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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 865 records · Page 48
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Impacts of Increasing Electrification on State Fleet Operations and Charging Demand

State fleets represent an enticing opportunity to explore the near-term feasibility of fleet electrification. In many instances, state fleet operations encompass a wide geographic area with fleet locations for many vehicles. Serving these wide areas will require a significant amount of energy and, in the case of electric vehicles (EVs), a significant level of charging power. The peak demand as a result of this charging demand is of interest for fleets, with impacts on both utility bills and installation costs ranking among some of the greatest concerns. The combination of a wide operational area and multiple fleet locations positions state fleets as ideal candidates to understand the impacts of vehicle charging on fleet operations. As the availability of electric drivetrains expands beyond light-duty sedans, fleets need to understand when it will be appropriate operationally and financially to start adding electric drivetrains to their fleets. Throughout this process, it will also be important to understand the charging implications of fleet electrification and the resulting impacts to facility electrical systems. To better understand these considerations, NREL contracted Sawatch Labs to analyze the role that increasing state fleet electrification may have on the charging demand at fleet parking facilities.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2024

Spacecraft surface charging as a function of material properties

Spacecraft material behavior plays a very important role in space missions. Spacecraft immersed in plasma get charged by absorbing plasma particles and by emitting electrons from spacecraft surfaces via photoelectron and secondary electron emission. Spacecraft charging depends heavily on material properties such as work function, secondary electron yield, dielectric constant, and electric conductivity among other. Material properties are typically assumed to be static in charging models. However, it is well known that this is not the case in space. This makes spacecraft charging predictions very challenging. Material properties are well characterized before the spacecraft is put in orbit through characterization in the lab under clean conditions. However, once in space, material properties change due to the harsh and very dynamic space environment. We present a new capability to predict material behavior in space from first-principles modeling. The ongoing effort seeks to couple material models, density functional theory (DFT) and molecular dynamic (MD) codes, with environment models, plasma kinetic codes. This preliminary study will show results of surface charging as a function of material work function, dielectric constant, and conductivity.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Solar Power + Electric Vehicle Charging: Capturing Synergies in Minnesota

Despite the state policy support, significant market barriers to decarbonization of transportation remain. Analysis conducted by the National Renewable Energy Laboratory (NREL) and others confirm that without routine access to charging infrastructure, both at home and in non-residential locations, bullish market forecasts are unlikely to materialize. Similarly, the expansion of EV charging and variable renewable energy deployment each have potentially disruptive and costly effects on the distribution grid. Finally, electrification of passenger vehicles is not enough to decarbonize transportation without pathways to carbon-free electrification, linking EV charging and clean energy generation. This document examines the opportunity to jointly deploy solar energy and EV charging infrastructure to capture synergistic value, mitigate for risks associated with integrating and scaling both solar and EV charging, and accelerate their mutual deployment.

14 SOLAR ENERGY↗
DOE OSTI2026

The Evolving Role of Demand Charges in Retail Electricity Rates

Retail electricity demand charges refer to a type of retail rate that is based on a metric of kilowatt (kW) demand rather than kilowatt-hour (kWh) energy usage. Demand charges are widely used in the commercial and industrial (C&I) electricity sectors to recover significant portions of utility revenue and are also used in residential rates in a modest but growing number of locations. This paper explores the historical context of and motivations for demand charges, describes their implementation and impacts in today's context, and uses a variety of opinions collected from relevant parties through semi-structured interviews to inform how demand charges align with four widely accepted rate design principles. This project is funded by the Department of Energy's Office of Electricity, which is interested in conducting research to understand the current state of affairs related to demand charges and how the future U.S. electricity grid will help to define retail rates.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2023

Effect of Si Content on Extreme Fast Charging Behavior in Silicon–Graphite Composite Anodes

Commercial Li-ion batteries typically incorporate a small amount of high-capacity silicon (Si)-based materials in the composite graphite-based anode to increase the energy density of the battery. However, very little is known about the effects of Si on the fast-charging behavior of composite anodes. Herein, we examine the effects of the Si/graphite ratio in the composite anode on the fast-charging behavior of full cells. We show that addition of Si increases the rate capability from 1C to 8C and improves the capacity retention in early cycles at 6C due to reduced overpotential in constant current charging cycles. The impacts of Si content on fast-charging aging were identified by Post-Test characterization. Despite realizing benefits of available capacity and reduced Li plating at 6C, silicon–electrolyte interactions lead the time-dependent cell performance to fade quickly in the long term. The Post-Test analysis also revealed the thickening of the electrode and nonuniform distribution of electrolyte decomposition products on the Si-containing anodes, as well as the organic-rich solid electrolyte interphase (SEI), which are the factors behind cell degradation. Our study sheds insight on the advantages and disadvantages of Si/graphite composite anodes when they are used in fast-charging applications and guides further research in the area by designing an optimized composition of Si incorporated in a mature graphite matrix.

25 ENERGY STORAGE↗
NASA NTRS1964

Effect of Initial Velocity on One-Dimensional, Ambipolar, Space-Charge Currents

Oppositely directed flows of positive and negative charges constitute an ambipolar current. A general case is analyzed in which the charges traverse the evacuated space between plane-parallel boundaries and all particles of a given charge species are monoenergetic. It is assumed that the charges may possess non-vanishing initial kinetic energy. This represents an extension of analyses by Langmuir and Muller-Lubeck for vanishing initial kinetic energy. Sample calculations of dimensionless current densities, electric and potential fields, and charge-density distributions are exhibited for cases where the electric field is assumed to vanish at one boundary but the species initial velocities may not. It is shown that resulting ion currents may be several times the Child's law limit if initial kinetic energies are of the order of the potential energy.

SPACE CHARGE↗
NASA NTRS2001

Impact of Charge Methodology upon the Performance of Lithium Ion Cells

This viewgraph gives an overview on the impact of charge methodology upon the performance of lithium ion cells. Charge characteristics are given on the following: (1) lithium ion prototype cells, including charge rate characteristics at different temperatures, the effect of charge methodology upon cycle life performance, the effect of charge voltage upon cell performance; (2) three-electrode cells; and (3) lithium-ion eight-cell batteries.

lithium ion cells↗
NASA NTRSDate not supplied

Solar Absorptivity Degradation of Spacecraft Materials Due to UV and Charged Particles in the Gateway Environment

The Gateway Passive Thermal Control System (PTCS) Group has identified charged particle and UV degradation of Gateway materials as a knowledge gap for the Near Rectilinear Halo Orbit (NRHO) and transit environment. Candidate materials and coatings were subjected to expected mission UV and charged particle environments at NASA Goddard Space Flight Center (GSFC). In situ change in reflectivity was observed at specified intervals during testing such that change in solar absorptivity could be plotted as a function of time of solar exposure. Gateway will be an outpost in cislunar space designed to survive a 15-year mission to support human moon landings and future deep space exploration. The Gateway Passive Thermal Control System (PTCS) Group has identified charged particle and UV degradation of potential Gateway materials as a knowledge gap for the Near Rectilinear Halo Orbit (NRHO) and transit environment, especially the slow spiral transit planned for the first two modules. Solar absorptivity degradation is important to quantify because the end-of-life absorptivity impacts thermal performance of the system. To address this, ground testing is being completed at NASA Goddard Space Flight Center in which potential Gateway materials, including radiators, multi-layer insulation (MLI), and structural materials are subjected to the expected transit plus 15-year on-orbit charged particle fluence (9.86x1015 protons/cm2 at 2.5 keV and 3.1x1016 electrons/cm2 at 10 keV) and up to 5000 Equivalent Solar Hours (ESH). Reflectivity of a single sample of each material was measured in atmosphere and in vacuum inside the chamber after exposure to incremental levels of ESH and charged particle fluence. Increase in absorptivity of most samples were seen throughout the test including large differences in absorptivity of materials of the same category. Future testing will validate these results and include additional materials of interest.

materials in the space environment↗
DOE OSTI2021

Grid Voltage Control Analysis for Heavy-Duty Electric Vehicle Charging Stations: Preprint

This paper presents an analysis of voltage control strategies for heavy duty electric vehicle (EV) charging stations. The performance of three voltage control approaches including power factor control, preset volt-var curve control, and customized volt-var curve control, have been investigated and evaluated for three different sizes of charging stations, including single-port small charging station, three-port middle size charging station, and 6-port travel center. The charging stations have been placed on various locations of four different types of distribution systems, to obtain a comprehensive performance analysis of the three voltage control approaches under different scenarios. To quantitively compare the performance of the three voltage control approaches, a series of metrics have been designed to quantify the performance and contribute to the comprehensive analysis summary.

47 OTHER INSTRUMENTATION↗
DOE OSTI2023

Disrupting EV Charging Sessions and Gaining Remote Code Execution with DoS, MITM, and Code Injection Exploits using OCPP 1.6

Open Charge Point Protocol (OCPP) 1.6 is widely used in the electric vehicle (EV) charging industry to communicate between Charging System Management Services (CSMSs) and Electric Vehicle Supply Equipment (EVSE). Unlike OCPP 2.0.1, OCPP 1.6 uses unencrypted websocket communications to exchange information between EVSE devices and an onpremise or cloud-based CSMS. In this work, we demonstrate two machine-in-the-middle (MITM) attacks on OCPP sessions to terminate charging sessions and gain root access to the EVSE equipment via remote code execution (RCE). Second, we demonstrate a malicious firmware update with a code injection payload to compromise an EVSE. Lastly, we demonstrate two methods to prevent availability of the EVSE or CSMS. One of these, originally reported by SaiFlow, prevents traffic to legitimate EVSE equipment using a DoS-like attack on CSMSs by repeatedly connecting and authenticating several CPs with the same identities as the legitimate CP. These vulnerabilities were demonstrated with proof-of-concept exploits in a virtualized Cyber Range at Wright State University and/or with a 350 kW Direct Current Fast Charger (DCFC) at Idaho National Laboratory. The team found that OCPP 1.6 could be protected from these attacks by adding secure shell (SSH) tunnels to the protocol, if upgrading to OCPP 2.0.1 was not an option. Index Terms—Electric vehicle charging, cybersecurity, OCPP, cyberattack, cyber-resilience. INSPEC Accession Number: 23981565

99 GENERAL AND MISCELLANEOUS↗
DOE OSTI2024

A Comparison of Battery Charge Controller Technologies for Wave Energy Converters: Preprint

Wave energy is a uniquely challenging field for electrical system designers. High peak and low average power potential with a constantly varying energy input is difficult to harness and control through conventional means. To power the blue economy, low-powered wave energy converters (WECs) need batteries for energy storage. Safely and effectively charging batteries from waves requires a charge controller to properly monitor and control voltage and current going to the battery. Currently, off-the-shelf charge controllers exist for other renewable generation such as wind, hydro, and solar. Two topologies were validated: a buck converter and a pulse width modulation (PWM) charge controller. Using an in-lab dry testbed, wave energy power inputs were simulated to properly validate the effectiveness of existing charge controller technologies, identifying the shortcomings and improvements needed to effectively harness wave energy.

battery storage↗
DOE OSTI2024

Nov. 2024 EVs@Scale High-Power Charging Deep Dive Technical Meeting

EVs@Scale Lab Consortium is addressing challenges, developing solutions, and enabling technologies for transportation electrification ecosystem. The consortium has five research pillars one of which focuses on high power charging (HPC). HPC pillar brings together hardware and software expertise, capabilities, and facilities related to high power EV charging, charge management, and grid integration. Deep-dive technical meetings are organized twice a year and provides an opportunity for more industry engagement and technical feedback for the national labs throughout the project lifecycle. High-Power Charging pillar has two active projects: (i) Next-Gen Profiles (NGP) and (ii) High-Power Electric Vehicle Charging Hub Integration Platform (eCHIP). This presentation summarizes the progress made in both projects during the past six months focusing on specific topics. There will be two deep-dive technical meetings twice a year. Every deep-dive meeting will focus on different aspects of the project progress.

ADVANCED PROPULSION SYSTEMS,DIRECT ENERGY CONVERSI↗
NASA NTRS2006

Spacecraft charging requirements and engineering issues

An effort is currently underway to recast and combine two NASA guidelines for mitigating the effects of spacecraft charging and electrostatic discharge on spacecraft. The task has the goal of taking the existing NASA guidelines for preventing surface electrostatic charging, NASA-TP-2361 (Purvis et al., 1984), and internal electrostatic charging, NASAHDBK 4002 (Whittlesey, 1999), and bringing them up to date with recent laboratory and onorbit findings. This paper will describe the status of those on-going efforts to combine and update the two guidelines. Reasons for the upgrades will be presented, including new subject material for which there is now a greater understanding or a greater need which changes satellite design procedures, or both. There will be an emphasis on the proposed contents and on the differences and similarities between surface and internal charging mitigation techniques. In addition, the mitigation requirements that can be derived from the combined handbook will be discussed with emphasis on how they might affect the engineering design and testing of future spacecraft.

charging guidelines↗
DOE OSTI2023

Enhancing the EVI-X National Framework to Address Emerging Questions on Charging Infrastructure Deployment

As large national investments in EV charging continue to be made, this project seeks to improve the state-of-the-art in EV infrastructure analysis. New and improved quantitative analysis capabilities will position VTO to support EERE Leadership, assist the DOT/DOE Joint Office through timely analysis, and provide a strategy for the deployment of the national charging network. This project supports on-going development of NREL's EVI-X Suite of charging infrastructure analysis tools, including tools supporting large-scale network planning, local site design decisions, and comprehensive financial analysis. EVI-X development complements and leverages other VTO-funded efforts to ensure inputs to EVI-X and output produced by EVI-X are consistent with and well-integrated into the VTO portfolio (e.g., EV adoption scenarios from TEMPO, charging infrastructure design provided to EVs@Scale, etc.).

ADVANCED PROPULSION SYSTEMS,ENERGY PLANNING, POLIC↗
DOE OSTI2024

Charge‐Programmable Photopolymers for 3D Electronics via Additive Manufacturing

Charge‐programmed 3D printing enables the fabrication of 3D electronics with lightweight and high precision via selective patterning of metals. This selective metal deposition is catalyzed by Pd nanoparticles that are specifically immobilized onto the charged surface and promises to fabricate a myriad of complex electronic devices with self‐sensing, actuation, and structural elements assembled in a designed 3D layout. However, the achievable property space and the material‐performance correlation of the charge‐programmed printing remain unexplored. Herein, a series of photo‐curable resins are designed for unveiling how the charge and crosslink densities synergistically impact the nanocatalyst‐guided selective deposition in catalytic efficiency and properties of the 3D printed charge‐programmed architectures, leading to high‐quality 3D patterning of solid and liquid metals. The findings offer a wide tunability of the structural properties of the printed electronics, ranging from stiff to extreme flexibility. Capitalizing on these results, the printing and successful application of an ultralight‐weight and deployable 3D multi‐layer antenna system operating at an ultrahigh‐frequency of 19 GHz are demonstrated.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Modulating Charge Transfer Efficiency of Hematite Photoanode with Hybrid Dual‐Metal–Organic Frameworks for Boosting Photoelectrochemical Water Oxidation

Abstract The glorious charge transfer efficiency of photoanode is an important factor for efficient photoelectrochemical (PEC) water oxidation. However, it is often limited by slow kinetics of oxygen evolution reaction. Herein, a dual transition metal‐based metal–organic frameworks (MOF) cocatalyst, Fe@Ni–MOF, is introduced into a titanium‐doped hematite (Fe 2 O 3 :Ti) photoanode. The combination of Ni and Fe can optimize the filling of 3d orbitals. Moreover, the introduction of Fe donates electrons to Ni in the MOF structure, thus, suppressing the irreversible (long‐life‐time) oxidation of Ni 2+ into Ni 3+ . The resulting Fe@Ni–MOF/Fe 2 O 3 :Ti photoanode exhibits ∼threefold enhancement in the photocurrent density at 1.23 V versus the reversible hydrogen electrode. Kinetic analysis of the PEC water oxidation processes indicates that this performance improvement is primarily due to modulating the charge transfer efficiency of hematite photoanode. Further results show that a single transition metal‐based MOF cocatalyst, Ni–MOF, exhibits slow charge transfer in spite of a reduction in surface charge recombination, resulting in a smaller charge transfer efficiency. These findings provide new insights for the development of photoelectrodes decorated with MOFs.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Low Catalyst Loading Enhances Charge Accumulation for Photoelectrochemical Water Splitting

Abstract Solar water oxidation is a critical step in artificial photosynthesis. Successful completion of the process requires four holes and releases four protons. It depends on the consecutive accumulation of charges at the active site. While recent research has shown an obvious dependence of the reaction kinetics on the hole concentrations on the surface of heterogeneous (photo)electrodes, little is known about how the catalyst density impacts the reaction rate. Using atomically dispersed Ir catalysts on hematite, we report a study on how the interplay between the catalyst density and the surface hole concentration influences the reaction kinetics. At low photon flux, where surface hole concentrations are low, faster charge transfer was observed on photoelectrodes with low catalyst density compared to high catalyst density; at high photon flux and high applied potentials, where surface hole concentrations are moderate or high, slower surface charge recombination was afforded by low‐density catalysts. The results support that charge transfer between the light absorber and the catalyst is reversible; they reveal the unexpected benefits of low‐density catalyst loading in facilitating forward charge transfer for desired chemical reactions. It is implied that for practical solar water splitting devices, a suitable catalyst loading is important for maximized performance.

Liu, Tianying↗
DOE OSTI2023

Low Catalyst Loading Enhances Charge Accumulation for Photoelectrochemical Water Splitting

Abstract Solar water oxidation is a critical step in artificial photosynthesis. Successful completion of the process requires four holes and releases four protons. It depends on the consecutive accumulation of charges at the active site. While recent research has shown an obvious dependence of the reaction kinetics on the hole concentrations on the surface of heterogeneous (photo)electrodes, little is known about how the catalyst density impacts the reaction rate. Using atomically dispersed Ir catalysts on hematite, we report a study on how the interplay between the catalyst density and the surface hole concentration influences the reaction kinetics. At low photon flux, where surface hole concentrations are low, faster charge transfer was observed on photoelectrodes with low catalyst density compared to high catalyst density; at high photon flux and high applied potentials, where surface hole concentrations are moderate or high, slower surface charge recombination was afforded by low‐density catalysts. The results support that charge transfer between the light absorber and the catalyst is reversible; they reveal the unexpected benefits of low‐density catalyst loading in facilitating forward charge transfer for desired chemical reactions. It is implied that for practical solar water splitting devices, a suitable catalyst loading is important for maximized performance.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗