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All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Rock Valley Direct Comparison Relocation Working Group Location Results and Recommendations (Version 4.0)

The Source Physics Experiments (SPE) were designed to improve our physics-based understanding of explosion sources for the purposes of nuclear test monitoring. Phase I consisted of 6 chemical explosions in the Climax Stock Granite of the Nevada National Security Site (NNSS), while Phase II consisted of 4 explosions in a contrasting dry alluvium geology (DAG) in Yucca Flat, providing essential data in various media and emplacement conditions to further modeling efforts. For Phase III, the Rock Valley Direct Comparison (RVDC) seeks to directly compare earthquake and explosion source types. An unusually shallow series of events in 1993 along the Rock Valley Fault Zone in the southeastern portion of the NNSS has been targeted for this direct comparison. Depth ranges for the events, previously estimated to be less than 3 km, is achievable by modern drilling techniques and accessibility to the epicentral locations would require minimal improvements to the infrastructure. The events providing this unique opportunity for direct comparison are the focus of this report.

58 GEOSCIENCES↗
DOE OSTI2024

Globally Gridded Groundwater Extraction Volumes and Costs under Six Depletion and Ponded Depth Targets

This repository contains simulated outputs from superwell – a hydro-economic tool for long-term assessment of groundwater cost and supply – providing globally gridded groundwater extractable volumes and associated unit costs ($/km³) for accessible groundwater production, based on a variety of user-defined depletion and ponded depth scenarios. Key model documentation: Niazi, H., Ferencz, S. B., Graham, N. T., Yoon, J., Wild, T. B., Hejazi, M., Watson, D. J., & Vernon, C. R. (2025). Long-term hydro-economic analysis tool for evaluating global groundwater cost and supply: Superwell v1.1. Geoscientific Model Development, 18(5), 1737-1767. https://doi.org/10.5194/gmd-18-1737-2025 Find the source code of the superwell model on GitHub: https://github.com/JGCRI/superwell Repository Overview Main output: superwell_outputs.7z contains 6 files (4.5 GB) named as superwell_py_deep_all_0.*PD_0.*DL.csv. These files present superwell outputs of global groundwater extraction volumes and cost estimates on a 0.5° scale for six scenarios with different Ponded Depth (PD; 0.3 and 0.6 m) and Depletion Limit (DL; 5%, 25%, and 40% of available volume) targets over the entire pumping lifetime of a grid cell superwell_py_deep_all_0.3PD_0.25DL_sample_100.csv contains superwell outputs for 100 data points sampled to match the global inputs' distribution superwell_py_deep_all_0.3PD_0.25DL_Grid_72548.csv contains superwell output for a single grid cell concept_v5.png provides an overview of the superwell workflow Outputs Description year_number: year of pumping depletion_limit: set depletion limit (DL) as a volume fraction of total available groundwater Mappings: continent, country, gcam_basin_id, Basin_long_name, grid_id: geographic identifiers and basin information Inputs: grid_area (km²): area of the grid cell whyclass: hydrogeological classification of the aquifer permeability (m/day), porosity (%), total_thickness (m), depth_to_water (m): aquifer properties. The geo-processed input data has been published separately: https://doi.org/10.57931/2307831 Model outputs: orig_aqfr_sat_thickness (m), aqfr_sat_thickness (m): original and remaining/instantaneous saturated thickness of the aquifer hydraulic_conductivity (m/day), transmissivity (m²/day): hydraulic properties of the aquifer radius_of_influence (m), areal_extent (km²): well radius and area of influence from the center of the well number_of_wells (-): number of wells in a grid cell determined by a ratio of well area and grid area max_drawdown (m), drawdown (m), drawdown_interference (m): well and aquifer drawdown during extraction total_head (m): total lift for the groundwater (depth to water plus drawdown) total_well_length (m): total depth of wells drilled well_yield (m³/day): pumping rate or well yield power (kW), energy (kWh): power and energy required for pumping groundwater Volume Outputs: volume_produced_perwell (m³), cumulative_vol_produced_perwell (m³): production volume metrics per well volume_produced_allwells (m³), cumulative_vol_produced_allwells (m³): aggregate extraction volumes for all wells in a grid cell available_volume (m³): available groundwater in storage for the grid cell as determined by aquifer properties depleted_vol_fraction: fraction of total volume pumped over available volumes in a grid cell (same as depletion limit) Cost Outputs: well_installation_cost ($): well installation cost based on the hydrogeological complexity of the aquifer annual_capital_cost, maintenance_cost, nonenergy_cost ($): nonenergy costs energy_cost_rate ($/kWh): electricity rate energy_cost ($): energy cost of pumping groundwater total_cost_perwell ($), total_cost_allwells ($): total annual energy and non-energy cost for each and all wells in a grid cell a unit_cost ($/m³), unit_cost_per_km3 ($/km³), unit_cost_per_acreft ($/acre-ft): total cost of pumping a unit of groundwater, indicated for different spatial units Key Resources Model documentation: Niazi, H., Ferencz, S., Graham, N., Yoon, J., Wild, T., Hejazi, M., Watson, D., & Vernon, C. (2024; In-prep). Long-term Hydro-economic Assessment Tool for Evaluating Global Groundwater Cost and Supply: Superwell v1. Geoscientific Model Development. Input data: Niazi, H., Watson, D., Hejazi, M., Yonkofski, C., Ferencz, S., Vernon, C., Graham, N., Wild, T., & Yoon, J. (2024). Global Geo-processed Data of Aquifer Properties by 0.5° Grid, Country and Water Basins. MSD-LIVE Data repository. https://doi.org/10.57931/2307831 superwell source code: https://github.com/JGCRI/superwell Cite as Niazi, H., Ferencz, S., Yoon, J., Graham, N., Wild, T., Hejazi, M., Watson, D., & Vernon, C. (2024). Globally Gridded Groundwater Extraction Volumes and Costs under Six Depletion and Ponded Depth Targets. MSD-LIVE Data repository. https://doi.org/10.57931/2307832 Contact Reach out to Hassan Niazi or Stephen Ferencz or open an issue in the superwell repository for questions or suggestions.

Earth Systems↗
DOE OSTI2017

Solving geosteering inverse problems by stochastic Hybrid Monte Carlo method

The inverse problems arise in almost all fields of science where the real-world parameters are extracted from a set of measured data. The geosteering inversion plays an essential role in the accurate prediction of oncoming strata as well as a reliable guidance to adjust the borehole position on the fly to reach one or more geological targets. This mathematical treatment is not easy to solve, which requires finding an optimum solution among a large solution space, especially when the problem is non-linear and non-convex. Nowadays, a new generation of logging-while-drilling (LWD) tools has emerged on the market. The so-called azimuthal resistivity LWD tools have azimuthal sensitivity and a large depth of investigation. Hence, the associated inverse problems become much more difficult since the earth model to be inverted will have more detailed structures. The conventional deterministic methods are incapable to solve such a complicated inverse problem, where they suffer from the local minimum trap. Alternatively, stochastic optimizations are in general better at finding global optimal solutions and handling uncertainty quantification. In this article, we investigate the Hybrid Monte Carlo (HMC) based statistical inversion approach and suggest that HMC based inference is more efficient in dealing with the increased complexity and uncertainty faced by the geosteering problems.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2025

Roughrider Carbon Storage Hub (Final Report)

The Roughrider Carbon Storage Hub was a 2-year project (October 2023 – September 2025) conducted by the Energy & Environmental Research Center (EERC) focused on advancing the feasibility of a commercial-scale carbon dioxide (CO 2 ) geologic storage hub in McKenzie County, North Dakota. The project’s objective was to investigate the potential that stacked storage complexes (multiple deep saline formations) can safely and economically store at least 50 million tonnes of CO 2 within 30 years. The captured CO 2 would be sourced from industrial emitters including project partner ONEOK, Inc.’s gas-processing plants and a planned gas-to-liquids facility. Drilling of the Roughrider 1 stratigraphic test well (14,979-ft total depth) was completed in November 2024. The wellbore intersected four candidate storage formations: Inyan Kara, Broom Creek, Mission Canyon, and Black Island–Deadwood. Operational challenges, including a stuck drill string, were resolved without long-term impact. A comprehensive logging and coring program was conducted, followed by successful well abandonment and site reclamation. Over 660 ft of 4-in. whole core was retrieved. Core plug samples were processed and analyzed for petrophysical and geochemical properties. Results confirmed promising porosity and permeability in the Inyan Kara and Broom Creek Formations and removal of the Mission Canyon and Black Island–Deadwood horizons from further investigation. Data derived from the logging and coring program were used to improve initial geologic models built from legacy data. CO 2 injection simulations showed that the Inyan Kara alone can feasibly store the target mass of CO 2 . Because of subtle differences in geologic structure and porosity trends between the formations, a stacked storage scenario using the Broom Creek and Inyan Kara Formations resulted in a larger overall plume area than using the Inyan Kara alone. Preliminary CO 2 pipeline routes from the industrial sources were mapped utilizing existing rights of way and evaluated for capacity and cost using U.S. Department of Energy Office of Fossil Energy and Carbon Management/National Energy Technology Laboratory models and U.S. Environmental Protection Agency emissions data. Integrating capture, transport, and storage cost estimates with policy incentives (e.g., 45Q credits) provided a total cost-per-ton analysis. Results indicate that the small scale of the volumes to be transported over the cumulative large distances does not support the project’s financial viability. However, the groundwork laid during this project from geological, regulatory, and social perspectives positions the Roughrider hub site as a promising candidate for commercial carbon storage in North Dakota, especially if the economy of scale is introduced for CO 2 transportation to the hub site.

01 COAL, LIGNITE, AND PEAT↗
NASA NTRS2013

Preparation of a Frozen Regolith Simulant Bed for ISRU Component Testing in a Vacuum Chamber

In-Situ Resource Utilization (ISRU) systems and components have undergone extensive laboratory and field tests to expose hardware to relevant soil environments. The next step is to combine these soil environments with relevant pressure and temperature conditions. Previous testing has demonstrated how to incorporate large bins of unconsolidated lunar regolith into sufficiently sized vacuum chambers. In order to create appropriate depth dependent soil characteristics that are needed to test drilling operations for the lunar surface, the regolith simulant bed must by properly compacted and frozen. While small cryogenic simulant beds have been created for laboratory tests, this scale effort will allow testing of a full 1m drill which has been developed for a potential lunar prospector mission. Compacted bulk densities were measured at various moisture contents for GRC-3 and Chenobi regolith simulants. Vibrational compaction methods were compared with the previously used hammer compaction, or "Proctor", method. All testing was done per ASTM standard methods. A full 6.13 m3 simulant bed with 6 percent moisture by weight was prepared, compacted in layers, and frozen in a commercial freezer. Temperature and desiccation data was collected to determine logistics for preparation and transport of the simulant bed for thermal vacuum testing. Once in the vacuum facility, the simulant bed will be cryogenically frozen with liquid nitrogen. These cryogenic vacuum tests are underway, but results will not be included in this manuscript.

Klenhenz, Julie↗
NASA NTRS2014

The Investigation of Chlorates as a Possible Source of Oxygen and Chlorine Detected by the Sample Analysis at Mars (SAM) Instrument in Gale Crater, Mars

The Sample Analysis at Mars (SAM) instrument onboard the Curiosity rover detect-ed O2 and HCl gas releases from the Rocknest (RN) eolian bedform and the John Klein (JK) and Cumberland (CB) drill hole materials in Gale Crater. Chlorinated hydrocarbons have also been detected by the SAM quadrupole mass spectrometer (QMS) and gas chromatography/mass spectrometer (GCMS). These detections along with the detection of perchlorate (ClO4-) by the Mars Phoenix Lander’s Wet Chemistry Laboratory (WCL) suggesting perchlorate is a possible candidate for evolved O2 and chlorine species. Laboratory thermal analysis of perchlorates has yet to provide an unequivocal temperature match to the SAM O2 and HCl release data. Iron mineralogy found in the Rocknest materials when mixed with Ca-perchlorate does cause O2 release temperatures to be closer match to the SAM O2 release data but more work is required in evaluating the catalytic effects of Fe mineralogy on perchlorate decomposition. Chlorates (ClO3-) are relevant Mars materials and potential O2 and Cl sources. The objective of this work is to evaluate the thermal decomposition of select chlorate (ClO3-) salts as possible sources of the O2 and HCl releases in the Gale Crater materials.

Sutter, B.↗
NASA NTRSDate not supplied

Investigating Buried Ice at Askja Volcano, Northern Iceland using Ground Penetrating Radar: A Planetary Analog Perspective

Shallow subsurface ice deposits on Mars and the Moon have been identified as potential targets for in situ resource utilization by future crewed missions to the surfaces of these bodies. On Mars, such deposits have been identified through a variety of orbital measurements at the poles, mid-latitudes, and even preserved by volcanic ash near the Tharsis Montes. At some locations, massive ice deposits have been documented to be 100 m in thickness at depths as shallow as 1 m. On the Moon, the presence of thick, massive ice has not been confirmed; however, orbital observations indicate that the upper 1-2 m of regolith may contain a few weight percent in thermally favorable locations. Eruptions of the Askja Volcano in March, 1875 and November, 1961 deposited abundant pyroclasts, which blanketed and insulated fresh snowfall that later densified into massive ice and is preserved today. The pyroclasts consist of a buff colored pumice from the eruption in 1875 and basaltic lapilli and ash from the eruption in 1961. The largely unvegetated, unconsolidated nature of the pyroclasts and their stratigraphic relationships with shallow subsurface ice make them potentially analogous to some ice deposits within regolith and pyroclasts at the Moon and Mars. Ground penetrating radar(GPR) can be used by future human or robotic missions to identify water ice similarly preserved in the shallow subsurface of these bodies. Our team conducted over 66 GPR surveys inside and surrounding the Askja caldera in August 2019 at 200 and 400 MHz to map both the volcanic deposits and the subsurface ice deposits. We also used a hammer drill augur to take boreholes in order to confirm subsurface stratigraphy and the presence of ice down to 1-1.5 m and aerial surveys using a Mavic 2 Pro quadcopter at each site for additional context. We observed shallow ice deposits within pore spaces of the pyroclasts at depths of ~15-30 cm and pure ice deposits at varying depths (0.6-1 m) as thick as 2-3 m. We also plan to use the data to characterize the frequency-dependent attenuation of the radar signal as it travels through volcanoclastic material and ice in the subsurface. Our investigation of Askja as a planetary analog will provide insight into analytical methods that can be used to investigate subsurface water ice from surface operations at other terrestrial bodies.

Geophysics↗
DOE OSTI2022

Risk matrix for legacy wells within the Area of Review (AoR) of Carbon Capture & Storage (CCS) projects

The success of CCS depends on the capacity, injectivity, and confinement by the storage medium. Thousands of wells drilled over the past century with the intention to find the trapped oil and gas may penetrate the containment seals. These wells may provide leakage pathways for the CO 2 to escape and contaminate the underground sources of drinking water (USDW) or reach the surface in the worst-case scenario. Identifying the risky wells penetrating the containment seals and predicting their current as well as future well integrity is the most challenging task when limited data is available. Here, this paper proposes a unique methodology for risk assessment of the wells penetrating the containment seals based on the proximity of these wells from the proposed injection location, mechanical integrity, and accessibility of these wells over the lifecycle of the CCS project. This helps in identifying the wells which need immediate attention from the wells that need little to no attention. It also highlights the corrective actions necessary for the success of the CCS project as well as help estimate the approximate cost required to perform the corrective actions. This methodology focuses on all wells (producers, injectors, orphan, abandoned, water, stratigraphic, etc) while the majority of the studies found in literature focused on wells with sustained casing pressure (SCP) reports and cement bond logs (CBL). The proposed risk matrix, if applied to future CCS projects across the globe, will uniformly categorize the wells within the Area of Review (AoR).

58 GEOSCIENCES↗
DOE OSTI2026

Oil in Alaska North Slope Gas Hydrate Reservoir: Micro-CT and Flow Simulation Insights into Permeability

Gas hydrate-bearing sands on the Alaska North Slope (ANS) host minor volumes of crude oil whose impact on formation permeability has never been quantified relative to a gas hydrate reservoir system. Here, we combine in situ pressure-core microcomputed-tomography (μ-CT), thermogravimetric analysis (TGA), gas-chromatography–mass-spectrometry (GC–MS), scanning-electron microscopy coupled with energy-dispersive spectroscopy (SEM-EDS), and Stokes-flow simulation to (i) quantify oil saturation, (ii) infer its source, and (iii) evaluate its influence on permeability after gas-hydrate dissociation. μ-CT and SEM-EDS imaging identify the host sediment as silty, with some grain-coating clay present. Eight representative 3003-voxel subvolumes extracted from a preserved pressure core (Core 15P-3c, from the B1 sand (unit B), HYDRATE 02 Geo Data Well (GDW), 886.96–887.29 m measured depth, MD) exhibit porosities of 0.34–0.37 and an average oil saturation of 0.09 ± 0.03, in comparison to an independent TGA-based estimate of 0.16. GC-MS fingerprints obtained from an adjacent depressurized core (Core 17P-1, 891.37–891.44 m MD), together with oil pore habit revealed by μ-CT, suggest that the oil is partly native but also includes contributions from mineral oil-based drilling fluid contamination. Further analysis of oil–porewater interactions and flushing tests confirms that native oil saturation in the analyzed samples ranges from 0.04 to 0.08 with an average of approximately 0.06, and the oil is highly immobile. Flow simulations demonstrate that the native oil saturation of ≈0.06 reduces permeability by approximately 50% due to both pore blockage and increased flow-path tortuosity. These findings reveal the potential presence of native oil within the ANS gas hydrate reservoir and suggest that future simulation models may need to account for its impact on permeability to improve long-term performance predictions of gas and water production.

02 PETROLEUM↗
DOE OSTI2019

Using geochemical indicators to distinguish high biogeochemical activity in floodplain soils and sediments, Science of the Total Environment: Dataset

Data associated with analysis of sediment samples collected in the East River watershed and Rifle floodplain sites, CO. Samples were collected and analyzed as part of two student MS theses at Colorado School of Mines (Kenwell and Prugue) over a time period ranging from 2012 to 2015. Analyses include total organic carbon, leachable Fe and Mn, and total microbial DNA; all analyses performed at Colorado School of Mines. Methods: Samples were collected from core during a drilling campaign at the Rifle Site. Samples were collected every 1.5 m. At the East River site soil and sediment samples were collected using hand-augered bulk density sampler. Collected samples were stored at -20C until analysis. Samples were thawed in an anaerobic chamber and subsampled for extractions and DNA analysis. Samples for DNA analysis were freeze-dried, the remaining sample was oven dried and ground to 0.991 cm for TOC and leaching analysis. TOC analysis was performed on duplicate samples using a CM 5014 Coulometer (UIC, Joliet, IL, USA). Two chemical extractions were performed: hydroxylamine (HA) extraction of Fe and Mn adapted from Lovley et al., 1987 and synthetic precipitation (ppt) leaching adapted from EPA method 1312 (EPA, 1994) . For theHA extraction 3g of wet sediment was mixed with 150 mL of 0.5 N HCl in one bottle and another 3 g of sediment was mixed with 150 mL of 0.25 N hydroxylamine hydrochloride in 0.5 N HCl. Extraction were performed for 24 hours at room temperature after which samples of the liquid were removed and filtered to 0.45 micron and analyzed by ICP-AES. HA-reducible iron and manganese concentrations were determined by difference between the two extractions. For ppt leaches, a 60:40 sulfuric:nitric acid mixture was added to Milliq water to a pH of 4.2 and combined with sediment in a 20:1 mass ratio of acid to sediment. The extraction was performed for 18 hours at room temperature after which the samples of the liquid were removed and filtered to 0.45 micron and analyzed by ICP-AES. DNA was sampled from sediment using a PowerSoil DNA Isolation Kit and extractions were performed according to manufactured instuctions with one adjustment, a 1 minute bead beating replaced the 10 minute vortexing step. Extracted DNA was stored at -20C. Quantitative PCR was performed in triplicate on a Roche LightCycler 480 system and working curves were created by amplifying environmental samples with primers and bead purifying them with Agencourt AMPure XP. Analysis was performed with a Qubit 2.0 Fluorometer and Qubit dsDNA High Sensitivity Assay Kit with results converted to copies using the URI Genomics and Sequencing Center converter (Staroscik, 2004). Additional method details can be found in Kenwell et al., 2016. Lovley, D.R., Phillips, E.J.P. (1987). Rapid assay for microbially reducible ferric iron in aquatic sediments. Applied and Environmental Microbiology, 53(7), 1536-1540. Staroscik, A. (2004). Calculator for determining the number of copies of a template. URI Genomics & Sequencing Center. <http://cels.uri.edu/gsc/cndna.html>. EPA. (1994). Method 1312: Synthetic precipitation leaching procedure.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

EGS Stimulation Design with Uncertainty Quantification at the EGS Collab Site

Engineering a robust hydraulic connection between wells is one of the most difficult aspects of enhanced geothermal systems (EGS). Designing and constructing such hydraulic connections requires and understanding of the in situ state of stress and the heterogeneities and discontinuities that naturally exist and may control the stimulation. Even with comprehensive stress and formation characterization programs substantial uncertainty remains in these key parameters. This is especially the case in high-temperature EGS environments where drilling conditions are often difficult and a far fewer logging and testing options are available. This paper presents a new approach for explicitly quantifying the uncertainties in the state of stress using a Bayesian Markov Chain Monte Carlo method. This approach produces a probability distribution for the stress tensor, including a general 3D orientation, that reflects the uncertainties in all the observations or indicators used to constrain the stress state. This method is demonstrated on the characterization data for the EGS Collab Experiment 2 site. The output of the analysis is used to guide the design of the planned stimulations. In the case of research projects like EGS Collab, explicitly quantifying the uncertainties in the stress state allow for more rigorous hypothesis testing by allowing conclusions drawn from the experiments to be interpreted in the context of the uncertain knowledge about conditions in the test bed.

Burghardt, Jeffrey A.↗
DOE OSTI2020

Micro- and nano-porosity of the active Alpine Fault zone, New Zealand

Porosity reduction in rocks from a fault core can cause elevated pore fluid pressures and consequently influence the recurrence time of earthquakes. We investigated the porosity distribution in the New Zealand's Alpine Fault core in samples recovered during the first phase of the Deep Fault Drilling Project (DFDP-1B) by using two-dimensional nanoscale and three-dimensional microscale imaging. Synchrotron X-ray microtomography-derived analyses of open pore spaces show total microscale porosities in the range of 0.1 %–0.24 %. These pores have mainly non-spherical, elongated, flat shapes and show subtle bipolar orientation. Scanning and transmission electron microscopy reveal the samples' microstructural organization, where nanoscale pores ornament grain boundaries of the gouge material, especially clay minerals. Our data imply that (i) the porosity of the fault core is very small and not connected; (ii) the distribution of clay minerals controls the shape and orientation of the associated pores; (iii) porosity was reduced due to pressure solution processes; and (iv) mineral precipitation in fluid-filled pores can affect the mechanical behavior of the Alpine Fault by decreasing the already critically low total porosity of the fault core, causing elevated pore fluid pressures and/or introducing weak mineral phases, and thus lowering the overall fault frictional strength. We conclude that the current state of very low porosity in the Alpine Fault core is likely to play a key role in the initiation of the next fault rupture.

58 GEOSCIENCES↗
NASA NTRS2015

The Investigation of Perchlorate/Iron Phase Mixtures as A Possible Source of Oxygen Detected by the Sample Analysis at Mars (SAM) Instrument in Gale Crater, Mars

The Sample Analysis at Mars (SAM) instrument onboard the Curiosity rover detected O2 and HCl gas releases from the Rocknest (RN) eolian bedform and the John Klein (JK) and Cumberland (CB) drill hole materials in Gale Crater. Chlorinated hydrocarbons have also been detected by the SAM quadrupole mass spectrometer (QMS) and gas chromatography/mass spectrometer (GCMS). These detections along with the detection of perchlorate (ClO4-) by the Mars Phoenix Lander's Wet Chemistry Laboratory (WCL) suggesting perchlorate is a possible candidate for evolved O2 and chlorine species. Laboratory thermal analysis of individual per-chlorates has yet to provide an unequivocal temperature match to the SAM O2 and HCl release data. These detections along with the detection of perchlorate (ClO4-) by the Mars Phoenix Lander's Wet Chemistry Laboratory suggested perchlorate is a possible candidate for evolved O2 and chlorine species. Laboratory thermal analysis of pure perchlorates has yet to provide an unequivocal temperature match to the SAM O2 and HCl release data. Analog laboratory analysis of iron mineralogy detected in Gale materials that was physically mixed with Ca- and Mg-perchlorate has been shown to catalyze lower O2 release temperatures and approach some SAM O2 release data. Instead of physical mixtures used in previous work, the work presented here utilized perchlorate solutions added to Fe phases. This technique allowed for perchlorate to come in closer contact with the Fe-phase and may more closely mimic Mars conditions where humidity can increase enough to cause deliquescence of the highly hygroscopic perchlorate phases. The objective of this work is to: 1) Utilize a laboratory SAM analog instrument to evaluate the O2 release temperatures from Mg- and Ca-perchlorates solutions applied to Fephases detetected in Gale Crate; and 2) Determine if perchlorate solutions can provide improved matches with the SAM O2 temperature release profiles.

Sutter, B.↗
DOE OSTI2017

GOM2: Prospecting, Drilling and Sampling Coarse-Grained Hydrate Reservoirs in the Deepwater Gulf of Mexico

The UT-GOM2-1 Hydrate Pressure Coring Expedition will drill two holes in Green Canyon Block 955 in the deepwater Gulf of Mexico to pressure core and wireline log a coarse-grained methane hydrate reservoir. We will take ten, 10 ft, pressure cores in each well. The cores will be imaged and logged under pressure. Samples will be degassed to interpret hydrate concentration. Microbiological and porewater analyses will be performed. 20 3 ft pressure cores will be returned to shore for analysis. The log and core data will provide a foundation for scientific exploration by the greater hydrate research community.

Flemings, Peter↗
DOE OSTI2016

There is Nothing Here for You: Passive Institutional Controls and Preemptive Resource Exploitation - 16197

The Department of Energy (DOE) Carlsbad Field Office (CBFO) is required by Title 40 CFR Part 191.14(c) and Title 40 CFR Part 194.43 to develop a Passive Institutional Controls (PICs) program to prevent the likelihood for future human intrusion into the Waste Isolation Pilot Plant (WIPP). The purpose of this paper is to explore how the exploitation of resources under nuclear waste repositories as a part of PICs could reduce the risk of future human intrusion. The WIPP, located in the northern Permian Basin near Carlsbad, New Mexico, is a geologic repository for the permanent isolation of defense-related transuranic waste. In 1995, a series of geophysical surveys by the New Mexico Bureau of Mines and Mineral Resources estimated the total hydrocarbon reserves underneath the WIPP, which included a 16-section area plus a one mile buffer. Since that time the Delaware Basin well database has been maintained to closely monitor hydrocarbon extraction activities. The database was used in compiling relevant oil and gas extraction data retrieved from The New Mexico Oil Conservation Division. The volume of hydrocarbons extracted from 1995 to the present suggests that if current extraction growth trends continue (as historic market and production data indicate they will), all known crude oil reserves under the WIPP, obtainable through current extraction technology, will be depleted within approximately 10 years, i.e., by 2026. This is well before the anticipated WIPP closure and start of the Active Institutional Controls (AICs) program called for in 40 CFR Part 194.41(b). In addition, gas resources, although more difficult to forecast, are not expected to last beyond 2137. Title 40 CFR 194.33 states, 'Inadvertent and intermittent intrusion by drilling for resources... is the most severe human intrusion scenario'. This human intrusion scenario is the feature, event, and process (FEP) that performance assessment (PA) has identified as having the most significant impact on radionuclide releases during the 10,000 year regulatory period for the WIPP. Title 40 CFR 194.43 requires a PICs program which contains '... [records] in the international archives that would likely be consulted by individuals in search of unexploited resources'. Due to political, social, and economic motivators for resource exploration and exploitation, the potential future absence of hydrocarbon resources under the WIPP is important in deterring possible human intrusion. To minimize the risk of future human intrusion, it may be necessary to consider actively removing as many of the exploitable hydrocarbon resources under and around a nuclear waste repository as is practicable before the end of the period of AICs (i.e., 100 years after closure of the repository). Additionally, communicating the absence of hydrocarbon resources under a nuclear repository should take a prominent role in any PICs program. Due to its high-cost nature, exploratory drilling of any kind currently involves cost/benefit analysis. If in the future the economic realities of resource exploration remain similar to today, and future oil companies know the resources for a particular area have already been heavily exploited, hypothetically, they would become less motivated to drill in that area. They would instead opt to explore an area with better prospects. It is important then that the remaining hydrocarbon reserves be clearly stated and prominently displayed. In essence we should communicate the message, loud and clear, 'There is nothing here for you'. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2014

FutureGen 2.0 Monitoring Program: An Overview of the Monitoring Approach and Technologies Selected for Implementation

The FutureGen 2.0 Project will design and build a first-of-its-kind, near-zero emissions coal-fueled power plant with carbon capture and storage (CCS). To assess storage site performance and meet the regulatory requirements of the Class VI Underground Injection Control (UIC) Program for CO2 Geologic Sequestration, the FutureGen 2.0 project will implement a suite of monitoring technologies designed to 1) evaluate CO2 mass balance and 2) detect any unforeseen loss in CO2 containment. The monitoring program will include direct monitoring of the injection stream and reservoir, and early-leak-detection monitoring directly above the primary confining zone. It will also implement an adaptive monitoring strategy whereby monitoring results are continually evaluated and the monitoring network is modified as required, including the option to drill additional wells in out-years. Wells will be monitored for changes in CO2 concentration and formation pressure, and other geochemical/isotopic signatures that provide indication of CO2 or brine leakage. Indirect geophysical monitoring technologies that were selected for implementation include passive seismic, integrated surface deformation, time-lapse gravity, and pulsed neutron capture logging. Near-surface monitoring approaches that have been initiated include surficial aquifer and surface- water monitoring, soil-gas monitoring, atmospheric monitoring, and hyperspectral data acquisition for assessment of vegetation conditions. Initially, only the collection of baseline data sets is planned; the need for additional near- surface monitoring will be continually evaluated throughout the design and operational phases of the project, and selected approaches may be reinstituted if conditions warrant. Given the current conceptual understanding of the subsurface environment, early and appreciable impacts to near-surface environments are not expected.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2015

Using Geothermal Play Types as an Analogue for Estimating Potential Resource Size

Blind geothermal systems are becoming increasingly common as more geothermal fields are developed. Geothermal development is known to have high risk in the early stages of a project development because reservoir characteristics are relatively unknown until wells are drilled. Play types (or occurrence models) categorize potential geothermal fields into groups based on geologic characteristics. To aid in lowering exploration risk, these groups' reservoir characteristics can be used as analogues in new site exploration. The play type schemes used in this paper were Moeck and Beardsmore play types (Moeck et al. 2014) and Brophy occurrence models (Brophy et al. 2011). Operating geothermal fields throughout the world were classified based on their associated play type, and then reservoir characteristics data were catalogued. The distributions of these characteristics were plotted in histograms to develop probability density functions for each individual characteristic. The probability density functions can be used as input analogues in Monte Carlo estimations of resource potential for similar play types in early exploration phases. A spreadsheet model was created to estimate resource potential in undeveloped fields. The user can choose to input their own values for each reservoir characteristic or choose to use the probability distribution functions provided from the selected play type. This paper also addresses the United States Geological Survey's 1978 and 2008 assessment of geothermal resources by comparing their estimated values to reported values from post-site development. Information from the collected data was used in the comparison for thirty developed sites in the United States. No significant trends or suggestions for methodologies could be made by the comparison.

15 GEOTHERMAL ENERGY↗
DOE OSTI2017

UT-GOM2-1 Hydrate Pressure Coring Expedition Prospectus

The UT-GOM2-1 Hydrate Pressure Coring Expedition will drill two holes in Green Canyon Block 955 in the deepwater Gulf of Mexico to pressure core and wireline log a coarse-grained methane hydrate reservoir. We will take ten, 10 ft, pressure cores in each well. The cores will be imaged and logged under pressure. Samples will be degassed to interpret hydrate concentration. Microbiological and pore water analyses will be performed. 20 3 ft pressure cores will be returned to shore for analysis. The log and core data will provide a foundation for scientific exploration by the greater hydrate research community

03 NATURAL GAS↗