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At least 865 records · Page 48

Microkinetic Modeling of the Transient CO 2 Methanation with DFT–Based Uncertainties in a Berty Reactor

The transient operation of methanation reactors can become desirable when coupled with fluctuating renewable energies in Power-to-Gas scenarios, which requires suitable kinetic approaches that can describe the transient catalytic phenomena. A combined experimental and theoretical investigation of the transient CO 2 methanation is conducted using concentration forcing to derive a suitable microkinetic model. Methanation experiments are performed with a Ni/SiO 2 catalyst in a Berty-type reactor at industrially relevant conditions. The microkinetics are based on previous work and were automatically constructed for the Ni(111) facet using the Reaction Mechanism Generator. A feasible set of energetic parameters of the microkinetic models was identified in a theory-constrained optimization procedure within the DFT uncertainty space that can accurately reproduce the experimental results on a first-principles basis. The microkinetic model unravels that the formation of H 2 O* and CH 3 * control the activity and selectivity of Ni(111) under the investigated conditions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

TrkA undergoes a tetramer-to-dimer conversion to open TrkH which enables changes in membrane potential

TrkH is a bacterial ion channel implicated in K + uptake and pH regulation. TrkH assembles with its regulatory protein, TrkA, which closes the channel when bound to ADP and opens it when bound to ATP. However, it is unknown how nucleotides control the gating of TrkH through TrkA. Here we report the structures of the TrkH-TrkA complex in the presence of ADP or ATP. TrkA forms a tetrameric ring when bound to ADP and constrains TrkH to a closed conformation. The TrkA ring splits into two TrkA dimers in the presence of ATP and releases the constraints on TrkH, resulting in an open channel conformation. Functional studies show that both the tetramer-to-dimer conversion of TrkA and the loss of constraints on TrkH are required for channel gating. In addition, deletion of TrkA in Escherichia coli depolarizes the cell, suggesting that the TrkH-TrkA complex couples changes in intracellular nucleotides to membrane potential.

36 MATERIALS SCIENCE↗

Effects of the dynamical magnetization state on spin transfer

We utilize simulations of electron scattering by a chain of dynamical quantum spins to analyze the interplay between the spin transfer effect and the magnetization dynamics.We show that the complex interactions between the spin-polarized electrons and the dynamical states of the local spins can be decomposed into separate processes involving electron reflection and transmission, as well as absorption and emission of magnons—the quanta of magnetization dynamics. Analysis shows that these processes are substantially constrained by the energy and momentum conservation laws, resulting in a significant dependence of spin transfer on the electron’s energy and the dynamical state of the local spins. Here, our results suggest that exquisite control of spin transfer efficiency and of the resulting dynamical magnetization states may be achievable by tailoring the spectral characteristics of the conduction electrons and of the magnetic systems.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Characterization of micro-sandwich structures via direct ink writing epoxy based cores

Sandwich structured (SS) composites demonstrate considerable flexural stiffness and high strength-to-weight ratios and can be tailored as functional materials. Historically they have been constrained to specific material types and geometry due to limitations in manufacturing methods. However, employing additive manufacturing (AM), specifically direct ink writing (DIW), can provide an alternative method for making SS composites with complex and controllable micro and mesostructures with multifunctionality targeted at desired mechanical, thermal, and electrical properties. DIW, an extrusion-based AM technique, uses a viscous and thixotropic ink with desired components that, once printed, is cured to obtain the final complex net shape parts. In this paper, a novel hybrid AM technique is employed to manufacture SS composite materials containing bisphenol A-based epoxy core and carbon fiber reinforced polymer (CFRP) face sheets that are fabricated via DIW and vacuum infusion process (VIP), respectfully. We demonstrate that the fabrication of these SS composites can be tailored from a thermosetting material, from which additives and/or various lattice structures can be manufactured to achieve enhanced and desirable mechanical integrity with functional properties. Surface topology and mechanical testing techniques are used to characterize the fabricated hybrid SS composites to study and assess mechanical stability. A rheo-kinetic cure model was developed for the core material to allow for additive manufacturing process requirements while ensuring complete cross-linking for the thermoset-based core material. Because of the ability to obtain relatively small core-thickness and controlled architecture, this method now allows for fabricating layered micro-sandwich structures for realizing further light-weighting in relevant applications.

36 MATERIALS SCIENCE↗

Nimbus D RMP program

The development of an advanced long life rate measuring package, designed for a five year useful life as a meteorological satellite control sensor is discussed. The primary function of the rate mesuring package is to provide rate information for the reaction wheel and gas jet torquing devices that are used to damp spacecraft oscillations and to constrain the spacecraft to the required attitude with respect to the orbital plane. The specifications for the rate measuring package sensor are described. Application of the rate measuring package to the Nimbus D satellite is proposed.

Source record↗

A preliminary study of the attitude control for the Shuttle Tethered Satellite System

The objective of this investigation is to determine the equations of motion governing the attitude of a tethered satellite and subsequently to gain insight toward obtaining an appropriate control law. This study relates the coupling of the rotational dynamics of the satellite with the dynamical system of the Orbiter already constructed. In particular, a simplified approach is utilized to describe the satellite as constrained to planar motion. Modifications to the existing tethered satellite trajectory simulation provide a conceptual study of the satellite's behavior and its effect on the overall system.

Rupp, C. C.↗

Coupling the Solar-Wind/IMF to the Ionosphere through the High Latitude Cusps

Magnetic merging is a primary means for coupling energy from the solar wind into the magnetosphere-ionosphere system. The location and nature of the process remain as open questions. By correlating measurements form diverse locations and using large-scale MHD models to put the measurements in context, it is possible to constrain out interpretations of the global and meso-scale dynamics of magnetic merging. Recent evidence demonstrates that merging often occurs at high latitudes in the vicinity of the cusps. The location is in part controlled by the clock angle in the interplanetary magnetic field (IMF) Y-Z plane. In fact, B(sub Y) bifurcated the cusp relative to source regions. The newly opened field lines may couple to the ionosphere at MLT locations of as much as 3 hr away from local noon. On the other side of noon the cusp may be connected to merging sites in the opposite hemisphere. In face, the small convection cell is generally driven by opposite hemisphere merging. B(sub X) controls the timing of the interaction and merging sites in each hemisphere, which may respond to planar features in the IMF at different times. Correlation times are variable and are controlled by the dynamics of the tilt of the interplanetary electric field phase plane. The orientation of the phase plane may change significantly on time scales of tens of minutes. Merging is temporally variable and may be occurring at multiple sites simultaneously. Accelerated electrons from the merging process excite optical signatures at the foot of the newly opened field lines. All-sky photometer observations of 557.7 nm emissions in the cusp region provide a "television picture" of the merging process and may be used to infer the temporal and spatial variability of merging, tied to variations in the IMF.

Maynard, Nelson C.↗

A UNIQUE APPROACH TO ACHIEVING SIZE-CONSTRAINED QUASI-HALO ORBITS FOR THE ROMAN SPACE TELESCOPE

The Nancy Grace Roman Space Telescope (RST) is an infrared space observatory planned for launch in the mid-2020’s. The launch window design for RST is subject to a wide variety of simultaneous requirements that require careful consideration and control of mission orbits and the trajectories used to achieve them. This work describes an innovative methodology that blends classical methods with modern manifold approaches and numerical optimization to flexibly determine optimal transfers to desriable mission orbits for any day of the year.Solutions found with this highly automated strategy are gaurunteed to meet requirements by construction. Results show that RST can launch for 80% of the year using maneuvers that are well within the fuel budget, significantly reducing cost and risk to the mission

Lauren Schlenker↗

Datascope to Enable Earth Independent Medical Operations (EIMO)

BACKGROUND: NASA has amassed sixty years of knowledge and experience relevant to maintenance of crew health and performance in low earth orbit. The Apollo Program introduced the importance of ensuring progressively autonomous operational capability. Earth Independent Medical Operations (EIMO) will require a gradual shift in the balance of medical responsibility, management, and authority from terrestrial to space-based assets. Terrestrial assets will continue to be essential for pre-mission screening and planning in addition to maintenance of crew health and performance. However, new capabilities are needed to enable EIMO and the amount of data required to support these systems, and mitigate the impacts of data transmission delays and reduced bandwidth coupled with lack of cloud-like resources and on-board computing capacity that is currently unclear or operationally insufficient. OVERVIEW: The overall goal of EIMO is to develop artificial intelligence (AI)-based solutions to analyze crew health and performance data utilizing a clinical decision support system (CDSS) to provide crew medical officers (CMO) with the equivalent of real-time, on-board medical consults. The EIMO ecosystem is envisioned as a “system of systems” where embedded reference databases and real-time data streams from multiple input vectors continuously and seamlessly assess crew health and performance. EIMO will be designed to make recommendations to the CMO using multi-modal AI-based natural language processing and machine learning methods with interoperability to push/pull data within and between multiple vehicle and habitat architectures. DISCUSSION: Data flows and storage/retrieval capacity are severely constrained during space missions and the challenges will become even greater during exploration missions. Just as each past program from Mercury to the International Space Station (ISS) required rethinking the interaction between ground-based controllers and space-based crew, so too will future missions to the Moon and Mars. While the NASA High-Performance Spaceflight Computing Processor project aims to increase computational capacity by 100 times over current spaceflight computers, the projected deliverable still lags considerably behind what will be needed to enable an AI-driven CDSS. Restrictions in processing speed and data storage capacity, coupled with transmission bottlenecks and delays, necessitate definition and optimization of an integrated data architecture to enable a progressively autonomous medical capability.

Medical operations↗

Utilizing Gaps and Performance Measures to Inform NASA Environmental Control and Life Support Systems and Crew Health and Performance Technology Decisions

Human spaceflight is a complex endeavor requiring multiple capabilities for transportation, crew health, scientific goals, and safe return to Earth. The difference between spaceflight proven capabilities and those needed for future exploration architectures is defined as a capability gap. Capability gaps are not technology specific. Each capability gap may be closed with a wide array of technologies that have unique benefits and challenges. Determining what a capability’s relevant and distinguishing key performance parameters (KPPs) are for a mission is critical. Mass, power, and volume are always constrained and important, but defining these in a way normalized by performance is very important. KPP definition for reliability, dormancy, and integration needs are hard to define but critical. Outside of technical considerations, the programmatic factors of the estimated time to develop the technology and how the technology validation objectives are matured are strong considerations in which technologies should be pursued and how they should leverage earlier mission elements. The Environmental Control and Life Support (ECLSS) and Crew Health and Performance (CHP) capability areas are decomposed to high level gaps. While KPPs should be technology agnostic, they can be used to both compare technologies and measure progress of technology development over time. KPPs help define when the gap is closed, and the core mission objectives can be accomplished. Proposed technology improvements to enhance a capability should balance improved KPPs and against investments in other capabilities that are not yet closed. A selection of gaps, KPPs, and validation objectives and their formulation, current state, and how they inform capability roadmap planning are discussed.

Life Support↗

Control-structure-thermal interactions in analysis of lunar telescopes

The lunar telescope project was an excellent model for the CSTI study because a telescope is a very sensitive instrument, and thermal expansion or mechanical vibration of the mirror assemblies will rapidly degrade the resolution of the device. Consequently, the interactions are strongly coupled. The lunar surface experiences very large temperature variations that range from approximately -180 C to over 100 C. Although the optical assemblies of the telescopes will be well insulated, the temperature of the mirrors will inevitably fluctuate in a similar cycle, but of much smaller magnitude. In order to obtain images of high quality and clarity, allowable thermal deformations of any point on a mirror must be less than 1 micron. Initial estimates indicate that this corresponds to a temperature variation of much less than 1 deg through the thickness of the mirror. Therefore, a lunar telescope design will most probably include active thermal control, a means of controlling the shape of the mirrors, or a combination of both systems. Historically, the design of a complex vehicle was primarily a sequential process in which the basic structure was defined without concurrent detailed analyses or other subsystems. The basic configuration was then passed to the different teams responsible for each subsystem, and their task was to produce a workable solution without requiring major alterations to any principal components or subsystems. Consequently, the final design of the vehicle was not always the most efficient, owing to the fact that each subsystem design was partially constrained by the previous work. This procedure was necessary at the time because the analysis process was extremely time-consuming and had to be started over with each significant alteration of the vehicle. With recent advances in the power and capacity of small computers, and the parallel development of powerful software in structural, thermal, and control system analysis, it is now possible to produce very detailed analyses of intermediate designs in a much shorter period of time. The subsystems can thus be designed concurrently, and alterations in the overall design can be quickly adopted into each analysis; the design becomes an iterative process in which it is much easier to experiment with new ideas, configurations, and components. Concurrent engineering has the potential to produce efficient, highly capable designs because the effect of one subystem on another can be assessed in much more detail at a very early point in the program. The research program consisted of several tasks: scale a prototype telescope assembly to a 1 m aperture, develop a model of the telescope assembly by using finite element (FEM) codes that are available on site, determine structural deflections of the mirror surfaces due to the temperature variations, develop a prototype control system to maintain the proper shape of the optical elements, and most important of all, demonstrate the concurrent engineering approach with this example. In addition, the software used for the finite element models and thermal analysis was relatively new within the Program Development Office and had yet to be applied to systems this large or complex; understanding the software and modifying it for use with this project was also required. The I-DEAS software by Structural Dynamics Research Corporation (SDRC) was used to build the finite element models, and TMG developed by Maya Heat Transfer Technologies, Ltd. (which runs as an I-DEAS module) was used for the thermal model calculations. All control system development was accomplished with MATRIX(sub X) by Integrated Systems, Inc.

Thompson, Roger C.↗

Utilizing Gaps and Performance Measures to Inform NASA Environmental Control and Life Support Systems and Human Health and Performance Capability Technology Decisions

Human spaceflight is a complex endeavor requiring multiple capabilities for transportation, crew health, scientific goals, and safe return to Earth. The difference between spaceflight proven capabilities and those needed for future exploration architectures is defined as a capability gap. Capability gaps are not technology specific. Each capability gap may be closed with a wide array of technologies that have unique benefits and challenges. Determining what a capability’s relevant and distinguishing key performance parameters (KPPs) are for a mission is critical. Mass, power, and volume are always constrained and important, but defining these in a way normalized by performance is very important. KPP definition for reliability, dormancy, and integration needs are hard to define but critical. Outside of technical considerations, the programmatic factors of the estimated time to develop the technology and how the technology validation objectives are matured are strong considerations in which technologies should be pursued and how they should leverage earlier mission elements. The Environmental Control and Life Support (ECLSS) and Crew Health and Performance (CHP) capability areas are decomposed to high level gaps. While KPPs should be technology agnostic, they can be used to both compare technologies and measure progress of technology development over time. KPPs help define when the gap is closed, and the core mission objectives can be accomplished. Proposed technology improvements to enhance a capability should balance improved KPPs and against investments in other capabilities that are not yet closed. A selection of gaps, KPPs, and validation objectives and their formulation, current state, and how they inform capability roadmap planning are discussed.

Life Support↗

Constrained optimization of image restoration filters.

A preprocessing method to correct for image degradation is proposed which can be thought of as a generalization and extension of previous work by Smith (1966) and Stuller (1972). This method accomodates the problem of noncircularly symmetric imaging system point-spread functions, provides for controlled extent of the preprocessing filter to minimize distortion due to transients resulting from truncation errors and edge effects, can be used with various kinds of system noise, and can be readily extended to provide constraint of other system parameters. The analysis relates to a line-scanner system, although it is applicable in principle to many other system configurations.

Riemer, T. E.↗

Crystalline Peptoid Nanofibers with a Single-Unit Cell Cross Section

Ultranarrow crystalline one-dimensional nanostructures formed from soft materials facilitate precise structural control in nanomaterial design, which is essential for biomedicine and nanotechnology applications. Systematic control of their hierarchical structure is challenging due to the complexities of simultaneously manipulating multiple noncovalent interactions at such small scales. We employed a polypeptoid crystal motif as a supramolecular synthon to engineer ultranarrow crystalline nanofibers constrained to a single lattice axis by incorporating a single ionizable side chain into the hydrophobic core of a nanosheet-forming peptoid. Cryogenic transmission electron microscopy of the nanofibers revealed detailed molecular arrangements of a unit-cell cross-section and the presence of distinct pH-dependent lattice isoforms that resulted in morphological transformations. Molecular dynamics simulations demonstrated that the ionizable side chain plays a critical role in changing the local conformation of the unit cell, which further impacts the dimensionality of hierarchical structures. Moreover, these fibers were readily functionalized with biological ligands to afford one-dimensional (1D) protein arrays. This approach for the high-precision bottom-up assembly of ultranarrow 1D nanostructures offers significant potential for developing novel biomimetic nanostructures.

Lee, Yen Jea↗

Exploring Western North Pacific Tropical Cyclone Activity in the High‐Resolution Community Atmosphere Model

Abstract High‐resolution climate models (∼28 km grid spacing) can permit realistic simulations of tropical cyclones (TCs), thus enabling their investigation in relation to the climate system. On the global scale, previous works have demonstrated that the Community Atmosphere Model (CAM) version 5 presents a reasonable TC climatology under prescribed present‐day (1980–2005) forcing. However, for the Western North Pacific (WNP) region, known biases in simulated TC genesis frequency and location under‐represent the basin's dominant share in observations. This study addresses these model biases in WNP by evaluating WNP TCs in a decadal simulation, and exploring potential improvements through nudging experiments. Among the major environmental controls of TC genesis, the lack of mid‐level moisture is identified as the leading cause of the deficit in simulated WNP TC genesis over the Pacific Warm Pool. Subsequent seasonal experiments explore the effect of constraining the large‐scale environment on TC development by nudging WNP temperature field toward reanalysis at various strengths. Temperature nudging elicits a significant response in TC genesis and intensity development, as well as in moisture and convection over the Warm Pool. These responses are sensitive to the choice of nudging timescale. Overall, the nudging experiments demonstrate that improvements in the large‐scale environment can lead to improvements in simulated TCs, suggesting future model developments in relation to model physics. In this way, the potential improvements in model fidelity will contribute to the understanding of how the mean state of current or future climates may give rise to extremes such as TCs.

58 GEOSCIENCES↗

The Cutplane - A tool for interactive solid modeling

A geometric modeling system which incorporates a new concept for intuitively and unambiguously specifying and manipulating points or features in three dimensional space is presented. The central concept, the Cutplane, consists of a plane that moves through space under control of a mouse or similar input device. The intersection of the plane and any object is highlighted, and only this highlighted section can be selected for manipulation. Selection is accomplished with a crosshair that is constrained to remain within the plane, so that the relationship between the crosshair and the feature of interest is immediately evident. Although the idea of a section view is not new, previously it has been used as a way to reveal hidden structure, not as a means of manipulating objects or indicating spatial position, as is proposed here.

Edwards, Laurence↗

Geometrically constrained observability

This paper deals with observed processes in situations in which observations are available only when the state vector lies in certain regions. For linear autonomous observed processes, necessary and sufficient conditions are obtained for half-space observation regions. These results are shown to contain a theorem dual to a controllability result proved by the author for a linear autonomous control system whose control restraint set does not contain the origin as an interior point. Observability results relating to continuous observation systems and sampled data systems are presented, and an example of observing the state of an electrical network is given.

Brammer, R. F.↗

Mars 2020 Entry, Descent, and Landing Software Implementation

On February 18th, 2021, the Mars 2020 project's Perseverance Rover successfully touched down on the Martian surface after nearly eight years of development. The Mars 2020 Entry, Descent, and Landing (EDL) System largely leveraged heritage from the Mars Science Laboratory (MSL) EDL System while employing targeted technological advancements. The landing process is autonomously directed by a software behavior implemented in the rover's primary flight computer called the EDL Timeline that assumes control of the vehicle six days before atmospheric entry. In addition to performing the critical function of landing the rover on the Martian surface, the EDL timeline behavior must co-exist in a non-partitioned software and system environment with other high-level functions that accomplish the goals for the rest of the mission. Due to the criticality of EDL, the potential for loss of mission, and a need for complete system autonomy, the standard for how the EDL Timeline interacts with other functions in the system is highly constrained. This paper first walks through the basics of the EDL Timeline mechanics and how the behavior is designed to account for internal system variations and environmental unknowns. It then summarizes the interactions between the EDL timeline and other high-level system behaviors like spacecraft mode transitions and system fault protection, focusing on the complications that arise when passing spacecraft control between executive functions. Although the MSL-inherited EDL System is reliable and capable, targeted updates and a thorough verification and validation program were required for Mars 2020. This paper discusses changes made to close vulnerabilities discovered during both MSL and Mars 2020 development cycles, landing system capability enhancements that were enabling for Mars 2020's mission, and how these updates were integrated with the heritage system. It then describes how both analysis and testing campaigns were utilized to verify and validate all aspects of EDL and system behaviors that run during the six days before landing, as well as the operational workarounds that were needed to address problems found during the development and commissioning process. Finally, this paper imparts lessons learned from Mars 2020 EDL development, implementation, and operations, emphasizing how systems designed to conduct time-critical mission events with low margin of error can be improved in the future.

Stehura, Aaron↗