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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 865 records · Page 48
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Impact of Dopants on Suppressing Gas Evolution from High-Nickel Layered Oxide Cathodes

Gas release from high-Ni layered-oxide cathodes (LiNi x Mn 1-x-y-z Co y Al z O 2 ; x > 0.8) can jeopardize the overall performance and safety characteristics of the cell. A comprehensive assessment of rational cathode design with common dopants, such as Ni, Co, Al, and Mn, to suppress gas evolution is crucial for battery safety, yet it remains to be conducted. Furthermore, we present an in-situ gas analysis on nine high-Ni cathode materials with online electrochemical mass spectrometry (OEMS). We show that regardless of the dopant, reactive oxygen release from the cathode lattice remains a critical process for gas evolution. A series of comparisons reveals that the intensity and onset point of gas release is strongly dependent on the cathode composition. Notably, Al and Mn are the most effective dopants to suppress gas evolution from the cathode at 4.4 V. We further highlight lattice stability limits, across these nine compositions, between 85 % to 93 % state of charge.

25 ENERGY STORAGE↗
DOE OSTI2023

Fast Charge Induced Phase Evolution and Element Contribution of Nickel-Rich Layered Cathode for Lithium-Ion Batteries

In nickel-rich layered cathode materials, three transition metals (TM = Ni, Co and Mn) play critical roles in Li storage performance. However, rate-dependent phase evolution and elemental contribution of nickel-rich cathode materials are not well understood, but very important for further design and development of these cathodes in high-power applications. Here, the rate-dependent phase evolution and elemental contribution of LiNi 0.5 Mn 0.3 Co 0.2 O 2 (NMC532) cathode are investigated thoroughly by using time-resolved synchrotron-based in situ X-ray diffraction and absorption techniques. The increase of Ni content in NMC532 has been found to be the main cause of the complex structural changes, resulting in distortion of TM-O 6 octahedron and strong static vibration between TM and O coordination. It is revealed that the fast charge (10C and 30C) of NMC532 leads to intermediate Li-poor phases, shrinking of H2 phase region, and prolonged O1 phase. During high-rate charging, Co is oxidized easily in low voltage region, while Ni mainly dominates charge compensation in high voltage region. It is found that delithiation-induced local structure distortion transfers from Ni to Co sites in fast kinetic process. In conclusion, these findings provide in-depth understanding for the fast charge behavior of Ni-rich layered cathode materials and help to guide further development of advanced high-power lithium-ion batteries.

25 ENERGY STORAGE↗
DOE OSTI2021

Bridging the gap of storage ring light sources and linac-driven free-electron lasers

High-gain free-electron lasers (FELs) are driven by short, high-charge density electron beams as only produced at dedicated single pass or recirculating linear accelerators. We describe new conceptual, technical, and modeling solutions to produce subpicosecond, up to ~100 μJ-energy extreme ultra-violet and soft x-ray FEL pulses at high- and tunable repetition rates, from diffraction-limited storage ring light source. In contrast to previously proposed schemes, we show that lasing can be simultaneous to the standard multibunch radiation emission from short insertion devices, and that it can be obtained with limited impact on the storage ring infrastructure. By virtue of the high-average power but moderate pulse energy, the storage ring-driven high-gain FEL would open the door to unprecedented accuracy in time-resolved spectroscopic analysis of matter in the linear response regime, in addition to inelastic scattering experiments.

43 PARTICLE ACCELERATORS↗
DOE OSTI2022

Hydrogen Crossover Flux through Two-Dimensional Nanomaterials

Energy storage and conversion devices require an ion-exchange membrane with high transmission of charge-balancing ions and separation of anode and cathode electrolytes/gases. This ensures optimum device performance. Most conventional membranes suffer huge cross-permeation resulting in low energy efficiency and material degradation. This work investigated hydrogen permeability and proton transmission through membrane electrode assemblies (MEAs) containing a monolayer of hexagonal boron nitride and single-layer and bi-layer graphene in a gas-phase small-scale cell and a liquid cell. Here we found that the hydrogen crossover flux through MEAs with 2D materials was inhibited by at least a factor of 5 compared to the one without. Single-layer graphene and boron nitride enabled high proton transmission, but bi-layer graphene inhibited proton conduction. Defect visualization of 2D materials revealed few atomic-scale defects in graphene. These findings suggest that a monolayer of 2D material may provide good selectivity for energy conversion and storage devices by blocking species crossover while allowing high proton transmission.

2D materials↗
NASA NTRS2009

NASA Biological Specimen Repository

The NASA Biological Specimen Repository (NBSR) has been established to collect, process, annotate, store, and distribute specimens under the authority of the NASA/JSC Committee for the Protection of Human Subjects. The International Space Station (ISS) provides a platform to investigate the effects of microgravity on human physiology prior to lunar and exploration class missions. The NBSR is a secure controlled storage facility that is used to maintain biological specimens over extended periods of time, under well-controlled conditions, for future use in approved human spaceflight-related research protocols. The repository supports the Human Research Program, which is charged with identifying and investigating physiological changes that occur during human spaceflight, and developing and implementing effective countermeasures when necessary. The storage of crewmember samples from many different ISS flights in a single repository will be a valuable resource with which researchers can validate clinical hypotheses, study space-flight related changes, and investigate physiological markers All samples collected require written informed consent from each long duration crewmember. The NBSR collects blood and urine samples from all participating long duration ISS crewmembers. These biological samples are collected pre-flight at approximately 45 days prior to launch, during flight on flight days 15, 30, 60 120 and within 2 weeks of landing. Postflight sessions are conducted 3 and 30 days following landing. The number of inflight sessions is dependent on the duration of the mission. Operations began in 2007 and as of October 2009, 23 USOS crewmembers have completed or agreed to participate in this project. As currently planned, these human biological samples will be collected from crewmembers covering multiple ISS missions until the end of U.S. presence on the ISS or 2017. The NBSR will establish guidelines for sample distribution that are consistent with ethical principles, protection of crewmember confidentiality, prevailing laws and regulations, intellectual property policies, and consent form language. A NBSR Advisory Board composed of representatives of all participating agencies will be established to evaluate each request by an investigator for use of the samples to ensure the request reflects the mission of the NBSR.

Pietrzyk, Robert↗
DOE OSTI2021

Design Considerations for Fast Charging Lithium Ion Cells for NMC/MCMB Electrode Pairs

Lithium ion cells that can be quickly charged are of critical importance for the continued and accelerated penetration of electric vehicles (EV) into the consumer market. Considering this, the U.S. Department of Energy (DOE) has set a cell recharge time goal of 10–15 min. The following study provides an investigation into the effect of cell design, specifically negative to positive matching ratio (1.2:1 vs. 1.7:1) on fast charging performance. By using specific charging procedures based on negative electrode performance, as opposed to the industrial standard constant current constant voltage procedures, we show that the cells with a higher N:P ratio can be charged to ~16% higher capacity in the ten-minute time frame. Cells with a higher N:P ratio also show similar cycle life performance to those with a conventional N:P ratio, despite the fact that these cells experience a much higher irreversible capacity loss, leading to a lower reversible specific capacity.

25 ENERGY STORAGE↗
NASA NTRS2010

Electrostatic Power Generation from Negatively Charged, Simulated Lunar Regolith

Research was conducted to develop an electrostatic power generator for future lunar missions that facilitate the utilization of lunar resources. The lunar surface is known to be negatively charged from the constant bombardment of electrons and protons from the solar wind. The resulting negative electrostatic charge on the dust particles, in the lunar vacuum, causes them to repel each other minimizing the potential. The result is a layer of suspended dust about one meter above the lunar surface. This phenomenon was observed by both Clementine and Surveyor spacecrafts. During the Apollo 17 lunar landing, the charged dust was a major hindrance, as it was attracted to the astronauts' spacesuits, equipment, and the lunar buggies. The dust accumulated on the spacesuits caused reduced visibility for the astronauts, and was unavoidably transported inside the spacecraft where it caused breathing irritation [1]. In the lunar vacuum, the maximum charge on the particles can be extremely high. An article in the journal "Nature", titled "Moon too static for astronauts?" (Feb 2, 2007) estimates that the lunar surface is charged with up to several thousand volts [2]. The electrostatic power generator was devised to alleviate the hazardous effects of negatively charged lunar soil by neutralizing the charged particles through capacitive coupling and thereby simultaneously harnessing power through electric charging [3]. The amount of power generated or collected is dependent on the areal coverage of the device and hovering speed over the lunar soil surface. A thin-film array of capacitors can be continuously charged and sequentially discharged using a time-differentiated trigger discharge process to produce a pulse train of discharge for DC mode output. By controlling the pulse interval, the DC mode power can be modulated for powering devices and equipment. In conjunction with a power storage system, the electrostatic power generator can be a power source for a lunar rover or other systems. The negatively charged lunar soil would also be neutralized mitigating some of the adverse effects resulting from lunar dust.

Choi, Sang H.↗
DOE OSTI2022

Performance and Durability of Proton Exchange Membrane Vapor-Fed Unitized Regenerative Fuel Cells

With a growing demand for electricity, clean hydrogen production and usage can be an asset not only to mitigate emissions but for long-term energy storage as well. Hydrogen gas, a high-density energy carrier, can be made through electrolysis in charging mode and generate electricity via a fuel cell in discharging mode in a unitized regenerative fuel cell (URFC). While URFCs reduce cost by combining the charging and discharging modes into a singular device, switching between modes becomes burdensome, and water management is a major challenge. One way to mitigate these issues is to operate the entire system in the vapor phase. Vapor-phase operation simplifies the physics of the system but will introduce losses within the system, primarily ohmic and mass transport during the charging mode. In this study, we explore the performance of a Proton-Exchange-Membrane (PEM)-URFC under vapor-phase conditions and the impact of different PEMs, feed gases, and relative humidity on the performance and durability. By tailoring operating conditions and membrane, the vapor-URFC achieves a roundtrip efficiency of 42% and a lifetime of 50,000 accelerated stress test cycles for fully humidified feeds. Discussion of vapor-URFC for energy storage and extensions to look at various applications shows the promise of this technology.

25 ENERGY STORAGE↗
DOE OSTI2020

Extreme Fast-Charging of Lithium-Ion Cells: Effect on Anode and Electrolyte

In this study, the effects of charge rate in coin cells containing NMC532/1506-Tgraphite are investigated. The cells are cycled at room temperature using charge rates of 1-, 2-, 4-, and 8-C and discharged at the 1-C rate for 50 cycles. The amounts of lithium and LiF are found to be highly correlated with charge time. Three decomposition products are identified in the organic electrolyte. The proposed, empirical formulae for these compounds are C 14 H 33 O 15 P 3 , C 16 H 37 O 15 P 3 , and C 11 H 22 O 7 PF; all are most likely organophosphates formed by the reaction of organic electrolyte decomposition products with LiPF 6 or P(=O)F 3 . The relative concentrations of these organics do not display sensitivity to charge rate. These results imply that a new performance fade mechanism is not introduced by electrolyte decomposition.

25 ENERGY STORAGE↗
DOE OSTI2023

Effect of Charged Block Length Mismatch on Double Diblock Polyelectrolyte Complex Micelle Cores

Polyelectrolyte complex micelles are hydrophilic nanoparticles that self-assemble in aqueous environments due to associative microphase separation between oppositely charged blocky polyelectrolytes. In this work, we employ a suite of physical characterization tools to examine the effect of charged block length mismatch on the equilibrium structure of double diblock polyelectrolyte complex micelles (D-PCMs) by mixing a diverse library of peptide and synthetic charged-neutral block polyelectrolytes with a wide range of charged block lengths (25–200 units) and chemistries. Early work on D-PCMs suggested that this class of micelles can only be formed from blocky polyelectrolytes with identical charged block lengths, a phenomenon referred to as chain length recognition. Here, we use salt annealing to create PCMs at equilibrium, which shows that chain length recognition, a longstanding hurdle to repeatable self-assembly from mismatched polyelectrolytes, can be overcome. Interestingly, D-PCM structure–property relationships display a range of values that vary systematically with the charged block lengths and chemical identity of constituent polyelectrolyte pairings and cannot be described by generalizable scaling laws. We discuss the interdependent growth behavior of the radius, ionic pair aggregation number, and density in the micelle core for three chemically distinct diblock pairings and suggest a potential physical mechanism that leads to this unique behavior. By comparing the results of these D-PCMs to the scaling laws recently developed for single diblock polyelectrolyte complex micelles (S-PCMs: diblock + homopolymer), we observe that D-PCM design schemes reduce the size and aggregation number and restrict their growth to a function of charged block length relative to S-PCMs. Understanding these favorable attributes enables more predictive use of a wider array of charged molecular building blocks to anticipate and control macroscopic properties of micelles spanning countless storage and delivery applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

SiM4DC [SWR-25-09]

SiM4DC is a suite of MATLAB/Simulink models specifically developed for simulating offline and real-time high-power charging hubs with various components such as grid-tie inverters, EVSEs, EVs, energy storage systems, renewable generation, and uncontrolled site loads.

Ucer, Emin [National Renewable Energy Laboratory (↗
NASA NTRS1976

Inductively coupled TI-MPD spacecraft electric propulsion

A nuclear electric propulsion concept using a thermionic reactor inductively coupled to a magnetoplasma-dynamic (MPD) accelerator is described and the results of preliminary analyses are presented. In this system, the thermionic generating unit operates continuously at a power level of approximately 0.4 MW, while the MPD thruster operates intermittently at higher voltages and power levels. Energy storage is provided by building up a large current in an inductor. Periodically, the charging current is interrupted and the energy stored in the magnetic field of the inductor is utilized for a short duration thrust pulse. A typical thrust pulse is characterized by a power level of 1 to 4 MWe, a duration of 1 msec, and a duty cycle of approximately 20%. Results of the preliminary analysis show that approximately 85 to 90% of the power available from the thermionic converter array can be delivered to the MPD thruster for a nominal 400 kWe system with an inductive unit suitable for a flight vehicle. Optimized values of the total specific mass of the system including the thermionic reactor, the inductor, and the MPD thruster are estimated in the range of 23 to 24 kg/kWe.

Britt, E. J.↗
NASA NTRS1981

Spinoff from a Moon Tool

Portable self-contained drill capable of extracting core samples as much as 10 feet below the surface was needed for the astronauts. Black & Decker used a specially developed computer program to optimize the design of the drill's motor and insure minimal power consumption. Refinement of the original technology led to the development of a cordless miniature vacuum cleaner called the Dustbuster. It has no hose, no cord, is 14 inches long, and also comes with a storage bracket that also serves as a recharger; plugs into a home outlet that charges the nickel cadmium batteries when not in use. Other home use cordless instruments include drills, shrub trimmers and grass shears. Company also manufactures a number of cordless tools used in the sheet metal automobile and construction industries, and a line of cordless orthopedic instruments.

Source record↗
NASA NTRS2013

No Vent Tank Fill and Transfer Line Chilldown Analysis by Generalized Fluid System Simulation Program (GFSSP)

The purpose of the paper is to present the analytical capability developed to model no vent chill and fill of cryogenic tank to support CPST (Cryogenic Propellant Storage and Transfer) program. Generalized Fluid System Simulation Program (GFSSP) was adapted to simulate charge‐holdvent method of Tank Chilldown. GFSSP models were developed to simulate chilldown of LH2 tank in K‐site Test Facility and numerical predictions were compared with test data. The report also describes the modeling technique of simulating the chilldown of a cryogenic transfer line and GFSSP models were developed to simulate the chilldown of a long transfer line and compared with test data.

Majumdar, Alok↗
NASA NTRS2021

Vertically Aligned Graphene/Metal Oxide Based Lightweight Super Strong, Energy Storage Carbon Fiber Composites

In this era of budding smart technologies, flexible and smart wearable textiles are a long awaited product which are anticipated to reach a $10 B market in few years.1 Supercapacitors are an excellent power source for these smart textiles, because they are light in weight, safe in operation, provide longer life cycle, high flexibility, and faster charge discharge capabilities.

Energy storage↗