiles every 5 deg in longitude. The fractional area of crater interiors provides a way of quantitatively characterizing the boundary between cratered highlands and relatively uncratered plains. In the vicinity of the nomimal scarp there is generally good agreement between the dropoff in fractional area of craters and a drop-off in topography. Contoured versions of the fractional area of crater interiors, even at the low resolution imposed by the sample box, show good agreement with the geologic mapping. The most northerly occurrence of detached plateaus and knobby terrain were located in order to test the plausibility of the hypothesis that much of the present day highland boundary scrap is due to southward migration of a former boundary.

Frey, H.↗

Geomagnetic main field modeling using magnetohydrodynamic constraints

The influence of physical constraints are investigated which may be approximately satisfied by the Earth's liquid core on models of the geomagnetic main field and its secular variation. A previous report describes the methodology used to incorporate nonlinear equations of constraint into the main field model. The application of that methodology to the GSFC 12/83 field model to test the frozen-flux hypothesis and the usefulness of incorporating magnetohydrodynamic constraints for obtaining improved geomagnetic field models is described.

Estes, R. H.↗

Thermoelastic stress - How important as a cause of earthquakes in young oceanic lithosphere?

Thermoelastic or thermal stress is a potentially important contributor to the state of stress in the oceanic lithosphere. The present paper provides several simple models for the state of thermoelastic stress in a young oceanic lithosphere, taking into account a comparison of the predictions of these models with the characteristics of near-ridge earthquakes. Attention is given to the characteristics of near-ridge earthquakes, sources of stress in an oceanic lithosphere, previous models of thermal stress, the calculation of thermal stress, and thermal stress models. A test is conducted of the hypothesis that thermoelastic stress is a significant component of the stress field in a young oceanic lithosphere. The considered models support the hypothesis that thermoelastic stress is a significant component of the stress field in a young oceanic lithosphere.

Bratt, S. R.↗

Further evidence for differential rotation in V1057 Cygni

Further tests of the accretion disk hypothesis for FU Orionis objects are presented. High spectral resolution, high signal to noise, 5820-6830 A and 7500-9370 A spectra of V1057 Cyg reveal a correlation between linewidth and line transition lower excitation potential expected from this hypothesis. The magnitude of the effect compares favorably with that predicted by synthetic disk spectra. Additional evidence for previously documented spectral type and linewidth versus wavelength correlations is also presented. This kinematic evidence strongly supports the accretion disk hypothesis.

Welty, Alan D.↗

Geologic evidence of hotspot activity of Venus - Predictions for Magellan

A number of distinctive types of geologic features have been identified on Venus that are interpreted to be related to thermal plumes including domal rises, coronae, and major composite shield volcanoes. The basic characteristics of these features as well as their distribution are documented. The three types of features have related morphologies and are interpreted to represent a continuum of features formed by mantle plumes at scales from 100s to over 1000 km. The Artemis structure, located in Aphrodite Terra, is proposed to be a large corona. If crustal spreading processes are operating on Venus, hotspot features should form chains on the surface as seen in terrestrial ocean basins. On the basis of current data on hotspot-related feature distribution on Venus, no clear evidence exists for hotspot chains. The complete distribution of hotspot features in Magellan data will be used to understand better the relationship between interior processes and surface features, as well as to provide a test for the crustal spreading hypothesis.

Stofan, Ellen R.↗

Centaur in-tank explosion flow fields within STS and Titan 4 payload spaces

Explosions are examined which result from the mixing of liquid hydrogen and liquid oxygen (LH2-LO2) such that the reactants are confined by the missile (CBM) body. Explosion which were confined by the ground surface (CBGS) were also studied, with results reported elsewhere. Initial attempts to predict the reported PYRO experimental results were unsuccessful. A new reaction energy addition hypothesis was then developed and tested. The results obtained provide reasonable agreement with the experiments both in the near and far field. Calculations were performed to predict the environment which would occur at the Galileo Radioisotope Thermoelectric Generator (RTG) location given a Centaur G' upper stage and an STS launch vehicle. It was concluded that the principle threat to the RTG in this environment would be the impact of a slug of LH2. No analyses were conducted to assess the response of the Galileo RTG to such an environment. It was shown that the flow field resulting from the failure of the Centaur G' tankage was benign. It was concluded that while the cryogen particle velocity was very high, the flow field density was extremely low. As a result, the dynamic pressure was a trivial eight psia.

Eck, M.↗

The radio structure source of X-ray-selected BL Lacertae objects

Arcsecond-size radio structure for a complete sample of 14 X-ray-selected BL Lac objects (XBLs) from the Einstein Extended Medium-Sensitivity Survey is presented. Most objects possess radio morphologies which are similar to those of nearby Fanaroff-Riley type 1 (FR 1) radio galaxies once the effects of surface brightness dimming and beam dilution as a function of redshift are taken into account. In order to test the beamed FR 1 hypothesis for BL Lac objects, the core and extended power levels are determined for these sources and compared with samples of radio-selected BL Lac objects (RBLs) and FR 1 from galaxies from the literature. RBLs and XBLs are found to possess extended (and thus unbeamed) power levels and the largest angular sizes similar to those of the FR 1 galaxies both supporting the beaming hypothesis and a common parent population for XBLs and RBLs.

Perlman, Eric S.↗

Studies for the loss of atomic and molecular species from Io

The general objective of this project is to advance theoretical understanding of Io's atmosphere and how various atomic and molecular species are lost from this atmosphere and are distributed in the circumplanetary environment of Jupiter. The major task for the University of Michigan portion of this work is the generalization of the Io sodium cloud model to simulate the ion-precursor of sodium that is the apparent source of the fast sodium jet observed by Schneider et al. (1991). The goal is a quantitative test of the molecular ion hypothesis with a model that is comparable to a general sodium cloud model published previously. A detailed comparison of observations with such a model will help to probe the feasibility of such a source and to examine the rates and scale lengths associated with the decay of the ion precursor so as to possibly uncover the identity of the parent ion. Another important task to be performed at Michigan is more support of AER in the general area of modeling the Na and SO2-family clouds.

Combi, Michael R.↗

Microgravity Experiments to Evaluate Electrostatic Forces in Controlling Cohesion and Adhesion of Granular Materials

The bulk behavior of dispersed, fluidized, or undispersed stationary granular systems cannot be fully understood in terms of adhesive/cohesive properties without understanding the role of electrostatic forces acting at the level of the grains themselves. When grains adhere to a surface, or come in contact with one another in a stationary bulk mass, it is difficult to measure the forces acting on the grains, and the forces themselves that induced the cohesion and adhesion are changed. Even if a single gain were to be scrutinized in the laboratory, it might be difficult, perhaps impossible, to define the distribution and character of surface charging and the three- dimensional relationship that charges (electrons, holes) have to one another. The hypothesis that we propose to test in microgravity (for dielectric materials) is that adhesion and cohesion of granular matter are mediated primarily by dipole forces that do not require the presence of a net charge; in fact, nominally electrically neutral materials should express adhesive and cohesive behavior when the neutrality results from a balance of positive and negative charge carriers. Moreover, the use of net charge alone as a measure of the electrical nature of grain-to-grain relationships within a granular mass may be misleading. We believe that the dipole forces arise from the presence of randomly-distributed positive and negative fixed charge carriers on grains that give rise to a resultant dipole moment. These dipole forces have long-range attraction. Random charges are created whenever there is triboelectrical activity of a granular mass, that is, whenever the grains experience contact/separation sequences or friction. Electrostatic forces are generally under-estimated for their role in causing agglomeration of dispersed grains in particulate clouds, or their role in affecting the internal frictional relationships in packed granular masses. We believe that electrostatic, in particular dipole-mediated processes, are pervasive and probably affect, at some level, everything from astrophysical-scale granular systems such as interstellar nebulae, protoplanetary dust and debris disks, planetary-scale systems such as debris palls from meteorite impact, volcanic eruptions, and aeolian dust storms, all the way to industrial-scale systems in mining, powder and grain processing, pharmaceuticals, and smoke-stack technologies. NASA must concern itself with the electrostatic behavior of dust and sand on Mars because of its potentially critical importance to human exploration. The motion and adhesion of martian surface materials will affect the design and performance of spacesuits, habitats, processing plants, solar panels, and any externally exposed equipment such as surface rovers or communication and weather stations. Additionally, the adhesion of dust and sand could greatly enhance contact with the potentially toxic components of the martian soil.

Marshall, J.↗

Microgravity Experiments to Evaluate Electrostatic Forces in Controlling Cohesion and Adhesion of Granular Materials

The bulk behavior of dispersed, fluidized, or undispersed stationary granular systems cannot be fully understood in terms of adhesive/cohesive properties without understanding the role of electrostatic forces acting at the level of the grains themselves. When grains adhere to a surface, or come in contact with one another in a stationary bulk mass, it is difficult to measure the forces acting on the grains, and the forces themselves that induced the cohesion and adhesion are changed. Even if a single grain were to be scrutinized in the laboratory, it might be difficult, perhaps impossible, to define the distribution and character of surface charging and the three-dimensional relationship that charges (electrons, holes) have to one another. The hypothesis that we propose to test in microgravity (for dielectric materials) is that adhesion and cohesion of granular matter are mediated primarily by dipole forces that do not require the presence of a net charge; in fact, nominally electrically neutral materials should express adhesive and cohesive behavior when the neutrality results from a balance of positive and negative charge carriers. Moreover, the use of net charge alone as a measure of the electrical nature of grain-to-grain relationships within a granular mass may be misleading. We believe that the dipole forces arise from the presence of randomly-distributed positive and negative fixed charge carriers on grains that give rise to a resultant dipole moment. These dipole forces have long-range attraction. Random charges are created whenever there is triboelectrical activity of a granular mass, that is, whenever the grains experience contact/separation sequences or friction.

Marshall, J.↗

Speech motor control and acute mountain sickness

BACKGROUND: An objective method that accurately quantifies the severity of Acute Mountain Sickness (AMS) symptoms is needed to enable more reliable evaluation of altitude acclimatization and testing of potentially beneficial interventions. HYPOTHESIS: Changes in human articulation, as quantified by timed variations in acoustic waveforms of specific spoken words (voice onset time; VOT), are correlated with the severity of AMS. METHODS: Fifteen volunteers were exposed to a simulated altitude of 4300 m (446 mm Hg) in a hypobaric chamber for 48 h. Speech motor control was determined from digitally recorded and analyzed timing patterns of 30 different monosyllabic words characterized as voiced and unvoiced, and as labial, alveolar, or velar. The Environmental Symptoms Questionnaire (ESQ) was used to assess AMS. RESULTS: Significant AMS symptoms occurred after 4 h, peaked at 16 h, and returned toward baseline after 48 h. Labial VOTs were shorter after 4 and 39 h of exposure; velar VOTs were altered only after 4 h; and there were no changes in alveolar VOTs. The duration of vowel sounds was increased after 4 h of exposure and returned to normal thereafter. Only 1 of 15 subjects did not increase vowel time after 4 h of exposure. The 39-h labial (p = 0.009) and velar (p = 0.037) voiced-unvoiced timed separations consonants and the symptoms of AMS were significantly correlated. CONCLUSIONS: Two objective measures of speech production were affected by exposure to 4300 m altitude and correlated with AMS severity. Alterations in speech production may represent an objective measure of AMS and central vulnerability to hypoxia.

NASA Discipline Space Human Factors↗

A blast of gas in the latest Paleocene: simulating first-order effects of massive dissociation of oceanic methane hydrate

Carbonate and organic matter deposited during the latest Paleocene thermal maximum is characterized by a remarkable -2.5% excursion in delta 13C that occurred over approximately 10(4) yr and returned to near initial values in an exponential pattern over approximately 2 x 10(5) yr. It has been hypothesized that this excursion signifies transfer of 1.4 to 2.8 x 10(18) g of CH4 from oceanic hydrates to the combined ocean-atmosphere inorganic carbon reservoir. A scenario with 1.12 x 10(18) g of CH4 is numerically simulated here within the framework of the present-day global carbon cycle to test the plausibility of the hypothesis. We find that (1) the delta 13C of the deep ocean, shallow ocean, and atmosphere decreases by -2.3% over 10(4) yr and returns to initial values in an exponential pattern over approximately 2 x 10(5) yr; (2) the depth of the lysocline shoals by up to 400 m over 10(4) yr, and this rise is most pronounced in one ocean region; and (3) global surface temperature increases by approximately 2 degrees C over 10(4) yr and returns to initial values over approximately 2 x 10(6) yr. The first effect is quantitatively consistent with the geologic record; the latter two effects are qualitatively consistent with observations. Thus, significant CH4 release from oceanic hydrates is a plausible explanation for observed carbon cycle perturbations during the thermal maximum. This conclusion is of broad interest because the flux of CH4 invoked during the maximum is of similar magnitude to that released to the atmosphere from present-day anthropogenic CH4 sources.

Non-NASA Center↗

Anatomic patterning in the expression of vestibulosympathetic reflexes

To investigate the possibility that expression of vestibulosympathetic reflexes (VSR) is related to a nerve's anatomic location rather than its target organ, we compared VSR recorded from the same type of postganglionic fiber [muscle vasoconstrictor (MVC)] located at three different rostrocaudal levels: hindlimb, forelimb, and face. Experiments were performed on chloralose-anesthetized cats, and vestibular afferents were stimulated electrically. Single MVC unit activity was extracted by spike shape analysis of few-fiber recordings, and unit discrimination was confirmed by autocorrelation. Poststimulus time histogram analysis revealed that about half of the neurons were initially inhibited by vestibular stimulation (type 1 response), whereas the other MVC fibers were initially strongly excited (type 2 response). MVC units with types 1 and 2 responses were present in the same nerve fascicle. Barosensitivity was equivalent in the two groups, but fibers showing type 1 responses fired significantly faster than those giving type 2 responses (0.29 +/- 0.04 vs. 0.20 +/- 0.02 Hz). Nerve fibers with type 1 responses were most common in the hindlimb (21 of 29 units) and least common in the face (2 of 11 units), the difference in relative proportion being significant (P < 0.05, chi(2) test). These results support the hypothesis that VSR are anatomically patterned.

Non-NASA Center↗

Implications for Core Formation of the Earth from High Pressure-Temperature Au Partitioning Experiments

Siderophile elements in the Earth.s mantle are depleted relative to chondrites. This is most pronounced for the highly siderophile elements (HSEs), which are approximately 400x lower than chondrites. Also remarkable is the relative chondritic abundances of the HSEs. This signature has been interpreted as representing their sequestration into an iron-rich core during the separation of metal from silicate liquids early in the Earth's history, followed by a late addition of chondritic material. Alternative efforts to explain this trace element signature have centered on element partitioning experiments at varying pressures, temperatures, and compositions (P-T-X). However, first results from experiments conducted at 1 bar did not match the observed mantle abundances, which motivated the model described above, a "late veneer" of chondritic material deposited on the earth and mixed into the upper mantle. Alternatively, the mantle trace element signature could be the result of equilibrium partitioning between metal and silicate in the deep mantle, under P-T-X conditions which are not yet completely identified. An earlier model determined that equilibrium between metal and silicate liquids could occur at a depth of approximately 700 km, 27(plus or minus 6) GPa and approximately 2000 (plus or minus 200) C, based on an extrapolation of partitioning data for a variety of moderately siderophile elements obtained at lower pressures and temperatures. Based on Ni-Co partitioning, the magma ocean may have been as deep as 1450 km. At present, only a small range of possible P-T-X trace element partitioning conditions has been explored, necessitating large extrapolations from experimental to mantle conditions for tests of equilibrium models. Our primary objective was to reduce or remove the additional uncertainty introduced by extrapolation by testing the equilibrium core formation hypothesis at P-T-X conditions appropriate to the mantle.

Danielson, L. R.↗

Too Little, Too Late: How the Tidal Evolution of Hot Jupiters Affects Transit Surveys of Clusters

The tidal evolution of hot Jupiters may change the efficiency of transit surveys of stellar clusters. The orbital decay that hot Jupiters suffer may result in their destruction, leaving fewer transiting planets in older clusters. We calculate the impact tidal evolution has for different assumed stellar populations, including that of 47 Tuc, a globular cluster that was the focus of an intense HST search for transits. We find that in older clusters one expects to detect fewer transiting planets by a factor of two for surveys sensitive to Jupiter-like planets in orbits out to 0.5 AU, and up to a factor of 25 for surveys sensitive to Jupiter-like planets in orbits out to 0.08 AU. Additionally, tidal evolution affects the distribution of transiting planets as a function of semi-major axis, producing larger orbital period gaps for transiting planets as the age of the cluster increases. Tidal evolution can explain the lack of detected exoplanets in 47 Tuc without invoking other mechanisms. Four open clusters residing within the Kepler fields of view have ages that span 0.4-8 Gyr-if Kepler can observe a significant number of planets in these clusters, it will provide key tests for our tidal evolution hypothesis. Finally, our results suggest that observers wishing to discover transiting planets in clusters must have sufficient accuracy to detect lower mass planets, search larger numbers of cluster members, or have longer observation windows to be confident that a significant number of transits will occur for a population of stars.

Debes, John H.↗