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At least 865 records · Page 48

Photochemical oxidant transport - Mesoscale lake breeze and synoptic-scale aspects

Data from routine ozone monitoring in southeastern Wisconsin and limited monitoring of the Milwaukee area by the Environmental Protection Agency are examined. Hourly averages as high as 30 pphm have been recorded in southeastern Wisconsin, and high readings have been reported in rural regions throughout the state. The observations indicate that photochemical oxidants and their nitrogen oxide and reactive hydrocarbon precursers advect from Chicago and northern Indiana into southeastern Wisconsin. There is evidence that synoptic-scale transport of photochemical oxidants occurs, allowing the pollution of entire anticyclones. These results cast doubt on the validity of the Air Quality Control Regions established by amendment to the Clean Air Act of 1970.

Lyons, W. A.↗

CARETS: A prototype regional environmental information system. Volume 3: Toward a national land use information system

It is recommended that a national land use information system be established by an agency of the Federal Government. This recommendation comes at a time of increasing demand for scientific information in support of environmentally relevant land use planning and management at all levels of government. It is also a time when new airborne and spaceborne remote sensors, tested in cooperation with the National Aeronautics and Space Administration (NASA) and the Earth Resources Observation Systems (EROS) Program of the Department of the Interior, make possible the gathering of land use information rapidly and on an unprecedented scale. Furthermore, information handling technology is developing toward a capability to receive, store, and disseminate the huge quantities of data that would be involved. The recommendation for the national land use information system is based upon careful analysis of the results of remote sensing experiments funded by NASA, EROS, and the Geography Program of the Geological Survey, with specific examples drawn from the demonstration project known as the Central Atlantic Regional Ecological Test Site (CARETS). CARETS is cast in the framework of a regional land use information system, channeling the flow bf information generated in response to users' declaration of their needs, through stages dealing with remote sensing data gathering systems, data processing and land mensuration, calibration in-terms of environmental impact, and evaluation with feedback from users. The proposed system would develop and implement a unified approach to the description and interpretation of the changing uses of the nation's land resources, building upon the base of interagency and intergovernmental cooperation already achieved in the experimental work to date. The land use data base that is being derived from high-altitude aerial color infrared photography would be the initial component of the recommended system. High-altitude photographic coverage would immediately be extended to as much of the nation as possible as technological developments and economic considerations permit. The system would later expand to include multiple-sensor, multiple-platform data sources. Six system characteristics are recommended: (1) High capacity storage of data available for quick retrieval, inexpensive processing, and update, (2) provision of accuracy appropriate to the scale of survey or to the level of detail dictated by different types of management and decision requirements; (3) permanent, publicly accessible sensor records for historical interpretation; (4) compatibility of the recording, storage, and retrieval system with all types of inputs, from ground observer to satellite; (5) products of diverse formats and scales, responsive to user feedback; (6) and standardization of formats, scales, and storage inputs to permit nationwide comparability.

Land use mapping↗

Equations of state and impact-induced shock-wave attenuation on the moon

Current equation of state formulations, used for finite difference cratering flow calculations, are cast into a framework permitting comparison of peak pressures attained upon impact of a sphere, with a half-space, along the impact symmetry axis, to one dimensional impedance match solutions. On the basis of this formulation and application of thermochemical data, the regimes of melting and vaporization are examined. For the purpose of identifying material which will, upon isentropic release from the impact-induced shock state, result in a solid just brought to its melting point, i.e., incipiently melted (IM); completely melted (CM); just brought to its boiling point, i.e., incipiently vaporized (IV); and completely vaporized (CV) state, the pressures at which the critical isentropes intersect the Hugoniots of iron and gabbroic anorthosite (GA) are examined in detail. The latter rock type is assumed to be representative of the lunar highlands. The Hugoniot pressures, for which IM, CM, IV, and CV will occur upon isentropic expansion, are calculated to be 2.2, 2.6, 4.2, and 16.8 Mbar, respectively.

Ahrens, T. J.↗

Further studies of unsteady boundary layers with flow reversal

One set of calculations was performed using the first order, time dependent turbulent boundary layer equations, and extended earlier work by Nash and Patel to a wider range of flows. Another set of calculations was performed for laminar flow using the time dependent Navier-Stokes equations. The results of the calculations confirm previous conclusions concerning the existence of a regime of unseparated flow, containing an embedded region of reversal, which is accessible to first order boundary layer theory. However, certain doubts are cast on the precise nature of the events which accompany the eventual breakdown of the theory due to singularity onset. The earlier view that the singularity appears as the final event in a sequence involving rapid thickening of the boundary layer and the formation of a localized region of steep gradients is called into question by the present results. It appears that singularity onset is not necessarily preceded by rapid boundary layer thickening, or even necessarily produces immediate thickening.

Nash, J. F.↗

Test particle propagation in magnetostatic turbulence. 2: The local approximation method

An approximation method for statistical mechanics is presented and applied to a class of problems which contains a test particle propagation problem. All of the available basic equations used in statistical mechanics are cast in the form of a single equation which is integrodifferential in time and which is then used as the starting point for the construction of the local approximation method. Simplification of the integrodifferential equation is achieved through approximation to the Laplace transform of its kernel. The approximation is valid near the origin in the Laplace space and is based on the assumption of small Laplace variable. No other small parameter is necessary for the construction of this approximation method. The n'th level of approximation is constructed formally, and the first five levels of approximation are calculated explicitly. It is shown that each level of approximation is governed by an inhomogeneous partial differential equation in time with time independent operator coefficients. The order in time of these partial differential equations is found to increase as n does. At n = 0 the most local first order partial differential equation which governs the Markovian limit is regained.

Klimas, A. J.↗

Space Processing Applications Rocket project, SPAR 1

The experiment objectives, design/operational concepts, and final results of each of nine scientific experiments conducted during the first Space Processing Applications Rocket (SPAR) flight are summarized. The nine individual SPAR experiments, covering a wide and varied range of scientific materials processing objectives, were entitled: solidification of Pb-Sb eutectic, feasibility of producing closed-cell metal foams, characterization of rocket vibration environment by measurement of mixing of two liquids, uniform dispersions of crystallization processing, direct observation of solidification as a function of gravity levels, casting thoria dispersion-strengthened interfaces, contained polycrystalline solidification, and preparation of a special alloy for manufacturing of magnetic hard superconductor under zero-g environment.

Reeves, F.↗

Solid propellant rocket motor and method of making same

A method is described for making a solid propellant rocket motor having a specific concavity formed within the fuel charge. A mandrel with an aperature wider than that of the casing is inserted within the motor casing and a solidifiable propellant cast above the mandrel. The mandrel is removed after the propellant is cured.

Thibodaux, J. G., Jr.↗

Effect of high-pressure oxygen on the mechanical properties of alloys

Unnotched and notched tensile properties of stressed and unstressed specimens of wrought 316 stainless steel, Incology 903, Monel K-500, and cast specimens of Inconel 718 were examined. Environmental tests were performed in atmospheric pressure air, high pressure nitrogen, and high pressure oxygen. Results show that oxygen did not alter the tensile properties of any of the alloys studied.

Schwartzberg, F. R.↗

Determination of constant-volume balloon capabilities for aeronautical research

The proper application of constant-volume balloons (CVB) for measurement of atmospheric phenomena was determined. And with the proper interpretation of the resulting data. A literature survey covering 176 references is included. the governing equations describing the three-dimensional motion of a CVB immersed in a flow field are developed. The flowfield model is periodic, three-dimensional, and nonhomogeneous, with mean translational motion. The balloon motion and flow field equations are cast into dimensionless form for greater generality, and certain significant dimensionless groups are identified. An alternate treatment of the balloon motion, based on first-order perturbation analysis, is also presented. A description of the digital computer program, BALLOON, used for numerically integrating the governing equations is provided.

Tatom, F. B.↗

Susceptibility to hot corrosion of four nickel-base superalloys, NASA-TRW VIA, B-1900, 713C and IN-738

The susceptibility to hot corrosion of four nickel-base, cast superalloys has been studied at 900 and 1000 C. The test consisted of coating alloy samples with known amounts of Na2SO4 and oxidizing the coated samples isothermally in 1 atmosphere of slowly flowing oxygen, the weight-gain being monitored on a sensitive recording microbalance. Susceptibility to hot corrosion decreased in the order of decreasing molybdenum content of the alloys. Preoxidation of samples before hot-corrosion testing markedly increased the induction period observed prior to the inception of hot corrosion for all alloys tested. X-ray diffraction analyses of the oxide scales were made. All samples that underwent hot corrosion showed the presence of a (Ni,Co)MoO4 layer near the alloy-oxide interface. Several specimens displayed resistance to hot corrosion and these showed NaTaO3 as a prominent feature in their oxide scale. Our results may be interpreted as indicating that molybdenum in an alloy is detrimental, with respect to hot corrosion, while tantalum is beneficial.

Stearns, C. A.↗

High purity silica reflective heat shield development

A hyperpure vitreous silica material is being developed for use as a reflective and ablative heat shield for planetary entry. Various purity grades and forms of raw materials were evaluated along with various processing methods. Slip casting of high purity grain was selected as the best processing method, resulting in a highly reflective material in the wavelength bands of interest (the visible and ultraviolet regions). The selected material was characterized with respect to optical, mechanical and physical properties using a limited number of specimens. The process has been scaled up to produce a one-half scale heat shield (18 in. dia.) (45.72 cm) for a Jupiter entry vehicle. This work is now being extended to improve the structural safety factor of the heat shield by making hyperpure silica material tougher through the addition of silica fibers.

Nachtscheim, P. R.↗

Improved high pressure turbine shroud

A new high pressure turbine shroud material has been developed from the consolidation of prealloyed powders of Ni, Cr, Al and Y. The new material, a filler for cast turbine shroud body segments, is called Genaseal. The development followed the identification of oxidation resistance as the primary cause of prior shroud deterioration, since conversion to oxides reduces erosion resistance and increases spalling under thermal cycled engine conditions. The NICrAlY composition was selected in preference to NIAL and FeCRALY alloys, and was formulated to a prescribed density range that offers suitable erosion resistance, thermal conductivity and elastic modulus for improved behavior as a shroud.

Bessen, I. I.↗

Directionally solidified eutectic gamma plus beta nickel-base superalloys

A directionally solidified multivariant eutectic gamma + beta nickel-base superalloy casting having improved high temperature strength and oxidation resistance properties is provided. This comprises a two phase eutectic structure containing, on a weight percent basis, 5.0-15.0 tungsten, 8.5-14.5 aluminum, 0.0-35.0 cobalt and the balance being nickel. Embedded within the gamma phase nickel-base matrix are aligned eutectic beta phase (primarily (NiCo)Al reinforcing lamellae.

Jackson, M. R.↗

An optical profilometer for spatial characterization of three-dimensional surfaces

The design concept and system operation of an optical profilometer are discussed, and a preliminary evaluation of a breadboard system is presented to demonstrate the feasibility of the optical profilometer technique. Measurement results are presented for several test surfaces; and to illustrate a typical application, results are shown for a cleft palate cast used by dental surgeons. Finally, recommendations are made for future development of the optical profilometer technique for specific engineering or scientific applications.

Kelly, W. L., IV↗

Mechanical properties of several nickel alloys in hydrogen at elevated temperatures

Tests were performed to determine low cycle fatigue and crack growth rate properties of one iron-base and two forms of one cast nickel-base alloy. The alloys were tested in various forms and/or heat-treat conditions that are proposed for use in a high-pressure hydrogen or a hydrogen-water vapor environment. Some general conclusions can be made comparing the results of tests in a hydrogen environment with those in a hydrogen-water vapor environment. The hydrogen-water vapor environment caused a 50 percent average reduction in fatigue life, indicating extreme degradation when compared with tests conducted in air, for Incoloy 903 at 1033 K (1400 F). Crack growth rates increased significantly for all materials with increasing test temperature. A very significant increase (three orders of magnitude) in crack growth rate occurred for Incoloy 903 tested in the hydrogen-water vapor environment when compared with testing done in hydrogen along at 922 K (1200 F).

Warren, J. R.↗

A preliminary assessment of the feasibility of deriving liquid and gaseous fuels from grown and waste organics

An estimate is obtained of the yearly supply of organic material for conversion to fuels, the energy potential is evaluated, and the fermentation and pyrolysis conversion processes are discussed. An investigation is conducted of the estimated cost of fuel from organics and the conclusions of an overall evaluation are presented. It is found that climate, land availability and economics of agricultural production and marketing, food demand, fertilizer shortage, and water availability combine to cast doubts on the feasibility of producing grown organic matter for fuel, in competition with food, feed, or fiber. Less controversial is the utilization of agricultural, industrial, and domestic waste as a conversion feedstock. The evaluation of a demonstration size system is recommended.

Graham, R. W.↗

An algorithm for automatic reduction of complex signal flow graphs

A computer algorithm is developed that provides efficient means to compute transmittances directly from a signal flow graph or a block diagram. Signal flow graphs are cast as directed graphs described by adjacency matrices. Nonsearch computation, designed for compilers without symbolic capability, is used to identify all arcs that are members of simple cycles for use with Mason's gain formula. The routine does not require the visual acumen of an interpreter to reduce the topology of the graph, and it is particularly useful for analyzing control systems described for computer analyses by means of interactive graphics.

Young, K. R.↗

Convection and dendrite crystallization

The convection and thermal conditions in aqueous and metallic liquid systems under conditions of the Dendrite Remelting Rocket Experiment were assessed to help establish the relevance of the rocket experiment to the metals casting phenomena. The results of the study indicate that aqueous or metallic convection velocities in the cell are of insignificant magnitudes at the 0.0001 to 0.00001 g levels of the experiment. The crystallization phenomena observed in the rocket experiment, therefore, may be indicative of how metals will solidify in low-g. The influence of possibly differing thermal fields, however, remains to be assessed. The rocket experiment may also be relevant to how metals solidify on the ground at temperature differences and in cell configurations such that the flow velocities are not high enough to break or bend delicate dendrite arms. Again, however, the influence of the thermal fields must be assessed.

Grodzka, P. G.↗